L. P. Zhang, X. Ye, H. Feng, Y. H. Jing, T. Ouyang et al., Heavy metal contamination in western Xiamen Bay sediments and its vicinity, China, Marine Pollution Bulletin, vol.54, issue.7, pp.974-982, 2007.
DOI : 10.1016/j.marpolbul.2007.02.010

Y. B. Sun, Q. X. Zhou, X. K. Xie, and R. Liu, Spatial, sources and risk assessment of heavy metal contamination of urban soils in typical regions of Shenyang, China, Journal of Hazardous Materials, vol.174, issue.1-3, pp.455-462, 2010.
DOI : 10.1016/j.jhazmat.2009.09.074

R. L. Yu, X. Yuan, Y. H. Zhao, and X. L. Tu, Heavy metal pollution in intertidal sediments from Quanzhou Bay, China, Journal of Environmental Sciences, vol.20, issue.6, pp.664-66910, 2008.
DOI : 10.1016/S1001-0742(08)62110-5

V. C. Srivastava, I. D. Mall, and I. M. Mishra, Characterization of mesoporous rice husk ash (RHA) and adsorption kinetics of metal ions from aqueous solution onto RHA, Journal of Hazardous Materials, vol.134, issue.1-3, pp.257-267, 2006.
DOI : 10.1016/j.jhazmat.2005.11.052

J. A. Grout and C. D. Levings, Effects of acid mine drainage from an abandoned copper mine, Britannia Mines, Howe Sound, British Columbia, Canada, on transplanted blue mussels (Mytilus edulis), Marine Environmental Research, vol.51, issue.3, pp.265-28810, 2001.
DOI : 10.1016/S0141-1136(00)00104-5

C. Lin, Y. Wu, W. Lu, A. Chen, and Y. Liu, Water chemistry and ecotoxicity of an acid mine drainage-affected stream in subtropical China during a major flood event, Journal of Hazardous Materials, vol.142, issue.1-2, pp.199-207, 2007.
DOI : 10.1016/j.jhazmat.2006.08.006

R. Y. Ning, Arsenic removal by reverse osmosis, Desalination, vol.143, issue.3, pp.237-24110, 2002.
DOI : 10.1016/S0011-9164(02)00262-X

X. Chen, G. Chen, and P. L. Yue, Novel Electrode System for Electroflotation of Wastewater, Environmental Science & Technology, vol.36, issue.4, pp.778-783, 2002.
DOI : 10.1021/es011003u

Z. Hu, L. Lei, Y. Li, and Y. Ni, Chromium adsorption on high-performance activated carbons from aqueous solution, Separation and Purification Technology, vol.31, issue.1, pp.13-18, 2003.
DOI : 10.1016/S1383-5866(02)00149-1

Z. Reddad, C. Gerente, Y. Andres, J. F. Thibault, and P. L. Cloirec, Cadmium and lead adsorption by a natural polysaccharide in MF membrane reactor: experimental analysis and modelling, Water Research, vol.37, issue.16, pp.3983-399110, 2003.
DOI : 10.1016/S0043-1354(03)00295-1

URL : https://hal.archives-ouvertes.fr/hal-00879459

W. Ciesielski, C. Y. Lii, and M. T. , Interactions of starch with salts of metals from the transition groups, Carbohydrate Polymers, vol.51, issue.1, pp.47-5610, 2003.
DOI : 10.1016/S0144-8617(02)00108-X

H. Hyung and J. H. Kim, A mechanistic study on boron rejection by sea water reverse osmosis membranes, Journal of Membrane Science, vol.286, issue.1-2, 2006.
DOI : 10.1016/j.memsci.2006.09.043

G. A. Waychunas, C. C. Fuller, and J. A. , Surface complexation and precipitate geometry for aqueous Zn(II) sorption on ferrihydrite I: X-ray absorption extended fine structure spectroscopy analysis, Geochimica et Cosmochimica Acta, vol.66, issue.7, pp.1119-113710, 2002.
DOI : 10.1016/S0016-7037(01)00853-5

D. Pérez-quintanillaa and I. D. Hierroa, Mesoporous silica functionalized with 2-mercaptopyridine: Synthesis, characterization and employment for Hg(II) adsorption, Microporous and Mesoporous Materials, vol.89, issue.1-3, pp.58-68, 2006.
DOI : 10.1016/j.micromeso.2005.10.012

R. De-pablo, M. L. Chávez, and M. Abatal, Adsorption of heavy metals in acid to alkaline environments by montmorillonite and Ca-montmorillonite, Chemical Engineering Journal, vol.171, issue.3, pp.1276-1286, 2011.
DOI : 10.1016/j.cej.2011.05.055

M. A. Zenasni, S. Benfarhi, A. Merlin, S. Molina, B. George et al., Adsorption of Cu(II) on maghnite from aqueous solution: Effects of pH, initial concentration, interaction time and temperature, Natural Science, vol.04, issue.11, pp.856-868, 2012.
DOI : 10.4236/ns.2012.411114

I. Ikhsan, B. B. Johson, J. D. Wells, and M. J. Angove, Adsorption of Aspartic Acid, Journal of Colloid and Interface Science, vol.273, issue.1, 2004.

A. Sari and O. Isildak, <b>Adsorption properties of stearic acid onto untreated kaolinite</b>, Bulletin of the Chemical Society of Ethiopia, vol.20, issue.2, 2006.
DOI : 10.4314/bcse.v20i2.61410

M. J. Angove, B. B. Johson, and J. D. Wells, Adsorption of cadmium(II) on kaolinite, Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol.126, issue.2-3, pp.137-14710, 1997.
DOI : 10.1016/S0927-7757(96)03990-8

K. O. Adebowale, I. E. Unuabonah, and B. I. Olu-owolabi, The effect of some operating variables on the adsorption of lead and cadmium ions on kaolinite clay, Journal of Hazardous Materials, vol.134, issue.1-3, pp.130-139, 2006.
DOI : 10.1016/j.jhazmat.2005.10.056

K. G. Bhattacharyya and S. S. Gupta, Kaolinite and montmorillonite as adsorbents for Fe(III), Co(II) and Ni(II) in aqueous medium, Applied Clay Science, vol.41, issue.1-2, pp.1-9, 2008.
DOI : 10.1016/j.clay.2007.09.005

. Cu, II) from Aqueous Solution, Separation and Purification Technology, vol.50, issue.3, pp.388-397, 2006.

S. S. Gupta and K. G. , Bhatt tal Ions with Clays: I. A Case Study w acharyya, Interaction of ith Pb

Y. Yukselen and A. Kaya, Suitability of the methylene blue test for surface area, cation exchange capacity and swell potential determination of clayey soils, Engineering Geology, vol.102, issue.1-2, pp.38-45, 2008.
DOI : 10.1016/j.enggeo.2008.07.002

S. Wang, Z. Nan, Y. Li, and Z. Zhao, The chemical bonding of copper ions on kaolin from Suzhou, China, Desalination, vol.249, issue.3, pp.97-107, 2009.
DOI : 10.1016/j.desal.2009.09.017

M. L. Granizo, M. T. Varela, and S. Martinez-ramirez, Alkali activation of metakaolins: parameters affecting mechanical, structural and microstructural properties, Journal of Materials Science, vol.26, issue.7, pp.2934-294310, 2007.
DOI : 10.1016/j.colsurfa.2005.06.060

A. G. Cristóbal, R. Castelló, M. A. Luengo, and C. Vizcayno, Zeolites prepared from calcined and mechanically modified kaolinsA comparative study, Applied Clay Science, vol.49, issue.3, pp.239-246, 2010.
DOI : 10.1016/j.clay.2010.05.012

E. Galan, P. Aparicio, A. Miras, K. Michailidis, and A. Tsirambides, Technical properties of compounded kaolin sample from Griva (Macedonia, Greece), Applied Clay Science, vol.10, issue.6, pp.477-49010, 1996.
DOI : 10.1016/0169-1317(95)00041-0

M. Q. Jiang, X. Y. Jin, X. Q. Lu, and Z. L. Chen, Adsorption of Pb(II), Cd(II), Ni(II) and Cu(II) onto natural kaolinite clay, Desalination, vol.252, issue.1-3, pp.33-39, 2010.
DOI : 10.1016/j.desal.2009.11.005

A. Sari, M. Tuzen, D. Citak, and M. Soylak, Equilibrium, kinetic and thermodynamic studies of adsorption of Pb(II) from aqueous solution onto Turkish kaolinite clay, Journal of Hazardous Materials, vol.149, issue.2, pp.283-291, 2007.
DOI : 10.1016/j.jhazmat.2007.03.078

I. Langmuir, THE ADSORPTION OF GASES ON PLANE SURFACES OF GLASS, MICA AND PLATINUM., Journal of the American Chemical Society, vol.40, issue.9, pp.1361-140310, 1021.
DOI : 10.1021/ja02242a004

M. O. Zacar and I. A. , Equilibrium Data and Process Design for Adsorption of Disperse Dyes onto Alunite, Environment Geology, vol.45, issue.2, pp.762-768

H. Freundlich, Über die Adsorption in lösungen, Zeitschrift für Physikalische Chemie (Leipzig), vol.57, pp.385-470, 1906.

E. Eren, Removal of Copper Ions by Clay, Turkey, Journal of Hazardous Materials, vol.159, issue.2-3, 2008.

A. Sari, M. Tuzen, and M. Soylak, Adsorption of Pb(II) and Cr(III) from aqueous solution on Celtek clay, Journal of Hazardous Materials, vol.144, issue.1-2, pp.41-46, 2007.
DOI : 10.1016/j.jhazmat.2006.09.080

A. Sari, M. Tuzen, D. Citak, and M. Soylak, Adsorption characteristics of Cu(II) and Pb(II) onto expanded perlite from aqueous solution, Journal of Hazardous Materials, vol.148, issue.1-2, pp.387-394, 2007.
DOI : 10.1016/j.jhazmat.2007.02.052

P. Tion, II) from Aqueous Solution to MX-80 Bentonite: Effect of pH, Ionic Strength, Foreign Ions and Temperature Applied Clay Sc 37-46

A. Günay, E. Arslankaya, and I. Tosun, Lead removal from aqueous solution by natural and pretreated clinoptilolite: Adsorption equilibrium and kinetics, Journal of Hazardous Materials, vol.146, issue.1-2, pp.362-371, 2007.
DOI : 10.1016/j.jhazmat.2006.12.034

S. Veli and B. Alyüz, Adsorption of copper and zinc from aqueous solutions by using natural clay, Journal of Hazardous Materials, vol.149, issue.1, 2007.
DOI : 10.1016/j.jhazmat.2007.04.109

P. Ding, K. L. Huang, G. Y. Li, Y. F. Liu, and W. W. Zeng, Kinetics of adsorption of Zn(II) ion on chitosan derivatives, International Journal of Biological Macromolecules, vol.39, issue.4-5, pp.222-227, 2006.
DOI : 10.1016/j.ijbiomac.2006.03.029

C. H. Weng and C. P. Huang, Adsorption characteristics of Zn(II) from dilute aqueous solution by fly ash, Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol.247, issue.1-3, pp.137-143, 2004.
DOI : 10.1016/j.colsurfa.2004.08.050

S. Lagergren, Zur Theorie der Sogenannten Adsorption gel Osterstoffe Kungliga Svenska vetenskapsakademiens, Handlingar, vol.24, pp.1-39, 1898.

Y. S. Ho, Citation Review of Lagergren Kinetic Rate Equation on Adsorption Reactions, Scientometrics, vol.59, issue.1, 2004.

Y. S. Ho, Selection of optimum sorption isotherm, Carbon, vol.42, issue.10, pp.2115-2116, 2004.
DOI : 10.1016/j.carbon.2004.03.019

C. Quintelas, H. Figueiredo, and T. Tavares, The effect of clay treatment on remediation of diethylketone contaminated wastewater: Uptake, equilibrium and kinetic studies, Journal of Hazardous Materials, vol.186, issue.2-3, pp.1241-1248, 2011.
DOI : 10.1016/j.jhazmat.2010.11.131

S. C. Tsai, S. Ouyang, and C. N. Hsu, Sorption and diffusion behavior of Cs and Sr on Jih-Hsing bentonite, Applied Radiation and Isotopes, vol.54, issue.2, pp.209-21510, 2001.
DOI : 10.1016/S0969-8043(00)00292-X

Y. S. Ho, Review of second-order models for adsorption systems, Journal of Hazardous Materials, vol.136, issue.3, pp.681-689, 2006.
DOI : 10.1016/j.jhazmat.2005.12.043

D. Wen, Y. S. Ho, and X. Tang, Comparative sorption kinetic studies of ammonium onto zeolite, Journal of Hazardous Materials, vol.133, issue.1-3, pp.1-3, 2006.
DOI : 10.1016/j.jhazmat.2005.10.020

Y. S. Ho and G. Mckay, Pseudo-second order model for sorption processes, Process Biochemistry, vol.34, issue.5, pp.451-46510, 1999.
DOI : 10.1016/S0032-9592(98)00112-5

URL : http://asiair.asia.edu.tw/ir/handle/310904400/6218

B. Meroufel, O. Benali, M. Benyah, and M. A. Zenasni, Adsorptive Remo ia, Y. Benmoussa and val of Anionic Dye aghnite, Materials Sciences, pp.153-161

A. Safa-Özcan, B. Erdem, and A. Özcan, Adsorption of Acid Blue 193 from aqueous solutions onto Na???bentonite and DTMA???bentonite, Journal of Colloid and Interface Science, vol.280, issue.1, pp.44-54, 2004.
DOI : 10.1016/j.jcis.2004.07.035

N. Caliskan, A. Kul, S. Alkan, E. G. Sogut, and I. Alacabey, Adsorption of Zinc(II) on diatomite and manganese-oxide-modified diatomite: A kinetic and equilibrium study, Journal of Hazardous Materials, vol.193, issue.15, pp.27-36, 2011.
DOI : 10.1016/j.jhazmat.2011.06.058

L. Guo, C. M. Sun, G. Y. Li, C. Liu, and C. Ji, Thermodynamics and kinetics of Zn(II) adsorption on crosslinked starch phosphates, Journal of Hazardous Materials, vol.161, issue.1, pp.510-515, 2009.
DOI : 10.1016/j.jhazmat.2008.04.003

M. K. Jhaa, R. R. Upadhyay, J. C. Lee, and V. Kumar, Treatment of rayon waste effluent for the removal of Zn and Ca using Indion BSR resin, Desalination, vol.228, issue.1-3, pp.97-107, 2008.
DOI : 10.1016/j.desal.2007.08.010

Y. Zhang, Y. Li, L. Q. Yang, X. J. Ma, L. Y. Wang et al., Characterization and adsorption mechanism of Zn2+ removal by PVA/EDTA resin in polluted water, Journal of Hazardous Materials, vol.178, issue.1-3, pp.1046-1054, 2010.
DOI : 10.1016/j.jhazmat.2010.02.046

P. C. Mishra and R. K. Patel, Removal of lead and zinc ions from water by low cost adsorbents, Journal of Hazardous Materials, vol.168, issue.1, pp.319-325, 2009.
DOI : 10.1016/j.jhazmat.2009.02.026

P. R. Puranik and K. M. Paknikar, Influence of co-cations on biosorption of lead and zinc ??? a comparative evaluation in binary and multimetal systems, Bioresource Technology, vol.70, issue.3, pp.269-27610, 1999.
DOI : 10.1016/S0960-8524(99)00037-1

A. Ucer, A. Uyanik, and S. F. Aygun, Zn(II), Mn(II) and Fe(II Immobilized Activated Carbon, " ) Ions by Tannic Acid Separation and Purification Technology, Adsorption of Cu(II), vol.47, issue.3, pp.113-118, 2006.

S. R. Shukla and R. S. Pai, Ni(II) and Zn(II) on Dye Loaded Groundnut Shells and Sawdust, Adsorption of Cu(II) Separation and Purification Technology, vol.43, issue.1, 2005.
DOI : 10.1016/j.seppur.2004.09.003

A. K. Meena, G. K. Mishra, P. K. Rai, C. Rajagopal, and P. N. Nager, Removal of heavy metal ions from aqueous solutions using carbon aerogel as an adsorbent, Journal of Hazardous Materials, vol.122, issue.1-2, pp.161-170, 2005.
DOI : 10.1016/j.jhazmat.2005.03.024

E. Pehlivan, S. Cetin, and B. H. Yanik, Equilibrium studies for the sorption of zinc and copper from aqueous solutions using sugar beet pulp and fly ash, Journal of Hazardous Materials, vol.135, issue.1-3, pp.193-199, 2006.
DOI : 10.1016/j.jhazmat.2005.11.049

S. Karabulut, A. Karabaka, A. Deaizbi, and Y. Yurcim, Batch removal of copper(II) and zinc(II) from aqueous solutions with low-rank Turkish coals, Separation and Purification Technology, vol.18, issue.3, pp.177-18410, 2000.
DOI : 10.1016/S1383-5866(99)00067-2

M. I. Kandah, Zinc and cadmium adsorption on low-grade phosphate, Separation and Purification Technology, vol.35, issue.1, pp.61-7010, 2004.
DOI : 10.1016/S1383-5866(03)00131-X

A. K. Bhattacharya, S. N. Mandal, and S. K. Das, Adsorption of Zn(II) from aqueous solution by using different adsorbents, Chemical Engineering Journal, vol.123, issue.1-2, pp.43-51, 2006.
DOI : 10.1016/j.cej.2006.06.012

Y. Li, Q. Yue, and B. Gao, Adsorption kinetics and desorption of Cu(II) and Zn(II) from aqueous solution onto humic acid, Journal of Hazardous Materials, vol.178, issue.1-3, pp.455-461, 2010.
DOI : 10.1016/j.jhazmat.2010.01.103

C. Pérez-novo, D. Fernández-calviño, and A. Bermúdez-couso, Phosphorus effect on Zn adsorption???desorption kinetics in acid soils, Chemosphere, vol.83, issue.7, pp.1028-1034, 2011.
DOI : 10.1016/j.chemosphere.2011.01.064

E. Katsou, S. Malamis, M. Tzanoudak, and M. Loizidou, Regeneration of natural zeolite polluted by lead and zinc in wastewater treatment systems, Journal of Hazardous Materials, vol.189, issue.3, pp.773-786, 2011.
DOI : 10.1016/j.jhazmat.2010.12.061