.. Alliages-coulés-par-gravitéélaboration, 102 III.2.2.a. Alliages dans des conditions de coeur (polis), Chronoampérométrie, p.105

.. De-masse, 111 III.3.1. Tests d'immersion dans l'eau, ., p.114

(. Revêtement-réalisé-dans-un-bain-contenant-du-ce, Aspect microstructural : morphologie et composition globale, ., p.136

!. Ade, *. Mesbah, !. U. Carolineinha, . Orr-7555, and . Unl, l.aboriJtoiN' J, Chlmù dM Soli&, rj Poin<:ad. Nan')' 1. Fa",I,1 &.. Sc~n"'?. BP 239
URL : https://hal.archives-ouvertes.fr/hal-01143191

. Ofll, . Iwo-n-<-!-el<flni, X. Ily, and . Ocli, Single crY<lal dala: Mg(C7) P2, )'. V .. 1800.3(15) Â', D... 1.242 F",-J. Z = 4. S}'ll<hrolrOl' powde

). Â. {j and M. .. , 85(8) A', D. _ 1.188 gc TI..i, layerai "'uClure' are q uile ,imilar and dilfe-r niai nly Ily 11 of Iwo plalleS of ().oclaho:l,a celllred Ily Mg am The diOI1o:1 oclahedra are C"'''liluled Ily lllrtt oxyg..., al"'''' rrom carboxylale groo ft' aIl<! Ily lh...e oxI:I,. TI.. carbo.ylale dlain, are localed I Ali rigl, lenglh of 11.. hydrG]>llObic cilai".. TI.. yc ooming from wale' mol..,ule .. TI.. lay.,., are 001' 1=10:1 Ily hydrog..., Il,dicu larly aIl<! CIl' 11011\ ,i<le, of 1IleSe planes. 0,, ca,bo.ylate cllain i, bridging Il.. Mg mom al""g [0101 while lbe olher, p.1

. Coo-noli, <:: 6) form film, al lhe memllic 'urfaoe and act a, corm,ion hallier" A moddling of rocmll M(CtI), '" rocml oxidiseJ/M(CtI), imi.'rfaoe ,hould enable 10 un- dl'[1;land, on an momic scale, thc mcehani,m of pmli.OClion again'l c",m,ion of 'ludied mcml" 11 requir..., lhc knowlcdge of lhe cT)"mllographic 'lructuri.... of lhe hydmphobic and pmli.OClivc roclal 'oap', For thi, rea'on, the crptallographic 'lructuri, ll) ? COffesponding aut~. Tel.: +33 3 AdelMesball@lc",u"'j>-oaJlry-f'(A. Mesball), pp.68-72

. 129l-~5-ho and M. .. El, SAS AU righl. t=rved doU IJlll1 Nj. .. I':I.~aIe><"n=12.007 hepmnoate, which are lhe meml sah, pmli.ocling zinc and lead 'urfaoe, re'Jl'Cctively, were previou,ly dClermined, Duc 10 thcir low dcn'ily, magnesium allop are vcl)' pmmi'ing a, regard' applicalion' in acronaulical and aUlOmolivc indu'lri Thcir dcvdopmem i, braked bccauSl: of their poor co",,ion resi,mnce.. Thl.,-cfore addilional 'urface lremmem ,howed lhal 'odium carboxylate' are environrocmally 'af~ candidate' 10 'Ub'lilUle chmmale in 'urfaoe lremmem of rapidly 'olidified magnesium-aluminium-zinc allop in neulral aqueou' 'olulion', The pmli, 2006.

(. For-mg-(-c-'th and C. I. , 98.39" for MglCIOh) The la)~ ~ c=tred by ....·0 planes of magnesium alOmS JI'll1l11d 10 (001). The SlJUC1OR"S OOIItain 1"'0 crys.tallognophicall )" indepen<knt chains named ChI and Ch2 dellned br CI" and C2n (Set Fig, pp.1-7

. .. Luoo and . P<ukiio, ? 12), pp.5-2000

X. Roceming and 1. Paf, .y diff<a<1ioo dala co~ I"".d in M<illation n>odo. in, CW. Cart Mac_ ,.",>nl.rulat Cry, M<thodo in EIIzymology. 001. 276- >\cadomic Pt=.I997.pp, p.7

G. M. Sh<ldrid, . Sh-el, _. St, R. 'lu<, and . Tin<, Rotin<m<n' of Cry, 1997.

M. N. Umaon, J. 11.1'1'1 CrystaUog?, pp.6-200

L. W22-bemnline, avaible l'rom hnp

B. Schmin, pflysics research, section A 501, p.267, 2003.

. Baril, Etude par spectroscopie d'impédance électrochimique des mécanismes de corrosion des alliages de magnésium AM50

M. Bernard, Cours de chimie minérale. Deuxième édition. Paris : Dunod, 1994. Page 326

F. H. Froes, D. Eliezer, and E. Aghion, The science, technology, and applications of magnesium, JOM, vol.119, issue.6, pp.30-34, 1998.
DOI : 10.5006/0010-9312-10.6.182

D. Daloz, Propriétés mécaniques et tenue à la corrosion d'alliages Mg-Zn-Al élaborés par solidification rapide et consolidés par extrusion, Thèse. Sciences. 1995. Institut National Polytechnique de Lorraine. utre ou basique Thèse. Sciences. 1996. niversité Paris XI

D. L. Hawke, Galvanic corrosion of magnesium. Dans : SDCE, 14 th International Die Casting Congress and Exposition, pp.6-87, 1987.

F. Decker, The renaissance in magnesium Advanced Materials and Processes, pp.31-33, 1998.

R. Bothwell, The corrosion of light metals, p.257, 1967.

G. Perrault, The potential-pH diagram of the magnesium-water system, Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, vol.51, issue.1, pp.107-119, 1974.
DOI : 10.1016/S0022-0728(74)80298-6

G. Perrault, Variations du potentiel de repos de l'électrode de magnésium en fonction du pH : solutions concentrées d'acétate de potassium

G. Perrault, Potentiostatic study of the magnesium electrode in aqueous solution, Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, vol.27, issue.1, pp.47-58, 1970.
DOI : 10.1016/S0022-0728(70)80201-7

A. Song and . Atrens, Corrosion Mechanisms of Magnesium Alloys, Advanced Engineering Materials, vol.1, issue.1, pp.1-11, 1999.
DOI : 10.1002/(SICI)1527-2648(199909)1:1<11::AID-ADEM11>3.0.CO;2-N

A. Song, D. Atrens, J. Stjohn, Y. Nairn, and . Li, The electrochemical corrosion of pure magnesium in 1N NaCl. Corrosion Science, pp.5-855, 1997.

. Hallopeau, Etude de l'efficacité inhibitrice d'oxoanions de type XO y n-sur la corrosion du magnésium pur et d'alliages magnésium-aluminium en milieux aqueux de pH ne

. Kouisni, Etude de la phosphatation et des phosphates formés sur la surface de l'alliage de magnésium AM60, Thèse. Sciences. 2004. Université Hassan II Aïn-Chock, faculté des sciences de Casablanca (Maroc)

. Poubaix, Atlas of electrochemical equilibria in aqueous solution. Houston (TX, E.-U.) : National association of corrosion engineers, p.141, 1974.

G. Lopez-buisan and . Natta, Evidence of two anodic processes in the polarisation curves of magnesium in aqueous media, Corrosion, vol.57, issue.8, pp.712-720, 2001.

G. Perrault, Diagramme d'équilibre potentiel-pH du magnésium : équilibres faisant intervenir les ions hydrures. Comptes rendus hebdomadaires des séances de l'académie des sciences. Série C, sciences chimiques, pp.12-1142, 1972.

G. Perrault, Complément au diagramme d'équilibre potentiel-pH du magnésium : calcul thermodynamique des équilibres faisant intervenir les hydrures de magnésium. Comptes rendus hebdomadaires des séances de l'académie des sciences. Série C, sciences chimiques, pp.25-1711, 1971.

P. Nazarov, A. P. Lisovskii, and Y. N. Mikhailovski, Magnesium dihydride formation in electrochemical dissolution of magnesium in aqueous electrolytes. Zashchita Metallov, pp.5-760, 1989.

. Gulbrandsen, Anodic behaviour of Mg in HCO 3 /CO 3 2-buffer solutions. Quasi-steady measurements

L. Makar and J. Kruger, Corrosion Studies of Rapidly Solidified Magnesium Alloys, Journal of The Electrochemical Society, vol.137, issue.2, pp.414-421, 1990.
DOI : 10.1149/1.2086455

E. Straumanis and B. K. Bhatia, Disintegration of Magnesium While Dissolving Anodically in Neutral and Acidic Solutions, Journal of The Electrochemical Society, vol.110, issue.5, pp.357-360, 1963.
DOI : 10.1149/1.2425763

J. James, M. E. Staumanis, B. K. Bhatia, and J. W. Johnson, The Difference Effect on Magnesium Dissolving in Acids, Journal of The Electrochemical Society, vol.110, issue.11, pp.11-1117, 1963.
DOI : 10.1149/1.2425601

H. Tunold, M. Holtran, A. Berge, R. Lasson, and . Steen-hansen, The corrosion of magnesium in aqueous solution containing chloride ions. Corrosion Science, pp.4-353, 1977.

L. Robinson and P. F. King, Electrochemical Behavior of the Magnesium Anode, Journal of The Electrochemical Society, vol.108, issue.1, pp.36-41, 1961.
DOI : 10.1149/1.2428007

F. King, The Role of the Anion in the Anodic Dissolution of Magnesium, Journal of The Electrochemical Society, vol.113, issue.6, pp.536-539, 1966.
DOI : 10.1149/1.2424019

N. Baril and . Pébère, The corrosion of pure magnesium in aerated and deaerated sodium sulphate solutions, Corrosion Science, vol.43, issue.3, pp.471-484, 2001.
DOI : 10.1016/S0010-938X(00)00095-0

L. Makar and J. Kruger, Corrosion of magnesium, International Materials Reviews, vol.41, issue.4, pp.138-153, 1993.
DOI : 10.1016/0025-5416(85)90328-3

M. Inoue, K. Iwai, S. Matuzawa, Y. Kamado, and . Kojima, Effect of impurities on corrosion behavior of pure magnesium in salt water environment., Journal of Japan Institute of Light Metals, vol.48, issue.6, pp.6-257, 1998.
DOI : 10.2464/jilm.48.257

A. Ferrando, Review of corrosion and corrosion control of magnesium alloys and composites, Journal of Materials Engineering, vol.40, issue.2, pp.299-313, 1989.
DOI : 10.5006/1.3583031

Y. Hara, D. Kobayashi, N. Kagaya, and . Akao, Formation and breakdown of surface films of magnesium an its alloys in aqueous solutions. Corrosion Science, pp.1-166, 2007.

A. Song, D. Atrens, X. Stjohn, J. Wu, and . Nairn, The anodic dissolution of magnesium in chloride and sulphate solutions. Corrosion Science, pp.10-11, 1997.

C. Pébère, F. Riera, and . Dabosi, Investigation of magnesium corrosion in aerated sodium sulfate solution by electrochemical impedance spectroscopy, Electrochimica Acta, vol.35, issue.2, pp.2-555, 1990.
DOI : 10.1016/0013-4686(90)87043-2

O. Augustin, Corrosion of magnesium in aqueous halides, Indian Journal of Chemical Technology, vol.1, pp.363-365, 1994.

N. N. Ambat, W. Aung, and . Zhou, Studies on the influence of chloride ion and pH on the corrosion and electrochemical behaviour of AZ91D magnesium alloy, Journal of Applied Electrochemistry, vol.30, pp.5-865, 2000.

A. Song, X. Atrens, B. Wu, and . Zhang, Corrosion behaviour of AZ21, AZ501 and AZ91 in sodium chloride. Corrosion Science, pp.10-1769, 1998.

J. Gulbrandsen, A. Taftø, and . Olsen, The passive behaviour of Mg in alkaline fluoride solutions. Electrochemical and electron microscopical investigations. Corrosion Science, pp.9-1423, 1993.

P. Daloz, G. Steinmetz, and . Michot, Corrosion behavior of rapidely solidified magnesium-aluminium-zinc alloys, Corrosion, vol.53, pp.12-944, 1997.

. Beldjoudi, Etude électrochimique du rôle de l'aluminium dans le comportement à la corrosion des alliages magnésium-aluminium en milieu neutre Na 2 SO 4 0,5 M. Caractérisation des films superficiels formés au cours du temps, Thèse. Sciences, 1995.

A. Vermilyea and C. F. Kirk, Studies of Inhibition of Magnesium Corrosion, Journal of The Electrochemical Society, vol.116, issue.11, pp.1487-1492, 1969.
DOI : 10.1149/1.2411579

H. Nordlien, S. Ono, N. Masuko, and K. Nisancioglu, Morphology and Structure of Oxide Films Formed on Magnesium by Exposure to Air and Water, Journal of The Electrochemical Society, vol.142, issue.10, pp.10-3320, 1995.
DOI : 10.1149/1.2049981

H. Nordlien, S. Ono, N. Masuko, and K. Nisancioglu, A TEM investigation of naturally formed oxide films on pure magnesium. Corrosion Science, pp.8-1397, 1997.

M. Bradford, B. Case, G. Dearnaley, J. F. Turner, and I. S. Woolsey, Ion beam analysis of corrosion films on a high magnesium alloy (Magnox AL 80) Corrosion Science, pp.10-747, 1976.

W. Ghali, K. Dietzel, and . Kainer, Testing of General and Localized Corrosion of Magnesium Alloys: A Critical Review, Journal of Materials Engineering and Performance, vol.13, issue.5, pp.5-517, 2004.
DOI : 10.1361/10599490420665

J. E. Lunder, T. Lein, . Kr, K. Aune, and . Nisancioglu, The role of Mg 17 Al 12 in the corrosion of Mg alloy AZ91. Corrosion, pp.9-741, 1989.

A. Robinson and P. F. George, Effect of Alloying and Impurity Elements In Magnesium Alloy Cast Anodes, CORROSION, vol.10, issue.6, pp.182-188, 1954.
DOI : 10.5006/0010-9312-10.6.182

T. Lunder, . Kr, K. Aune, and . Nisancioglu, Effect of Mn Additions on the Corrosion Behavior of Mould-Cast Magnesium ASTM AZ91, CORROSION, vol.43, issue.5, pp.5-291, 1987.
DOI : 10.5006/1.3583151

K. Lunder, T. K. Nisancioglu, and . Aune, Influence of alloying elements in the corrosion of cast magnesium

C. Beldjoudi, L. Fiaud, and . Robbiola, Influence of Homogenization and Artificial Aging Heat Treatments on Corrosion Behavior of Mg-Al Alloys, CORROSION, vol.49, issue.9, pp.9-738, 1993.
DOI : 10.5006/1.3316126

G. Guillaumin and . Mankowski, Localized corrosion of 6056 T6 aluminium alloy in chloride media, Corrosion Science, vol.42, issue.1, pp.105-125, 2000.
DOI : 10.1016/S0010-938X(99)00053-0

C. Baril, N. Blanc, and . Pébère, AC Impedance Spectroscopy in Characterizing Time-Dependent Corrosion of AZ91 and AM50 Magnesium Alloys Characterization with Respect to Their Microstructures, Journal of The Electrochemical Society, vol.41, issue.12, pp.12-489, 2001.
DOI : 10.1016/0013-4686(95)00462-9

Y. Wu, H. Fan, C. Gao, Y. P. Zhai, and . Zhu, The effect of Ca and rare earth elements on the microstructure, mechanical properties and corrosion behavior of AZ91D, Materials Science and Engineering A: Structural Materials -Properties, Microstructure and Processing, pp.1-2, 2005.
DOI : 10.1016/j.msea.2005.08.011

V. Zucchi, A. Grassi, . Frignani, G. Monticelli, and . Trabanelli, Electrochemical behaviour of a magnesium alloy containing rare earth elements, Journal of Applied Electrochemistry, vol.173, issue.9, pp.2-195, 2006.
DOI : 10.1007/s10800-005-9053-3

. Collot, Rh??oformage et thixoformage des alliages de magn??sium et d???aluminium : les avantages de l???induction, Matériaux et Techniques, pp.7-8, 1997.
DOI : 10.1051/mattech/199785070013

W. Pluchon, P. Y. Loue, M. Menet, and . Garat, Development of semi-solid metal forming feedstock and finished parts, Light Metals Warrendale : Minerals, Metals & Materials Society, pp.1233-1242, 1995.

. Verdier, Corrosion et protection anti-corrosion de l'alliage de magnésium AM60, Thèse. Sciences

D. Schaberger, M. Kahn, and . Lang, Development of a metallographic microstructure characterisation for the high-purity magnesium alloy AZ91. Practical metallography, pp.6-306, 1998.

. Hansen, Constitution of Binary Alloys, Journal of The Electrochemical Society, vol.105, issue.12, 1958.
DOI : 10.1149/1.2428700

A. L. Song, D. H. Bowles, and . Stjohn, Corrosion resistance of aged die cast magnesium alloy AZ91D, Materials Sciences and Engineering A: Structural Materials -Properties, Microstructure and Processing, pp.1-74, 2004.
DOI : 10.1016/j.msea.2003.08.060

E. Hazan, C. Rocca, J. Juers, and . Steinmetz, EIS study of corrosion behavior of AZ91 and AM50 alloys

C. Baril, N. Blanc, and . Pébère, Influence of microstructure on the corrosion behavior of two magnesium alloys by EIS, Proceedings of the Electrochemical Society -Corrosion and Corrosion Prevention of Low Density Metals and Alloys, pp.166-175, 2003.

C. Baril, M. Blanc, N. Keddam, and . Pébère, Local Electrochemical Impedance Spectroscopy Applied to the Corrosion Behavior of an AZ91 Magnesium Alloy, Journal of The Electrochemical Society, vol.135, issue.10, pp.12-488, 2003.
DOI : 10.1149/1.2095910

D. Hanawalt, C. E. Nelson, and J. A. Peloubet, Corrosion studies of magnesium and its alloys, Trans. Am. Inst. Mining Met. Engrs, vol.147, pp.1353-273, 1941.

L. Hawke, J. E. Hillis, M. Pekguleryuz, and I. Nakatsugawa, Magnesium and magnesium alloys, ASM Speciality Handbook. Ohio (EU) : ASM Int, Materials Park, pp.196-196, 1999.

O. Nisancioglu, T. K. Lunder, and . Aune, The International Magnesium Association, Proceedings of the 47th annual world magnesium conference, p.47, 1990.

D. Jönsson, N. Thierry, and . Lebozec, The influence of microstructure on the corrosion behaviour of AZ91D studied by scanning Kelvin probe force microscopy and scanning Kelvin probe, Corrosion Science, vol.48, issue.5, pp.3-1193, 2007.
DOI : 10.1016/j.corsci.2005.05.008

C. Mathieu, J. Rapin, P. Steinmetz, and . Steinmetz, A corrosion study of the main constituent phases of AZ91D magnesium alloys. Corrosion Science, pp.12-2741, 2003.

. Song, Recent Progress in Corrosion and Protection of Magnesium Alloys, Advanced Engineering Materials, vol.19, issue.489, pp.563-586, 2005.
DOI : 10.1515/CORRREV.1995.13.2-4.245

J. H. Lunder, K. Nordlien, and . Nisancioglu, Corrosion Resistance of Cast Mg-Al Alloys, Corrosion Reviews, vol.42, issue.3-4, pp.3-4, 1997.
DOI : 10.1149/1.2049981

A. Song and . Atrens, Understanding Magnesium Corrosion???A Framework for Improved Alloy Performance, Advanced Engineering Materials, vol.5, issue.12, pp.837-858, 2003.
DOI : 10.1002/adem.200310405

N. N. Ambat, W. Aung, and . Zhou, Evaluation of microstructural effects on corrosion behaviour of AZ91D magnesium alloy, Corrosion Science, vol.42, issue.8, pp.8-1433, 2000.
DOI : 10.1016/S0010-938X(99)00143-2

U. Ballerini, R. Bardi, G. Bignucolo, and . Ceraolo, About some corrosion mechanisms of AZ91D magnesium alloy. Corrosion Science, pp.9-2173, 2005.

C. Mathieu, J. Rapin, P. Hazan, and . Steinmetz, Corrosion behaviour of high pressure die-cast and semi-solid cast AZ91D alloys. Corrosion Science, pp.12-2737, 2002.

D. Uzan, E. Elizer, and . Aghion, The effect of the ? phase and heat treatment on the corrosion behavior of magnesium AZ91 alloy, Synthesis of Lightweight Metals III, proceedings of the symposium held at the TMS Annual Meeting Warrendale: Minerals, Metals & Materials Society, pp.171-176, 1999.

J. Ko, C. D. Yim, J. D. Lim, and K. S. Shin, Effect of Mg 17 Al 12 precipitate on corrosion behaviour of AZ91D magnesium alloy, Materials Science Forum, pp.419-422, 2003.

A. Song, M. Atrens, and . Dargusch, Influence of microstructure on the corrosion of diecast AZ91D, Corrosion Science, vol.41, issue.2, pp.2-249, 1999.
DOI : 10.1016/S0010-938X(98)00121-8

E. Blawert, V. Morales, W. Heitmann, S. Dietzel, E. Jin et al., Corrosion properties of the skin of high pressure die cast AZ91 alloy, Light metals 2005 -Calgary COM 2005 -44 th annual Conference of Metallurgists, pp.109-126, 2005.

S. Zhang, E. Jin, R. Ghali, and . Tremblay, Skin and bulk corrosion properties of die cast and thixocast AZ91D magnesium alloy in 0.005M NaCl solution, Canadian Metallurgical Quartely, vol.45, pp.2-181, 2006.

S. Jin, E. Amira, and . Ghali, Electrochemical Impedance Spectroscopy Evaluation of the Corrosion Behavior of Die Cast and Thixocast AXJ530 Magnesium Alloy in Chloride Solution, Advanced Engineering Materials, vol.13, issue.1-2, pp.1-2, 2007.
DOI : 10.1002/adem.200600199

P. Anik, A. Avci, I. Tanverdi, B. Celikyurek, R. Baksan et al., Effect of the eutectic phase mixture on the anodic behavior of alloy AZ91, Materials & Design, vol.27, issue.5, pp.5-347, 2005.
DOI : 10.1016/j.matdes.2004.11.016

C. Baril, G. Deslouis, N. Galicia, B. Pébère, and . Tribollet, Corrosion study of Mg and AZ91D Mg alloy by electrochemical impedance spectroscopy, 2004.

L. Lindström, J. Johansson, and . Svensson, The influence of NaCl and CO 2 on the atmospheric corrosion of magnesium alloy AZ91, Materials and Corrosion, vol.54, pp.8-587, 2003.

B. Baliga and P. Tsakiropoulos, Development of corrosion resistant magnesium alloys Part 2 Structure of corrosion products on rapidly solidified Mg???16Al alloys, Materials Science and Technology, vol.16, issue.6, pp.6-513, 1993.
DOI : 10.1149/1.2428728

B. Baliga and P. Tsakiropoulos, Design of magnesium alloys with improved corrosion properties, Magnesium Alloys and their Applications -DGM Conference, pp.119-126, 1992.

J. Li, F. C. Lin, K. L. Loh, and . Tan, Characterization of corrosion products formed on a rapidly solidified Mg based EA55RS alloy, Journal of Materials Science, vol.99, issue.3, pp.15-4017, 1996.
DOI : 10.1007/BF00352663

H. Nordlien, K. Nisancioglu, S. Ono, and N. Masuko, Morphology and Structure of Oxide Films Formed on MgAl Alloys by Exposure to Air and Water, Journal of The Electrochemical Society, vol.143, issue.8, pp.8-2564, 1996.
DOI : 10.1149/1.1837048

H. Nordlien, K. Nisancioglu, S. Ono, and N. Masuko, Morphology and Structure of Water-Formed Oxides on Ternary MgAl Alloys, Journal of The Electrochemical Society, vol.144, issue.2, pp.2-461, 1997.
DOI : 10.1149/1.1837432

D. Jönsson, D. Persson, and . Thierry, Corrosion Product formation during NaCl induced atmospheric corrosion of magnesium alloy AZ91D. Corrosion Science, pp.3-1540, 2007.

C. Ardelean, P. Pradier, and . Marcus, Rapport d'étude bibliographique sur la corrosion et la protection anticorrosion du magnésium et de ses alliages Ecole Nationale Supérieure de Chimie de Paris. corrosion processes on pure magnesium, Rapport. Journal of the Electrochemical Society, vol.150, pp.4-99, 1998.

L. Makar, J. Kruger, and K. Sieradzki, Stress corrosion cracking of rapidly solidified magnesium-aluminium alloys. Corrosion Sciences, pp.8-1311, 1993.

T. Hallopeau, C. Beldjoudi, L. Fiaud, and . Robbiola, Corrosion resistance and electrochemical behaviour of Mg and AZ91E alloy in aqueous electrolyte solutions. Inhibiting effect of XO y n-ions. Corrosion Reviews, pp.1-2, 1998.

T. Parthiban, S. Muralidhran, N. Palaniswamy, K. Chittukala, D. Chanthraleka et al., Studies on surface treatment of magnesium alloy for corrosion protection, Journal of the Electrochemical Society of India, vol.54, pp.4-129, 2005.

C. Daloz, P. Rapin, G. Steinmetz, and . Michot, Corrosion Inhibition of Rapidly Solidified Mg-3% Zn-15% Al Magnesium Alloy with Sodium Carboxylates, CORROSION, vol.54, issue.6, pp.6-444, 1998.
DOI : 10.5006/1.3284872

E. Gray and B. Luan, Protective coatings on magnesium and its alloys ??? a critical review, Journal of Alloys and Compounds, vol.336, issue.1-2, pp.1-2, 2002.
DOI : 10.1016/S0925-8388(01)01899-0

I. Skar, M. Walter, and D. Albright, Non-chromate conversion coatings for magnesium die castings. Society of Automotive engineers. Special publication: characteristics and applications of magnesium in automotive design, pp.7-11, 1997.

. Lacourcelle, La préparation des surfaces (suite) Alliages de magnésium. Galvano-Organo, pp.275-278, 1996.

M. Brunelli, I. Dabalà, M. Calliari, and . Magrini, Effect of HCl pre-treatment on corrosion resistance of cerium-based conversion coatings on magnesium and magnesium alloys, Corrosion Science, vol.47, issue.4, pp.4-989, 2005.
DOI : 10.1016/j.corsci.2004.06.016

W. Eppensteiner and M. R. Jenkins, Chromate conversion coatings. Metal finishing, pp.29-34, 1975.

. Horner, Chromate post treatments. Metal finishing, pp.76-80, 1990.

F. G. Williams, The mechanism of formation of chromate conversion films on zinc. Surface Technology, pp.355-366, 1976.

M. Umehara, T. Takaya, and . Itoh, Corrosion resistance of the die casting AZ91D magnesium alloy with paint finishing. Aluminium, pp.7-8, 1999.

K. Ono, T. Asami, and . Osaka, Characterization of chemical conversion coating films grown on magnesium

V. Natarajan and . Ravikiran, Evaluation of electrochemical and surface characteristics of conversion coatings on ZM21 magnesium alloy, Surface Engineering, vol.2, issue.5, pp.4-287, 2006.
DOI : 10.4028/www.scientific.net/MSF.350-351.273

P. Zhang and G. Chen, Immersion and electrochemical tests study on corrosion resistance of chrome-free chemical conversion film on AZ91D Mg alloy in 5 wt% NaCl solution. Surface Review and Letters, pp.3-417, 2005.

J. Hill and J. B. Jones, The crystal structure of hopeite, American Mineralogist, vol.61, pp.9-10, 1976.

M. Kouisni, M. Azzi, F. Zertoubi, S. Dalard, and . Maximovitch, Phoshate coatings on magnesium alloy AM60 part 1: study of the formation and the growth of zinc phosphate films, Surface and Coatings Technology, vol.185, pp.1-58, 2004.

M. Kouisni, F. Azzi, S. Dalard, and . Maximovitch, Phoshate coatings on magnesium alloy AM60 part 2: electrochemical behaviour in borate buffer solution, Surface and Coatings Technology, vol.192, pp.2-3, 2005.

H. Hawke and D. L. Albright, A phosphate-permanganate conversion coating for magnesium. Metal Finishnig, pp.34-38, 1995.

D. Zhou, E. Shan, W. Han, and . Ke, Phosphate conversion coating on diecast AZ91D and its corrosion resistance, Materials Science Forum, pp.488-489, 2005.

M. Wu, J. Zhao, Y. Luo, and . Mao, Properties of conversion coatings of magnesium alloys by a phosphatepermanganate solution, Materials Science Forum, pp.488-489, 2005.

S. Zhao, J. Wu, Y. Luo, H. Fukuda, and . Nakae, A chromium-free conversion coating of magnesium alloy by a phosphate???permanganate solution, Surface and Coatings Technology, vol.200, issue.18-19, pp.18-19, 2006.
DOI : 10.1016/j.surfcoat.2005.07.064

Z. Chong and T. S. Shih, Conversion-coating treatment for magnesium alloys by a permanganate???phosphate solution, Materials Chemistry and Physics, vol.80, issue.1, pp.1-191, 2003.
DOI : 10.1016/S0254-0584(02)00481-9

P. Bech-nielsen and . Leisner, Development and corrosion testing of new conversion coatings for magnesium alloys (in particular AZ91B + 0.5 % Si): stannate and zincate coatings, th Annual technical conference of the American electroplaters and surface finishers society AESF, pp.78-743, 1991.

Y. Huo, F. Li, and . Wang, Corrosion of AZ91D magnesium alloy with a chemical conversion coating and electroless nickel layer. Corrosion Science, pp.6-1467, 2004.

. Wilks, A non-chromate conversion coating for magnesium alloys and magnesium-based metal matrix composites. Corrosion Science, pp.1763-1772, 1995.

A. González-nuñez, P. Skeldon, G. E. Thompson, and H. Karimzadeh, Kinetics of the Development of a Nonchromate Conversion Coating for Magnesium Alloys and Magnesium-Based Metal Matrix Composites, coatings on Mg substrates, pp.1136-1143, 1999.
DOI : 10.5006/1.3283951

S. Lin, H. C. Lin, K. M. Lin, and W. C. Lai, Formation and properties of stannate conversion coatings on AZ61 magnesium alloys. Corrosion Science, pp.1-93, 2006.

L. Rudd, C. B. Breslin, and F. Mansfeld, The corrosion protection afforded by rare earth convertion coatings applied to magnesium, Corrosion Science, vol.42, pp.2-275, 2000.

K. Dabalà, E. Brunelli, M. Napolitani, and . Magrini, Cerium-based chemical conversion coating on AZ63 magnesium alloy, Surface and Coatings Technology, vol.172, issue.2-3, pp.2-3, 2003.
DOI : 10.1016/S0257-8972(03)00336-0

C. Ardelean, P. Fiaud, and . Marcus, Enhanced corrosion resistance of magnesium and its alloys through the formation of cerium (and aluminium) oxide surface films, Materials and Corrosion, vol.52, issue.12, pp.12-889, 2001.
DOI : 10.1002/1521-4176(200112)52:12<889::AID-MACO889>3.0.CO;2-0

. Rapin, Etude de l'inhibition de la corrosion aqueuse du cuivre, Thèse. Sciences, 1994.
URL : https://hal.archives-ouvertes.fr/tel-01754171

G. Rocca, C. Bertrand, J. C. Rapin, and . Labrune, Inhibition of copper aqueous corrosion by non-toxic linear sodium heptanoate: mechanism and ECAFM study, Journal of Electroanalytical Chemistry, vol.503, issue.1-2, pp.1-2, 2001.
DOI : 10.1016/S0022-0728(01)00384-9

P. Rapin and J. Steinmetz, Steinmetz Etude de l'inhibition de la corrosion aqueuse du cuivre par les carboxylates linéaires saturés. I : Pouvoir inhibiteur des carboxylates linéaires de formule CH 3

. Coona and . La, Revue de Métallurgie -Cahiers d'Informations Techniques, pp.281-290, 1996.

. Beucler-bour, Etude d'une famille d'inhibiteurs organiques de la corrosion de l'acier, Thèse. Sciences, 1993.

M. I. Francois, P. Saleh, M. Rabu, B. Souhassou, J. Malaman et al., Structural transition at 225 K of the trinuclear Fe(III) heptanoate [Fe 3 O(O 2 CC 6 H 13 ) 6 (H 2 O) 3 ]NO 3 . Solide State Science, pp.10-1236, 2005.

. Peultier, Traitement de conversion du zinc à base d'acides carboxyliques, Thèse. Sciences, 2000.
URL : https://hal.archives-ouvertes.fr/tel-01746678

E. Peultier, J. Rocca, and . Steinmetz, Zinc carboxylating: a new conversion treatment of zinc, Corrosion Science, vol.45, issue.8, pp.8-1703, 2003.
DOI : 10.1016/S0010-938X(03)00020-9

. Rocca, Passivation du plomb pur et de ses alliages en milieux sulfurique et atmosphérique, Thèse. Sciences, 1999.

C. Rocca, F. Rapin, and . Mirambet, Inhibition treatment of the corrosion of lead artefacts in atmospheric conditions and by acetic acid vapour: use of sodium decanoate, Corrosion Science, vol.46, issue.3, pp.3-653, 2004.
DOI : 10.1016/S0010-938X(03)00175-6

J. Rocca and . Steinmetz, Inhibition of lead corrosion with saturated linear aliphatic chain monocarboxylates of sodium, Corrosion Science, vol.43, issue.5, pp.891-902, 2001.
DOI : 10.1016/S0010-938X(00)00115-3

P. Steinmetz, M. Steinmetz, E. François, and . Rocca, Protection anticorrosion des métaux par des savons métalliques, Proceedings Matériaux, 2006.