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. Les-réactifs-suivants, Anhydride acétique acide de 2-bromoisobutanoïque, NEt 3 , DMAP sont fournis par Aldrich et ont été utilisés dans l'état. La pyridine (Aldrich) a été séchée avec BaO une nuit et filtrée avant utilisation. La formamide et le DMF ont été séchés sur CaH 2 puis distillés sur paroi froide avant utilisation, alors que le THF a été séché sur le complexe sodium/benzophénone puis distillé

. Le-méthacrylate-de-méthyle-(-mma and 9. Aldrich, éthyle (AcEt, Fluka 99,5%) ont été distillés sous vide après séchage sur CaH 2 puis stockés sous pression d'azote. L'amorceur 2-bromoisobutanoate d'éthyle (EiBr), le catalyseur bromure de cuivre (Cu I Br, 9%) et dibromure de cuivre (Cu II Br 2 ), les ligands 2,2'-bipyridine (bpy), 1,1,4,7 et l'anisole ont été fournis par Aldrich, sauf Cu II Br 2 obtenu de Fluka. Ils ont été utilisés sans aucune purification. Les ligands N-(n-propyl)-2-pyridylméthanimine (n-Pr-PMI), p.10

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I. Schéma, 1 : Différentes voies pour modifier hydrophobiquement les dérivés de la cellulose (HEC : hydroxyéthycellulose, HPC : hydroxypropylcellulose, MC : méthylcellulose, CMC : carbométhylcellulose)

I. Schéma, Equilibres de désactivation/activation (haut) et d'échange dégénératif (bas) mis en oeuvre pour contrôler une polymérisation radicalaire. k p , k t , k tr , k act , k désact et k éch sont respectivement les constantes cinétiques de propagation, de terminaison

I. Schéma, Mécanisme général de l'ATRP. k p , k t , k act et k désact sont respectivement les constantes cinétiques de propagation, de terminaison, d'activation et de désactivation

I. Schéma, Principe de l'AGET, cas d'un macroamorceur halogéné

I. Schéma, Mécanisme proposé pour la régénération des activateurs par transfert d'électron. Cas de l'ATRP ARGET et ICAR

I. Schéma, Mécanisme réactionnel de la SET. k dis : constante cinétique de dismutation

I. Schéma, k éch sont respectivement les constantes cinétiques de propagation, de terminaison, d'addition, de fragmentation et d'échange

I. Schéma, Synthèse du glycopolymère maltoheptaose acétylé-b-PMMA (2) et structure des autres monomères testés, Styrène (S), méthacrylate diméthylaminoéthyle (DMAEMA), glycomonomère méthacrylique, pp.et méthacrylate poly(éthylène glycol) ?-méthoxy

I. Schéma, Synthèse de dextrane ?-fonctionnalisé xanthate. A) propargylamine, NaBH 3 CN, solution tampon pH=7, 37°C, 7j ; B) agent de transfert de chaîne azido-xanthate, p.48

I. Schéma, Représentation schématique des trois méthodes de synthèse de copolymères greffés

I. Schéma, Synthèse de copolymères greffés à partir de fibres de cellulose. i) THF, NEt 3 , DMAP, bromure de 2-bromoisobutanoate, 25°C, 1 à 24h ; ii) MA, 18h ; iii) HEMA, H 2 O, p.2

I. Schéma, Introduction de greffons de PMPC sur la cellulose par ATRP en solution homogène

I. Schéma, Méthodes convergente (Z-group approach) et divergente (R-group approach) pour obtenir des copolymères greffés par RAFT

I. Schéma, Méthodologie de synthèse des cellulose-g-polystyrène par RAFT amorcée par irradiation d'une source de cobalt

I. Schéma, Stratégie de synthèse des étoiles de type AB 20 à coeur de cyclodextrine avec une branche PS et 20 branches PMMA ou PtBa. i) polymérisation en masse du styrène avec (1) à 120°C ; ii) désacétylation avec NaOMe dans le THF ; iii) estérification (synthèse du macroamorceur ATRP) ; iv) ATRP avec

I. Schéma, Synthèse de glycopolymères en étoile par NMP, avec l

I. Schéma, Stratégies de synthèse (Voie A et B) utilisées pour synthétiser des macroamorceurs d'ATRP à base de

I. Schéma, Acétylation de la cellulose par un mélange d'anhydride acétique

I. Schéma, Mécanismes généraux d'une oxydation d'un nucléophile via le DMSO (a) et de l

I. Schéma, Structures des dérivés du dextrane obtenus par réaction avec l'acide ?-naphtylacétique, l'acide nicotinique et le naproxène

I. Schéma, Réaction de Moffatt sur l'extrémité non-réduite du

I. Schéma, Réaction de Swern dans le cadre d'une introduction directe des groupements amorceurs sur le dextrane

I. Schéma and H. , Comparaison des valeurs relatives des constantes cinétiques d'activation entre un unimère H-MMA-Br (équivalent à l'EiBr), et deux dimères