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. Le-p-tertiobutylcalix, 758 mg, 1.17 mmol, 1éq) est mis en solution dans 25 ml d'acétonitrile fraîchement distillé. On rajoute K 2 CO 3 (326 mg, 2.34 mmol, 2 éq) puis le mélange est porté à reflux pendant 30 mn, 2002.

L. Büchi, Le résidu est chromatographié sur alumine (éluant : CH 2 Cl 2 /Hex 1/1) Le produit récupéré est alors recristallisé dans un mélange dichlorométhane/acétonitrile évaporé à froid au Büchi, filtré et séché On obtient un solide blanc, p.61

2. Hz, CH 2 CH 2 CH 2 O-Ar c), AB, J AB = 13.2 Hz, 4H, Ar-CH 2 -Ar), pp.9-13

A. , J. Ab-=-13-',, A. , and J. , 2 Hz, 4H, Ar-CH 2 -Ar) ArH b), p.99425384

2. Hz and A. D. , d + s + s, 6H, H(5')bpy + ArH a + ArH c, pp.10-17

2. Hz and H. , 62 (t, J = 7.6 Hz, p.13

4. Hz, 29 (d, J = 8.4 Hz, 2H, ArH d); 6.53 (s, 4H, ArH b), bpy, vol.6, issue.64

2. Hz and A. D. , 05 (s, 2H09 (s, 2H, ArH c ou a) H(4') et H(5') bpy), pp.62-69

4. Hz, A. Ar-ch-',, and J. , Ar-CH 2 -Ar)24 (m,2H,CH 2 -N); 3.68 (t, 2H)56 (s, 1H,NH), Hz, vol.2878780, issue.8, pp.94-98

. Ar-ch, 95 (Ar-CH 2 -Ar), 18 (CH 2 CH 2 NH); 41.69 (CH 2 CH 2 NH), pp.31-75

A. and J. Ab, 08 (s, 9H); 1.11 (s, 9H)Ar), RMN 1 H (400 MHz 11H, Mebpy + CH 2 -CH 2 -CH 2 ); 2.65 (t, 2H, CH 2 -CH 2 -N), pp.0-99389092

. Le-chlorure-de-cyanuryle, 88 mg, 3.2 10 -5 mol) est solubilisé dans 10 ml d'acétone. A 0°c, le bis-(1,3)-bipyridyl-2-propoxy-p- phényl-triflate-(amino-éthyl)-tetra-tertiobutyl

. Éq, Le milieu est agité 45 minutés à 0°c, puis le solvant est évaporé. Le résidu est repris dans 10 ml de dichlorométhane et lavé à l'eau (2x5ml), la phase organique est récupérée et évaporée, p.72

. Dans-un-flacon-scellé, le polymère greffé 18 (environ 10 mg) est mis en suspension, sous agitation dans 10 ml d'une solution monométallique de Cu(I) ou de Zn(II) de concentration connue (4 à 7.10 -4 mol.L -1 ) Selon la solubilité des sels

. La-boucle-d, injection est de 100 µl dans les expériences avec le sulfate de cuivre et 20 µl avec le nitrate de cérium

. Dans-un-flacon-scellé, le polymère greffé (10 à 20 mg) est mis en suspension, sous agitation dans 10 ml d'une solution mono/bi/trimétallique de concentration initiale connue