On the Modeling of Acrylic Acid Copolymerization in an Aqueous Solution: A Modular, Integrated Approach

Abstract : A complete mathematical model of the free-radical copolymerization of acrylic acid in an aqueous solution, taking place in a pilot-scale tubular reactor equipped with static mixers, is presented. The developed kinetic/reactor model is numerically integrated in terms of a coupled deterministic-stochastic numerical approach that combines the advantages of speed, efficiency, and increased predictive capabilities. A series of experimental measurements on the monomer conversion and the molecular weight characteristics of the produced copolymer, under a wide range of process conditions, are used for the identification of the kinetic model parameters while a thorough analysis of the compositional characteristics of the produced copolymers is also carried out in terms of a series of bivariate distributed properties.
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Macromolecular Reaction Engineering, Wiley-VCH Verlag, 2016, 10 (4, SI), pp.389-405. 〈10.1002/mren.201500036〉
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Soumis le : mercredi 29 mars 2017 - 10:46:24
Dernière modification le : mardi 24 juillet 2018 - 16:43:07

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Dimitrios Meimaroglou, Marie-Claire Chevrel, Sandrine Hoppe, Alain Durand, Laurent Falk, et al.. On the Modeling of Acrylic Acid Copolymerization in an Aqueous Solution: A Modular, Integrated Approach. Macromolecular Reaction Engineering, Wiley-VCH Verlag, 2016, 10 (4, SI), pp.389-405. 〈10.1002/mren.201500036〉. 〈hal-01497715〉

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