C. A. Lundgren and R. W. Murray, Microporous glass films as support media for electroactive films on electrodes, Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, vol.227, issue.1-2, pp.1-2, 1987.
DOI : 10.1016/0022-0728(87)80087-6

S. Sampath, Sol-gel materials in electrochemistry, Chem. Mater, vol.9, issue.11, pp.2354-2375, 1997.

M. M. Collinson, Analytical applications of organically modified silicates, Mikrochimica Acta, vol.34, issue.10
DOI : 10.1117/12.132043

A. Walcarius, Analytical Applications of Silica-Modified Electrodes -A Comprehensive Review, Electroanalysis, vol.14, issue.39, pp.1217-1235, 1998.
DOI : 10.1557/PROC-180-961

J. Wang, Sol???gel materials for electrochemical biosensors, Analytica Chimica Acta, vol.399, issue.1-2, pp.1-2, 1999.
DOI : 10.1016/S0003-2670(99)00572-3

A. Walcarius, Electrochemical Applications of Silica-Based Organic???Inorganic Hybrid Materials, Chemistry of Materials, vol.13, issue.10, pp.3351-3372, 2001.
DOI : 10.1021/cm0110167

M. M. Collinson, Recent trends in analytical applications of organically modified silicate materials, TrAC Trends in Analytical Chemistry, vol.21, issue.1, pp.30-38, 2002.
DOI : 10.1016/S0165-9936(01)00125-X

G. Shustak, S. Marx, I. Turyan, and D. Mandler, Application of Sol-Gel Technology for Electroanalytical Sensing, Electroanalysis, vol.48, issue.5-6, pp.5-6, 2003.
DOI : 10.1021/jf000118z

P. Audebert, A. Walcarius, A. M. Gomez-romero-walcarius, and O. Lev, Electrochemistry of sol-gel hybrid materials Electrochemistry of silicate-based nanomaterials. Encyclopedia of Nanoscience and Nanotechnologiy Exciting new directions in the intersection of functionalized sol-gel materials with electrochemistry, Organic- Inorganic Materials, pp.172-209, 2004.

A. Walcarius, L. Rabinovich, O. Lev, B. L. Su, and L. Lamberts, Impact of mesoporous silica-based materials on electrochemistry and feedback from electrochemical science to the characterization of these ordered materials Sol-gel derived composite ceramic carbon electrodes Electrochemical evaluation of polysiloxane-immobilized amine ligands for the accumulation of copper(II) species, C. R. Chimie Electroanalysis Walcarius, A.; Luthi, N.; Blin, J. L Electrochim. Acta, vol.8, issue.1425, pp.693-712, 1999.

S. Sayen, M. Etienne, J. Bessière, and A. Walcarius, Tuning the Sensitivity of Electrodes Modified with an Organic-Inorganic Hybrid by Tailoring the Structure of the Nanocomposite Material, Electroanalysis, vol.14, issue.21, pp.14-1521, 2002.
DOI : 10.1002/1521-4109(200211)14:21<1521::AID-ELAN1521>3.0.CO;2-7

A. Walcarius, M. Etienne, S. Sayen, and B. Lebeau, Grafted silicas in electroanalysis : Amorphous versus ordered mesoporous materials Dipeptidefunctionalized mesoporous silica spheres, Electroanalysis Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol.15, issue.17, pp.414-421, 2003.

A. Bibby and L. Mercier, Mercury(II) Ion Adsorption Behavior in Thiol-Functionalized Mesoporous Silica Microspheres, Chemistry of Materials, vol.14, issue.4, pp.14-1591, 2002.
DOI : 10.1021/cm0112082

M. Etienne, S. Sayen, B. Lebeau, A. Walcarius, J. Brown et al., Organically-modified mesoporous silica spheres with MCM-41 architecture as sorbents for heavy metals Studies in Surface Science and Catalysis Selective adsorption of Hg 2+ by thiolfunctinalized nanoporous silica Rate of access to the binding sites in organically modified silicates. 1. Amorphous silica gels grafted with amine or thiol groups, Chem. Commun. Walcarius, A Chem. Mater, vol.141, issue.376, pp.615-622, 1999.

C. Delacote, Etudes électroanalytiques de processus de transfert de matière et de charge au sein de silices mésoporeuses organiquement modifiées. Université Henri-Poincaré, 2005.

J. Patarin, Synthesis and characterization of mesoporous silicas functionalized by thiol groups, and applications as sorbents for mercury(II) Studies in Surface Science and Catalysis, pp.925-932, 2005.

A. Walcarius, M. Etienne, and C. Delacote, Uptake of inorganic HgII by organically modified silicates: influence of pH and chloride concentration on the binding pathways and electrochemical monitoring of the processes, Analytica Chimica Acta, vol.508, issue.1, pp.87-98, 2004.
DOI : 10.1016/j.aca.2003.11.055

C. T. Kresge, M. E. Leonowicz, W. J. Roth, J. C. Vartuli, and J. S. Beck, Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism, Nature, vol.359, issue.6397, pp.359-710, 1992.
DOI : 10.1038/359710a0

J. L. Schlenker, A new family of mesoporous molecular sieves prepared with liquid crystals templates, J. Am. Chem. Soc, vol.114, issue.27, pp.10834-10843, 1992.

A. Walcarius, Electroanalysis with pure, chemically modified, and sol-gel-derivated silica-based materials, Electroanalysis, vol.13, pp.8-9, 2001.

W. Yantasee, Y. Lin, G. E. Fryxell, and B. J. Busche, Simultaneous detection of cadmium, copper, and lead using a carbon paste electrode modified with carbamoylphosphonic acid self-assembled monolayer on mesoporous silica (SAMMS), Analytica Chimica Acta, vol.502, issue.2, pp.502-207, 2004.
DOI : 10.1016/j.aca.2003.10.001

L. Li, W. Li, C. Sun, and L. Li, Fabrication of Carbon Paste Electrode Containing 1:12 Phosphomolybdic Anions Encapsulated in Modified Mesoporous Molecular Sieve MCM-41 and Its Electrochemistry, Electroanalysis, vol.20, issue.5, pp.14-368, 2002.
DOI : 10.1246/bcsj.57.597

Y. Jiang, N. Ding, S. Sun, M. Alvaro, B. Ferrer et al., Enhanced IR absorption of CO adsorbed on Pd nanoparticles embedded in the mesoporous molecular sieve SBA-15 Electrochemistry of mesoporous organosilica of MCM-41 type containing 4,4'-bipyridinium units: Voltammetric response and electrocatalytic effect on 1,4-dihydrobenzoquinone oxidation, J. Electroanal. Chem. Domenech, A J. Phys. Chem. B, vol.563, issue.10746, pp.15-21, 2003.

L. Washmon-kriel, V. L. Jimenez, and K. J. Balkus, Cytochrome c immobilization into mesoporous molecular sieves, Journal of Molecular Catalysis B: Enzymatic, vol.10, issue.5, pp.453-469, 2000.
DOI : 10.1016/S1381-1177(99)00123-X

Z. Dai, S. Liu, H. Ju, and H. Chen, Direct electron transfer and enzymatic activity of hemoglobin in a hexagonal mesoporous silica matrix, Biosensors and Bioelectronics, vol.19, issue.8, pp.861-867, 2004.
DOI : 10.1016/j.bios.2003.08.024

P. Innocenzi, A. Martucci, M. Guglielmi, A. Bearzotti, and E. Traversa, Electrical and structural characterisation of mesoporous silica thin films as humidity sensors, Sensors and Actuators B: Chemical, vol.76, issue.1-3
DOI : 10.1016/S0925-4005(01)00590-1

P. Innocenzi, A. Martucci, M. Guglielmi, A. Bearzotti, E. Traversa et al., Mesoporous silica thin films for alcohol sensors, Journal of the European Ceramic Society, vol.21, issue.10-11, pp.10-11, 2001.
DOI : 10.1016/S0955-2219(01)00156-X

URL : https://hal.archives-ouvertes.fr/in2p3-00010538

J. M. Bertolo, A. Bearzotti, P. Falcaro, E. Traversa, and P. Innocenzi, Sensoristic applications of self-assembled mesostructured silica films Sensor Letters Humidity sensors based on mesoporous silica thin films synthesised by block copolymers, Journal of the European Ceramic Society, vol.1, issue.16, pp.64-70, 2003.

C. J. Brinker, G. W. Scherer, C. Sanchez, F. Ribot, P. Grobet et al., The physics and chemistry of sol-gel processing Design of hybrid organic-inorganic materials synthesized via sol-gel chemistry The physisorption and condensation of aminosilanes on silica gel Hybrid inorganic-organic mesoporous silicates -nanoscopic reactors coming of age, New Journal of Chemistry Vrancken, K. C.; Van der Voort, P.; Possemiers, K Melde, B. J. Adv. Mater, vol.18, issue.58, pp.1007-1047, 1990.

S. L. Burkett, S. D. Sims, and S. Mann, Synthesis of hybrid inorganic???organic mesoporous silica by co-condensation of siloxane and organosiloxane precursors, Chem. Commun., vol.4, issue.11, pp.1367-1368, 1996.
DOI : 10.1016/0927-6513(94)00077-9

D. J. Macquarrie, Direct preparation of organically modified MCM-type materials. Preparation and characterization of aminopropyl-MCM and 2-cyanoethyl-MCM, Chem. Commun, vol.16, pp.1961-1962, 1996.

B. Lebeau and C. Sanchez, Sol-gel derived hybrid inorganic-organic nanocomposites for optics. Current Opinion in Solid State and Materials Science, pp.11-23, 1999.

C. Sanchez, B. Lebeau, F. Ribot, and M. In, Molecular design of sol-gel derived hybrid organic-inorganic nanocomposites, Journal of Sol-Gel Science and Technology, vol.19, issue.1/3, pp.31-38, 2000.
DOI : 10.1023/A:1008753919925

D. L. Wetzel, J. Striova, D. A. Higgins, and M. M. Collinson, Synchrotron infrared microspectroscopy reveals localized heterogeneities in an organically modified silicate film, Vibrational Spectroscopy, vol.35, issue.1-2, pp.1-2, 2004.
DOI : 10.1016/j.vibspec.2003.12.018

Y. Fu, M. M. Collinson, and D. A. Higgins, Single-Molecule Spectroscopy Studies of Microenvironmental Acidity in Silicate Thin Films, Journal of the American Chemical Society, vol.126, issue.42, pp.126-13838, 2004.
DOI : 10.1021/ja046527j

S. A. Martin-brown, Y. Fu, G. Saroja, M. M. Collinson, and D. A. Higgins, Singlemolecule studies of diffusion by oligomer-bound dyes in organically modified sol-gel-derived silicate films, Anal. Chem, issue.2, pp.77-486, 2005.

G. Wu, J. Wang, J. Shen, T. Yang, Q. Zhang et al., A new method to control nano-porous structure of sol-gel-derived silica films and their properties, Materials Research Bulletin, vol.36, issue.12, pp.36-2127, 2001.
DOI : 10.1016/S0025-5408(01)00691-2

A. Doménech, M. T. Doménech-carbo, E. Garcia-espana, and M. D. Soriano, Voltammetric determination of trace mercury in concentrated chloride media using polymerfilm electrodes modified with polyammonium macrocyclic receptors The Analyst, pp.1661-1667, 1999.

D. A. Higgins and M. M. Collinson, Gaining Insight into the Nanoscale Properties of Sol???Gel-Derived Silicate Thin Films by Single-Molecule Spectroscopy, Langmuir, vol.21, issue.20, pp.9023-9031, 2005.
DOI : 10.1021/la050384c

S. Flink, F. C. Van-veggel, and D. N. Reinhoudt, Self-assembled Monolayers on Gold for Applications in Chemical Sensing, Sensors Update, vol.8, issue.1, pp.3-19, 2000.
DOI : 10.1002/1616-8984(200011)8:1<3::AID-SEUP3>3.0.CO;2-X

R. K. Smith, P. A. Lewis, and P. S. Weiss, Patterning self-assembled monolayers, Progress in Surface Science, vol.75, issue.1-2, pp.751-753, 2004.
DOI : 10.1016/j.progsurf.2003.12.001

W. R. Thompson and J. E. Pemberton, Thin Sol-Gel Silica Films on (3-Mercaptopropyl)trimethoxysilane-Modified Ag and Au Surfaces, Chemistry of Materials, vol.7, issue.1, pp.130-136, 1995.
DOI : 10.1021/cm00049a020

J. Wang, P. V. Pamidi, and D. R. Zanette, Self-Assembled Silica Gel Networks, Journal of the American Chemical Society, vol.120, issue.23, pp.5852-5853, 1998.
DOI : 10.1021/ja9742747

A. Ulman, Formation and Structure of Self-Assembled Monolayers, Chemical Reviews, vol.96, issue.4, pp.1533-1554, 1996.
DOI : 10.1021/cr9502357

V. M. Mirsky, New electroanalytical applications of self-assembled monolayers, TrAC Trends in Analytical Chemistry, vol.21, issue.6-7, pp.6-7, 2002.
DOI : 10.1016/S0165-9936(02)00601-5

B. Mihailova, V. Engström, J. Hedlund, A. Holmgren, and J. Sterte, Infrared spectroscopic study of a ??-mercaptopropyltrimethoxysilane monolayer on a gold surface, Journal of Materials Chemistry, vol.9, issue.7
DOI : 10.1039/a903577j

Y. Kim, R. L. Mccarley, and A. J. Bard, Observation of n-octadecanethiol multilayer formation from solution onto gold, Langmuir, vol.9, issue.8, pp.1941-1944, 1993.
DOI : 10.1021/la00032a001

T. W. Schneider and D. A. Buttry, Electrochemical quartz crystal microbalance studies of adsorption and desorption of self-assembled monolayers of alkyl thiols on gold, Journal of the American Chemical Society, vol.115, issue.26
DOI : 10.1021/ja00079a021

H. M. Schessler, D. S. Karpovich, and G. J. Blanchard, Quantitating the Balance between Enthalpic and Entropic Forces in Alkanethiol/Gold Monolayer Self Assembly, Journal of the American Chemical Society, vol.118, issue.40, pp.118-9645, 1996.
DOI : 10.1021/ja961565r

K. S. Choi, H. C. Lichtenegger, G. D. Stucky, and E. W. Mcfarland, Electrochemical synthesis of nanostructured ZnO films utilizing self-assembly of surfactant molecules at solidliquid Interfaces, J. Am. Chem. Soc, issue.42, pp.124-12402, 2002.

J. R. Owen, Nanostructured platinum (HI-ePt) films: Effects of electrodeposition conditions on film properties, Chem. Mater, issue.1112, pp.3602-3609, 1999.

P. R. Birkin, J. M. Elliott, and Y. E. Watson, Electrochemical reduction of oxygen on mesoporous platinum microelectrodes, Chemical Communications, issue.17, pp.1693-1694, 2000.
DOI : 10.1039/b004468g

S. A. Evans, J. M. Elliott, L. M. Andrews, P. N. Bartlett, P. J. Doyle et al., Detection of Hydrogen Peroxide at Mesoporous Platinum Microelectrodes, Analytical Chemistry, vol.74, issue.6, pp.74-1322, 2002.
DOI : 10.1021/ac011052p

J. M. Elliott, P. R. Birkin, P. N. Bartlett, and G. S. Attard, Platinum Microelectrodes with Unique High Surface Areas, Langmuir, vol.15, issue.22, pp.7411-7415, 1999.
DOI : 10.1021/la9908945

P. N. Bartlett and J. Marwan, -e) Layers of Two Metals in Which Pores within the Two Layers Interconnect, Chemistry of Materials, vol.15, issue.15, pp.15-2962, 2003.
DOI : 10.1021/cm0210400

M. Etienne, B. Lebeau, and A. Walcarius, Organically-modified mesoporous silica spheres with MCM-41 architecture, New Journal of Chemistry, vol.26, issue.4, pp.384-386, 2002.
DOI : 10.1039/b110741k

S. Sayen and A. Walcarius, Electro-assisted generation of functionalized silica films on gold, Electrochemistry Communications, vol.5, issue.4, pp.341-348, 2003.
DOI : 10.1016/S1388-2481(03)00065-1

M. Etienne, A. Quach, D. Grosso, L. Nicole, C. Sanchez et al., Molecular transport into mesostructured silica thin films: Electrochemical monitoring and comparison between p6m, P6 3 /mmc, and Pm3n structures Fundamentals of mesostructuring through evaporation-induced self-assembly, Chem. Mater. Grosso, D.; Cagnol, F Adv. Funct. Mater, vol.11, issue.4, pp.14-309, 2004.

L. Nicole, C. Boissière, D. Grosso, A. Quach, C. Sanchez et al., Mesostructured hybrid organic-inorganic thin films Deposition of thin nanoporous silica layers on solid surfaces Deposition of thin mesoporous silica films on glass substrates from basic solution, J. Mater. Chem Chem. Mater. Journal of Colloid and Interface Science, vol.15, issue.141, pp.3598-3627, 2005.

M. Palomar-pardave, Electrochemical deposition of cetyltrimethylammonium surface hemimicelles at the Hg/0.1 M NaCl[sub (aq)] interface, J. Electrochem. Soc, issue.10, pp.151-666, 2004.

E. Sibottier, S. Sayen, F. Gaboriaud, and A. Walcarius, Factors Affecting the Preparation and Properties of Electrodeposited Silica Thin Films Functionalized with Amine or Thiol Groups, Langmuir, vol.22, issue.20, pp.8366-8373, 2006.
DOI : 10.1021/la060984r

M. Etienne, J. Cortot, A. Walcarius, A. D. Ryabov, A. Amon et al., Preconcentration electroanalysis at surfactanttemplated thiol-functionalized silica thin films Mechanism of a "jumping off" ferricinium in glucose oxidase-D-glucose-ferrocene micellar electrochemical system, Electroanalysis J. Phys. Chem, vol.1923, issue.1838, pp.129-138, 1995.

R. K. Iler, The Chemistry of silica, 1979.

M. Etienne, A. Walcarius, A. Walcarius, M. Etienne, B. Lebeau et al., Evaporation induced self-assembly of templated silica and organosilica thin films on various electrode surfaces Rate of acces to the binding sites in organically modified silica. 2. Ordered mesoporous silica grafted with amine or thiol groups Phase and orientation control of mesoporous silica thin film via phase transformation, Electrochem. Commun. Chem. Mater. Naik, S. P.; Ogura, M Thin Solid Films, vol.21, issue.22, pp.1449-1456, 2003.

M. Matheron, A. Bourgeois, A. Brunet-bruneau, P. A. Albouy, J. Biteau et al., Highly ordered CTAB-templated organosilicate films, Journal of Materials Chemistry, vol.14, issue.12, pp.4741-4745, 2005.
DOI : 10.1039/b510554d

URL : https://hal.archives-ouvertes.fr/hal-01281574

A. Yamaguchi, Self-assembly of a silica???surfactant nanocomposite in a porous alumina membrane, Nature Materials, vol.17, issue.5, pp.337-341, 2004.
DOI : 10.1080/01496398208068547

C. J. Brinker, D. R. Dunphy, A. Walcarius, and E. Sibottier, Morphological control of surfactant-templated metal oxide films, Current Opinion in Colloid & Interface Science, vol.11, issue.2-3, pp.126-132, 2005.
DOI : 10.1016/j.cocis.2005.10.006

R. Shacham, D. Avnir, D. Mandler, P. N. Deepa, M. Kanungo et al., Electrodeposition of methylated sol-gel films on conducting surfaces Electrochemically deposited sol-gel-derived silicate films as a viable alternative in thin-film design, 5399-5405. 29. Burges, I.; al., e., Direct visualization of the potential-controlled transformation of hemimicellar aggregates of dodecyl sulfate into a condensed monolayer at the Au(111) electrode surface Langmuir, pp.384-388, 1999.

K. S. Choi, E. W. Mcfarland, and G. D. Stucky, Electrocatalytic properties of thin mesoporous platinum films synthesized utilizing potential-controlled surfactant assembly

A. M. Massari, R. W. Gurney, C. P. Schwartz, S. T. Nguyen, and J. T. Hupp, Walljet Electrochemistry:?? Quantifying Molecular Transport through Metallopolymeric and Zirconium Phosphonate Assembled Porphyrin Square Thin Films, Langmuir, vol.20, issue.11, pp.4422-4429, 2004.
DOI : 10.1021/la049900+

E. Sibottier, S. Sayen, F. Gaboriaud, and A. Walcarius, Factors Affecting the Preparation and Properties of Electrodeposited Silica Thin Films Functionalized with Amine or Thiol Groups, Langmuir, vol.22, issue.20, pp.8366-8373, 2006.
DOI : 10.1021/la060984r

A. Walcarius, E. Sibottier, M. Etienne, and J. Ghanbaja, Electrochemically assisted self-assembly of mesoporous silica thin films, Nature Materials, vol.72, issue.4, pp.602-608, 2007.
DOI : 10.1016/j.crci.2004.10.003

URL : https://hal.archives-ouvertes.fr/hal-01343998

A. J. Bard and M. V. Mirkin, Scanning electrochemical microscopy, 2001.

D. Mandler and A. J. Bard, Scanning Electrochemical Microscopy: The Application of the Feedback Mode for High Resolution Copper Etching, Journal of The Electrochemical Society, vol.136, issue.10, pp.136-3143, 1989.
DOI : 10.1149/1.2096416

D. Mandler and A. J. Bard, A New Approach to the High Resolution Electrodeposition of Metals via the Feedback Mode of the Scanning Electrochemical Microscope, Journal of The Electrochemical Society, vol.137, issue.4
DOI : 10.1149/1.2086606

S. Meltzer and D. Mandler, Microwriting of Gold Patterns with the Scanning Electrochemical Microscope, Journal of The Electrochemical Society, vol.142, issue.6, pp.142-82, 1995.
DOI : 10.1149/1.2044252

C. He?, K. Borgwarth, C. Ricken, D. G. Ebling, and J. Heinze, Scanning electrochemical microscopy: Study of silver deposition on non-conducting substrates, Electrochimica Acta, vol.42, issue.20-22, pp.4220-4242, 1997.
DOI : 10.1016/S0013-4686(97)00154-0

E. Amman and D. Mandler, Local Deposition of Gold on Silicon by the Scanning Electrochemical Microscope, Journal of The Electrochemical Society, vol.31, issue.8, pp.148-533, 2001.
DOI : 10.1002/9783527614936

Y. Yatziv, I. Turyan, and D. Mandler, A New Approach to Micropatterning:?? Application of Potential-Assisted Ion Transfer at the Liquid???Liquid Interface for the Local Metal Deposition, Journal of the American Chemical Society, vol.124, issue.20, pp.124-5618, 2002.
DOI : 10.1021/ja0257826

I. Turyan, M. Etienne, D. Mandler, and W. Schuhmann, Improved Resolution of Local Metal Deposition by Means of Constant Distance Mode Scanning Electrochemical Microscopy, Electroanalysis, vol.16, issue.5-6, pp.5-6, 2005.
DOI : 10.1201/9780203910771

Y. M. Wuu, F. R. Fan, and A. J. Bard, High resolution of polyaniline on platinum with the scanning electrochemical microscope, J. Electrochem. Soc, issue.3, pp.136-885, 1989.

C. Kranz, M. Ludwig, E. Herrmann, and W. Schuhmann, Lateral deposition of polypyrrole lines by means of the scanning electrochemical microscope, Advanced Materials, vol.61, issue.1, pp.38-40, 1995.
DOI : 10.1007/978-1-4613-3309-8

C. Kranz, M. Ludwig, E. Herrmann, and W. Schuhmann, Lateral deposition of polypyrrole lines over insulating gaps. Towards the development of polymer-based electronic devices, Advanced Materials, vol.2, issue.6, pp.568-571, 1995.
DOI : 10.1002/adma.19950070613

C. Kranz, H. E. Gaub, and W. Schuhmann, Polypyrrole towers grown with the scanning electrochemical microscope, Advanced Materials, vol.137, issue.8, pp.634-637, 1996.
DOI : 10.1002/bbpc.19940981016

W. Schuhmann, C. Kranz, H. Wohlschlager, and J. Strohmeier, Pulse technique for the electrochemical deposition of polymer films on electrode surfaces, Biosensors and Bioelectronics, vol.12, issue.12, pp.1157-1167, 1997.
DOI : 10.1016/S0956-5663(97)00086-9

J. Zhou and D. O. Wipf, Deposition of Conducting Polyaniline Patterns with the Scanning Electrochemical Microscope, Journal of The Electrochemical Society, vol.144, issue.4, pp.1202-1207, 1997.
DOI : 10.1149/1.1837573

C. Kranz, G. Wittstock, H. Wohlschlager, and W. Schuhmann, Imaging of microstructured biochemically active surfaces by means of scanning electrochemical microscopy, Electrochimica Acta, vol.42, issue.20-22, pp.4220-4242, 1997.
DOI : 10.1016/S0013-4686(97)00158-8

I. Shohat and D. Mandler, Deposition of Nickel Hydroxide Structures Using the Scanning Electrochemical Microscope, Journal of The Electrochemical Society, vol.141, issue.4, pp.141-995, 1994.
DOI : 10.1149/1.2054870

I. Turyan, U. O. Krasovec, B. Orel, T. Saraidorov, R. Reisfeld et al., ???Writing???Reading???Erasing??? on Tungsten Oxide Films Using the Scanning Electrochemical Microscope, Advanced Materials, vol.12, issue.5, pp.12-330, 2000.
DOI : 10.1002/(SICI)1521-4095(200003)12:5<330::AID-ADMA330>3.0.CO;2-8

H. Shiku, T. Takeda, H. Yamada, T. Matsue, and I. Uchida, Microfabrication and Characterization of Diaphorase-Patterned Surfaces by Scanning Electrochemical Microscopy, Analytical Chemistry, vol.67, issue.2, pp.67-312, 1995.
DOI : 10.1021/ac00098a014

H. Shiku, I. Uchida, and T. Matsue, Microfabrication of Alkylsilanized Glass Substrate by Electrogenerated Hydroxyl Radical Using Scanning Electrochemical Microscopy, Langmuir, vol.13, issue.26, pp.7239-7244, 1997.
DOI : 10.1021/la970554o

G. Wittstock and W. Schuhmann, Formation and Imaging of Microscopic Enzymatically Active Spots on an Alkanethiolate-Covered Gold Electrode by Scanning Electrochemical Microscopy, Analytical Chemistry, vol.69, issue.24, pp.69-5059, 1997.
DOI : 10.1021/ac970504o

I. Turyan, T. Matsue, and D. Mandler, Patterning and Characterization of Surfaces with Organic and Biological Molecules by the Scanning Electrochemical Microscope, Analytical Chemistry, vol.72, issue.15, pp.72-3431, 2000.
DOI : 10.1021/ac000046a

T. Wilhelm and G. Wittstock, Localised electrochemical desorption of gold alkanethiolate monolayers by means of scanning electrochemical microscopy (SECM)

E. Fortin, P. Mailley, L. Lacroix, and S. Szunerits, Imaging of DNA hybridization on microscopic polypyrrole patterns using scanning electrochemical microscopy (SECM): the HRP bio-catalyzed oxidation of 4-chloro-1-naphthol, The Analyst, vol.406, issue.5, pp.131-186, 2006.
DOI : 10.1016/S0003-2670(99)00630-3

URL : https://hal.archives-ouvertes.fr/hal-00333713

E. M. Un-système-d-richter, M. A. Augelli, and G. H. Kume, CD) a été conçu 1-3 . La fine couche d'or présente sur le CD peut être utilisée en électrochimie 1, 3-5 . C'est en effet une source d'or peu coûteuse qui permet une production d'électrodes d'or en grandes quantités par le biais d'une mise en oeuvre simple et compatible avec différents types 1, Gold electrodes from recordable CDs, pp.72-5503, 2000.

H. Yu, Self-Assembly on ???Recordable CDs???, Analytical Chemistry, vol.73, issue.19, pp.4743-4747, 2001.
DOI : 10.1021/ac015521z

D. Daniel and I. G. Gutz, Quick production of gold electrode sets or arrays and of microfluidic flow cells based on heat transfer of laser printed toner masks onto compact discs, Electrochemistry Communications, vol.5, issue.9, pp.5-782, 2003.
DOI : 10.1016/j.elecom.2003.07.004

E. M. Richter, M. A. Augelli, G. H. Kume, R. N. Mioshi, and L. Angnes, Gold electrodes from recordable CDs for mercury quantification by flow injection analysis, Fresenius' Journal of Analytical Chemistry, vol.366, issue.5
DOI : 10.1007/s002160050090

E. M. Richter, M. A. Augelli, and L. Angnes, Compact disks, a new source for gold Eeectrodes. Application to the quantification of copper by PSA, Electroanalysis, vol.13, pp.8-9, 2001.

C. A. Goss, D. H. Charych, and M. Majda, Application of (3- mercaptopropyl)trimethoxysilane as a molecular adhesive in the fabrication of vapordeposited gold electrodes on glass substrates, Anal. Chem, issue.1, pp.63-85, 1991.

K. C. Grabar, R. G. Freeman, M. B. Hommer, and M. J. Natan, Preparation and Characterization of Au Colloid Monolayers, Analytical Chemistry, vol.67, issue.4, pp.67-735, 1995.
DOI : 10.1021/ac00100a008

M. Kambayashi, J. Zhang, and M. Oyama, Crystal Growth of Gold Nanoparticles on Indium Tin Oxides in the Absence and Presence of 3-Mercaptopropyl-trimethoxysilane, Crystal Growth & Design, vol.5, issue.1, pp.81-84, 2005.
DOI : 10.1021/cg0499156

W. R. Thompson and J. E. Pemberton, Thin Sol-Gel Silica Films on (3-Mercaptopropyl)trimethoxysilane-Modified Ag and Au Surfaces, Chemistry of Materials, vol.7, issue.1, pp.130-136, 1995.
DOI : 10.1021/cm00049a020

F. Bedioui, . Voltampérométrie, T. Théorie-et-mise-en-oeuvre-expérimentale, and F. Bedioui, Microbalance à quartz Scanning electrochemical microscopy assessment of rates of molecular transport through mesoporous thin-films of porphyrinic "molecular squares, Bedioui, F., Voltampérométrie. Perfectionnement des techniques J. Phys. Chem. B, vol.3, issue.222037, pp.2126-2137, 1999.

M. E. Williams, K. J. Stevenson, A. M. Massari, and J. T. Hupp, Imaging Size-Selective Permeation through Micropatterned Thin Films Using Scanning Electrochemical Microscopy, Analytical Chemistry, vol.72, issue.14, pp.72-3122, 2000.
DOI : 10.1021/ac9914622

M. E. Williams, K. D. Benkstein, C. Abel, P. H. Dinolfo, and J. T. Hupp, Supramolecular chemistry and self-assembly special feature: shape-selective transport through rectangle-based molecular materials: thin-film scanning electrochemical microscopy studies Electrochemical methods : fundamentals and applications, pp.5171-5177, 2001.