Service interruption on Monday 11 July from 12:30 to 13:00: all the sites of the CCSD (HAL, EpiSciences, SciencesConf, AureHAL) will be inaccessible (network hardware connection).
Skip to Main content Skip to Navigation
Journal articles

Structural reinvestigation of the photoluminescent complex [NdCl2(H2O)(6)]Cl

Abstract : The structure of the photoluminescent compound hexaaqua-dichloridoneodymium(III) chloride has been redetermined from single-crystal X-ray diffraction data at 100 K, with the aim of providing an accurate structural model for the bulk crystalline material. The crystal structure may be described as a network of [NdCl2(H2O)(6)](+) cations with distorted square-antiprism geometry around the Nd-III centre. The Nd-III cation and the nonbonded Cl- anion are both located on twofold symmetry axes. The crystal packing consists of three different neodymium pairs linked by a three-dimensional network of O-H center dot center dot center dot Cl intermolecular interactions. The pair distribution function (PDF) calculated from the experimentally determined structure is used for the discussion of the local structure.
Document type :
Journal articles
Complete list of metadata
Contributor : CRM2 UL Connect in order to contact the contributor
Submitted on : Thursday, May 11, 2017 - 12:15:14 PM
Last modification on : Monday, January 31, 2022 - 4:52:03 PM

Links full text




Kuan-ying Hsieh, El-Eulmi Bendeif, Sébastien Pillet, Abdelatif Doudouh, Dominik Schaniel, et al.. Structural reinvestigation of the photoluminescent complex [NdCl2(H2O)(6)]Cl. Acta Crystallographica Section C : Crystal Structure Communications [1968-2013], International Union of Crystallography, 2013, 69 (9, SI), pp.1002+. ⟨10.1107/S0108270113021367⟩. ⟨hal-01520996⟩



Record views