D. Gennes and P. , Angewandte Chemie International Edition, vol.31, pp.842-845, 1992.

F. Ruedinger, A. Lavrentieva, C. Blume, I. Pepelanova, and T. Scheper, Hydrogels for 3D mammalian cell culture: A starting guide for laboratory practice, Applied Microbiology and Biotechnology [Internet], vol.99, issue.2, pp.623-636, 2015.

W. Y. Seow and C. Hauser, Short to ultrashort peptide hydrogels for biomedical uses, Materials Today, vol.17, pp.381-388, 2014.

P. Worthington, D. J. Pochan, and S. A. Langhans, Peptide hydrogels-Versatile matrices for 3D cell culture in cancer medicine, Frontiers in Oncology [Internet], vol.5, p.92, 2015.

H. Hosseinkhani, P. Hong, and D. Yu, Self-assembled proteins and peptides for regenerative medicine, Chemical Reviews [Internet], vol.113, issue.7, pp.4837-4861, 2013.

Y. Li, M. Qin, Y. Cao, and W. Wang, Designing the mechanical properties of peptide-based supramolecular hydrogels for biomedical applications, Science China: Physics, Mechanics and Astronomy, vol.57, pp.849-858, 2014.

J. P. Jung, J. Z. Gasiorowski, and J. H. Collier, Fibrillar peptide gels in biotechnology and biomedicine, Biopolymers, vol.94, pp.49-59, 2010.

R. Bischoff and H. Schlüter, Amino acids: Chemistry, functionality and selected non-enzymatic post-translational modifications, Journal of Proteomics, vol.75, pp.2275-2296, 2012.

T. Knowles and M. J. Buehler, Nanomechanics of functional and pathological amyloid materials, Nature Nanotechnology [Internet], vol.6, issue.8, pp.469-479, 2011.

K. Petkau-milroy and L. Brunsveld, Supramolecular chemical biology; bioactive synthetic self-assemblies, Organic & Biomolecular Chemistry [Internet], vol.11, issue.2, pp.219-232, 2013.

D. N. Woolfson, Building fibrous biomaterials from alpha-helical and collagen-like coiled-coil peptides, Biopolymers, vol.94, pp.118-127, 2010.

V. A. Kumar, B. K. Wang, and S. M. Kanahara, Rational design of fiber forming supramolecular structures, Experimental Biology and Medicine [Internet], vol.241, issue.9, pp.1-10, 2016.

H. Dong, S. E. Paramonov, and J. D. Hartgerink, Self-assembly of alpha-helical coiled coil nanofibers_Supporting Info, Journal of the American Chemical Society

, , vol.130, pp.13691-13695, 2017.

S. A. Potekhin, T. N. Melnik, V. Popov, N. F. Lanina, A. A. Vazina et al., De novo design of fibrils made of short ?-helical coiled coil peptides, Chemistry and Biology, vol.8, issue.11, pp.1025-1032, 2001.

N. L. Fletcher, C. V. Lockett, and A. F. Dexter, A pH-responsive coiled-coil peptide hydrogel, Soft Matter [Internet], vol.7, issue.21, p.10210, 2011.

E. F. Banwell, E. S. Abelardo, D. J. Adams, M. A. Birchall, A. Corrigan et al., Rational design and application of responsive alpha-helical peptide hydrogels, Nature Materials [Internet], vol.8, issue.7, pp.596-600, 2009.

D. Santis, E. Ryadnov, and M. G. , Peptide self-assembly for nanomaterials: The old new kid on the block, Chemical Society Reviews [Internet], vol.44, issue.22, pp.8288-8300, 2015.

A. Markey, V. L. Workman, I. A. Bruce, T. J. Woolford, D. B. Miller et al., Peptide hydrogel in vitro non-inflammatory potential, Journal of Peptide Science

, , 2016.

D. Seliktar, Designing cell-compatible hydrogels for biomedical applications, Science, vol.336, issue.6085, pp.1124-1128, 2012.

S. Motamed, D. Borgo, M. P. Kulkarni, K. Habila, N. Zhou et al., A selfassembling [small beta]-peptide hydrogel for neural tissue engineering, Soft Matter, vol.12, issue.8, pp.2243-2246, 2016.

E. T. Pashuck, B. Duchet, C. S. Hansel, S. A. Maynard, L. W. Chow et al., Controlled sub-nanometer epitope spacing in a three-dimensional self-assembled peptide hydrogel, ACS Nano [Internet], vol.10, issue.12, pp.11096-11104, 2016.

C. Martin, E. Oyen, J. Mangelschots, M. Bibian, B. Haddou et al., Injectable peptide hydrogels for controlled-release of opioids, MedChemComm

E. L. Bakota, Y. Wang, F. R. Danesh, and J. D. Hartgerink, Injectable multidomain peptide nanofiber hydrogel as a delivery agent for stem cell secretome, Biomacromolecules

, , vol.12, pp.1651-1657, 2017.

L. Li, M. Han, X. Jiang, X. Yin, F. Chen et al., Peptide-tethered hydrogel scaffold promotes recovery from spinal cord transection via synergism with mesenchymal stem cells, ACS Applied Materials & Interfaces, 2017.

N. Zhang, L. He, and W. Wu, Self-assembling peptide nanofibrous hydrogel as a promising strategy in nerve repair after traumatic injury in the nervous system, Neural Regeneration Research, vol.11, pp.717-718, 2016.

B. He, Y. Ou, A. Zhou, S. Chen, W. Zhao et al., Functionalized D-form self-assembling peptide hydrogels for bone regeneration. Drug Design, Development and Therapy, Internet], vol.10, pp.1379-1388, 2016.

B. M. Friedrich, D. Beasley, and J. S. Rudra, Supramolecular peptide hydrogel adjuvanted subunit vaccine elicits protective antibody responses against West Nile virus, Vaccine, vol.34, issue.46, pp.5479-5482, 2016.

C. Chen, Y. Zhang, R. Fei, C. Cao, M. Wang et al., Hydrogelation of the short selfassembling peptide I3QGK regulated by transglutaminase and use for rapid hemostasis, ACS Applied Materials & Interfaces [Internet], vol.8, issue.28, pp.17833-17841, 2016.

S. Lindsey, J. H. Piatt, P. Worthington, C. Sönmez, S. Satheye et al., Beta hairpin peptide hydrogels as an injectable solid vehicle for neurotrophic growth factor delivery, Biomacromolecules [Internet], vol.16, issue.9, pp.2672-2683, 2015.

M. L. Briuglia, A. J. Urquhart, and D. A. Lamprou, Sustained and controlled release of lipophilic drugs from a self-assembling amphiphilic peptide hydrogel, International Journal of Pharmaceutics, vol.474, issue.1-2, pp.103-111, 2014.

L. Liang, J. Yang, Q. Li, M. Huo, F. Jiang et al., A novel targeting drug delivery system based on self-assembled peptide hydrogel, Journal of Biomaterials and Nanobiotechnology [Internet], vol.2, issue.5, pp.622-625, 2011.

A. Baral, S. Roy, A. Dehsorkhi, I. W. Hamley, S. Mohapatra et al., Assembly of an injectable noncytotoxic peptide-based hydrogelator for sustained release of drugs, Langmuir [Internet], vol.30, issue.3, pp.929-936, 2014.

Y. Yin, C. Wu, J. Wang, F. Song, W. Yue et al., A simply triggered peptide-based hydrogel as an injectable nanocarrier of tanshinone IIA and tanshinones, Chemical Communications, vol.53, issue.3, pp.529-561, 2017.

J. Li, R. Kooger, M. He, X. Xiao, L. Zheng et al., A supramolecular hydrogel as a carrier to deliver microRNA into the encapsulated cells, Chemical Communications

S. Koutsopoulos, L. D. Unsworth, Y. Nagai, and S. Zhang, Controlled release of functional proteins through designer self-assembling peptide nanofiber hydrogel scaffold, Proceedings of the National Academy of Sciences, vol.106, pp.4623-4628, 2009.

C. Hickling, H. S. Toogood, A. Saiani, N. S. Scrutton, and A. F. Miller, Nanofibrillar peptide hydrogels for the immobilization of biocatalysts for chemical transformations, Macromolecular Rapid Communications, vol.35, pp.868-874, 2014.

N. Nandi, A. Baral, K. Basu, S. Roy, and A. Banerjee, A dipeptide-based superhydrogel: Removal of toxic dyes and heavy metal ions from waste-water, Biopolymers, 2016.

A. Altunbas, N. Sharma, M. S. Lamm, C. Yan, R. P. Nagarkar et al., Peptidesilica hybrid networks: Biomimetic control of network mechanical behavior, ACS Nano [Internet], vol.4, issue.1, pp.181-188, 2010.

C. Li and R. Mezzenga, The interplay between carbon nanomaterials and amyloid fibrils in bio-nanotechnology, Nanoscale [Internet], vol.5, issue.14, pp.6207-6208, 2013.

V. Ng, J. Chan, H. Sardon, R. J. Ono, J. M. García et al., Antimicrobial hydrogels: A new weapon in the arsenal against multidrug-resistant infections, Advanced Drug Delivery Reviews, vol.78, pp.46-62, 2014.

D. A. Salick, D. J. Pochan, and J. P. Schneider, Design of an injectable ß-hairpin peptide hydrogel that kills methicillin-resistant staphylococcus aureus, Advanced Materials

, , vol.21, pp.4120-4123, 2017.

Y. Liu, Y. Yang, C. Wang, and X. Zhao, Stimuli-responsive self-assembling peptides made from antibacterial peptides, Nanoscale [Internet], vol.5, issue.14, pp.6413-6421, 2013.

S. Chatterjee, IIT-B has Come up with Hydrogels Mimicking Natural Brain Tissue to Cure Parkinson's Disease via Stem Cell Therapy, 2016.

, The Wonder Stuff-How Peptide Hydrogels Could Change the Face of Biomedicine

. Laboratorynews, , 2015.

, Tuned Gels Reveal Molecules that Drive Stem Cell Differentiation

. Physorg, , 2016.

, New Antibacterial Gel Could Revolutionize Treatment of Superbug Infections

, Medical News Today, 2016.

, To Fight Drug-Resistant Superbugs in Hospitals, Researchers Have Developed New BioFilm Targeting Antibacterial Gel

M. Daily, , 2014.

, HydroMatrix TM Peptide Cell Culture Scaffold

S. Aldrich, , 2017.

. Puramatrix,

. 3d-matrix-group, , 2017.

. Peptigel,

. Peptigel-design, , 2017.

. Pgmatrix,

L. Pepgel, , 2017.

. Curolox,

. Credentis, , 2017.

C. Ou, J. Zhang, X. Zhang, Z. Yang, and M. Chen, Phenothiazine as an aromatic capping group to construct a short peptide-based "super gelator

J. Shi, Y. Gao, Z. Yang, and B. Xu, Exceptionally small supramolecular hydrogelators based on aromatic-aromatic interactions, Beilstein Journal of Organic Chemistry

L. Chen, K. Morris, A. Laybourn, D. Elias, M. R. Hicks et al., Self-assembly mechanism for a naphthalene-dipeptide leading to hydrogelation, Langmuir, vol.26, issue.7, pp.5232-5242, 2010.

Z. Yang, G. Liang, M. Ma, Y. Gao, and B. Xu, Conjugates of naphthalene and dipeptides produce molecular hydrogelators with high efficiency of hydrogelation and superhelical nanofibers, Journal of Materials Chemistry, vol.17, issue.9, pp.850-854, 2007.

M. Ma, Y. Kuang, Y. Gao, Y. Zhang, P. Gao et al., Aromatic?aromatic interactions induce the self-assembly of pentapeptidic derivatives in water to form nanofibers and supramolecular hydrogels, Journal of the American Chemical Society [Internet], vol.132, issue.8, pp.2719-2728, 2010.

J. Nanda, A. Biswas, and A. Banerjee, Single amino acid based thixotropic hydrogel formation and pH-dependent morphological change of gel nanofibers, Soft Matter

Z. Qiu, H. Yu, J. Li, Y. Wang, and Y. Zhang, Spiropyran-linked dipeptide forms supramolecular hydrogel with dual responses to light and to ligand-receptor interaction, Chemical Communications, vol.7345, issue.23, pp.3342-3344, 2009.

V. J. Nebot, J. Armengol, J. Smets, S. F. Prieto, B. Escuder et al., Molecular hydrogels from bolaform amino acid derivatives: A structure-properties study based on the thermodynamics of gel solubilization, Chemistry-A European Journal

, , vol.18, pp.4063-4072, 2017.

H. A. Behanna, K. Rajangam, and S. I. Stupp, Modulation of fluorescence through coassembly of molecules in organic nanostructures, Journal of the American Chemical Society, vol.129, issue.2, pp.321-327, 2007.

Y. Huang, Z. Qiu, Y. Xu, J. Shi, H. Lin et al., Supramolecular hydrogels based on short peptides linked with conformational switch, Organic & Biomolecular Chemistry

K. Shroff, E. L. Rexeisen, M. A. Arunagirinathan, and E. Kokkoli, Fibronectin-mimetic peptideamphiphile nanofiber gels support increased cell adhesion and promote ECM production, Soft Matter [Internet], vol.6, issue.20, pp.5064-5072, 2010.

A. Shome, S. Dutta, S. Maiti, and P. K. Das, In situ synthesized Ag nanoparticle in self-assemblies of amino acid based amphiphilic hydrogelators: Development of antibacterial soft nanocomposites, Soft Matter [Internet], vol.7, issue.6, pp.3011-3022, 2011.

S. Dutta, A. Shome, T. Kar, and P. K. Das, Counterion-induced modulation in the antimicrobial activity and biocompatibility of amphiphilic hydrogelators: Influence of in-situ-synthesized ag-nanoparticle on the bactericidal property, Langmuir [Internet], vol.27, issue.8, pp.5000-5008, 2011.

H. Jun, V. Yuwono, S. E. Paramonov, and J. D. Hartgerink, Enzyme-mediated degradation of peptide-amphiphile nanofiber networks, Advanced Materials

, , vol.17, pp.2612-2617, 2017.

M. A. Greenfield, J. R. Hoffman, D. Cruz, M. O. Stupp, and S. I. , Tunable mechanics of peptide nanofiber gels, Langmuir [Internet], vol.26, issue.5, pp.3641-3647, 2010.

S. Roy and P. K. Das, Antibacterial hydrogels of amino acid-based cationic amphiphiles, Biotechnology and Bioengineering [Internet], vol.100, issue.4, pp.756-764, 2008.

R. N. Mitra and P. K. Das, In situ preparation of gold nanoparticles of varying shape in molecular hydrogel of peptide amphiphiles, Journal of Physical Chemistry C

, , vol.112, pp.8159-8166, 2017.

D. Das, S. Maiti, S. Brahmachari, and P. K. Das, Refining hydrogelator design: Soft materials with improved gelation ability, biocompatibility and matrix for in situ synthesis of specific shaped GNP. Soft Matter. The Royal Society of Chemistry, vol.7, pp.7291-7303, 2011.

X. Li, Y. Kuang, H. Lin, Y. Gao, J. Shi et al., Supramolecular nanofibers and hydrogels of nucleopeptides, Angewandte Chemie International Edition [Internet], vol.50, issue.40, pp.9365-9369, 2011.

X. Li, Y. Kuang, J. Shi, Y. Gao, H. C. Lin et al., Multifunctional, biocompatible supramolecular hydrogelators consist only of nucleobase, amino acid, and glycoside, Journal of the American Chemical Society, vol.133, issue.43, pp.17513-17518, 2011.

L. Ruan, H. Zhang, H. Luo, J. Liu, F. Tang et al., Designed amphiphilic peptide forms stable nanoweb, slowly releases encapsulated hydrophobic drug, and accelerates animal hemostasis, Proceedings of the National Academy of Sciences of the United States of America, vol.106, pp.5105-5110, 2009.

M. R. Caplan, P. N. Moore, S. Zhang, R. D. Kamm, and D. A. Lauffenburger, Self-assembly of a beta-sheet protein governed by relief of electrostatic repulsion relative to van der Waals attraction, Biomacromolecules, vol.1, issue.4, pp.627-631, 2000.

J. Kisiday, J. M. Kurz, B. Hung, H. Semino, C. Zhang et al., Self-assembling peptide hydrogel fosters chondrocyte extracellular matrix production and cell division: Implications for cartilage tissue repair, Proceedings of the National Academy of Sciences, vol.99, pp.9996-10001, 2002.

S. Maity, P. Jana, D. Haldar, M. E. Davis, J. L. Atwood et al., Fabrication of nanoporous material from a hydrophobic peptide, CrystEngComm [Internet], vol.13, issue.8, pp.3064-3071, 2011.

S. Maity, P. Kumar, D. Haldar, C. J. Bowerman, B. L. Nilson et al., Sonicationinduced instant amyloid-like fibril formation and organogelation by a tripeptide, Soft Matter [Internet], vol.7, issue.11, p.5239, 2011.

A. K. Das, P. P. Bose, M. Drew, and A. Banerjee, The role of protecting groups in the formation of organogels through a nano-fibrillar network formed by self-assembling terminally protected tripeptides, Tetrahedron, vol.63, issue.31, pp.7432-7442, 2007.

A. Banerjee, G. Palui, and A. Banerjee, Pentapeptide based organogels: The role of adjacently located phenylalanine residues in gel formation, Soft Matter [Internet], vol.4, issue.7, pp.1430-1437, 2008.

A. Baral, S. Roy, S. Ghosh, D. Hermida-merino, I. W. Hamley et al., A peptide-based mechano-sensitive, proteolytically stable hydrogel with remarkable antibacterial properties, Langmuir [Internet], vol.32, issue.7, pp.1836-1845, 2016.

R. C. Claussen, B. M. Rabatic, and S. I. Stupp, Aqueous self-assembly of unsymmetric peptide bolaamphiphiles into nanofibers with hydrophilic cores and surfaces, Journal of the American Chemical Society, vol.125, issue.42, pp.12680-12681, 2003.

N. Tzokova, C. M. Fernyhough, P. D. Topham, N. Sandon, D. J. Adams et al., Soft hydrogels from nanotubes of poly(ethylene oxide)-tetraphenylalanine conjugates prepared by click chemistry, Langmuir [Internet], vol.25, issue.4, pp.2479-2485, 2009.

A. Aggeli, M. Bell, N. Boden, L. M. Carrick, and A. E. Strong, Self-assembling peptide polyelectrolyte?-Sheet complexes form nematic hydrogels, Angewandte Chemie, vol.42, issue.45, pp.5603-5606, 2003.

S. Zhang, C. Lockshin, R. Cook, and A. Rich, Unusually stable beta-sheet formation in an ionic self-complementary oligopeptide, Biopolymers [Internet], vol.34, issue.5, pp.663-672, 1994.

S. Zhang, T. C. Holmes, C. M. Dipersio, R. O. Hynes, X. Su et al., Self-complementary oligopeptide matrices support mammalian cell attachment, Biomaterials, vol.16, issue.18, pp.1385-1393, 1995.

T. C. Holmes, S. De-lacalle, X. Su, G. Liu, A. Rich et al., Extensive neurite outgrowth and active synapse formation on self-assembling peptide scaffolds, Proceedings of the National Academy of Sciences of the United States of America

D. M. Ryan, T. M. Doran, S. B. Anderson, and B. L. Nilsson, Effect of C-terminal modification on the Self-Assembly and hydrogelation of fluorinated Fmoc-Phe derivatives, Langmuir [Internet], vol.27, issue.7, pp.4029-4039, 2011.

A. Aggeli, I. A. Nyrkova, M. Bell, R. Harding, L. Carrick et al., Hierarchical self-assembly of chiral rod-like molecules as a model for peptide beta-sheet tapes, ribbons, fibrils, and fibers, Proceedings of the National Academy of Sciences of the United States of America, vol.98, pp.11857-11862, 2001.

C. J. Bowerman and B. L. Nilsson, A reductive trigger for peptide self-assembly and hydrogelation, Journal of the American Chemical Society [Internet], vol.132, issue.28, pp.9526-9527, 2010.

S. Debnath, A. Shome, D. Das, and P. K. Das, Hydrogelation through self-assembly of fmocpeptide functionalized cationic amphiphiles: Potent antibacterial agent, Journal of Physical Chemistry B [Internet], vol.114, issue.13, pp.4407-4415, 2010.

C. Ren, Z. Song, W. Zheng, X. Chen, L. Wang et al., Disulfide bond as a cleavable linker for molecular self-assembly and hydrogelation, Chemical Communications, vol.47, issue.5, pp.1619-1621, 2011.

M. Kogiso, T. Hanada, K. Yase, and T. Shimizu, Intralayer hydrogen-bond-directed nano-fiber formation from dicarboxylic valylvaline bolaamphiphiles, Chemical Communications [Internet], issue.2, pp.1791-1792, 1998.

S. Franceschi, N. De-viguerie, M. Riviere, and A. Lattes, Synthesis and aggregation of twoheaded surfactants bearing amino acid moieties, New Journal of Chemistry

S. R. Diegelmann, N. Hartman, N. Markovic, and J. D. Tovar, Synthesis and alignment of discrete polydiacetylene-peptide nanostructures, Journal of the American Chemical Society, vol.134, issue.4, pp.2028-2031, 2012.

G. S. Vadehra, B. D. Wall, S. R. Diegelmann, and J. D. Tovar, On-resin dimerization incorporates a diverse array of pi-conjugated functionality within aqueous self-assembling peptide backbones, Chemical communications [Internet], vol.46, issue.22, pp.3947-3949, 2010.

M. Mba, A. Moretto, L. Armelao, M. Crisma, C. Toniolo et al., Synthesis and selfassembly of oligo(p-phenylenevinylene) peptide conjugates in water, Chemistry -A European Journal [Internet], vol.17, issue.7, pp.2044-2047, 2011.

B. D. Wall and J. D. Tovar, Synthesis and characterization of ?-conjugated peptide-based supramolecular materials. Pure and Applied Chemistry, vol.84, pp.1039-1045, 2012.

B. D. Wall, S. R. Diegelmann, S. Zhang, T. J. Dawidczyk, W. L. Wilson et al., Aligned macroscopic domains of optoelectronic nanostructures prepared via shear-flow assembly of peptide hydrogels, Advanced Materials [Internet], vol.23, issue.43, pp.5009-5014, 2011.

M. F. Mossuto, B. Bolognesi, B. Guixer, A. Dhulesia, F. Agostini et al., Disulfide bonds reduce the toxicity of the amyloid fibrils formed by an extracellular protein

, Angewandte Chemie, vol.50, issue.31, pp.7048-7051, 2011.

Y. Li, J. Yan, X. Zhang, and K. Huang, Disulfide bonds in amyloidogenesis diseases related proteins, Proteins: Structure, Function and Bioinformatics [Internet], vol.81, pp.1862-1873, 2013.

S. D. Heck, W. S. Faraci, P. R. Kelbaugh, N. A. Saccomano, P. F. Thadeio et al., Posttranslational amino acid epimerization: Enzyme-catalyzed isomerization of amino acid residues in peptide chains, Proceedings of the National Academy of Sciences of the United States of America, vol.93, pp.4036-4039, 1996.

C. Ollivaux, D. Soyez, and J. Y. Toullec, Biogenesis of D-amino acid containing peptides/proteins: Where, when and how, Journal of Peptide Science [Internet], vol.20, pp.595-612, 2014.
URL : https://hal.archives-ouvertes.fr/hal-01139947

S. A. Fuchs, R. Berger, L. Klomp, and T. J. De-koning, D-amino acids in the central nervous system in health and disease. Molecular Genetics and Metabolism

Y. Kaji, T. Oshika, Y. Takazawa, M. Fukayama, and N. Fujii, Pathological role of D-amino acidcontaining proteins and advanced glycation end products in the development of agerelated macular degeneration, Anti-Aging Medicine, vol.7, issue.10, pp.107-111, 2010.

B. Adhikari, J. Nanda, A. Banerjee, E. Yashima, K. Maeda et al., Multicomponent hydrogels from enantiomeric amino acid derivatives: Helical nanofibers, handedness and self-sorting, Soft Matter [Internet], vol.7, issue.19, p.8913, 2011.

Y. Zhang, H. Gu, Z. Yang, and B. Xu, Supramolecular hydrogels respond to ligand-receptor interaction, Journal of the American Chemical Society, vol.125, issue.45, pp.13680-13681, 2003.

L. Chronopoulou, S. Sennato, F. Bordi, D. Giannella, D. Nitto et al., Designing unconventional Fmoc-peptide-based biomaterials: Structure and related properties, Soft Matter [Internet], vol.10, issue.12, pp.1944-1952, 2014.

S. Marchesan, C. D. Easton, F. Kushkaki, L. Waddington, and P. G. Hartley, Tripeptide self-assembled hydrogels: Unexpected twists of chirality, Chemical Communications

, Amino Acid -New Insights and Roles in Plant and Animal, vol.66

L. A. Haines, K. Rajagopal, B. Ozbas, D. A. Salick, D. J. Pochan et al., Light-activated hydrogel formation via the triggered folding and self-assembly of a designed peptide, Journal of the American Chemical Society, vol.127, issue.48, pp.17025-17029, 2005.

T. H. Larsen, M. C. Branco, K. Rajagopal, J. P. Schneider, and E. M. Furst, Sequence-dependent gelation kinetics of ?-hairpin peptide hydrogels, Macromolecules

, , vol.42, pp.8443-8450, 2017.

J. P. Schneider, D. J. Pochan, B. Ozbas, K. Rajagopal, L. Pakstis et al., Responsive hydrogels from the intramolecular folding and self-assembly of a designed peptide, Journal of the American Chemical Society, vol.124, issue.50, pp.15030-15037, 2002.

B. Ozbas, J. Kretsinger, K. Rajagopal, J. P. Schneider, and D. J. Pochan, Salt-triggered peptide folding and consequent self-assembly into hydrogels with tunable modulus, Macromolecules, vol.37, pp.7331-7337, 2004.

D. J. Pochan, J. P. Schneider, J. Kretsinger, B. Ozbas, K. Rajagopal et al., Thermally reversible hydrogels via intramolecular folding and consequent self-assembly of a de novo designed peptide, Journal of the American Chemical Society, vol.125, issue.39, pp.11802-11803, 2003.

J. K. Kretsinger, L. A. Haines, B. Ozbas, D. J. Pochan, and J. P. Schneider, Cytocompatibility of selfassembled ?-hairpin peptide hydrogel surfaces, Biomaterials, vol.26, issue.25, pp.5177-5186, 2005.

M. C. Branco, F. Nettesheim, D. J. Pochan, J. P. Schneider, and N. J. Wagner, Fast dynamics of semiflexible chain networks of self-assembled peptides, Biomacromolecules [Internet], vol.10, issue.6, pp.1374-1380, 2009.

T. Yucel, C. M. Micklitsch, J. P. Schneider, and D. J. Pochan, Direct observation of earlytime hydrogelation in ?-hairpin peptide self-assembly, Macromolecules

, , pp.5763-5772, 2017.

L. Haines-butterick, K. Rajagopal, M. Branco, D. Salick, R. Rughani et al., Controlling hydrogelation kinetics by peptide design for three-dimensional encapsulation and injectable delivery of cells, Proceedings of the National Academy of Sciences of the United States of America, vol.104, pp.7791-7796, 2007.

R. A. Hule, R. P. Nagarkar, B. Hammouda, J. P. Schneider, and D. J. Pochan, Dependence of self-assembled peptide hydrogel network structure on local fibril nanostructure

, Macromolecules, vol.42, issue.18, pp.7137-7145, 2009.

R. P. Nagarkar, R. A. Hule, D. J. Pochan, and J. P. Schneider, De novo design of strand-swapped ?-hairpin hydrogels, Journal of the American Chemical Society, vol.130, issue.13, pp.4466-4474, 2008.

R. V. Rughani, D. A. Salick, M. S. Lamm, T. Yucel, D. J. Pochan et al., Folding, selfassembly, and bulk material properties of a de novo designed three-stranded ?-sheet hydrogel, Biomacromolecules [Internet], vol.10, issue.5, pp.1295-1304, 2009.

Z. Luo, X. Zhao, and S. Zhang, Self-organization of a chiral D-EAK16 designer peptide into a 3D nanofiber scaffold, Macromolecular Bioscience [Internet], vol.8, issue.8, pp.785-791, 2008.

Z. Luo, Y. Yue, Y. Zhang, X. Yuan, J. Gong et al., Designer D-form self-assembling peptide nanofiber scaffolds for 3-dimensional cell cultures, Biomaterials, vol.34, issue.21, pp.4902-4913, 2013.

Z. Luo, X. Zhao, and S. Zhang, Structural dynamic of a self-assembling peptide d-EAK16 made of only D-amino acids, PLoS One [Internet], vol.3, issue.5, 2008.

Z. Luo, S. Wang, and S. Zhang, Fabrication of self-assembling d-form peptide nanofiber scaffold d-EAK16 for rapid hemostasis, Biomaterials, vol.32, issue.8, pp.2013-2020, 2011.

C. J. Bowerman, D. M. Ryan, D. A. Nissan, and B. L. Nilsson, The effect of increasing hydrophobicity on the self-assembly of amphipathic beta-sheet peptides, Molecular BioSystems [Internet], vol.5, issue.9, pp.1058-1069, 2009.

C. J. Bowerman, W. Liyanage, A. J. Federation, and B. L. Nilsson, Tuning beta-sheet peptide selfassembly and hydrogelation behavior by modification of sequence hydrophobicity and aromaticity, Biomacromolecules [Internet], vol.12, issue.7, pp.2735-2745, 2011.

A. Aggeli, M. Bell, N. Boden, J. N. Keen, T. Mcleish et al., Engineering of peptide ?-sheet nanotapes, Journal of Materials Chemistry [Internet], vol.7, issue.7, pp.1135-1145, 1997.

C. K. Thota, N. Yadav, and V. S. Chauhan, A novel highly stable and injectable hydrogel based on a conformationally restricted ultrashort peptide, Scientific Reports [Internet], vol.6, p.31167, 2016.

J. J. Panda, A. Mishra, A. Basu, and V. S. Chauhan, Stimuli responsive self-assembled hydrogel of a low molecular weight free dipeptide with potential for tunable drug delivery, Biomacromolecules [Internet], vol.9, issue.8, pp.2244-2250, 2008.

C. M. Micklitsch, S. H. Medina, T. Yucel, K. J. Nagy-smith, D. J. Pochan et al., Influence of hydrophobic face amino acids on the hydrogelation of ?-hairpin peptide amphiphiles, Macromolecules, vol.48, issue.5, pp.1281-1288, 2015.

Z. Xie, A. Zhang, L. Ye, X. Wang, and Z. Feng, Shear-assisted hydrogels based on selfassembly of cyclic dipeptide derivatives, Journal of Materials Chemistry

, Amino Acid -New Insights and Roles in Plant and Animal, vol.19, issue.34, pp.6100-6102, 2009.

R. Orbach, L. Adler-abramovich, S. Zigerson, I. Mironi-harpaz, D. Seliktar et al., Selfassembled Fmoc-peptides as a platform for the formation of nanostructures and hydrogels, Biomacromolecules, vol.10, issue.9, pp.2646-2651, 2009.

I. W. Hamley, G. D. Brown, V. Castelletto, G. Cheng, M. Venanzi et al., Selfassembly of a designed amyloid peptide containing the functional thienylalanine unit, Journal of Physical Chemistry B [Internet], vol.114, issue.32, pp.10674-10683, 2010.

Y. A. Gao, M. Long, J. Shi, L. Hedstrom, and B. Xu, Using supramolecular hydrogels to discover the interactions between proteins and molecular nanofibers of small molecules, Chemical Communications [Internet], vol.48, issue.67, pp.8404-8406, 2012.

J. Brinckmann, H. Notbohm, P. K. Müller, and . Collagen, Primer in structure, processing and assembly, p.252, 2005.

Y. Hu, H. Wang, J. Wang, S. Wang, W. Liao et al., Supramolecular hydrogels inspired by collagen for tissue engineering, Organic & Biomolecular Chemistry [Internet], vol.8, issue.14, pp.3267-3271, 2010.

W. Liyanage and B. L. Nilsson, Substituent effects on the self-assembly/coassembly and hydrogelation of phenylalanine derivatives, Langmuir [Internet], vol.32, issue.3, pp.787-799, 2016.

D. M. Ryan, S. B. Anderson, F. T. Senguen, R. E. Youngman, and B. L. Nilsson, Self-assembly and hydrogelation promoted by F5-phenylalanine, Soft Matter [Internet], vol.6, issue.3, pp.475-479, 2010.

D. M. Ryan, T. M. Doran, and B. L. Nilsson, Complementary ?-? interactions induce multicomponent coassembly into functional fibrils, Langmuir [Internet], vol.27, issue.17, pp.11145-11156, 2011.

D. M. Ryan, S. B. Anderson, and B. L. Nilsson, The influence of side-chain halogenation on the self-assembly and hydrogelation of Fmoc-phenylalanine derivatives, Soft Matter [Internet], vol.6, issue.14, pp.3220-3231, 2010.

A. Bertolani, L. Pirrie, L. Stefan, N. Houbenov, J. S. Haataja et al., Supramolecular amplification of amyloid self-assembly by iodination, Nature Communications [Internet], vol.6, p.7574, 2015.
URL : https://hal.archives-ouvertes.fr/hal-02086232

H. Shao and J. R. Parquette, A ?-conjugated hydrogel based on an Fmoc-dipeptide naphthalene diimide semiconductor, Chemical Communications [Internet], vol.46, issue.24, pp.4285-4287, 2010.

X. Li, Y. Gao, Y. Kuang, and B. Xu, Enzymatic formation of a photoresponsive supramolecular hydrogel, Chemical Communications [Internet], vol.46, issue.29, pp.5364-5366, 2010.

X. Li, J. Li, Y. Gao, Y. Kuang, J. Shi et al., Molecular nanofibers of olsalazine form supramolecular hydrogels for reductive release of an anti-inflammatory agent, Journal of the American Chemical Society, vol.132, issue.50, pp.17707-17709, 2010.

R. V. Rughani, M. C. Branco, D. J. Pochan, and J. P. Schneider, De novo design of a shear-thin recoverable peptide-based hydrogel capable of intrafibrillar photopolymerization

, Macromolecules [Internet], vol.43, pp.7924-7930, 2010.

A. Mata, L. Hsu, R. Capito, C. Aparicio, K. Henrikson et al., Micropatterning of bioactive self-assembling gels, Soft Matter [Internet], vol.5, issue.6, pp.1228-1236, 2009.

Y. Zhang, N. Li, J. Delgado, Y. Gao, Y. Kuang et al., Post-self-assembly cross-linking of molecular nanofibers for oscillatory hydrogels, Langmuir, vol.28, issue.6, pp.3063-3066, 2012.

J. B. Matson and S. I. Stupp, Drug release from hydrazone-containing peptide amphiphiles, Chemical Communications [Internet], vol.47, issue.28, pp.7962-7964, 2011.

G. Cheng, V. Castelletto, C. M. Moulton, G. E. Newby, and I. W. Hamley, Hydrogelation and self-assembly of Fmoc-tripeptides: Unexpected influence of sequence on self-assembled fibril structure, and hydrogel modulus and anisotropy, Langmuir

, , vol.26, pp.4990-4998, 2017.

Z. Yang, L. Wang, J. Wang, P. Gao, and B. Xu, Phenyl groups in supramolecular nanofibers confer hydrogels with high elasticity and rapid recovery, Journal of Materials Chemistry [Internet], vol.20, issue.11, pp.2128-2132, 2010.

Z. Yang, K. Xu, L. Wang, H. Gu, H. Wei et al., Self-assembly of small molecules affords multifunctional supramolecular hydrogels for topically treating simulated uranium wounds, Chemical Communications [Internet], vol.101, issue.35, pp.4414-4416, 2005.

M. O. Guler and S. I. Stupp, A self-assembled nanofiber catalyst for ester hydrolysis, Journal of the American Chemical Society, vol.129, issue.40, pp.12082-12083, 2007.

, Amino Acid -New Insights and Roles in Plant and Animal, vol.70

C. M. Micklitsch, P. J. Knerr, M. C. Branco, R. Nagarkar, D. J. Pochan et al., Zinctriggered hydrogelation of a self-assembling ?-hairpin peptide, Angewandte Chemie International Edition [Internet], vol.50, issue.7, pp.1577-1579, 2011.

J. D. Hartgerink, Self-assembly and mineralization of peptide-amphiphile nanofibers, Science [Internet], vol.294, issue.5547, pp.1684-1688, 2001.

J. C. Stendahl, M. S. Rao, M. O. Guler, and S. I. Stupp, Intermolecular forces in the self-assembly of peptide amphiphile nanofibers, Advanced Functional Materials [Internet], vol.16, issue.4, pp.499-508, 2006.

Y. Ding, Y. Li, M. Qin, Y. Cao, and W. Wang, Photo-cross-linking approach to engineering small tyrosine-containing peptide hydrogels with enhanced mechanical stability, Langmuir [Internet], vol.29, issue.43, pp.13299-13306, 2013.

R. Su, Y. Kim, and J. C. Liu, Resilin: Protein-based elastomeric biomaterials, Acta Biomaterialia, vol.10, pp.1601-1611, 2014.

R. Guillemin, Peptides in the brain. The new endocrinology of the neuron, Science, vol.202, issue.4366, pp.390-402, 1978.

A. V. Schally, Aspects of hypothalamic regulation of the pituitary gland with major emphasis on its implications for the control of reproductive processes, Materia Medica Polona, vol.12, issue.1-2, pp.9-27, 1980.

R. S. Yalow, Radioimmunoassays: A probe for fine structure of biologic systems, Medical Physics, vol.5, issue.4, pp.247-257, 1978.

S. K. Maji, D. Schubert, C. Rivier, S. Lee, J. E. Rivier et al., Amyloid as a depot for the formulation of long-acting drugs, PLoS Biology [Internet], vol.6, issue.2, pp.240-52, 2008.

B. Xing, C. W. Yu, K. H. Chow, P. L. Ho, D. Fu et al., Hydrophobic interaction and hydrogen bonding cooperatively confer a vancomycin hydrogel: A potential candidate for biomaterials, Journal of the American Chemical Society, vol.124, issue.50, pp.14846-14847, 2002.

N. Qvit, S. Rubin, T. J. Urban, D. Mochly-rosen, and E. R. Gross, Peptidomimetic therapeutics: Scientific approaches and opportunities. Drug Discovery Today, vol.22, pp.454-462, 2017.

N. Venkatesan and B. H. Kim, Synthesis and enzyme inhibitory activities of novel peptide isosteres, Current Medicinal Chemistry [Internet], vol.9, issue.24, pp.2243-2270, 2002.

I. Avan, C. D. Hall, and A. R. Katritzky, Peptidomimetics via modifications of amino acids and peptide bonds, Chemical Society Reviews [Internet], vol.43, issue.10, pp.3575-3594, 2014.

J. Gante, Angewandte Chemie International Edition in English, vol.33, pp.1699-1720, 1994.

J. H. Jones, Words derived from the noun peptide, vol.12, pp.79-81, 2006.

R. D. Gopalan, D. Borgo, M. P. Mechler, A. I. Perlmutter, P. Aguilar et al., Geometrically precise building blocks: The self-assembly of beta-peptides, Chemistry and Biology, vol.22, pp.1417-1423, 2015.

Z. Yang, G. Liang, and B. Xu, Supramolecular hydrogels based on beta-amino acid derivatives, Chemical Communications [Internet], vol.97, issue.7, pp.738-740, 2006.

Z. Yang, G. Liang, M. Ma, Y. Gao, and B. Xu, In vitro and in vivo enzymatic formation of supramolecular hydrogels based on self-assembled nanofibers of a beta-amino acid derivative, Small [Internet], vol.3, issue.4, pp.558-562, 2007.

J. Nanda and A. Banerjee, Amino acid containing proteolitically stable dipeptide based hydrogels: Encapsulation and sustained release of some important biomolecules at physiological pH and temperature, Soft Matter [Internet], vol.8, issue.12, pp.3380-3386, 2012.

V. Castelletto, G. Cheng, B. W. Greenland, I. W. Hamley, and P. Harris, Tuning the self-assembly of the bioactive dipeptide l-carnosine by incorporation of a bulky aromatic substituent, Langmuir [Internet], vol.27, issue.6, pp.2980-2988, 2011.

M. M. Nguyen, K. M. Eckes, and L. J. Suggs, Charge and sequence effects on the self-assembly and subsequent hydrogelation of Fmoc-depsipeptides. Soft matter, Internet], vol.10, issue.15, pp.2693-2702, 2014.

J. Makarevi?, M. Joki?, B. Peri?, V. Tomi?i?, B. Koji?-prodi? et al., Bis(Amino Acid) oxalyl amides as ambidextrous gelators of water and organic solvents: Supramolecular gels with temperature dependent assembly/dissolution equilibrium, Chemistry-A European Journal [Internet], vol.7, issue.15, pp.3328-3341, 2001.

M. Joki?, J. Makarevi?, and M. ?ini?, A novel type of small organic gelators: Bis(amino acid) oxalyl amides, Journal of the Chemical Society Chemical Communications

L. Frkanec, M. Joki?, J. Makarevi?, K. Wolsperger, and M. ?ini?, Bis(PheOH) maleic acid amidefumaric acid amide photoizomerization induces microsphere-to-gel fiber morphological transition: The photoinduced gelation system, Journal of the American Chemical Society, vol.124, issue.33, pp.9716-9717, 2002.

N. Castellucci, G. Angelici, G. Falini, M. Monari, C. Tomasini et al., A privileged scaffold for the formation of supramolecular materials, European Journal of Organic Chemistry [Internet], issue.16, pp.3082-3088, 2011.

N. Castellucci, G. Falini, G. Angelici, and C. Tomasini, Formation of gels in the presence of metal ions, Amino Acids [Internet], vol.41, issue.3, pp.609-620, 2011.

N. Castellucci, G. Sartor, N. Calonghi, C. Parolin, G. Falini et al., A peptidic hydrogel that may behave as a "trojan Horse, Beilstein Journal of Organic Chemistry [Internet], vol.9, pp.417-424, 2013.

L. Milli, N. Zanna, A. Merlettini, D. Giosia, M. Calvaresi et al., Pseudopeptide-based hydrogels trapping methylene blue and eosin Y, Chemistry-A European Journal [Internet], vol.22, issue.34, pp.12106-12112, 2016.

A. Rajbhandary and B. L. Nilsson, Investigating the effects of peptoid substitutions in selfassembly of Fmoc-Diphenylalanine derivatives, Biopolymers [Internet], vol.108, 2016.