L. E. Baker and K. D. Luks, Critical point and saturation pressure calculations for multicomponents systems, Soc. Petrol. Eng. J, 1978.
DOI : 10.2118/7478-pa

L. E. Baker, A. C. Pierce, and K. D. Luks, Gibbs Energy Analysis of Phase Equilibria, Society of Petroleum Engineers Journal, vol.22, issue.05
DOI : 10.2118/9806-PA

P. Benedek and F. Olti, Computer aided chemical thermodynamics of gases and liquids, Theory, Models, Programs, 1985.

J. D. Cox and E. F. Herington, The coexistence curve in liquid-liquid binary systems, Transactions of the Faraday Society, vol.52, pp.926-956, 1956.
DOI : 10.1039/tf9565200926

D. and T. Design, Institute for Physical Property Data, Data compilation of pure compound properties, 1985.

A. W. Francis, Liquid liquid Equilibrium, Inter Science, 1963.

A. W. Francis, CRITICAL SOLUTION TEMPERATURES, Copyright, ADVANCES IN CHEMISTRY SERIES, Am. Chem. Soc, vol.32, 1961.
DOI : 10.1021/ba-1961-0031.fw001

J. Gmehling, . Li, . Jidding, and M. Schiller, A modified UNIFAC model. 2. Present parameter matrix and results for different thermodynamic properties, Industrial & Engineering Chemistry Research, vol.32, issue.1, pp.178-193, 1993.
DOI : 10.1021/ie00013a024

J. Gmehling, J. Lohmann, A. Jakob, J. Li, and R. Joh, A Modified UNIFAC (Dortmund) Model. 3. Revision and Extension, ) Model. 3. Revision and Extension, pp.4876-4882, 1998.
DOI : 10.1021/ie980347z

R. A. Heidmann and A. M. Khalil, The calculation of critical points, AIChE Journal, vol.26, issue.5, pp.769-779, 1980.
DOI : 10.1002/aic.690260510

. Institut-français-du-pétrole, Les méthodes de calcul sur ordinateurs appliquées au raffinage et à la pétrochimie, Collectif, Editions TECHNIP, 1969.

B. L. Larsen, P. Rasmussen, and A. Fredenslund, A modified UNIFAC group-contribution model for prediction of phase equilibria and heats of mixing, Industrial & Engineering Chemistry Research, vol.26, issue.11, pp.2274-2286, 1987.
DOI : 10.1021/ie00071a018

H. Matsuda, M. Fujita, and K. Ochi, Measurement and Correlation of Mutual Solubilities for High-Viscosity Binary Systems:??? Aniline + Methylcyclohexane, Phenol + Heptane, Phenol + Octane, and Glycerol + 1-Pentanol, Journal of Chemical & Engineering Data, vol.48, issue.4, pp.1076-1080, 2003.
DOI : 10.1021/je034043h

M. L. Michelsen, The isothermal flash problem. Part I, Stability, Fluid phase equilibria, pp.1-19, 1982.

M. L. Michelsen, The isothermal flash problem. Part II, Phase-Split calculation, Fluid phase equilibria, pp.21-40, 1982.

P. E. Poling, J. M. Prausnitz, and J. P. O-'connell, Properties of gases and liquids, 2000.

J. M. Prausnitz, R. N. Lichtenthaler, and E. G. De-azevedo, Molecular thermodynamics of fluidphase equilibria, pp.260-261, 1968.

R. C. Reid, J. M. Prausnitz, and B. Poiling, The properties of gases and liquids, -, 5 éme Edition, 2001.

H. Renon and J. M. Prausnitz, Local compositions in thermodynamic excess functions for liquid mixtures, AIChE Journal, vol.14, issue.1, pp.135-144, 1968.
DOI : 10.1002/aic.690140124

K. H. Simmrock, Critical data of pure substances, Dechema, pp.3-921567, 1986.

J. M. Sorensen and W. Arlt, Liquid Liquid Equilibrium Data Collection, Binary Systems, part 1 of Chemistry Data Series, 1979.

J. Vidal and . Thermodynamique, Application au génie chimique et à l'industrie pétrolière, 1997.

.. Calcul-des-coefficients-d-'activité, 48 IV.1. Etat de référence, 50 IV.2. Calcul des propriétés des corps purs, p.51

). Saut-thermique-externe-(-?t-e, 74 III.3. Coefficient de performance (COP), p.79

.. Colonne-de-rectification-inverse, 84 a) Description et bilans 84 b) Construction de PONCHON, 86 c) Recherche des points limites de, p.91

.. De-chaleur, 104 IV.2. Cycle avec récupération interne de chaleur 106 III.1. Representation du cycle simple sur les diagrammes température-composition (Tx ,y) et enthalpie-composition (H-x,y) 116 III.2. Representation du Cycle modifie sur les diagrammes température-composition (Tx ,y) et enthalpie-composition (H-x,y), IV.1. Cycle sans récupération interne, p.118

). Th, 118 III.3.2. Saut thermique interne maximal (?T i max ), III.3.1. Saut thermique interne (?T i ) ? Rendement thermique, p.120

J. Influence-de, ?. Sur-le-saut-thermique-(-?t-i-ou, and N. Max, 124 IV.2. Influence de la température de démixtion (T démix ) sur le saut tHermique interne maximal (?T i max ), p.126

). Enthalpie-de-vaporisationlv-i, 132 II.1.2. Capacité calorifique du gaz parfait (Cp gi ), p.136

L. Capacité-calorifique-du-liquidecp, 137 II.2. Variation des propriétés de corps purs pour le cycle modifié, p.140

.. Liquide-liquide-et-de-l-'équilibre-liquide-vapeur and K. , 155 IV.2.1. Variation simultanée des enthalpies de vaporisation (Lv i ) et des paramètres Variation simultanée des paramètres d'interaction (b 12 , b 21 et ?) et Lv i et Cp li .... 156 IV.3. Influence de la variation simultanée des paramètres d'ELL et d'ELV sur les deux types de cycle, Chapitre III. Thermo Transformateur à Absorption-Démixtion : Principe et outil de simulation IV.2. Variations simultanée des paramètres de l'équilibre................. 161 III.2. SELECTION DES MELANGES à ETUDIER ................................................... 162 IV.1. Comparaison des performances maximales des deux types de cycle 164 IV.2. Performances du cycle modifié pour des conditions opératoires fixées, p.168

/. Enthalpie-de-vaporisationj and ). , 231 II. Données d'équilibre liquide-liquide, p.231

D. Alonso, Thermo-transformateur à absorption?démixtion: Expérimentation et Optimisation

D. Alonso, T. Cachot, and J. M. Hornut, Performance simulation of an absorption heat transformer operating with partially miscible mixtures, Applied Energy, vol.72, issue.3-4, pp.583-597, 2002.
DOI : 10.1016/S0306-2619(02)00052-1

D. Alonso, T. Cachot, and J. M. Hornut, Experimental study of an innovative absorption heat transformer using partially miscible working mixtures, International Journal of Thermal Sciences, vol.42, issue.6, pp.631-638, 2003.
DOI : 10.1016/S1290-0729(03)00028-0

J. D. Cox and E. F. Herington, The coexistence curve in liquid-liquid binary systems, Transactions of the Faraday Society, vol.52, pp.926-956, 1956.
DOI : 10.1039/tf9565200926

J. Gmehling, U. Ouken, and W. Arlt, Vapor-Liquid Equilibrium data collection, Chemistry data series, 1981.

J. M. Sorensen and W. Arlt, Liquid Liquid Equilibrium Data Collection, Binary Systems, 1979.

S. D. White and B. K. O-'neill, A novel absorption-cycle heat-pump, pp.355-367, 1994.
DOI : 10.1016/0306-2619(94)90043-4

I. , C. Et-dimensionnement, .. , and .. , 174 II.1. Description de l'installation 175 II.1.1. Colonne de rectification inverse, p.177

.. Mesure-des-températures-et-des-débits, 179 II.2.1. Capteurs de température, p.179

I. , R. Experimentaux, and E. , 191 IV.1. Mode opératoire, Paramères 191 IV.2. Exploitation des enregistrements des mesures expérimentales, .

.. Exemple-de-resultats-des-données-enregistrées and Y. , Exemple de résultats : représentation des différentes phases sur le diagramme d'équilibre de la puissance fournie à l'évaporateur sur le rendement thermique, 210 IV.5.3. Comparaison des performances expérimentales et simulées............................ 213 IV.5.4. Détermination du nombre d'étages théoriques de la colonne (NET), p.215

T. A. Al-sahhaf, E. Kapetanivic, and Q. Kadhem, Salt effects on liquid liquid equilibria in partially miscible systems water+2 butanone and water +ethyl acetate, Fluid Phase Equilibria, pp.271-283, 1999.

M. Aznar, R. N. Araùjo, J. F. Romanato, G. R. Santos, and S. G. Avila, Salt Effects on Liquid???Liquid Equilibrium in Water + Ethanol + Alcohol + Salt Systems, Journal of Chemical & Engineering Data, vol.45, issue.6, pp.1055-1059, 2000.
DOI : 10.1021/je000029i

D. Santis and R. , Phase equilibria of the water sodium chloride Trielethylamine system, Journal of Chemical and Engineering Data, vol.21, issue.3, 1976.

D. Santis, R. Marrelli, L. Muscetta, and P. N. , Influence of temperature on the liquid-liquid equilibrium of the water-n-butyl alcohol-sodium chloride system, Journal of Chemical & Engineering Data, vol.21, issue.3, pp.324-327, 1976.
DOI : 10.1021/je60070a008

Z. Li, Y. Tang, Y. Liu, and Y. Li, Salting effect in partially miscible systems of n-butanol???water and butanone???water 1. Determination and correlation of liquid-liquid equilibrium data, Fluid Phase Equilibria, vol.103, issue.1, pp.143-153, 1995.
DOI : 10.1016/0378-3812(94)02615-8

M. Perumalsamy and T. Murugesan, Prediction of liquid???liquid equilibria for PEG 2000???sodium citrate based aqueous two-phase systems, Fluid Phase Equilibria, vol.244, issue.1, pp.52-61, 2006.
DOI : 10.1016/j.fluid.2006.03.008

J. A. Reyes, A. Gomez, and A. Marcilla, Graphical Concepts To Orient the Minimum Reflux Ratio Calculation on Ternary Mixtures Distillation, Industrial & Engineering Chemistry Research, vol.39, issue.10, pp.3912-3919, 2000.
DOI : 10.1021/ie9907021

A. Salabat, The influence of salts on the phase composition in aqueous two-phase: experiments and predictions, Fluid Phase Equilibria 187-188, pp.489-498, 2001.

F. S. Santos, S. G. Avila, and M. Aznar, Salt effect on liquid???liquid equilibrium of water+1-butanol+acetone system: experimental determination and thermodynamic modeling, Fluid Phase Equilibria, vol.187, issue.188, pp.187-188, 2001.
DOI : 10.1016/S0378-3812(01)00541-6

T. C. Tan and S. Aravinth, Liquid liquid equilibria of water/acetic acid/1-butanol system effects of sodium (potassium) chloride and correlations, Fluid Phase Equilibria, pp.243-257, 1999.

A. Toumi, M. Bouanz, and A. Gharbi, Coexistence curves of the binary mixture isobutyric acid???water with added ions (K+,Cl???), Chemical Physics Letters, pp.567-573, 2002.
DOI : 10.1016/S0009-2614(02)01107-7

P. Wang, A. Anderko, R. D. Springer, and R. D. Young, Modeling phase equilibria and speciation in mixed-solvent electrolyte systems: II. Liquid???liquid equilibria and properties of associating electrolyte solutions, Journal of Molecular Liquids, vol.125, issue.1, pp.37-44, 2006.
DOI : 10.1016/j.molliq.2005.11.030

M. T. Zafarani-moattar, . Hamzehzadeh, and . Sh, Liquid liquid equilibria of aqueous two-phase systems containing plyethylene glycol and sodium succinate or sodium formate, Computer Coupling of Phase Diagrams and Thermochemistry, pp.1-6, 2005.

P. Entrée-de, T. Démix, and . Et-x-i, Initialisation de T bulle : T bulle = ? T eb i . x i Initialisation de coefficients d

P. Entrée-de, T. Démix, and . Et-x-i, Initialisation de T bulle : T bulle = ? T eb i . x i Initialisation de coefficients d

P. Et, O. De, and S. , 258 PARTIE 2 : INFLUENCE, p.258

I. Chapitre, Enjeux énergétiques et environnementaux des pompes à chaleur Figure 1 : Consommation mondiale d'énergie primaire en, 1971.