S. Précipitation-de and .. Modèle-de-langmuir, 48 III. D) Les isothermes d " adsorption 48 D) 1. Classification 48 D) 2. Modèles les plus courants, 51 2. f) Autres isothermes, p.51

.. Validité-des-isothermes-d-"-adsorption and .. Sur-la-goethite, 52 III. E) Etudes d " adsorption 52 E) 1. Ions métalliques 52 E) 3. Apport de la spectroscopie infrarouge : exemple du salicylate sur la goethite 53 E) 4. Critique de ces travaux 55 A) 1, 52 E) 2. Molécules organiques 54 IV. Du batch vers 54 IV. A) Phénomènes impliqués dans le transport 55 IV. B) Le modèle eau mobile-eau immobile (Mobile-Immobile Water, p.56

B. Chapitre, M. Matériaux, I. A. Choix-du-matériau-support, and .. , 61 I. Préparation des matériaux mixtes employés en colonne. 63 I. B) Synthèse de la goethite et intérêt de la méthode proposée 65 B) 1. Considérations préliminaires 65 B) 2 66 B) 3. Caractérisation de la goethite NaClO 3 68 3. a) Caractérisations de base, 70 b) i. Observation sous forme de film en mode réflexion totale atténuée .................................... 70 b) ii, p.72

D. Mise-au-point-1 and .. Quartz-roth-ferrihydrite, 81 2. a) Synthèse d " un assemblage quartz-goethite selon la méthode par, adsorption, p.81

M. Materials, 131 Synthesis of Goethite-Coated Sand (GCS), 131 Synthesis of Hematite-Coated Sand (HCS), p.131

D. Chapitre, .. Sorption-et-transport-du-salicylate-et-du-gentisate-sur-les-matériaux-quartz-oxyde-de-fer, I. A-)-cinétique, and .. , 163 I. Quantification du salicylate et du gentisate en solution 165 II Etude en batch des équilibres d " adsorption 166 II. B) 167 II. C) Saut de sorption 169 II. D) Dissolution des oxydes de fer en présence d " anions complexant le fer en solution 169 III. Manipulation d " adsorption en colonne 171 III. C) Interaction de l " acide salicylique avec le quartz seul, 171 III. A) Dissolution des oxydes de 171 III. B) Quantification du salicylate et du gentisate en solution 172 III. D) Détermination de la charge de surface et de la densité de sites réactifs de surface 173 III. E) Remarque à propos du pH, p.174

.. Batch, 181 1. a) Equilibration times 182 1. b) Equilibrium sorption experiments, p.182

D. Results, 188 3.1. Batch experiments 188 3.1.1. The effect of time, pH value and SA concentration on salicylate sorption, 188 3.1.2. Spectroscopic investigations and modeling approach

.. Environmental, 202 IV. A) Principaux résultats de cette étude 203 IV. C) Comparaison de la cinétique d " adsorption de SA sur la goethite et sur, 203 IV. B) Extraction du salicylate sorbé et dosage de la quantité. 203 IV. D) Rôle du fer dissous, p.205

.. Sorption-du-salicylate-sur-hcs-en-colonne, 207 VI. Reactive transport of gentisic acid in a hematite-coated sand column: Experimental study and modeling, p.208

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C. Discrepancy-between-batch, 236 3.3.1 Relevance of the difference between batch and column experiments 236 3.3.2. The kinetics hypothesis 237 3.3.3. The differences in sorption mechanisms The change in sorption site accessibility, p.239

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