(s) ? n-C3H7· + OH(s) C3H8 + (s) ? n-C3H7· + H(s) C2H4 + O(s) ? C2H3· + OH(s) C2H4 + (s) ? C2H3· + H(s) O2 + (s) ?O2(s) 2O(s) ? O2(s) + (s) O2(s) + (s) ? 2O(s) O2(s) ?, O2 + (s) HO2· + O(s) ? O2 + OH(s) H2 + 2O(s) ? 2OH(s) H2 + O(s) ? OH(s) + H· CO + O(s) ? CO2 + (s) H2 CO CO2 ,
Catalytic conversion of propane to hydrogen in microstructured reactors, Chemical Engineering Journal, vol.101, issue.1-3, pp.93-99, 2004. ,
DOI : 10.1016/j.cej.2004.01.006
Temperature profiles and residence time effects during catalytic partial oxidation and oxidative steam reforming of propane in metallic microchannel reactors, Catalysis Today, vol.110, issue.1-2, pp.98-107, 2005. ,
DOI : 10.1016/j.cattod.2005.09.001
Surface Effects in Partial Oxidation of Propane, Industrial & Engineering Chemistry Product Research and Development, vol.5, issue.3, pp.244-249, 1966. ,
DOI : 10.1021/i360019a008
Hydrogen Storage in Liquid Organic Hydride: Producing Hydrogen Catalytically from Methylcyclohexane, Energy & Fuels, vol.25, issue.10, pp.4217-4234, 2011. ,
DOI : 10.1021/ef200829x
Conversion of Methane by Oxidative Coupling, Catalysis Reviews, vol.11, issue.3, pp.163-227, 1990. ,
DOI : 10.1246/cl.1988.317
Etude experimentale de la réaction de couplage oxydant du méthane à l'aide d'un réacteur continu agité à surface catalytique variable, 1993. ,
Experimental and modelling study of methane and ethane oxidation between 773 and 1573 K, Journal de Chimie Physique, vol.92, pp.1666-1692, 1995. ,
DOI : 10.1051/jcp/1995921666
A new " catalytic jet-stirred reactor " application to the study of the oxidative coupling of methane, Oxidation Communications, vol.19, pp.173-185, 1996. ,
Competition between the gas and surface reactions for the oxidative coupling of methane, Catalysis Today, vol.21, issue.2-3, pp.409-415, 1994. ,
DOI : 10.1016/0920-5861(94)80162-2
La1-xSrxCrO3 composites: Catalytic activity for propane partial oxidation and reforming, Solid State Ionics, vol.177, pp.3473-3484 ,
Modeling of hydrogen-rich gas production by plasma reforming of hydrocarbon fuels, International Journal of Hydrogen Energy, vol.31, issue.6, pp.769-774, 2006. ,
DOI : 10.1016/j.ijhydene.2005.06.018
Thermochemical kinetics : methods for the estimation of thermochemical data and rate parameters, J. Wiley & sons, 1976. ,
Analysis of a catalytic annular reactor for very short contact times, Chemical Engineering Science, vol.54, issue.6, pp.765-773, 1999. ,
DOI : 10.1016/S0009-2509(98)00261-9
Production of Olefins via Oxidative Dehydrogenation of Propane in Autothermal Conditions, Journal of Catalysis, vol.184, issue.2, pp.469-478, 1999. ,
DOI : 10.1006/jcat.1999.2447
An Investigation on the Role of a Pt/Al2O3 Catalyst in the Oxidative Dehydrogenation of Propane in Annular Reactor, Journal of Catalysis, vol.184, issue.2, pp.455-468, 1999. ,
DOI : 10.1006/jcat.1999.2446
Thermal evolution of a sample of La2O3 exposed to the atmosphere, Thermochimica Acta, vol.66, issue.1-3, pp.139-145, 1993. ,
DOI : 10.1016/0040-6031(93)85026-6
Olefins by Catalytic Oxidation of Alkanes in Fluidized-Bed Reactors, Journal of Catalysis, vol.155, issue.2, pp.403-413, 1995. ,
DOI : 10.1006/jcat.1995.1222
Direct catalytic oxidation of methane to formaldehyde: New investigation opportunities provided by an improved flow circulation method, Kinetics and Catalysis, vol.31, issue.4, pp.676-692, 2007. ,
DOI : 10.1007/978-94-010-0554-8_10
Catalytic selective oxidation of propane, Catalysis Today, vol.42, issue.3, pp.315-323, 1998. ,
DOI : 10.1016/S0920-5861(98)00108-4
The oxidative dehydrogenation of ethane and propane as an alternative way for the production of light olefins, Catalysis Today, vol.24, issue.3, pp.307-313, 1995. ,
DOI : 10.1016/0920-5861(95)00051-G
Aromatic site description of soot particles, Combustion and Flame, vol.155, issue.1-2, pp.161-180, 2008. ,
DOI : 10.1016/j.combustflame.2008.04.011
Investigation of the Stability of CeO2, V2O5 and CeV Mixed Oxide on the Partial Oxidation of Propane, 2012) Investigation of the Stability of CeO2, V2O5 and CeV Mixed Oxide on the Partial Oxidation of Propane, pp.753-762 ,
DOI : 10.1366/000370209787944334
Oxidative Conversion of Methane/Natural Gas into Higher Hydrocarbons, Catalysis Surveys from Asia, vol.8, issue.1, pp.15-25, 2004. ,
DOI : 10.1023/B:CATS.0000015111.23332.7d
Surface Chemkin (Version 4.0) : A fortran package for analyzing heterogeneous chemical kinetics at a solid-surface-gas phase interface, 1991. ,
Hydrogen production by catalytic partial oxidation of methane and propane on Ni and Pt catalysts, International Journal of Hydrogen Energy, vol.32, issue.1, pp.55-66, 2007. ,
DOI : 10.1016/j.ijhydene.2006.06.032
Methane Oxidation: Experimental and Kinetic Modeling Study, Combustion Science and Technology, vol.113, issue.1-3, pp.127-148, 1991. ,
DOI : 10.1021/j100321a050
Kinetic modeling of propane oxidation and pyrolysis, International Journal of Chemical Kinetics, vol.75, issue.9, pp.813-837, 1992. ,
DOI : 10.1002/bbpc.19720760514
Combustible hydrogène Utilisation, p.11, 2006. ,
Règles de construction et d'extrapolation des réacteurs autoagité par jets gazeux. The canadian journal of chemical engineering 53, pp.297-300, 1975. ,
Heterogeneous Catalysis and Solid Catalysts, 2009. ,
DOI : 10.1016/0926-3373(96)00021-5
Numerical and experimental study of the conversion of methane to hydrogen in a porous media reactor, Combustion and Flame, vol.144, issue.4, pp.698-709, 2006. ,
DOI : 10.1016/j.combustflame.2005.08.038
Gas-phase radical formation during the reactions of methane, ethane, ethylene, and propylene over selected oxide catalysts, The Journal of Physical Chemistry, vol.89, issue.21, pp.4415-4418, 1985. ,
DOI : 10.1021/j100267a002
Formation of gas-phase methyl radicals over magnesium oxide, Journal of the American Chemical Society, vol.107, issue.1, pp.58-63, 1985. ,
DOI : 10.1021/ja00287a011
NO prediction in natural gas flames using GDF-Kin??3.0 mechanism NCN and HCN contribution to prompt-NO formation, Fuel, vol.85, issue.7-8, pp.896-909, 2006. ,
DOI : 10.1016/j.fuel.2005.10.012
Performance and SEM characterization of Rh impregnated microchannel reactors in the catalytic partial oxidation of methane and propane, Chemical Engineering Journal, vol.144, issue.3, pp.489-501, 2008. ,
DOI : 10.1016/j.cej.2008.07.055
Kinetic-Studies of the Catalytic-Oxidation of Methane .2. Methyl Radical Recombination and Ethane Formation Over 1-Percent Sr, 1991. ,
Conversion catalytique du méthane en gaz de synthèse par oxydation partielle, 2006. ,
Catalyst. Part 1:?? Experimental Results, Industrial & Engineering Chemistry Research, vol.46, issue.4, pp.1063-1068, 2007. ,
DOI : 10.1021/ie060342z
URL : https://hal.archives-ouvertes.fr/hal-00139862
Detailed kinetic study of the partial oxidation of methane over La2O3 catalyst, Part Mechanism. Industrial and Engineering Chemistry Research, vol.2, issue.46, pp.1069-1078, 2007. ,
URL : https://hal.archives-ouvertes.fr/hal-00139862
Discussion on the oxidative and the pyrolysis routes of the CH3 radicals in the partial oxidation of methane over La2O3, Journal of Analytical and Applied Pyrolysis, vol.79, issue.1-2, pp.259-267, 2007. ,
DOI : 10.1016/j.jaap.2006.09.001
URL : https://hal.archives-ouvertes.fr/hal-00140008
Catalyst, Energy & Fuels, vol.20, issue.6, pp.2321-2329, 2006. ,
DOI : 10.1021/ef0602729
URL : https://hal.archives-ouvertes.fr/hal-00139862
Detailed surface and gas-phase chemical kinetics of diamond deposition, Physical Review B, vol.341, issue.2, pp.1520-1545, 1991. ,
DOI : 10.1086/167501
Experimental and numerical investigation of hetero-/homogeneous combustion of CO/H2/O2/N2 mixtures over platinum at pressures up to 5bar, Proceedings of the Combustion Institute, pp.1827-1835, 2011. ,
DOI : 10.1016/j.proci.2010.06.135
PSR : A FORTRAN program for modeling well stirred reactos, 1990. ,
Valorisation chimique du méthane par oxydation catalytique sélective, 1996. ,
Calcul des réacteurs catalytiques Approche préliminaire, p.11, 2005. ,
Development and testing of a comprehensive chemical mechanism for the oxidation of methane, International Journal of Chemical Kinetics, vol.32, issue.9, pp.513-538, 2001. ,
DOI : 10.1021/j100039a027
Surface Structures and Oxygen Hole Formation on the La2O3 Catalyst. A Computer Simulation Study, The Journal of Physical Chemistry, vol.98, issue.38, pp.9637-9641, 1994. ,
DOI : 10.1021/j100089a044
Synthesis of ethylene and ethane by partial oxidation of methane over lithium-doped magnesium oxide, Nature, vol.47, issue.6013, pp.721-722, 1985. ,
DOI : 10.1038/314721b0
Experimental and numerical investigation of the hetero-/homogeneous combustion of lean propane/air mixtures over platinum, Proceedings of the Combustion Institute, pp.1947-1955, 2009. ,
Hetero/homogeneous combustion and stability maps in methane-fueled catalytic microreactors, Proceedings of the Combustion Institute, pp.3309-3317, 2007. ,
Chemkin-III : a fortran chemical kinetics package for the analysis of gas-phase chemical and plasma kinetics, 1996. ,
DOI : 10.2172/481621
Synthesis of ethylene via oxidative coupling of methane I. Determination of active catalysts, Journal of Catalysis, vol.73, issue.1, pp.9-19, 1982. ,
DOI : 10.1016/0021-9517(82)90075-6
Effect of nature and surface density of oxygen species on product distribution in the oxidative dehydrogenation of propane over oxide catalysts, Applied Catalysis A: General, vol.325, issue.2, pp.353-361, 2007. ,
DOI : 10.1016/j.apcata.2007.02.041
NONCATALYTIC PARTIAL OXIDATION OF METHANE INTO SYNGAS OVER A WIDE TEMPERATURE RANGE, Combustion Science and Technology, vol.4, issue.7, pp.1093-1116, 2004. ,
DOI : 10.1063/1.1376128
Detailed surface reaction mechanism for Pt-catalyzed abatement of automotive exhaust gases, Applied Catalysis B: Environmental, vol.91, issue.1-2, pp.47-58, 2009. ,
DOI : 10.1016/j.apcatb.2009.05.006
Mechanistic studies on the oxidative coupling of methane, The Journal of Physical Chemistry, vol.91, issue.11, pp.2682-2684, 1987. ,
DOI : 10.1021/j100295a003
Oxidative Coupling of Methane over Lanthana Catalysts I. Identification and Role of Specific Active-Sites, Journal of Catalysis, vol.151, issue.2, pp.439-452, 1995. ,
DOI : 10.1006/jcat.1995.1046
Major Precursors of Pyrocarbon Deposition from Propane Pyrolysis, ECS Transactions, pp.91-98, 2009. ,
DOI : 10.1149/1.3207579
Kinetic modeling of surface reactions involved in CVI of pyrocarbon obtained by propane pyrolysis, Carbon, vol.48, issue.1, pp.132-144, 2010. ,
DOI : 10.1016/j.carbon.2009.08.041
URL : https://hal.archives-ouvertes.fr/hal-00799742
Hydrogen production from steam and autothermal reforming of LPG over high surface area ceria, Journal of Power Sources, vol.158, issue.2, pp.1348-1357, 2006. ,
DOI : 10.1016/j.jpowsour.2005.10.058
Optimal conditions for partial oxidation of propane over ceria-promoted nickel/calcium hydroxyapatite, Korean Journal of Chemical Engineering, vol.24, issue.2, pp.226-232, 2007. ,
DOI : 10.1007/s11814-007-5057-5
Oxidative conversion of propane over lithium-promoted magnesia catalyst I. Kinetics and mechanism, Journal of Catalysis, vol.218, issue.2, pp.296-306, 2003. ,
DOI : 10.1016/S0021-9517(03)00112-X
Oxidative conversion of propane over lithium-promoted magnesia catalyst II. Active site characterization and hydrocarbon activation, Journal of Catalysis, vol.218, issue.2, pp.307-314, 2003. ,
DOI : 10.1016/S0021-9517(03)00113-1
Oxidative dimerization of methane over lanthanum oxide, The Journal of Physical Chemistry, vol.90, issue.4, pp.534-537, 1986. ,
DOI : 10.1021/j100276a004
Hetero-/homogeneous combustion of hydrogen/air mixtures over platinum at pressures up to 10 bar, Proceedings of the Combustion Institute, pp.1937-1945, 2009. ,
Kinetic study of the oxidative Coupling of Methane in a Catalytic Jet Stirred Reactor, Natural Gas Conversion II Proceedings of the Third Natural Gas Conversion Symposium, pp.149-154, 1994. ,
Effect of gas phase reactions in the oxidative coupling of methane, pp.383-388, 1997. ,
DOI : 10.1016/S0167-2991(97)80365-5
Gazéification des résidus pétroliers par le procédé Shell, 1997. ,
Un r??acteur continu parfaitement agit?? par jets gazeux pour l'??tude cin??tique de r??actions chimiques rapides, Chemical Engineering Science, vol.28, issue.1, pp.129-137, 1973. ,
DOI : 10.1016/0009-2509(73)85093-6
Mechanism of cooxidative methane dimerization catalysis : kinetic and thermodynamic aspects, Methane Conversion by Oxidative Processes. Fundamental and Engineering Aspects, 1992. ,
Inherent limitation in the direct catalytic conversion of natural gas into higher hydrocarbons, 1989. ,
Catalyse hétérogène dans les procédés industriels, 2005. ,
Detailed Kinetic Modeling of Gas-Phase Reactions in the Chemical Vapor Deposition of Carbon from Light Hydrocarbons, Industrial & Engineering Chemistry Research, vol.46, issue.11, pp.3547-3557, 2007. ,
DOI : 10.1021/ie061207p
Lanthanum catalysts for methane oxidative coupling: a comparison of the reactivity of phases, Industrial & Engineering Chemistry Research, vol.30, issue.5, pp.1016-1023, 1991. ,
DOI : 10.1021/ie00053a025
Conception, réalisation et évaluation d'un réacteur à plaques millistructurées pour le couplage autotherme de la déhydrogénation du méthylcyclohexane et de la combustion du toluène, Récents Progrès En Génie Des Procédés, 2011. ,
Partial Oxidation of Propane - The Role of Hydrogen Peroxide, Industrial & Engineering Chemistry, vol.46, issue.5, pp.1001-1007, 1954. ,
DOI : 10.1021/ie50533a050
Cinétique et catalyse, 1996. ,
Millisecond chemical reactions and reactors, 12th International Congress on Catalysis Proceedings of the 12th ICC, pp.61-81, 2000. ,
DOI : 10.1016/S0167-2991(00)80945-3
The biomethane potential in Chile, Biomass and Bioenergy, vol.33, issue.4, pp.564-572, 2009. ,
DOI : 10.1016/j.biombioe.2008.09.005
Syngas production from partial oxidation of methane over Ce1???XNiXOY catalysts prepared by complexation???combustion method, Applied Catalysis A: General, vol.311, pp.24-33, 2006. ,
DOI : 10.1016/j.apcata.2006.05.044
URL : https://hal.archives-ouvertes.fr/hal-00128435
Partial oxidation of propane to synthesis gas over noble metals-promoted Ni/Mg(Al)O catalysts???High activity of Ru???Ni/Mg(Al)O catalyst, Applied Catalysis A: General, vol.318, pp.143-154, 2007. ,
DOI : 10.1016/j.apcata.2006.10.049
Production of hydrogen by short contact time partial oxidation and oxidative steam reforming of propane, Catalysis Today, vol.99, issue.1-2, pp.69-76, 2005. ,
DOI : 10.1016/j.cattod.2004.09.025
Detailed mechanism of the oxidative coupling of methane. Studies in surface science and catalysis 147, pp.571-576, 2004. ,
Kinetic Modeling of the Oxidative Coupling of Methane, Industrial & Engineering Chemistry Research, vol.46, issue.7, pp.1914-1922, 2007. ,
DOI : 10.1021/ie060151w
URL : https://hal.archives-ouvertes.fr/hal-00140031
Free radicals in catalytic oxidation of light alkanes: kinetic and thermochemical aspects, Journal of Catalysis, vol.216, issue.1-2, pp.468-476, 2003. ,
DOI : 10.1016/S0021-9517(02)00116-1
Actualité chimique, Société chimique de France, 1973. ,
Microkinetics of methane oxidative coupling, Catalysis Today, vol.137, issue.1, pp.90-102, 2008. ,
DOI : 10.1016/j.cattod.2008.02.026
Purification process for chemical storage of hydrogen for fuel cell vehicles applications, International Journal of Hydrogen Energy, vol.32, issue.18, pp.5059-5066, 2007. ,
DOI : 10.1016/j.ijhydene.2007.08.015
URL : https://hal.archives-ouvertes.fr/hal-00258947
Plasma synthesis of catalytic thin films, Pure and Applied Chemistry, vol.74, issue.3, pp.471-474, 2002. ,
DOI : 10.1351/pac200274030471
URL : https://hal.archives-ouvertes.fr/hal-00007265
Partial oxidation of methane: the role of surface reactions, Industrial & Engineering Chemistry Research, vol.31, issue.10, pp.2272-2278, 1992. ,
DOI : 10.1021/ie00010a003
Catalyst design based on microkinetic models: Oxidative coupling of methane, Catalysis Today, vol.159, issue.1, pp.29-36, 2011. ,
DOI : 10.1016/j.cattod.2010.09.002
URL : https://hal.archives-ouvertes.fr/hal-00699726
Les techniques de production de l'hydrogène et les risques associés, 2008. ,
Catalysis by Ceria and Related Materials, 2002. ,
Génie de la réaction chimique, conception et fonctionnement des réacteurs, Tec & doc, 2005. ,
Photocatalyst Using LIF, The Journal of Physical Chemistry C, vol.112, issue.25, pp.9115-9119, 2008. ,
DOI : 10.1021/jp802653k
URL : https://hal.archives-ouvertes.fr/hal-00350464
Computer based generation of reaction mechanisms for gas-phase oxidation, Computers & Chemistry, vol.24, issue.5, pp.541-560, 2000. ,
DOI : 10.1016/S0097-8485(99)00092-3
Kinetic Modeling of Coke Formation during Steam Cracking, Industrial & Engineering Chemistry Research, vol.41, issue.10, pp.2379-2391, 2002. ,
DOI : 10.1021/ie010822k
Brief overview of the partial oxidation of methane to synthesis gas, Topics in Catalysis, vol.22, issue.3/4, pp.345-358, 2003. ,
DOI : 10.1023/A:1023552709642
Oxidative coupling of methane in the gas phase. Kinetic simulation and experimental verification, Industrial & Engineering Chemistry Research, vol.29, issue.1, pp.2-10, 1990. ,
DOI : 10.1021/ie00097a001
Understanding Homogeneous and Heterogeneous Contributions to the Platinum-Catalyzed Partial Oxidation of Ethane in a Short-Contact-Time Reactor, Journal of Catalysis, vol.196, issue.1, pp.18-39, 2000. ,
DOI : 10.1006/jcat.2000.3009
Direct conversion of methane in formaldehyde at very short residence time, Chemical Engineering Science, vol.66, issue.24, pp.6331-6340, 2011. ,
DOI : 10.1016/j.ces.2011.03.059
URL : https://hal.archives-ouvertes.fr/hal-00666722
Reforming of CH4 by partial oxidation: thermodynamic and kinetic analyses, Fuel, vol.80, issue.7, pp.899-905, 2001. ,
DOI : 10.1016/S0016-2361(00)00165-4
Pyrolysis of propane for CVI of pyrocarbon Part III: Experimental and modeling study of the formation of pyrocarbon, J, 2007. ,
169 a. Fabrication des pastilles, p.169 ,
Etude expérimentale de la réaction catalytique en présence, ANNEXE, vol.4, p.188 ,
206 a. Dimension caractéristique de la pastille, p.206 ,