R. H. Crabtree, G. Kimmerlin, and . Gaz-naturel, Aspects of methane chemistry [2] BP Amoco, Statical Review of World Energy, Techniques de l'Ingénieur. 2010. [4] Dewerdt, F., Combustibles gazeux, Gaz naturel Techniques de l'Ingénieur, pp.987-1007, 1984.

M. G. Poirier, A. R. Sanger, and K. J. Smith, Direct catalytic conversion of methane, The Canadian Journal of Chemical Engineering, vol.10, issue.222, pp.69-1027, 1991.
DOI : 10.2172/6166436

A. Rojey, B. Durand, and L. Sajus, Le gaz naturel : production, traitement, transport Paris, 1994.

J. H. Lunsford, Catalytic conversion of methane to more useful chemicals and fuels: a challenge for the 21st century, Catalysis Today, vol.63, issue.2-4, pp.165-174, 2000.
DOI : 10.1016/S0920-5861(00)00456-9

J. Zaman, Oxidative processes in natural gas conversion, Fuel Processing Technology, vol.58, issue.2-3, pp.61-81, 1999.
DOI : 10.1016/S0378-3820(98)00090-3

Y. I. Pyatnitskii, Contemporary methods for the direct catalytic conversion of methane, Theoretical and Experimental Chemistry, vol.39, issue.4, pp.201-218, 2003.
DOI : 10.1023/A:1025797710504

A. L. Lapidus, A. Y. Krylova, and B. P. Tonkonogov, Gas chemistry: Status and prospects for development, Chemistry and Technology of Fuels and Oils, vol.70, issue.2, pp.82-88, 2000.
DOI : 10.1016/S0166-9834(00)80612-0

S. Han and C. D. Chang, Fuels, Synthetic, Liquid Fuels, in Kirk-Othmer Encyclopedia of Chemical Technology, 2000.

B. Eisenberg, R. A. Fiato, T. G. Kaufmann, and R. F. Bauman, The evolution of advanced gas-to-liquids technology, CHEMTECH, issue.10, pp.29-32, 1999.

M. E. Dry, The Fischer???Tropsch process: 1950???2000, Catalysis Today, vol.71, issue.3-4, pp.227-241, 2002.
DOI : 10.1016/S0920-5861(01)00453-9

H. Schulz, Short history and present trends of Fischer???Tropsch synthesis, Applied Catalysis A: General, vol.186, issue.1-2, pp.3-12, 1999.
DOI : 10.1016/S0926-860X(99)00160-X

D. Schanke, E. Rytter, and F. O. Jaer, Scale-up of Statoil's Fischer-Tropsch process. Studies in surface science and catalysis, pp.43-48, 2004.

T. H. Fleisch, R. A. Sills, and M. D. Briscoe, 2002 -Emergence of the gas-to-liquids industry: a review of global GTL developments, Journal of Natural Gas Chemistry, issue.11, pp.1-14, 2002.

O. L. Eliseev, Gas-to-liquid technologies, Russian Journal of General Chemistry, vol.186, issue.10, pp.2509-2519, 2009.
DOI : 10.1007/BF00764496

A. Holmen, Direct conversion of methane to fuels and chemicals, Catalysis Today, vol.142, issue.1-2, pp.2-8, 2009.
DOI : 10.1016/j.cattod.2009.01.004

B. Bernauer, I. Janou?kovcová, M. Mare?ek, and Z. Sobalík, Direct catalytic conversion of methane to higher hydrocarbons, Chemicke Listy, issue.7, pp.94-423, 2000.

L. Wang, L. Tao, M. Xie, G. Xu, J. Huang et al., Dehydrogenation and aromatization of methane under non-oxidizing conditions, Catalysis Letters, vol.32, issue.1-2, pp.35-41, 1993.
DOI : 10.1007/BF00767368

M. R. Toosi, B. Sabour, T. Hamuleh, and M. H. Peyrovi, Methane dehydroaromatization over Mo and W catalysts supported on HZSM-5: the effect of preactivation and use of the CH4/H2 cycle, Reaction Kinetics, Mechanisms and Catalysis, vol.244, issue.1, pp.221-226, 2010.
DOI : 10.1007/s11144-010-0206-y

A. Agiral, T. Nozaki, M. Nakase, S. Yuzawa, K. Okazaki et al., Gas-to-liquids process using multi-phase flow, non-thermal plasma microreactor, Chemical Engineering Journal, vol.167, pp.2-3, 2011.

T. Nozaki, A. Agiral, S. Yuzawa, J. G. Han-gardeniers, and K. Okazaki, A single step methane conversion into synthetic fuels using microplasma reactor, Chemical Engineering Journal, vol.166, issue.1, pp.288-293, 2011.
DOI : 10.1016/j.cej.2010.08.001

S. G. Podkolzin, E. E. Stangland, M. E. Jones, E. Peringer, and J. A. Lercher, Methyl Chloride Production from Methane over Lanthanum-Based Catalysts, Journal of the American Chemical Society, vol.129, issue.9, pp.129-2569, 2007.
DOI : 10.1021/ja066913w

E. Peringer, S. G. Podkolzin, M. E. Jones, R. Olindo, and J. A. Lercher, LaCl 3 -based catalysts for oxidative chlorination of CH 4, Topics in Catalysis, vol.38, pp.1-3, 2006.

C. Lombard, Valorisation chimique du gaz naturel par chloropyrolyse du chlorure de méthyle, in Thesis, 2001.

C. Lombard and P. M. Marquaire, New study of methane to vinyl chloride process, Studies in Surface Science and Satalysis, vol.147, pp.529-534, 2004.
DOI : 10.1016/S0167-2991(04)80106-X

A. Holmen, O. Olsvik, R. , and O. A. , Pyrolysis of natural gas: chemistry and process concepts, Fuel Processing Technology, vol.42, issue.2-3, pp.249-267, 1995.
DOI : 10.1016/0378-3820(94)00109-7

C. Guéret, M. Daroux, and F. Billaud, Methane pyrolysis: thermodynamics, Chemical Engineering Science, vol.52, issue.5, pp.815-827, 1997.
DOI : 10.1016/S0009-2509(96)00444-7

D. Wang, J. H. Lunsford, and M. P. Rosynek, Characterization of a Mo/ZSM-5 Catalyst for the Conversion of Methane to Benzene, Journal of Catalysis, vol.169, issue.1, pp.347-358, 1997.
DOI : 10.1006/jcat.1997.1712

Y. Xu and L. Lin, Recent advances in methane dehydro-aromatization over transition metal ion-modified zeolite catalysts under non-oxidative conditions Applied Catalysis A: General, pp.53-67, 1999.

M. C. Alvarez-galvan, N. Mota, M. Ojeda, S. Rojas, R. M. Navarro et al., Direct methane conversion routes to chemicals and fuels, Catalysis Today, vol.171, issue.1, 2011.
DOI : 10.1016/j.cattod.2011.02.028

Y. Jiang, I. V. Yentekakis, and C. G. Vayenas, Methane to Ethylene with 85 Percent Yield in a Gas Recycle Electrocatalytic Reactor-Separator, Science, vol.264, issue.5165, pp.264-1563, 1994.
DOI : 10.1126/science.264.5165.1563

F. T. Akin and Y. S. Lin, Controlled oxidative coupling of methane by ionic conducting ceramic membrane, Catalysis Letters, vol.78, pp.1-4, 2002.

M. Bistolfi, G. Fornasari, M. Molinari, S. Palmery, M. Dente et al., Kinetic model for methane oxidative coupling reactors, Chemical Engineering Science, vol.47, issue.9-11, pp.47-56, 1992.
DOI : 10.1016/0009-2509(92)87107-2

S. C. Reyes, E. Iglesia, and C. P. Kelkar, Kinetic-transport models of bimodal reaction sequences???I. Homogeneous and heterogeneous pathways in oxidative coupling of methane, Chemical Engineering Science, vol.48, issue.14, pp.48-2643, 1993.
DOI : 10.1016/0009-2509(93)80274-T

Y. Simon, F. Baronnet, and P. M. Marquaire, Kinetic Modeling of the Oxidative Coupling of Methane, Industrial & Engineering Chemistry Research, vol.46, issue.7, pp.46-1914, 2007.
DOI : 10.1021/ie060151w

URL : https://hal.archives-ouvertes.fr/hal-00140031

M. J. Brown and N. D. Parkyns, Progress in the partial oxidation of methane to methanol and formaldehyde, Catalysis Today, vol.8, issue.3, pp.305-335, 1991.
DOI : 10.1016/0920-5861(91)80056-F

J. H. Edwards and N. R. Foster, THE POTENTIAL FOR METHANOL PRODUCTION FROM NATURAL GAS BY DIRECT CATALYTIC PARTIAL OXIDATION, Fuel Science and Technology International, vol.15, issue.4, pp.365-390, 1986.
DOI : 10.1021/ja00327a009

J. C. Kuo, C. T. Kresge, and R. E. Palermo, Evaluation of direct methane conversion to higher hydrocarbons and oxygenates, Catalysis Today, vol.4, issue.3-4, pp.3-4, 1989.
DOI : 10.1016/0920-5861(89)85042-4

J. W. Geerts, J. H. Hoebink, and K. Van-der-wiele, Methanol from natural gas. Proven and new technologies., Catalysis Today, vol.6, issue.4, pp.613-620, 1990.
DOI : 10.1016/0920-5861(90)85059-W

M. J. Gradassi, W. Green, and N. , Economics of natural gas conversion processes, Fuel Processing Technology, vol.42, issue.2-3, pp.65-83, 1995.
DOI : 10.1016/0378-3820(94)00094-A

H. Launay, Développement de catalyseurs à base d'oxyde de molybdène ou de vanadium supporté sur silice pour l'oxydation ménagée du méthane en formaldéhyde (Thesis), Université Claude Bernard-Lyon 1. 2005, Ecole doctorale de chimie

K. Otsuka and Y. Wang, Direct conversion of methane into oxygenates, Applied Catalysis A: General, vol.222, issue.1-2, pp.145-161, 2001.
DOI : 10.1016/S0926-860X(01)00837-7

R. S. Mann and M. K. Dosi, Partial oxidation of methane to formaldehyde over halogen modified catalyst, Journal of Chemical Technology and Biotechnology, vol.4, issue.8, pp.29-467, 1979.
DOI : 10.1002/aic.690080106

C. F. Cullis, D. E. Keene, and D. L. Trimm, Studies of the partial oxidation of methane over heterogeneous catalysts, Journal of Catalysis, vol.19, issue.3, pp.378-385, 1970.
DOI : 10.1016/0021-9517(70)90262-9

R. G. Herman, Q. Sun, C. Shi, K. Klier, C. B. Wang et al., Development of active oxide catalysts for the direct oxidation of methane to formaldehyde, Catalysis Today, vol.37, issue.1, pp.1-14, 1997.
DOI : 10.1016/S0920-5861(96)00256-8

D. Vekki, A. V. Marakaev, and S. T. , Catalytic partial oxidation of methane to formaldehyde, Russian Journal of Applied Chemistry, vol.55, issue.2, pp.529-543, 2009.
DOI : 10.1016/S0926-860X(99)00423-8

K. Otsuka and M. Hatano, The catalysts for the synthesis of formaldehyde by partial oxidation of methane, Journal of Catalysis, vol.108, issue.1, pp.252-255, 1987.
DOI : 10.1016/0021-9517(87)90172-2

T. J. Hall, J. S. Hargreaves, G. J. Hutchings, R. W. Joyner, T. et al., Catalytic synthesis of methanol and formaldehyde by partial oxidation of methane, Fuel Processing Technology, vol.42, issue.2-3, pp.2-3, 1995.
DOI : 10.1016/0378-3820(94)00125-D

V. Amir-ebrahimi and J. J. Rooney, Selective air oxidation of methane to formaldehyde using silica-supported MoCl5/R4Sn olefin metathesis catalysts, Journal of Molecular Catalysis, vol.50, issue.3, pp.17-22, 1989.
DOI : 10.1016/0304-5102(89)80280-9

T. Weng and E. E. Wolf, Partial oxidation of methane on mo/sn/p silica supported catalysts, Applied Catalysis A: General, vol.96, issue.2, pp.383-396, 1993.
DOI : 10.1016/0926-860X(90)80024-9

B. Lin, X. Wang, Q. Guo, W. Yang, Q. Zhang et al., Excellent Catalytic Performances of SBA-15-supported Vanadium Oxide for Partial Oxidation of Methane to Formaldehyde, Chemistry Letters, issue.9, pp.32-860, 2003.

A. Parmaliana, F. Frusteri, A. Mezzapica, M. S. Scurrell, G. et al., Novel high activity catalyst for partial oxidation of methane to formaldehyde, Journal of the Chemical Society, Chemical Communications, issue.9, pp.751-753, 1993.
DOI : 10.1039/c39930000751

K. Otsuka, Y. Wang, I. Yamanaka, A. Morikawa, and M. Y. Sinev, Partial oxidation of methane over iron molybdate catalyst. Studies in surface science and catalysis, pp.503-508, 1994.

M. A. Bañares, L. J. Alemany, L. Granados, M. Faraldos, M. Fierro et al., Partial oxidation of methane to formaldehyde on silica-supported transition metal oxide catalysts, Catalysis Today, vol.33, issue.1-3, pp.1-3, 1997.
DOI : 10.1016/S0920-5861(96)00099-5

W. Yang, X. Wang, Q. Guo, Q. Zhang, W. et al., Superior catalytic performance of phosphorus-modified molybdenum oxide clusters encapsulated inside SBA-15 in the partial oxidation of methane, New Journal of Chemistry, vol.27, issue.9, pp.27-1301, 2003.
DOI : 10.1039/b305929d

E. Echigoya, Conversion of methane to formaldehyde, Applied Catalysis, vol.26, issue.1 2, pp.410-410, 1986.

T. Sugino, A. Kido, N. Azuma, A. Ueno, and Y. Udagawa, Partial Oxidation of Methane on Silica-Supported Silicomolybdic Acid Catalysts in an Excess Amount of Water Vapor, Journal of Catalysis, vol.190, issue.1, pp.118-127, 2000.
DOI : 10.1006/jcat.1999.2732

A. Ueno, N. Azuma, K. Aoki, and T. Sugino, Method of producing formaldehyde directly from methane, p.17, 2000.

J. A. Barbero, M. C. Alvarez, M. A. Bañares, M. A. Peña, and J. L. Fierro, Breakthrough in the direct conversion of methane into c1-oxygenates, Chemical Communications, issue.11, pp.2002-1184
DOI : 10.1039/b202812n

I. C. Bafas, I. E. Constantinou, and C. G. Vayenas, Partial oxidation of methane to formaldehyde with 50% yield in a continuous recycle reactor separator (CRRS), Chemical Engineering Journal, vol.82, issue.1-3, pp.1-3, 2001.
DOI : 10.1016/S1385-8947(00)00346-6

C. Batiot and B. K. Hodnett, The role of reactant and product bond energies in determining limitations to selective catalytic oxidations Applied Catalysis A: General, pp.179-191, 1996.

G. A. Foulds and B. F. Gray, Homogeneous gas-phase partial oxidation of methane to methanol and formaldehyde, Fuel Processing Technology, vol.42, issue.2-3, pp.129-150, 1995.
DOI : 10.1016/0378-3820(94)00122-A

D. J. Thomas, R. Willi, and A. Baiker, Partial oxidation of methane: the role of surface reactions, Industrial & Engineering Chemistry Research, vol.31, issue.10, pp.31-2272, 1992.
DOI : 10.1021/ie00010a003

C. L. Rasmussen and P. Glarborg, Direct Partial Oxidation of Natural Gas to Liquid Chemicals: Chemical Kinetic Modeling and Global Optimization, Industrial & Engineering Chemistry Research, vol.47, issue.17, pp.47-6579, 2008.
DOI : 10.1021/ie800137d

N. R. Hunter, H. D. Gesser, L. A. Morton, P. S. Yarlagadda, and D. P. Fung, Methanol formation at high pressure by the catalyzed oxidation of natural gas and by the sensitized oxidation of methane, Applied Catalysis, vol.57, issue.1, pp.45-54, 1990.
DOI : 10.1016/S0166-9834(00)80722-8

P. S. Yarlagadda, L. A. Morton, N. R. Hunter, and H. D. Gesser, Direct conversion of methane to methanol in a flow reactor, Industrial & Engineering Chemistry Research, vol.27, issue.2, pp.252-256, 1988.
DOI : 10.1021/ie00074a008

W. Feng, C. Knopf, F. Dooley, and K. M. , Effects of pressure, third bodies, and temperature profiling on the noncatalytic partial oxidation of methane. Energy and Fuels, pp.815-822, 1994.

Q. Zhang, D. He, J. Li, B. Xu, Y. Liang et al., Comparatively high yield methanol production from gas phase partial oxidation of methane, Applied Catalysis A: General, vol.224, issue.1-2, pp.201-207, 2002.
DOI : 10.1016/S0926-860X(01)00820-1

R. Burch, G. D. Squire, and S. C. Tsang, Direct conversion of methane into methanol, Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, vol.85, issue.10, pp.85-3561, 1989.
DOI : 10.1039/f19898503561

G. A. Foulds, B. F. Gray, S. A. Miller, S. Walker, and G. , Homogeneous gasphase oxidation of methane using oxygen as oxidant in an annular reactor, Industrial and Engineering Chemistry Research, issue.5, pp.32-780, 1993.

D. W. Rytz and A. Baiker, Partial oxidation of methane to methanol in a flow reactor at elevated pressure, Industrial & Engineering Chemistry Research, vol.30, issue.10, pp.30-2287, 1991.
DOI : 10.1021/ie00058a007

Q. Liu, J. Rogut, B. Chen, J. L. Falconer, N. et al., Improved methanol yield from methane oxidation in a non-isothermal reactor, Fuel, vol.75, issue.15, pp.75-1748, 1996.
DOI : 10.1016/S0016-2361(96)00112-3

P. S. Casey, T. Mcallister, and K. Foger, Selective Oxidation of Methane to Methanol at High Pressures, Industrial & Engineering Chemistry Research, vol.33, issue.5, pp.1120-1125, 1994.
DOI : 10.1021/ie00029a008

Q. Zhang, D. He, and Q. Zhu, Direct partial oxidation of methane to methanol: Reaction zones and role of catalyst location, Journal of Natural Gas Chemistry, vol.17, issue.1, pp.24-28, 2008.
DOI : 10.1016/S1003-9953(08)60021-3

R. Lødeng, O. A. Lindvag, P. Søraker, P. T. Roterud, and O. T. Onsager, Experimental and Modeling Study of the Selective Homogeneous Gas Phase Oxidation of Methane to Methanol, Industrial & Engineering Chemistry Research, vol.34, issue.4, pp.1044-1059, 1995.
DOI : 10.1021/ie00043a006

K. Omata, N. Fukuoka, and K. Fujimoto, Methane Partial Oxidation to Methanol. 1. Effects of Reaction Conditions and Additives, Industrial & Engineering Chemistry Research, vol.33, issue.4, pp.784-789, 1994.
DOI : 10.1021/ie00028a002

M. C. Bjorklund and R. W. Carr, Enhanced Methanol Yields from the Direct Partial Oxidation of Methane in a Simulated Countercurrent Moving Bed Chromatographic Reactor, Industrial & Engineering Chemistry Research, vol.41, issue.25, pp.41-6528, 2002.
DOI : 10.1021/ie0201617

D. M. Newitt and A. E. Haffner, The formation of methyl alcohol and formaldedhyde in the slow combustion of methane at high pressure, Proceddeding the Royal of Society A, vol.125, p.277, 1932.

J. L. Lott and C. M. Sliepcevich, Partial oxidation of methane at high pressures. Industrial and Engineering Chemistry Process Design and Development, pp.67-74, 1967.

O. T. Onsager, R. Lødeng, P. Søraker, A. Anundskaas, and B. Helleborg, The homogeneous gas phase oxidation of methane and the retarding effect of basic/inert surfaces, Catalysis Today, vol.4, issue.3-4, pp.3-4, 1989.
DOI : 10.1016/0920-5861(89)85031-X

V. S. Arutyunov, V. M. Rudakov, V. I. Savchenko, E. V. Sheverdenkin, O. G. Sheverdenkina et al., Partial alkane oxidation kinetics at high pressures: Methane oxidation in stainless steel and quartz reactors, Theoretical Foundations of Chemical Engineering, issue.5, pp.36-472, 2002.

T. C. Chou and L. F. Albright, Partial oxidation of methane in glass and metal tubular reactors. Industrial and Engineering Chemistry Process Design and Development, pp.454-459, 1978.

G. N. Kastanas, G. A. Tsigdinos, and J. Schwank, Selective oxidation of methane over vycor glass, quartz glass and various silica, magnesia and alumina surfaces, Applied Catalysis, vol.44, pp.44-77, 1988.
DOI : 10.1016/S0166-9834(00)80043-3

S. Ozturk, I. Onal, and S. Senkan, SurfaceA Quantum Chemical Study, Industrial & Engineering Chemistry Research, vol.39, issue.2, pp.250-258, 2000.
DOI : 10.1021/ie990252c

J. W. Chun and R. G. Anthony, Catalytic oxidations of methane to methanol, Industrial & Engineering Chemistry Research, vol.32, issue.2, pp.259-263, 1993.
DOI : 10.1021/ie00014a003

A. S. Chellappa, S. Fuangfoo, and D. S. Viswanath, Homogeneous oxidation of methane to methanol: Effect of CO 2 , N 2 , and H 2 at high oxygen conversions, Industrial and Engineering Chemistry Research, issue.5, pp.36-1401, 1997.

V. I. Bedeneev, M. Y. Gol-'denberg, N. I. Gorban, and M. A. Boim, Quantitative model of the oxidation of methane at high pressures. I. Description of model, Kinetics and Catalysis, vol.291, issue.1, pp.1-8, 1988.

J. W. Chun and R. G. Anthony, Partial oxidation of methane, methanol, and mixtures of methane and methanol, methane and ethane, and methane, carbon dioxide, and carbon monoxide, Industrial & Engineering Chemistry Research, vol.32, issue.5, pp.32-788, 1993.
DOI : 10.1021/ie00017a004

H. D. Gesser, N. R. Hunter, and P. A. Das, The ozone sensitized oxidative conversion of methane to methanol and ethane to ethanol, Catalysis Letters, vol.5, issue.1-2, pp.217-221, 1992.
DOI : 10.1007/BF00764374

T. M. Nagiev, Conjugated reactions of oxidation with hydrogen peroxide in the gas phase, in Coherent Synchronized Oxidation Reactions by Hydrogen Peroxide, pp.91-145, 2006.

J. M. Simmie, Detailed chemical kinetic models for the combustion of hydrocarbon fuels, Progress in Energy and Combustion Science, pp.599-634, 2003.
DOI : 10.1016/S0360-1285(03)00060-1

Y. Hidaka, K. Sato, Y. Henmi, H. Tanaka, and K. Inami, Shock-tube and modeling study of methane pyrolysis and oxidation, Combustion and Flame, vol.118, issue.3, pp.340-358, 1999.
DOI : 10.1016/S0010-2180(99)00010-3

M. Musick, T. P. Van, and J. Vandooren, Detailed mechanism of CH 4Ar flames and modeling in fuel-rich conditions, Bulletin des Sociétés Chimiques Belges, vol.105, issue.2, pp.555-574, 1996.

S. B. Jee, W. K. Kim, and K. S. Shin, Shock tube and modeling study of ignition in methane, Journal of the Korean Chemical Society, vol.43, pp.156-160, 1999.

J. W. Chun and R. G. Anthony, Free-radical kinetic model for homogeneous oxidation of methane to methanol, Industrial & Engineering Chemistry Research, vol.32, issue.5, pp.796-799, 1993.
DOI : 10.1021/ie00017a005

B. F. Gray, J. F. Griffiths, G. A. Foulds, B. G. Charlton, and G. S. Walker, The relevance of thermokinetic interactions and numerical modeling to the homogeneous partial oxidation of methane, Industrial & Engineering Chemistry Research, vol.33, issue.5, pp.33-1126, 1994.
DOI : 10.1021/ie00029a009

J. C. Mackie, Partial Oxidation of Methane: The Role of the Gas Phase Reactions, Catalysis Reviews, vol.95, issue.1-2, pp.169-240, 1991.
DOI : 10.1071/CH9861929

P. Dagaut, J. C. Boettner, and M. Cathonnet, Methane Oxidation: Experimental and Kinetic Modeling Study, Combustion Science and Technology, vol.113, issue.1-3, pp.127-175, 1991.
DOI : 10.1021/j100321a050

Y. Tan, P. Dagaut, M. Cathonnet, and J. C. Boettner, Oxidation and Ignition of Methane-Propane and Methane-Ethane-Propane Mixtures: Experiments and Modeling, Combustion Science and Technology, vol.88, issue.1-6, pp.133-51, 1994.
DOI : 10.1016/0360-1285(92)90003-J

E. Ranzi, A. Sogaro, P. Gaffuri, G. Pennati, and T. Faravelli, A Wide Range Modeling Study of Methane Oxidation, Combustion Science and Technology, vol.2, issue.6, pp.4-6, 1994.
DOI : 10.1021/ie00074a008

T. Kunugi, T. Tamura, and T. Naito, New acetylene process uses hydrogen dilution, Chemical Engineering Progress, issue.11, pp.57-100, 1961.

F. G. Billaud, C. P. Gueret, F. Baronnet, and J. Weill, Thermal coupling of methane in a tubular flow reactor: experimental setup and influence of temperature, Industrial & Engineering Chemistry Research, vol.31, issue.12, pp.31-2748, 1992.
DOI : 10.1021/ie00012a018

M. Bistolfi, A. Giusti, M. Dente, R. , and E. , Direct conversion of methane to methanol: Kinetic modeling and experimental data, International Symposium on Alcohol Fuels, 1991.

V. R. Choudhary, S. T. Chaudhari, and A. M. Rajput, Oxidative pyrolysis of methane to higher hydrocarbons: Effects of water in feed, AIChE Journal, vol.37, issue.6, pp.915-922, 1991.
DOI : 10.1002/aic.690370614

Q. Chen, J. H. Hoebink, M. , and G. B. , Kinetics of the oxidative coupling of methane at atmospheric pressure in the absence of catalyst, Industrial & Engineering Chemistry Research, vol.30, issue.9, pp.2088-2097, 1991.
DOI : 10.1021/ie00057a006

G. Rotzoll, Experimental investigation and computer simulation of products during the induction phase of methane oxidation from 1170 to 1460 K. Combustion Science and Technology, pp.47-275, 1986.

P. Dagaut and M. Cathonnet, Kinetics of methane oxidation in a high pressure jetstirred reactor : experimental results, Journal de Chimie Physique, vol.87, p.221, 1990.
DOI : 10.1051/jcp/1990870221

T. B. Hunter, H. Wang, T. A. Litzinger, and M. Frenklach, The oxidation of methane at elevated pressures: Experiments and modeling, Combustion and Flame, vol.97, issue.2, pp.201-224, 1994.
DOI : 10.1016/0010-2180(94)90005-1

P. Barbe, F. Battin-leclerc, C. , and G. M. , Experimental and modeling study of methane and ethane oxidation between 773 and 1573 K, Journal de Chimie Physique, issue.92, pp.1666-1692, 1995.

D. L. Baulch, C. J. Cobos, R. A. Cox, P. Frank, G. Hayman et al., Summary table of evaluated kinetic data for combustion modeling: Supplement 1, Combustion and Flame, vol.98, issue.1-2, pp.59-79, 1994.
DOI : 10.1016/0010-2180(94)90198-8

W. Tsang and R. F. Hampson, Chemical Kinetic Data Base for Combustion Chemistry. Part I. Methane and Related Compounds, Journal of Physical and Chemical Reference Data, vol.15, issue.3, pp.1087-1279, 1986.
DOI : 10.1063/1.555759

R. Fournet, J. C. Bauge, and F. Battin-leclerc, Experimental and modeling of oxidation of acetylene, propyne, allene and 1,3-butadiene, International Journal of Chemical Kinetics, vol.92, issue.117, pp.31-361, 1999.
DOI : 10.1051/jcp/1995921154

N. Belmekki, P. A. Glaude, I. Da-costa, R. Fournet, and F. Battin-leclerc, Experimental and modeling study of the oxidation of 1-butyne and 2-butyne, International Journal of Chemical Kinetics, vol.121, issue.2, pp.34-172, 2002.
DOI : 10.1016/S0010-2180(99)00129-7

A. El-bakali, L. Pillier, P. Desgroux, B. Lefort, L. Gasnot et al., NO prediction in natural gas flames using GDF-Kin??3.0 mechanism NCN and HCN contribution to prompt-NO formation, Fuel, vol.85, issue.7-8, pp.85-92, 2006.
DOI : 10.1016/j.fuel.2005.10.012

M. Frenklach, H. Wang, and M. J. Rabinowitz, Optimization and analysis of large chemical kinetic mechanisms using the solution mapping method???combustion of methane, Progress in Energy and Combustion Science, pp.47-73, 1992.
DOI : 10.1016/0360-1285(92)90032-V

M. Frenklach, Systematic optimization of a detailed kinetic model using a methane ignition example, Combustion and Flame, vol.58, issue.1, pp.69-72, 1984.
DOI : 10.1016/0010-2180(84)90079-8

A. A. Konnov, Development and validation of a detailed reaction mechanism for the combustion of small hydrocarbons, 28-th Symposium (Int.) on Combustion. 2000: Edinburgh, Abstr. Symp. Pap. p. 317

A. A. Konnov, J. N. Zhu, J. H. Bromly, and D. K. Zhang, NONCATALYTIC PARTIAL OXIDATION OF METHANE INTO SYNGAS OVER A WIDE TEMPERATURE RANGE, Combustion Science and Technology, vol.4, issue.7, pp.176-1093, 2004.
DOI : 10.1063/1.1376128

K. J. Hughes, T. Turanyi, A. R. Clague, and M. J. Pilling, Development and testing of a comprehensive chemical mechanism for the oxidation of methane, International Journal of Chemical Kinetics, vol.32, issue.9, pp.33-513, 2001.
DOI : 10.1021/j100039a027

S. Rolland and J. M. Simmie, The comparison of detailed chemical kinetic mechanisms: Application to the combustion of methane, International Journal of Chemical Kinetics, vol.151, issue.9, pp.467-471, 2004.
DOI : 10.1016/S0082-0784(06)80427-3

P. Glarborg, Hidden interactions???Trace species governing combustion and emissions, Proceedings of the Combustion Institute, pp.77-98, 2007.
DOI : 10.1016/j.proci.2006.08.119

T. Faravelli, A. Frassoldati, R. , and E. , Kinetic modeling of the interactions between NO and hydrocarbons in the oxidation of hydrocarbons at low temperatures, Combustion and Flame, vol.132, issue.1-2, pp.188-207, 2003.
DOI : 10.1016/S0010-2180(02)00437-6

S. Irusta, E. A. Lombardo, and E. E. Miró, Effects of NO and solids on the oxidation of methane to formaldehyde, Catalysis Letters, vol.79, issue.3-4, pp.29-32, 1994.
DOI : 10.1007/BF00807113

M. A. Bañares, J. H. Cardoso, G. J. Hutchings, J. M. Bueno, and J. L. Fierro, Selective oxidation of methane to methanol and formaldehyde over V 2 O 5 /SiO 2 catalysts. Role of NO in the gas phase, Catalysis Letters, pp.56-59, 1998.

K. Otsuka, R. Takahashi, K. Amakawa, Y. , and I. , Partial oxidation of light alkanes by NOx in the gas phase, Catalysis Today, vol.45, issue.1-4, pp.45-46, 1998.
DOI : 10.1016/S0920-5861(98)00233-8

K. Otsuka, R. Takahashi, Y. , and I. , Oxygenates from Light Alkanes Catalyzed by NOx in the Gas Phase, Journal of Catalysis, vol.185, issue.1, pp.182-191, 1999.
DOI : 10.1006/jcat.1999.2507

Y. Teng, H. Sakurai, K. Tabata, and E. Suzuki, Methanol formation from methane partial oxidation in CH4???O2???NO gaseous phase at atmospheric pressure, Applied Catalysis A: General, vol.190, issue.1-2, pp.283-289, 2000.
DOI : 10.1016/S0926-860X(99)00325-7

K. Tabata, Y. Teng, Y. Yamaguchi, H. Sakurai, and E. Suzuki, Experimental Verification of Theoretically Calculated Transition Barriers of the Reactions in a Gaseous Selective Oxidation of CH 4 -O 2 -NO 2, Journal of Physical Chemistry A, issue.12, pp.104-2648, 2000.

T. Takemoto, K. Tabata, Y. Teng, A. Nakayama, and E. Suzuki, Effects of reaction pressures on the production of methanol through the selective oxidation of methane in CH 4 -O 2 -NO x (x = 1 or 2) Applied Catalysis A: General, pp.51-59, 2001.

T. Takemoto, K. Tabata, Y. Teng, L. X. Dai, and E. Suzuki, Selective oxidation of methane in CH4???O2???NO2 over MoO3, Catalysis Today, vol.71, issue.1-2, pp.47-53, 2001.
DOI : 10.1016/S0920-5861(01)00441-2

T. Takemoto, K. Tabata, Y. Teng, S. Yao, A. Nakayama et al., Optimization of C 1 -oxygenates for the selective oxidation of methane in a gas-phase reaction of CH 4 -O 2 -NO at atmospheric pressure. Energy and Fuels, pp.44-51, 2001.

A. Sen and M. Lin, NO x -catalyzed partial oxidation of methane and ethane to formaldehyde by dioxygen, Topics in Catalysis, vol.32, pp.3-4, 2005.

Y. Yamaguchi, Y. Teng, S. Shimomura, K. Tabata, and E. Suzuki, = 1, 2), The Journal of Physical Chemistry A, vol.103, issue.41, pp.8272-8278, 1999.
DOI : 10.1021/jp990985a

T. Takemoto, D. He, Y. Teng, A. Nakayama, K. Tabata et al., Enhancement of Methanol Selectivity in the Products of Direct Selective Oxidation of Methane in CH4???O2???NO with Cu???ZnO/Al2O3, Journal of Catalysis, vol.198, issue.1, pp.109-115, 2001.
DOI : 10.1006/jcat.2000.3119

T. Takemoto, D. He, Y. Teng, K. Tabata, and E. Suzuki, The optimization of methanol yield in direct selective oxidation of methane with O2 and NO in the presence of Cu-ZnO/Al2O3, Journal of Molecular Catalysis A: Chemical, vol.179, issue.1-2, pp.279-286, 2002.
DOI : 10.1016/S1381-1169(01)00399-5

T. Takemoto, D. He, Y. Teng, K. Tabata, and E. Suzuki, Enhancement of methanol selectivity in the products of direct selective oxidation of methane in CH4-O2-NO with Cu-ZnO/SiO2, Applied Catalysis A: General, vol.225, issue.1-2, pp.177-184, 2002.
DOI : 10.1016/S0926-860X(01)00867-5

J. H. Bromly, F. J. Barnes, S. Muris, X. You, and B. S. Haynes, Kinetic and Thermodynamic Sensitivity Analysis of the NO-Sensitised Oxidation of Methane, Combustion Science and Technology, vol.87, issue.4-6, pp.4-6, 1996.
DOI : 10.1039/f29888400549

A. B. Bendtsen, P. Glarborg, and K. Dam-johansen, Low temperature oxidation of methane: the influence of nitrogen oxides, Combustion Science and Technology, vol.145, issue.1, pp.31-71, 2000.
DOI : 10.1021/j100039a027

P. Glarborg, M. U. Alzueta, K. Dam-johansen, and J. A. Miller, Kinetic Modeling of Hydrocarbon/Nitric Oxide Interactions in a Flow Reactor, Combustion and Flame, vol.115, issue.1-2, pp.1-2, 1998.
DOI : 10.1016/S0010-2180(97)00359-3

C. L. Rasmussen, A. E. Rasmussen, and P. Glarborg, Sensitizing effects of NOx on CH4 oxidation at high pressure, Combustion and Flame, vol.154, issue.3, pp.529-545, 2008.
DOI : 10.1016/j.combustflame.2008.01.012

M. Hori, N. Matsunaga, N. Marinov, W. Pitz, W. et al., An experimental and kinetic calculation of the promotion effect of hydrocarbons on the NO-NO2 conversion in a flow reactor, Symposium (International) on Combustion, pp.389-396, 1998.
DOI : 10.1016/S0082-0784(98)80427-X

A. A. Konnov, J. N. Zhu, J. H. Bromly, and D. K. Zhang, The effect of NO and NO2 on the partial oxidation of methane: experiments and modeling, Proceedings of the Combustion Institute, pp.30-1093, 2005.
DOI : 10.1016/j.proci.2004.07.012

K. J. Hughes, A. S. Tomlin, E. Hampartsoumian, W. Nimmo, I. G. Zsély et al., An investigation of important gas-phase reactions of nitrogenous species from the simulation of experimental measurements in combustion systems, Combustion and Flame, vol.124, issue.4, pp.573-589, 2001.
DOI : 10.1016/S0010-2180(00)00228-5

V. S. Arutyunov, V. Y. Basevich, and V. I. Vedeneev, Direct high-pressure gas-phase oxidation of natural gas to methanol and other oxygenates, Russian Chemical Reviews, vol.65, issue.3, pp.65-197, 1996.
DOI : 10.1070/RC1996v065n03ABEH000207

J. C. Tricot, A. Perche, and M. Lucquin, Gas phase oxidation of nitromethane, Combustion and Flame, vol.40, pp.40-269, 1981.
DOI : 10.1016/0010-2180(81)90130-9

J. M. Zalc, W. H. Green, and E. Iglesia, NO x -mediated homogeneous pathways for the synthesis of formaldehyde from CH 4 -O 2 mixtures, Industrial and Engineering Chemistry Research, issue.8, pp.45-2677, 2006.

L. Schmidt, Millisecond chemical reactions and reactors. Studies in surface science and catalysis, 130A(International Congress on Catalysis, pp.61-76, 2000.

E. C. Wanat, B. Suman, and L. D. Schmidt, Partial oxidation of alcohols to produce hydrogen and chemicals in millisecond-contact time reactors, Journal of Catalysis, vol.235, issue.1, pp.18-27, 2005.
DOI : 10.1016/j.jcat.2005.07.015

L. Bobrova, N. Vernikovskaya, and V. Sadykov, Conversion of hydrocarbon fuels to syngas in a short contact time catalytic reactor, Catalysis Today, vol.144, issue.3-4, pp.3-4, 2009.
DOI : 10.1016/j.cattod.2009.01.034

D. A. Hickman and L. D. Schmidt, Production of Syngas by Direct Catalytic Oxidation of Methane, Science, vol.259, issue.5093, pp.343-346, 1993.
DOI : 10.1126/science.259.5093.343

A. Mitri, D. Neumann, T. Liu, and G. Veser, Reverse-flow reactor operation and catalyst deactivation during high-temperature catalytic partial oxidation, Chemical Engineering Science, vol.59, issue.22-23, pp.22-23, 2004.
DOI : 10.1016/j.ces.2004.07.104

N. Popova, R. Salakhova, K. Dosumov, S. Tungatarova, A. Sass et al., Nickel-copper-chromium catalyst for selective methane oxidation to synthesis gas at short residence times, Kinetics and Catalysis, vol.434, issue.435, pp.567-576, 2009.
DOI : 10.1023/A:1010465315877

M. Fleys, Y. Simon, and P. M. Marquaire, Catalyst. Part 2:?? Mechanism, Industrial & Engineering Chemistry Research, vol.46, issue.4, pp.1069-1078, 2007.
DOI : 10.1021/ie060343r

URL : https://hal.archives-ouvertes.fr/hal-00139862

A. B. Mhadeshwar and D. G. Vlachos, A Catalytic Reaction Mechanism for Methane Partial Oxidation at Short Contact Times, Reforming, and Combustion, and for Oxygenate Decomposition and Oxidation on Platinum, Industrial & Engineering Chemistry Research, vol.46, issue.16, pp.46-5310, 2007.
DOI : 10.1021/ie070322c

R. J. Kee, F. M. Rupley, J. A. Miller, and C. Lombard, Chemkin-II: A Fortran chemical kinetics package for the analysis of gas-phase chemical kinetics, in Report SAND 89-8009, Thesis. 2001, INPL-LRGP: Nancy. [2] Lombard, C. and Marquaire, P.M., New study of methane to vinyl chloride process. Studies in Surface Science and Catalysis, pp.529-534, 1989.

J. L. Houzelot and J. Villermaux, Mass transfer in annular cylindrical reactors in laminar flow, Chemical Engineering Science, vol.32, issue.12, pp.32-1465, 1977.
DOI : 10.1016/0009-2509(77)80243-1

A. Beretta, P. Baiardi, D. Prina, and P. Forzatti, Analysis of a catalytic annular reactor for very short contact times, Chemical Engineering Science, vol.54, issue.6, pp.765-773, 1999.
DOI : 10.1016/S0009-2509(98)00261-9

J. L. Houzelot and J. Villermaux, A novel device for quenching: The cylindrical annular exchanger in laminar flow, Chemical Engineering Science, vol.39, issue.9, pp.1409-1413, 1984.
DOI : 10.1016/0009-2509(84)80074-3

K. F. Jensen, Microreaction engineering ??? is small better?, Chemical Engineering Science, vol.56, issue.2, pp.293-303, 2001.
DOI : 10.1016/S0009-2509(00)00230-X

H. Löwe, V. Hessel, A. Mueller, M. Mills, P. L. Quiram et al., Prospects already achieved and possible misuse Microreactor technology and process miniaturization for catalytic reactions--A perspective on recent developments and emerging technologies, Génie de la réaction chimique: conception et fonctionnement des réacteurs, pp.74-2271, 1993.

F. Vasbien, Dimensionnement et Caractérisation d'un Microréacteur, in Rapport de stage de fin d'études DUT Génie des Procédés, Juin, 2007.

V. Burklé-vitzthum, F. Moulis, J. M. Commenge, E. Schaer, and P. M. Marquaire, Residence Time Distribution and Computational Fluid Dynamics in an annular flow microreactor, in 19-th CHISA, 2010.

F. Moulis, Gas flow and methane oxidation modelling: Computational fluid dynamics in an annular microreactor

B. E. Poling, J. M. Prausnitz, O. Connell, and J. P. , The properties of gases and liquids, 2001.

A. Karch, Synthèse de formaldéhyde par oxydation directe du méthane, in Stage de recherche, 2010.

Q. Zhang, D. He, and Q. Zhu, Direct partial oxidation of methane to methanol: Reaction zones and role of catalyst location, Journal of Natural Gas Chemistry, vol.17, issue.1, pp.24-28, 2008.
DOI : 10.1016/S1003-9953(08)60021-3

J. W. Chun and R. G. Anthony, Partial oxidation of methane, methanol, and mixtures of methane and methanol, methane and ethane, and methane, carbon dioxide, and carbon monoxide, Industrial & Engineering Chemistry Research, vol.32, issue.5, pp.32-788, 1993.
DOI : 10.1021/ie00017a004

. Les-mélanges-explosifs, Gaz et vapeurs, in DE911, Bulletin INRS, 2004.

J. L. Gustin, Risque d'explosion de gaz, SE5020. 10 avril, 2002.

W. Mason, R. V. Wheeler, and . Vii, VII.???The effect of temperature and of pressure on the limits of inflammability of mixtures of methane and air, J. Chem. Soc., Trans., vol.113, issue.0, pp.45-57, 1918.
DOI : 10.1039/CT9181300045

L. Medard, Les Explosifs occasionnels, pp.186-208

O. L. Brady and G. V. Elsmie, The use of 2:4-dinitrophenylhydrazine as a reagent for aldehydes and ketones. The Analyst, pp.51-77, 1926.

F. Lipari and S. J. Swarin, Determination of formaldehyde and other aldehydes in automobile exhaust with an improved 2,4-dinitrophenylhydrazine method, Journal of Chromatography A, vol.247, issue.2, pp.297-306, 1982.
DOI : 10.1016/S0021-9673(00)85953-1

R. J. Kee, F. M. Rupley, and J. A. Miller, Chemkin-II: A Fortran chemical kinetics package for the analysis of gas-phase chemical kinetics, 1989.

J. Troe, Fall-off curves of unimolecular reactions. Berichte der Bunsen-Gesellschaft - Physycal Chemistry, pp.478-88, 1974.

S. Gordon and B. J. Mcbride, Computer Program for Calculation of Complex Chemical Equilibrium Compositions, Rocket Performance, Incident and Reflected Shocks, and Chapman-Jouguet Detonations. NASA SP-273 MECHMOD: Software Aid to the Development of Reaction Mechanisms, 1971.

C. Morley, Gaseq: A Chemical Equilibrium Program for Windows

S. Rolland and J. M. Simmie, The comparison of detailed chemical kinetic mechanisms; forward versus reverse rates with CHEMRev, International Journal of Chemical Kinetics, vol.33, issue.3, pp.119-125, 2005.
DOI : 10.1002/kin.20049

J. M. Simmie, Automated comparison of thermodynamic data, 2011.

Y. Tan, P. Dagaut, M. Cathonnet, and J. C. Boettner, Oxidation and Ignition of Methane-Propane and Methane-Ethane-Propane Mixtures: Experiments and Modeling, Combustion Science and Technology, vol.88, issue.1-6, pp.133-51, 1994.
DOI : 10.1016/0360-1285(92)90003-J

P. Barbe, F. Battin-leclerc, C. , and G. M. , Experimental and modeling study of methane and ethane oxidation between 773 and 1573 K, Journal de Chimie Physique, issue.92, pp.1666-1692, 1995.

A. A. Konnov, M. J. Turányi, T. Hughes, K. J. Tomlin, and A. S. , Development and validation of a detailed reaction mechanism for the combustion of small hydrocarbons, 28-th Symposium (Int.) on Combustion, p.317, 2000.

T. C. Chou and L. F. Albright, Partial oxidation of methane in glass and metal tubular reactors. Industrial and Engineering Chemistry Process Design and Development, pp.454-459, 1978.

D. J. Thomas, R. Willi, and A. Baiker, Partial oxidation of methane: the role of surface reactions, Industrial & Engineering Chemistry Research, vol.31, issue.10, pp.31-2272, 1992.
DOI : 10.1021/ie00010a003

A. A. Konnov, J. N. Zhu, J. H. Bromly, and D. K. Zhang, NONCATALYTIC PARTIAL OXIDATION OF METHANE INTO SYNGAS OVER A WIDE TEMPERATURE RANGE, Combustion Science and Technology, vol.4, issue.7, pp.176-1093, 2004.
DOI : 10.1063/1.1376128

B. H. Mcconkey and P. R. Wilkinson, Oxidation of methane to formaldehyde in a fluidized bed reactor. Industrial and Engineering Chemistry Process Design and Development, pp.436-440, 1967.

I. I. Bobrova, N. N. Bobrov, L. G. Simonova, and V. N. Parmon, Direct catalytic oxidation of methane to formaldehyde: New investigation opportunities provided by an improved flow circulation method, Kinetics and Catalysis, vol.31, issue.4, pp.48-676, 2007.
DOI : 10.1007/978-94-010-0554-8_10

Y. Simon, F. Baronnet, and P. M. Marquaire, Kinetic Modeling of the Oxidative Coupling of Methane, Industrial & Engineering Chemistry Research, vol.46, issue.7, pp.46-1914, 2007.
DOI : 10.1021/ie060151w

URL : https://hal.archives-ouvertes.fr/hal-00140031

R. Lødeng, O. A. Lindvag, P. Soraker, P. T. Roterud, and O. T. Onsager, Experimental and Modeling Study of the Selective Homogeneous Gas Phase Oxidation of Methane to Methanol, Industrial & Engineering Chemistry Research, vol.34, issue.4, pp.1044-1059, 1995.
DOI : 10.1021/ie00043a006

K. Omata, N. Fukuoka, and K. Fujimoto, Methane Partial Oxidation to Methanol. 1. Effects of Reaction Conditions and Additives, Industrial & Engineering Chemistry Research, vol.33, issue.4, pp.784-789, 1994.
DOI : 10.1021/ie00028a002

J. W. Chun and R. G. Anthony, Free-radical kinetic model for homogeneous oxidation of methane to methanol, Industrial & Engineering Chemistry Research, vol.32, issue.5, pp.796-799, 1993.
DOI : 10.1021/ie00017a005

H. Zanthoff and M. Baerns, Oxidative coupling of methane in the gas phase. Kinetic simulation and experimental verification, Industrial & Engineering Chemistry Research, vol.29, issue.1, pp.2-10, 1990.
DOI : 10.1021/ie00097a001

J. M. Zalc, W. H. Green, and E. Iglesia, NO x -mediated homogeneous pathways for the synthesis of formaldehyde from CH 4 -O 2 mixtures, Industrial and Engineering Chemistry Research, issue.8, pp.45-2677, 2006.

T. Takemoto, K. Tabata, Y. Teng, S. Yao, A. Nakayama et al., Optimization of C 1 -oxygenates for the selective oxidation of methane in a gas-phase reaction of CH 4 -O 2 -NO at atmospheric pressure. Energy and Fuels, pp.44-51, 2001.

J. H. Bromly, F. J. Barnes, S. Muris, X. You, and B. S. Haynes, Kinetic and Thermodynamic Sensitivity Analysis of the NO-Sensitised Oxidation of Methane, Combustion Science and Technology, vol.87, issue.4-6, pp.4-6, 1996.
DOI : 10.1039/f29888400549

D. L. Baulch, C. J. Cobos, R. A. Cox, P. Frank, G. Hayman et al., Summary table of evaluated kinetic data for combustion modeling: Supplement 1, Combustion and Flame, vol.98, issue.1-2, pp.59-79, 1994.
DOI : 10.1016/0010-2180(94)90198-8

A. B. Bendtsen, P. Glarborg, and K. Dam-johansen, Low temperature oxidation of methane: the influence of nitrogen oxides, Combustion Science and Technology, vol.145, issue.1, pp.31-71, 2000.
DOI : 10.1021/j100039a027

P. Glarborg, A. B. Bendtsen, and J. A. Miller, Nitromethane dissociation: Implications for the CH 3 + NO 2 Reaction, International Journal of Chemical Kinetics, issue.9, pp.31-591, 1999.

D. L. Baulch, C. T. Bowman, C. J. Cobos, R. A. Cox, T. Just et al., Evaluated Kinetic Data for Combustion Modeling: Supplement II, Journal of Physical and Chemical Reference Data, vol.34, issue.3, pp.34-757, 2005.
DOI : 10.1063/1.1748524

M. Hori, N. Matsunaga, N. Marinov, W. Pitz, W. et al., An experimental and kinetic calculation of the promotion effect of hydrocarbons on the NO-NO2 conversion in a flow reactor, Symposium (International) on Combustion, pp.389-396, 1998.
DOI : 10.1016/S0082-0784(98)80427-X

W. Tsang, O, Journal of Physical and Chemical Reference Data, vol.20, issue.4, pp.609-663, 1991.
DOI : 10.1063/1.555890

URL : https://hal.archives-ouvertes.fr/cea-01505556

J. C. Tricot, A. Perche, and M. Lucquin, Gas phase oxidation of nitromethane, Combustion and Flame, vol.40, pp.40-269, 1981.
DOI : 10.1016/0010-2180(81)90130-9

K. Glaenzer and J. Troe, Reactions of alkyl radicals in the shock wave-induced pyrolysis of nitroalkanes, Berichte der Bunsen-Gesellschaft Physical Chemistry, vol.78, pp.182-186, 1974.

K. Glanzer and J. Troe, Thermische Zerfallsreaktionen von Nitroverbindungen I: Dissoziation von Nitromethan, Helvetica Chimica Acta, vol.48, issue.8, p.2884, 1972.
DOI : 10.1063/1.1668710

I. S. Zaslonko, Y. P. Petrov, and V. N. Smirnov, Thermal Decomposition of Nitromethane in Shock Waves: The Effect of Pressure and Collision Partners, Kinetics and Catalysis, vol.38, issue.3, pp.321-324, 1997.

R. J. Kee, F. M. Rupley, and J. A. Miller, The CHEMKIN Thermodynamic Database, 1987.

A. Burcat and B. Ruscic, Third Millennium Ideal Gas and Condensed Phase Thermochemical Database for Combustion with updates from Active Thermochemical Tables ANL-05/20 and TAE 960 Technion-IIT, Chemistry Division. Available, 2005.

T. Ko and A. Fontijn, High-temperature photochemistry kinetics study of the reaction H + NO 2 ? OH + NO from 296 to 760 K, Journal of Physical Chemistry, issue.10, pp.95-3984, 1991.

T. Faravelli, A. Frassoldati, R. , and E. , Kinetic modeling of the interactions between NO and hydrocarbons in the oxidation of hydrocarbons at low temperatures, Combustion and Flame, vol.132, issue.1-2, pp.188-207, 2003.
DOI : 10.1016/S0010-2180(02)00437-6

M. Hori, Y. Koshiishi, N. Matsunaga, P. Glaude, and N. Marinov, Temperature dependence of NO to NO2 conversion by n-butane and n-pentane oxidation, Proceedings of the Combustion Institute, pp.2219-2226, 2002.
DOI : 10.1016/S1540-7489(02)80270-X

Y. L. Chan, F. J. Barnes, J. H. Bromly, A. A. Konnov, and D. K. Zhang, The differentiated effect of NO and NO2 in promoting methane oxidation, Proceedings of the Combustion Institute, pp.441-447, 2011.
DOI : 10.1016/j.proci.2010.05.029

P. Glarborg, M. U. Alzueta, K. Kjaergaard, and K. Dam-johansen, Oxidation of formaldehyde and its interaction with nitric oxide in a flow reactor, Combustion and Flame, vol.132, issue.4, pp.629-638, 2003.
DOI : 10.1016/S0010-2180(02)00535-7

M. W. Slack and A. R. Grillo, Shock tube investigation of methane-oxygen ignition sensitized by NO2, Combustion and Flame, vol.40, pp.40-155, 1981.
DOI : 10.1016/0010-2180(81)90120-6

K. J. Hughes, A. S. Tomlin, E. Hampartsoumian, W. Nimmo, I. G. Zsély et al., An investigation of important gas-phase reactions of nitrogenous species from the simulation of experimental measurements in combustion systems, Combustion and Flame, vol.124, issue.4, pp.573-589, 2001.
DOI : 10.1016/S0010-2180(00)00228-5

K. Otsuka, R. Takahashi, Y. , and I. , Oxygenates from Light Alkanes Catalyzed by NOx in the Gas Phase, Journal of Catalysis, vol.185, issue.1, pp.182-191, 1999.
DOI : 10.1006/jcat.1999.2507

J. C. Mackie, Partial Oxidation of Methane: The Role of the Gas Phase Reactions, Catalysis Reviews, vol.95, issue.1-2, pp.169-240, 1991.
DOI : 10.1071/CH9861929

Y. Teng, H. Sakurai, K. Tabata, and E. Suzuki, Methanol formation from methane partial oxidation in CH4???O2???NO gaseous phase at atmospheric pressure, Applied Catalysis A: General, vol.190, issue.1-2, pp.283-289, 2000.
DOI : 10.1016/S0926-860X(99)00325-7

K. Tabata, Y. Teng, Y. Yamaguchi, H. Sakurai, and E. Suzuki, Experimental Verification of Theoretically Calculated Transition Barriers of the Reactions in a Gaseous Selective Oxidation of CH 4 -O 2 -NO 2, Journal of Physical Chemistry A, issue.12, pp.104-2648, 2000.

C. L. Rasmussen, A. E. Rasmussen, and P. Glarborg, Sensitizing effects of NOx on CH4 oxidation at high pressure, Combustion and Flame, vol.154, issue.3, pp.529-545, 2008.
DOI : 10.1016/j.combustflame.2008.01.012

R. J. Kee, F. M. Rupley, and J. A. Miller, Chemkin-II: A Fortran chemical kinetics package for the analysis of gas-phase chemical kinetics, 1989.

J. M. Zalc, W. H. Green, and E. Iglesia, NO x -mediated homogeneous pathways for the synthesis of formaldehyde from CH 4 -O 2 mixtures, Industrial and Engineering Chemistry Research, issue.8, pp.45-2677, 2006.

J. H. Bromly, F. J. Barnes, S. Muris, X. You, and B. S. Haynes, Kinetic and Thermodynamic Sensitivity Analysis of the NO-Sensitised Oxidation of Methane, Combustion Science and Technology, vol.87, issue.4-6, pp.4-6, 1996.
DOI : 10.1039/f29888400549

A. B. Bendtsen, P. Glarborg, and K. Dam-johansen, Low temperature oxidation of methane: the influence of nitrogen oxides, Combustion Science and Technology, vol.145, issue.1, pp.31-71, 2000.
DOI : 10.1021/j100039a027

M. Hori, N. Matsunaga, N. Marinov, W. Pitz, W. et al., An experimental and kinetic calculation of the promotion effect of hydrocarbons on the NO-NO2 conversion in a flow reactor, Symposium (International) on Combustion, pp.389-396173, 1998.
DOI : 10.1016/S0082-0784(98)80427-X

B. L. Lefrançois, Chimie industrielle T. 3: Combustions et explosions des mélanges gazeux -Cours et problèmes résolus, pp.70-93, 1999.

F. Vasbien, Dimensionnement et Caractérisation d'un Microréacteur, Rapport de stage de fin d'études DUT Génie des Procédés. Juin, 2007.

J. M. Commenge, T. Obein, G. Genin, X. Framboisier, S. Rode et al., Gas-phase residence time distribution in a falling-film microreactor, Chemical Engineering Science, vol.61, issue.2, pp.61-597, 2006.
DOI : 10.1016/j.ces.2005.07.015

URL : https://hal.archives-ouvertes.fr/hal-00285805

B. E. Poling, J. M. Prausnitz, O. Connell, and J. P. , The properties of gases and liquids, 2001.

A. Karch, Synthèse de formaldéhyde par oxydation directe du méthane, Stage de recherche. 2010, INPL-LRGP-EEIGM: Nancy

J. Troe, Fall-off curves of unimolecular reactions. Berichte der Bunsen-Gesellschaft - Physycal Chemistry, pp.478-88, 1974.

A. A. Konnov, M. J. Turányi, T. Hughes, K. J. Tomlin, and A. S. , Development and validation of a detailed reaction mechanism for the combustion of small hydrocarbons, 28-th Symposium (Int.) on Combustion, p.317, 2000.

P. Barbe, F. Battin-leclerc, C. , and G. M. , Experimental and modeling study of methane and ethane oxidation between 773 and 1573 K, Journal de Chimie Physique, issue.92, pp.1666-1692, 1995.

A. A. Konnov, J. N. Zhu, J. H. Bromly, and D. K. Zhang, The effect of NO and NO2 on the partial oxidation of methane: experiments and modeling, Proceedings of the Combustion Institute, pp.1093-1100, 2005.
DOI : 10.1016/j.proci.2004.07.012

V. Zhang, P. M. Burklé-vitzthum, J. M. Marquaire, and G. Commenge, Wild Direct conversion of methane in formaldehyde at very short residence time. Communication internationale par affiche, 9th Novel Gas Conversion Symposium (NGCS9), 2010.

V. Zhang, P. M. Burklé-vitzthum, J. M. Marquaire, and G. Commenge, Wild Partial oxidation of methane in an annular flow microreactor. Experimental results. Communication internationale par affiche, International Conference on Microreaction Technology, vol.11, 2010.

V. Zhang, P. M. Burklé-vitzthum, J. M. Marquaire, and G. Commenge, Wild Partial oxidation of methane in an annular flow microreactor. Experimental results. Communication par affiche

J. Zhang, V. Burklé-vitzthum, P. M. Marquaire, G. Wild, and J. M. , Commenge Direct conversion of methane in formaldehyde at very short residence time, Chemical Engineering Science, issue.24, pp.666331-6340, 2011.