<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-02132363</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-04-28T10:39:12+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Aging as the main factor controlling PAH and polar-PAC (polycyclic aromatic compound) release mechanisms in historically coal-tar-contaminated soils</title>
            <author role="aut">
              <persName>
                <forename type="first">Marine</forename>
                <surname>Boulange</surname>
              </persName>
              <idno type="halauthorid">1408341-0</idno>
              <affiliation ref="#struct-237201"/>
              <affiliation ref="#struct-247127"/>
              <affiliation ref="#struct-3186"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Catherine</forename>
                <surname>Lorgeoux</surname>
              </persName>
              <email type="md5">15d2349ceb3fc86b11864b68c8c93204</email>
              <email type="domain">u-pec.fr</email>
              <idno type="idhal" notation="numeric">879819</idno>
              <idno type="halauthorid" notation="string">493897-879819</idno>
              <affiliation ref="#struct-247127"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Coralie</forename>
                <surname>Biache</surname>
              </persName>
              <email type="md5">6748df60635e6206ce9ff001cf6c8a20</email>
              <email type="domain">univ-lorraine.fr</email>
              <idno type="idhal" notation="string">coraliebiache</idno>
              <idno type="idhal" notation="numeric">17444</idno>
              <idno type="halauthorid" notation="string">10389-17444</idno>
              <idno type="IDREF">https://www.idref.fr/148257240</idno>
              <affiliation ref="#struct-237201"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Julien</forename>
                <surname>Michel</surname>
              </persName>
              <email type="md5">dc8cd789895f059963eaa4a23f89e0b5</email>
              <email type="domain">ineris.fr</email>
              <idno type="idhal" notation="string">j-michel</idno>
              <idno type="idhal" notation="numeric">1311935</idno>
              <idno type="halauthorid" notation="string">244467-1311935</idno>
              <idno type="ORCID">https://orcid.org/0000-0003-2851-1104</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/X-2852-2018</idno>
              <affiliation ref="#struct-3186"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Raymond</forename>
                <surname>Michels</surname>
              </persName>
              <email type="md5">75e100e729b440194adec359dd7e4cd8</email>
              <email type="domain">univ-lorraine.fr</email>
              <idno type="idhal" notation="string">raymond-michels</idno>
              <idno type="idhal" notation="numeric">179722</idno>
              <idno type="halauthorid" notation="string">2538-179722</idno>
              <idno type="IDREF">https://www.idref.fr/073969559</idno>
              <affiliation ref="#struct-247127"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Pierre</forename>
                <surname>Faure</surname>
              </persName>
              <email type="md5">9e7ecf4accb0dd71d65fe9f144cc2578</email>
              <email type="domain">univ-lorraine.fr</email>
              <idno type="idhal" notation="string">pierre-faure</idno>
              <idno type="idhal" notation="numeric">17319</idno>
              <idno type="halauthorid" notation="string">28796-17319</idno>
              <idno type="ORCID">https://orcid.org/0000-0001-5629-0068</idno>
              <idno type="IDREF">https://www.idref.fr/125290764</idno>
              <affiliation ref="#struct-237201"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Coralie</forename>
                <surname>Biache</surname>
              </persName>
              <email type="md5">6748df60635e6206ce9ff001cf6c8a20</email>
              <email type="domain">univ-lorraine.fr</email>
            </editor>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2019-05-17 09:47:03</date>
              <date type="whenModified">2026-03-26 08:18:01</date>
              <date type="whenReleased">2019-05-24 09:17:37</date>
              <date type="whenProduced">2019-01</date>
              <date type="whenEndEmbargoed">2019-05-17</date>
              <ref type="file" target="https://hal.univ-lorraine.fr/hal-02132363v1/document">
                <date notBefore="2019-05-17"/>
              </ref>
              <ref type="file" subtype="author" n="1" target="https://hal.univ-lorraine.fr/hal-02132363v1/file/Boulang%C3%A9%20et%20al%2C%202019_postprint%20HAL.docx.pdf" id="file-2132364-2124527">
                <date notBefore="2019-05-17"/>
              </ref>
              <ref type="annex" n="0" target="https://hal.univ-lorraine.fr/hal-02132363v1/file/Supplementary%20materials%20Boulange%CC%81%20et%20al%2C2019.pdf" id="file-2132364-2124528">
                <date notBefore="2019-05-17"/>
              </ref>
              <ref type="externalLink" target="https://hal.univ-lorraine.fr/hal-02132363/file/Boulang%C3%A9%20et%20al%2C%202019_postprint%20HAL.docx.pdf"/>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="391963">
                <persName>
                  <forename>Coralie</forename>
                  <surname>Biache</surname>
                </persName>
                <email type="md5">6748df60635e6206ce9ff001cf6c8a20</email>
                <email type="domain">univ-lorraine.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-02132363</idno>
            <idno type="halUri">https://hal.univ-lorraine.fr/hal-02132363</idno>
            <idno type="halBibtex">boulange:hal-02132363</idno>
            <idno type="halRefHtml">&lt;i&gt;Environmental Science and Pollution Research&lt;/i&gt;, 2019, 26 (2), pp.1693-1705. &lt;a target="_blank" href="https://dx.doi.org/10.1007/s11356-018-3708-1"&gt;&amp;#x27E8;10.1007/s11356-018-3708-1&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">Environmental Science and Pollution Research, 2019, 26 (2), pp.1693-1705. &amp;#x27E8;10.1007/s11356-018-3708-1&amp;#x27E9;</idno>
            <availability status="restricted">
              <licence target="https://about.hal.science/hal-authorisation-v1/">HAL Authorization<ref corresp="#file-2132364-2124527"/><ref corresp="#file-2132364-2124528"/></licence>
            </availability>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="SDE">Sciences De l'Environnement</idno>
            <idno type="stamp" n="INERIS">INERIS - Institut National de l'Environnement industriel et des RISques</idno>
            <idno type="stamp" n="INSU">INSU - Institut National des Sciences de l'Univers</idno>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="GIP-BE">GIP Bretagne Environnement</idno>
            <idno type="stamp" n="UNIV-LORRAINE">Université de Lorraine</idno>
            <idno type="stamp" n="GEORESSOURCES-UL">GeoRessources</idno>
            <idno type="stamp" n="LIEC-UL">LIEC</idno>
            <idno type="stamp" n="OTELO-UL">Pôle scientifique Observatoire Terre et Environnement de Lorraine de l'Université de Lorraine</idno>
            <idno type="stamp" n="IMPACT-DEEPSURF">LUE - IMPACT DEEPSURF</idno>
            <idno type="stamp" n="TEST4-HALCNRS">collection test</idno>
            <idno type="stamp" n="TEST5-HALCNRS">collection test 5</idno>
            <idno type="stamp" n="INEE-CNRS">Institut écologie et environnement du CNRS</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Aging as the main factor controlling PAH and polar-PAC (polycyclic aromatic compound) release mechanisms in historically coal-tar-contaminated soils</title>
                <author role="aut">
                  <persName>
                    <forename type="first">Marine</forename>
                    <surname>Boulange</surname>
                  </persName>
                  <idno type="halauthorid">1408341-0</idno>
                  <affiliation ref="#struct-237201"/>
                  <affiliation ref="#struct-247127"/>
                  <affiliation ref="#struct-3186"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Catherine</forename>
                    <surname>Lorgeoux</surname>
                  </persName>
                  <email type="md5">15d2349ceb3fc86b11864b68c8c93204</email>
                  <email type="domain">u-pec.fr</email>
                  <idno type="idhal" notation="numeric">879819</idno>
                  <idno type="halauthorid" notation="string">493897-879819</idno>
                  <affiliation ref="#struct-247127"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Coralie</forename>
                    <surname>Biache</surname>
                  </persName>
                  <email type="md5">6748df60635e6206ce9ff001cf6c8a20</email>
                  <email type="domain">univ-lorraine.fr</email>
                  <idno type="idhal" notation="string">coraliebiache</idno>
                  <idno type="idhal" notation="numeric">17444</idno>
                  <idno type="halauthorid" notation="string">10389-17444</idno>
                  <idno type="IDREF">https://www.idref.fr/148257240</idno>
                  <affiliation ref="#struct-237201"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Julien</forename>
                    <surname>Michel</surname>
                  </persName>
                  <email type="md5">dc8cd789895f059963eaa4a23f89e0b5</email>
                  <email type="domain">ineris.fr</email>
                  <idno type="idhal" notation="string">j-michel</idno>
                  <idno type="idhal" notation="numeric">1311935</idno>
                  <idno type="halauthorid" notation="string">244467-1311935</idno>
                  <idno type="ORCID">https://orcid.org/0000-0003-2851-1104</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/X-2852-2018</idno>
                  <affiliation ref="#struct-3186"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Raymond</forename>
                    <surname>Michels</surname>
                  </persName>
                  <email type="md5">75e100e729b440194adec359dd7e4cd8</email>
                  <email type="domain">univ-lorraine.fr</email>
                  <idno type="idhal" notation="string">raymond-michels</idno>
                  <idno type="idhal" notation="numeric">179722</idno>
                  <idno type="halauthorid" notation="string">2538-179722</idno>
                  <idno type="IDREF">https://www.idref.fr/073969559</idno>
                  <affiliation ref="#struct-247127"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Pierre</forename>
                    <surname>Faure</surname>
                  </persName>
                  <email type="md5">9e7ecf4accb0dd71d65fe9f144cc2578</email>
                  <email type="domain">univ-lorraine.fr</email>
                  <idno type="idhal" notation="string">pierre-faure</idno>
                  <idno type="idhal" notation="numeric">17319</idno>
                  <idno type="halauthorid" notation="string">28796-17319</idno>
                  <idno type="ORCID">https://orcid.org/0000-0001-5629-0068</idno>
                  <idno type="IDREF">https://www.idref.fr/125290764</idno>
                  <affiliation ref="#struct-237201"/>
                </author>
              </analytic>
              <monogr>
                <idno type="halJournalId" status="VALID">12952</idno>
                <idno type="issn">0944-1344</idno>
                <idno type="eissn">1614-7499</idno>
                <title level="j">Environmental Science and Pollution Research</title>
                <imprint>
                  <publisher>Springer Verlag</publisher>
                  <biblScope unit="volume">26</biblScope>
                  <biblScope unit="issue">2</biblScope>
                  <biblScope unit="pp">1693-1705</biblScope>
                  <date type="datePub">2019-01</date>
                </imprint>
              </monogr>
              <idno type="doi">10.1007/s11356-018-3708-1</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <keywords scheme="author">
                <term xml:lang="en">Colloidal mobilization</term>
                <term xml:lang="en">Groundwater</term>
                <term xml:lang="en">Nitrogenated PACs</term>
                <term xml:lang="en">Oxygenated PACs</term>
                <term xml:lang="en">Ionic strength</term>
                <term xml:lang="en">Availability</term>
              </keywords>
              <classCode scheme="halDomain" n="sde">Environmental Sciences</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>In industrial sites, historically contaminated by coal tar (abandoned coking and manufactured gas plants), other families of organic pollutants than the 16 PAHs (polycyclic aromatic hydrocarbons) classified by the US-EPA can occur and induce potential risk for groundwater resources. Polar PACs (polycyclic aromatic compounds), especially oxygenated and nitrogenated PACs (O-PACs and N-PACs), are present in the initial pollution and can also be generated over time (i.e., O-PACs). Their aqueous solubilities are much greater than those of the PAHs. For these reasons, we need to increase our knowledge on polar PACs in order to better predict their behavior and the potential on-site risk. Batch leaching tests were carried out under various conditions of temperature, ionic strength, and availability of pollutants to determine the mechanisms and key parameters controlling their release. The results show a release of low-molecularweight PAHs and polar PACs mainly by dissolution, while higher molecular weight PAHs are mainly released in association with colloids. Aging mainly controls the former mechanism, and ionic strength mainly controls the latter. Temperature increased both dissolution and colloidal mobilization. The Raoult law predicts the PAC equilibrium concentration for soils presenting high pollutant availability, but this law overestimates PAC concentration in aged soils (low pollutant availability). This is mainly due to limitation of PAC diffusion within coal-tar particles with aging. The most soluble PACs (especially polar PACs) are the most sensitive to aging. For better prediction of the PAC behavior in soils and water resources management, aging needs to be taken into account.</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="laboratory" xml:id="struct-237201" status="VALID">
          <idno type="IdRef">174161565</idno>
          <idno type="ISNI">0000000417588250</idno>
          <idno type="RNSR">201320576N</idno>
          <idno type="IdUnivLorraine">[UL]RRI--</idno>
          <idno type="ROR">https://ror.org/05je79696</idno>
          <orgName>Laboratoire Interdisciplinaire des Environnements Continentaux</orgName>
          <orgName type="acronym">LIEC</orgName>
          <date type="start">2013-01-01</date>
          <desc>
            <address>
              <addrLine>Site Charmois : 15 Avenue du Charmois, F-54500 VANDOEUVRE-LES-NANCY ; Site Aiguillettes : Faculté des Sciences et Technologies, F-54506 VANDOEUVRE-LES-NANCY ; Site Bridoux : Campus Bridoux - Rue du Général Delestraint, F-57070 METZ ; Site Thionville : IUT de Thionville-Yutz - Espace Cormontaigne, F-57970 THIONVILLE-YUTZ</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://liec.univ-lorraine.fr/</ref>
          </desc>
          <listRelation>
            <relation name="UMR7360" active="#struct-300045" type="direct"/>
            <relation active="#struct-413289" type="direct"/>
            <relation name="UMR7360" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="laboratory" xml:id="struct-247127" status="VALID">
          <idno type="IdRef">169440087</idno>
          <idno type="RNSR">201320575M</idno>
          <idno type="IdUnivLorraine">[UL]RRJ--</idno>
          <idno type="ROR">04mq2px33</idno>
          <orgName>GeoRessources</orgName>
          <date type="start">2013-01-01</date>
          <desc>
            <address>
              <addrLine>Université de Lorraine, Faculté des Sciences et Technologies, rue Jacques Callot, BP 70239, 54506 Vandoeuvre-lès-Nancy Cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://georessources.univ-lorraine.fr/fr</ref>
          </desc>
          <listRelation>
            <relation active="#struct-300045" type="direct"/>
            <relation active="#struct-320707" type="direct"/>
            <relation active="#struct-413289" type="direct"/>
            <relation name="UMR7359" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-3186" status="VALID">
          <idno type="ROR">https://ror.org/034yrjf77</idno>
          <orgName>Institut National de l'Environnement Industriel et des Risques</orgName>
          <orgName type="acronym">INERIS</orgName>
          <desc>
            <address>
              <addrLine>Verneuil-en-Halatte ; Nancy ; Aix en Provence</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.ineris.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-300045" status="VALID">
          <idno type="IdRef">029349265</idno>
          <idno type="ISNI">0000 0001 2154 1736</idno>
          <idno type="ROR">https://ror.org/04kdfz702</idno>
          <idno type="Wikidata">Q3152437</idno>
          <orgName>Institut national des sciences de l'Univers</orgName>
          <orgName type="acronym">INSU - CNRS</orgName>
          <date type="start">2007-04-19</date>
          <desc>
            <address>
              <addrLine>INSU-CNRS3 rue Michel-Ange, 75794 Paris Cedex 16</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.insu.cnrs.fr</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-413289" status="VALID">
          <idno type="IdRef">157040569</idno>
          <idno type="IdUnivLorraine">[UL]100--</idno>
          <idno type="ROR">https://ror.org/04vfs2w97</idno>
          <orgName>Université de Lorraine</orgName>
          <orgName type="acronym">UL</orgName>
          <date type="start">2012-01-01</date>
          <desc>
            <address>
              <addrLine>34 cours Léopold - CS 25233 - 54052 Nancy cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.univ-lorraine.fr/</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-320707" status="VALID">
          <orgName>Centre de recherches sur la géologie des matières premières minérales et énergétiques</orgName>
          <orgName type="acronym">CREGU</orgName>
          <date type="start">1979-01-01</date>
          <desc>
            <address>
              <addrLine>BP 20023, 54501 Vandoeuvre-lès-Nancy cedex, France</addrLine>
              <country key="FR"/>
            </address>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>