G. E. Powell, J. D. Chambley, and N. M. Cole, The effect of oxygen and carbon dioxide levels on enzyme development in malting, Proc. Conv. Inst. Brew. (Cent. And South African Sect), pp.45-54, 1993.

V. Psota, K. Vejrazka, O. Famera, and M. Hrcka, Relationship Between Grain Hardness and Malting Quality of Barley (Hordeum vulgare L.), Journal of the Institute of Brewing, vol.31, issue.6, pp.80-86, 2007.
DOI : 10.1111/j.1745-4603.1979.tb01305.x

L. M. Reid, T. Woodcock, C. P. O-'donnell, J. D. Kelly, and G. Downey, Differentiation of apple juice samples on the basis of heat treatment and variety using chemometric analysis of MIR and NIR data, Food Research International, vol.38, issue.10, pp.1109-1115, 2005.
DOI : 10.1016/j.foodres.2005.03.005

J. B. Reeves and S. R. Delwiche, Determination of Protein in Ground Wheat Samples by Mid-Infrared Diffuse Reflectance Spectroscopy, Applied Spectroscopy, vol.63, issue.8, pp.1200-1204, 1997.
DOI : 10.2135/cropsci1972.0011183X001200030035x

C. Ridgway, J. Chambers, and I. A. Cowe, Detection of grain weevils inside single wheat kernels by a very near infrared two-wavelength model J. Near Infrared spectroscopy, pp.213-221, 1999.

Y. Roggo, P. Chalus, L. Maurer, C. Lema-martinez, A. Edmond et al., A review of near infrared spectroscopy and chemometrics in pharmaceutical technologies, Journal of Pharmaceutical and Biomedical Analysis, vol.44, issue.3, pp.683-700, 2007.
DOI : 10.1016/j.jpba.2007.03.023

H. F. Seefeldt, F. V. Berg, W. Kockenberger, S. B. Engelsen, and B. Wollenweber, Water mobility in the endosperm of high beta-glucan barley mutants as studied by nuclear magnetic resonance imaging, Magnetic Resonance Imaging, vol.25, issue.3, pp.425-432, 2007.
DOI : 10.1016/j.mri.2006.09.030

Y. Shao, C. Zhao, Y. He, and Y. Bao, Infrared spectroscopy and chemometrics for the starch and protein prediction in irradiated rice, Food Chemistry, vol.126, issue.4, pp.1856-1861, 2008.
DOI : 10.1016/j.foodchem.2010.11.166

M. Sheehy, A. Marafioti, C. Krawec, B. Löfqvist, and D. Stewart, Active stark management-activity undoing malt quality, Proc. 14 th Australian barley technical symposium, 2009.

V. Sileoni, G. Perretti, . Marte, L. Marte, O. Marconi et al., Near-Infrared Spectroscopy for Proficient Quality Evaluation of the Malt and Maize Used for Beer Production, Journal of the Institute of Brewing, vol.56, issue.2, pp.134-140, 2010.
DOI : 10.1021/jf073407x

V. Sottnikova, L. Hrivna, and I. Hartman, Influence of Starch Content on the Germination Speed of Spring Barley Seeds. Book Group Authors:CULS Prague. Source: Seed and Seedlings, pp.118-123, 2013.

P. A. Tarantilis, V. E. Troianou, C. S. Pappas, Y. S. Kotseridis, and M. G. Polissiou, Differentiation of Greek red wines on the basis of grape variety using attenuated total reflectance Fourier transform infrared spectroscopy, Food Chemistry, vol.111, issue.1, pp.192-196, 2008.
DOI : 10.1016/j.foodchem.2008.03.020

A. Tarr, D. Diepeveen, and R. Appels, Spectroscopic and chemical fingerprints in malted barley, Journal of Cereal Science, vol.56, issue.2, pp.268-275, 2012.
DOI : 10.1016/j.jcs.2012.02.007

A. Tay, R. K. Singh, S. S. Krishnan, and J. P. Gore, Authentication of olive oil adulterated with vegetable oils using Fourier transforms infrared spectroscopy. Lebensmittel-Wissnschaft und-Technologie-food science and technology 35, pp.99-103, 2002.

W. Tinsson, Plans d'expérience: constructions et analyses statistiques, Math´ematiques et Applications, vol.67, 2010.

R. D. Tobias, . Sas-institute-inc, and N. C. Cary, An Introduction to Partial Least Squares Regression

G. A. Toole, L. Gall, G. Colquhoun, I. J. Drea, S. Opanowicz et al., Spectroscopic analysis of diversity in the spatial distribution of arabinoxylan structures in endosperm cell walls of cereal species in the HEALTHGRAIN diversity collection, Journal of Cereal Science, vol.56, issue.2, pp.134-141, 2012.
DOI : 10.1016/j.jcs.2012.02.016

J. S. Torano and S. C. Van-hattum, Quantitative analysis of active compounds in pharmaceutical preparations by use of attenuated total-reflection Fourier transform mid-infrared spectrophotometry and the internal standard method, Journal of analytical chemistry, vol.371, pp.532-535, 2001.

S. Tsuchikawa and M. Schwanninger, A Review of Recent Near-Infrared Research for Wood and Paper (Part 2) Applied spectroscopy reviews 48, pp.560-587, 2013.

K. M. Turnbull and S. Rahman, Endosperm Texture in Wheat, Journal of Cereal Science, vol.36, issue.3, pp.327-337, 2002.
DOI : 10.1006/jcrs.2002.0468

L. Van-campenhout, H. Y. Shen, . Iserentant, and . Verchtert, The gas environment of germinating barley in various microbial states during malting, Process Biochemistry, vol.34, issue.9, pp.929-937, 1999.
DOI : 10.1016/S0032-9592(99)00018-7

J. G. Vansoest, D. De-wit, H. Tournois, and J. G. Vliegenthart, The influence of glycerol on structural changes in waxy maize starch as studied by Fourier transform infra-red spectroscopy, Polymer, vol.35, issue.22, pp.4722-4727, 1994.
DOI : 10.1016/0032-3861(94)90724-2

K. Vejrazka, V. Psota, J. Ehrenbergerova, and P. Hrstkova, Relationship between grain milling energy and malting quality of barley, Cereal Research Communications, vol.36, issue.1, pp.97-105, 2008.
DOI : 10.1556/CRC.36.2008.1.10

R. Viennet, Nouvelle technologie de planification expérimentale pour l'optimisation multicritères de procédés

J. Wallon, S. H. Yan, J. Tong, M. Meurens, and J. Haot, Identification of Breast Carcinomatous Tissue by Near-Infrared Reflectance Spectroscopy, Applied Spectroscopy, vol.52, issue.2, pp.190-193, 1994.
DOI : 10.1073/pnas.88.24.10988

X. J. Wang, X. F. Yuan, H. Wang, J. Li, X. F. Wang et al., Characteristics and community diversity of a wheat straw-colonizing microbial community, African Journal of Biotechnology, vol.10, pp.7853-7861, 2011.

P. C. Williams and D. C. Sobering, Attempts at standardization of hardness testing of wheat. 1. The grinding sievieng (particle size index) method. Cereal Foods World 31, pp.359-364, 1986.

H. Wold, Estimation of principal components and related models by iterative least squares, pp.391-420, 1966.

T. Woodcock, C. C. Fagan, C. P. O-'donnell, and G. Downey, Application of Near and Mid-Infrared Spectroscopy to Determine Cheese Quality and Authenticity. Food and bioprocess technology 1, pp.117-129, 2008.

J. L. Molina-cano, A. Sopena, J. P. Polo, C. Bergareche, M. A. Moralejo et al., Relationships Between Barley Hordeins and Malting Quality in a Mutant of cv. Triumph. II. Genetic and Environmental Effects on Water Uptake, Journal of Cereal Science, vol.36, issue.1, pp.39-50, 2002.
DOI : 10.1006/jcrs.2002.0440

A. G. Morgan, A. A. Gilland, D. Smith, and D. B. , some barley grain and green malt properties and their influence on malt hot water extract, 1983.

J. S. Swanston, A. C. Newton, S. P. Hoad, and W. Spoor, Variation across environments in patterns of water uptake and endosperm modification in barley varieties and variety mixtures, Journal of the Science of Food and Agriculture, vol.1, issue.5, pp.826-833, 2006.
DOI : 10.1002/j.2050-0416.2004.tb00202.x

E. Urion and H. Rouleau, Bière et malt, 1948.

R. Viennet, Nouvelle technologie de planification expérimentale pour l'optimisation multicritères de procédés, Thèse de l'Institut National Polytechnique de Lorraine, 1997.

E. Walter and L. Et-pronzato, Identification des modèles paramétriques à partir des données expérimentales, 1994.

D. E. Briggs, J. S. Hough, and R. Stevens, Malting and brewing science 2nd edition, 1981.

A. Hariri, Etude et modélisation de la trempe en malterie, Thesis de l'Institut National Polytechnique de Lorraine, 2003.

J. E. Holmberg, J. J. Hamalainen, P. Reinikainen, and J. Olkku, A Model for Predicting the Effects of a Steeping Program on the Germination of Barley with Different Water Sensitivities, Journal of the Institute of Brewing, vol.26, issue.4, pp.416-423, 2002.
DOI : 10.1002/0471725234

O. Grujic, D. J. Pejin, and N. M. Pruzulj, The effect of Winter barley variety and technological factors during malting on malt quality, Acta periodica technologica, vol.36, issue.36, pp.33-42, 2005.
DOI : 10.2298/APT0536033G

E. Bravi, O. Marconi, G. Perretti, and P. Fantozzi, Influence of barley variety and malting process on lipid content of malt, Food Chemistry, vol.135, issue.3, pp.1112-1117, 2012.
DOI : 10.1016/j.foodchem.2012.06.041

I. P. Mctaggart and K. A. Smith, The effect of fertiliser and soil nitrogen on the overall uptake of nitrogen in the plant, and the grain nitrogen content of spring-sown malting barley, HGCA Project Report, vol.46, 1992.

M. D. Fleury, M. J. Edney, L. D. Campbell, and G. H. Crow, Total, water-soluble and acid-soluble arabinoxylans in western Canadian barleys, Canadian Journal of Plant Science, vol.77, issue.2, pp.191-196, 1997.
DOI : 10.4141/P96-033

T. J. March, D. Richter, T. Colby, A. Harzen, J. R. Schmidt et al., Identification of proteins associated with malting quality in a subset of wild barley introgression lines, PROTEOMICS, vol.11, issue.18, pp.2843-2851, 2012.
DOI : 10.1002/pmic.201200117

J. Peltonen, H. Rita, R. Aikasalo, and S. Home, Hordein and Malting Quality in Northern Barleys, Hereditas, vol.1, issue.3, pp.231-239, 1994.
DOI : 10.1002/j.2050-0416.1980.tb03974.x

G. P. Fox, K. Onley-watson, and A. Osman, Multiple Linear Regression Calibrations for Barley and Malt Protein Based on the Spectra of Hordein, Journal of the Institute of Brewing, vol.2, issue.2, pp.155-159, 2002.
DOI : 10.1255/jnirs.41

G. S. Chandra, M. O. Proudlove, and E. D. Baxter, The structure of barley endosperm - an important determinant of malt modification, Journal of the Science of Food and Agriculture, vol.45, issue.1, pp.37-46, 1999.
DOI : 10.1002/j.2050-0416.1987.tb04489.x

U. R. Holopainen, A. Willhelmson, M. S. Marttila, P. P. Sainio, A. Arirajala et al., L.), Endosperm Structure Affects the Malting Quality of Barley, pp.7279-7287, 2005.
DOI : 10.1021/jf050349b

H. F. Seefeldt, F. V. Berg, W. Kockenberger, S. B. Engelsen, and B. Wollenweber, Water mobility in the endosperm of high beta-glucan barley mutants as studied by nuclear magnetic resonance imaging, Magnetic Resonance Imaging, vol.25, issue.3, pp.25-425, 2007.
DOI : 10.1016/j.mri.2006.09.030

P. Zapotocny, M. Zielinska, and Z. Nita, Application of image analysis for the varietal classification of barley:, Journal of Cereal Science, vol.48, issue.1, pp.104-110, 2008.
DOI : 10.1016/j.jcs.2007.08.006

D. Cozzolino, K. Allder, S. Roumeliotis, and J. Eglinton, Feasibility study on the use of multivariate data methods and derivatives to enhance information from barley flour and malt samples analysed using the Rapid Visco Analyser, Journal of Cereal Science, vol.56, issue.3, pp.1-5, 2012.
DOI : 10.1016/j.jcs.2012.07.004

S. Jacobsen, I. Sondergaard, B. Moller, T. Desler, and . Munk, A chemometric evaluation of the underlying physical and chemical patterns that support near infrared spectroscopy of barley seeds as a tool for explorative classification of endosperm genes and gene combinations, Journal of Cereal Science, vol.42, issue.3, pp.281-299, 2005.
DOI : 10.1016/j.jcs.2005.02.008

L. , M. , P. Belloni, E. Genorini, V. Sileoni et al., Near-infrared reflectance models for the rapid prediction of quality of brewing raw materials, J. Agri. Food Sci, vol.57, pp.326-333, 2009.

V. Sileoni, G. Perretti, L. Marte, O. Marconi, and P. Fantozzi, Near-Infrared Spectroscopy for Proficient Quality Evaluation of the Malt and Maize Used for Beer Production, Journal of the Institute of Brewing, vol.56, issue.2, pp.134-140, 2010.
DOI : 10.1021/jf073407x

A. R. Barr, R. Roumeliotis, S. J. Logue, and S. P. Jefferies, The heritability of malt extract predicted using NIR spectroscopy. Australian Barley Technical Symposium online, 1999.

A. Tarr, D. Diepeveen, and R. Appels, Spectroscopic and chemical fingerprints in malted barley, Journal of Cereal Science, vol.56, issue.2, pp.268-275, 2012.
DOI : 10.1016/j.jcs.2012.02.007

R. Davis and L. J. Mauer, Fourier transform infrared (FT-IR) spectroscopy: A rapid tool for detection and analysis of foodborne pathogenic bacteria Online published by: App. microbiology and microbial biotechnology © Formatex, pp.1582-1594, 2010.

B. Smith, Fundamentals of Fourier Transform Infrared Spectroscopy, 2011.

D. W. Lachenmeier, Rapid quality control of spirit drinks and beer using multivariate data analysis of Fourier transform infrared spectra, Food Chemistry, vol.101, issue.2, pp.825-832, 2007.
DOI : 10.1016/j.foodchem.2005.12.032

R. Lleti, E. Meléndez, M. C. Ortiz, L. A. Sarabia, and M. S. Sànchez, Outliers in partial least squares regression, Analytica Chimica Acta, vol.544, issue.1-2, pp.60-70, 2005.
DOI : 10.1016/j.aca.2005.03.075

E. Polshin, B. Aernouts, W. Saeys, F. Delvaux, F. R. Delvaux et al., Beer quality screening by FT-IR spectrometry: Impact of measurement strategies, data pre-processings and variable selection algorithms, Journal of Food Engineering, vol.106, issue.3, pp.188-198, 2011.
DOI : 10.1016/j.jfoodeng.2011.05.003

M. D. Guillén and N. Cabo, Infrared spectroscopy in the study of edible oils and fats, Journal of the Science of Food and Agriculture, vol.75, issue.1, pp.1-11, 1997.
DOI : 10.1002/(SICI)1097-0010(199709)75:1<1::AID-JSFA842>3.0.CO;2-R

M. Safar, D. Bertrand, P. Robert, M. F. Devaux, and C. Genot, Characterization of edible oils, butters and margarines by Fourier transform infrared spectroscopy with attenuated total reflectance, Journal of the American Oil Chemists' Society, vol.44, issue.4, pp.371-377, 1994.
DOI : 10.1366/0003702904085796

N. Koca, N. A. Kocaoglu, W. J. Harper, and L. E. Rodriguez, Application of temperature-controlled attenuated total reflectance-mid-infrared (ATR-MIR) spectroscopy for rapid estimation of butter adulteration, Food Chemistry, vol.121, issue.3, pp.778-782, 2010.
DOI : 10.1016/j.foodchem.2009.12.083

P. Robert, M. Malanie, C. Barron, F. Guillon, and L. Saulnier, FT-IR Investigation of Cell Wall Polysaccharides from Cereal Grains. Arabinoxylan Infrared Assignment, Journal of Agricultural and Food Chemistry, vol.53, issue.18, pp.7014-7018, 2005.
DOI : 10.1021/jf051145y

S. Philippe, P. Robert, C. Barron, L. Saulnier, and F. Gullon, Deposition of Cell Wall Polysaccharides in Wheat Endosperm during Grain Development:?? Fourier Transform-Infrared Microspectroscopy Study, Journal of Agricultural and Food Chemistry, vol.54, issue.6, pp.2303-2308, 2006.
DOI : 10.1021/jf052922x

URL : https://hal.archives-ouvertes.fr/hal-01600045

H. Hotelling, Analysis of a complex of statistical variables into principal components., Journal of Educational Psychology, vol.24, issue.6, pp.417-441, 1933.
DOI : 10.1037/h0071325

D. M. Gottieb, J. Schultz, S. W. Bruun, S. Jacobsen, and I. Sondergaard, Multivariate approaches in plant science, Phytochemistry, vol.65, issue.11, pp.1531-1548, 2004.
DOI : 10.1016/j.phytochem.2004.04.008

L. Munck and B. Moller, A New Germinative Classification Model of Barley for Prediction of Malt Quality Amplified by a Near Infrared Transmission Spectroscopy Calibration for Vigour ???On Line??? Both Implemented by Multivariate Data Analysis, Journal of the Institute of Brewing, vol.100, issue.1, pp.110-113, 2004.
DOI : 10.1002/j.2050-0416.1994.tb00822.x

C. Cordella, I. Moussa, A. C. Martel, N. Sbirrazzuoli, and L. Lizzani-cuvelier, Recent Developments in Food Characterization and Adulteration Detection:?? Technique-Oriented Perspectives, Journal of Agricultural and Food Chemistry, vol.50, issue.7, pp.1751-1764, 2002.
DOI : 10.1021/jf011096z

D. Downey, Food and food ingredient authentication by mid-infrared spectroscopy and chemometrics, TrAC Trends in Analytical Chemistry, vol.17, issue.7, pp.418-424, 1998.
DOI : 10.1016/S0165-9936(98)00042-9

J. L. Molina-cano, T. Ramo, R. Ellis, J. S. Swanston, H. Bain et al., EFFECT OF GRAIN COMPOSITION ON WATER UPTAKE BY MALTING BARLEY: A GENETIC AND ENVIRONMENTAL STUDY, Journal of the Institute of Brewing, vol.59, issue.35, pp.79-83, 1995.
DOI : 10.1002/j.2050-0416.1993.tb01171.x

J. P. Nielsen and L. Munck, Evaluation of malting barley quality using exploratory data analysis. I. Extraction of information from micro-malting data of spring and winter barley, Journal of Cereal Science, vol.38, issue.2, pp.173-180, 2003.
DOI : 10.1016/S0733-5210(03)00023-7

B. Moller, Near Infrared Transmission Spectra of Barley of Malting Grade Represent a Physical-Chemical Fingerprint of the Sample That Is Able to Predict Germinative Vigour in a Multivariate Data Evaluation Model, Journal of the Institute of Brewing, vol.34, issue.1, pp.110-128, 2004.
DOI : 10.1006/jcrs.2001.0414

R. Karoui, G. Downey, and C. Blecker, Mid-Infrared Spectroscopy Coupled with Chemometrics: A Tool for the Analysis of Intact Food Systems and the Exploration of Their Molecular Structure???Quality Relationships ??? A Review, Chemical Reviews, vol.110, issue.10, 2010.
DOI : 10.1021/cr100090k

M. Mcclelland, Storage of High Moisture Barley. Alberta Agriculture and Rural Development, Agdex, vol.114, pp.61-62, 2008.

G. Zhang, J. Chen, J. Wang, and S. Ding, Cultivar and Environmental Effects on (1???3,1???4)-??-D-Glucan and Protein Content in Malting Barley, Journal of Cereal Science, vol.34, issue.3, pp.295-301, 2001.
DOI : 10.1006/jcrs.2001.0414

M. Brophy, Canadian Barley Malting and Brewing Technical Guide. Canadian Malting Barley TechnicalCentre, 2012.

J. Wang, G. Zhang, J. Chen, and F. Wu, The changes of ??-glucan content and ??-glucanase activity in barley before and after malting and their relationships to malt qualities, Food Chemistry, vol.86, issue.2, pp.223-228, 2004.
DOI : 10.1016/j.foodchem.2003.08.020

R. B. Vis and K. Lorenz, Malting and Brewing with a High ?-Glucan Barley, LWT, J. Food Sci. Tech, pp.31-51, 1998.

M. Munoz-amatriaín, Y. Xiong, M. R. Schmitt, H. Bilgic, A. D. Budde et al., Transcriptome analysis of a barley breeding program examines gene expression diversity and reveals target genes for malting quality improvement, BMC Genomics, vol.11, issue.1, pp.1-15, 2010.
DOI : 10.1186/1471-2164-11-653

B. Paynter, Malt quality parameters for malting barley, Research Agronomist (Barley) Farmnote, vol.3896, 2012.

D. Evans, L. Chengdao, K. Eglinton, and . Jason, Improved Prediction of Malt Fermentability by Measurement of the Diastatic Power Enzymes beta-Amylase, alpha-Amylase, and Limit Dextrinase: I. Survey of the Levels of Diastatic Power Enzymes in Commercial Malts, Journal of the American Society of Brewing Chemists, pp.66-223, 2008.
DOI : 10.1094/ASBCJ-2008-0909-02

P. Schwarz and H. Horsley, A Comparison of North American Two-Row and Six-Row Malting Barley. The brewer's market guide, 1997.

J. S. Hough, D. E. Briggs, R. Stevens, and T. W. Young, Malting and brewing Science: Hopped Wort and Beer, 1999.
DOI : 10.1007/978-1-4615-1799-3

A. Savitzky and M. J. Golay, Smoothing and Differentiation of Data by Simplified Least Squares Procedures., Analytical Chemistry, vol.36, issue.8, pp.1627-1639, 1964.
DOI : 10.1021/ac60214a047

H. Buddenbaum and M. Steffens, The Effects of Spectral Pretreatments on Chemometric Analyses of Soil Profiles Using Laboratory Imaging Spectroscopy, Applied and Environmental Soil Science, vol.20, issue.14, pp.1-12
DOI : 10.1016/S0003-2670(01)01265-X

A. Candolfi, R. Maesschalck, D. Jouan-rimbaud, P. A. Hailey, and D. L. Massart, The influence of data pre-processing in the pattern recognition of excipients near-infrared spectra, Journal of Pharmaceutical and Biomedical Analysis, vol.21, issue.1, pp.115-132, 1999.
DOI : 10.1016/S0731-7085(99)00125-9

R. J. Barnes, M. S. Dhanoa, and S. J. Lister, Standard Normal Variate Transformation and De-Trending of Near-Infrared Diffuse Reflectance Spectra, Applied Spectroscopy, vol.50, issue.5, pp.43-772, 1989.
DOI : 10.1039/an9851001227

M. A. Coimbra, A. Barros, M. Barros, N. R. Rutledge, and I. Delgadillo, Multivariate analysis of uronic acid and neutral sugars in whole pectic samples by FT-IR spectroscopy, Carbohydrate Polymers, vol.37, issue.3, pp.241-248, 1998.
DOI : 10.1016/S0144-8617(98)00066-6

X. Fang, B. Jiang, and X. Wang, Purification and Partial Characterization of an Acidic Polysaccharide with Complement Fixing Ability from the Stems of Avicennia Marina, BMB Reports, vol.39, issue.5, pp.39-546, 2006.
DOI : 10.5483/BMBRep.2006.39.5.546

L. M. Nollet and F. Toldrá, Advances in Food Diagnostics, 2007.
DOI : 10.1002/9780470277805

B. , F. Fournier, P. Boivin, M. Schmitt, and M. Fick, Classification of barley according to harvest year and species by using Mid-infrared spectroscopy and multivariate analysis, Journal of Food Science and Engineering, vol.4, pp.36-54, 2014.

G. Zhang, J. Chen, J. Wang, and S. Ding, Cultivar and Environmental Effects on (1???3,1???4)-??-D-Glucan and Protein Content in Malting Barley, Journal of Cereal Science, vol.34, issue.3, pp.295-301, 2001.
DOI : 10.1006/jcrs.2001.0414

O. Østergaard, S. Melchior, P. Roepstorff, and B. Svensson, Initial proteome analysis of mature barley seeds and malt, PROTEOMICS, vol.40, issue.6, pp.733-739, 2002.
DOI : 10.1002/j.2050-0416.1988.tb04550.x

C. Brennan, L. Cleary, and L. , The potential use of cereal (1???3,1???4)-??-d-glucans as functional food ingredients, Journal of Cereal Science, vol.42, issue.1, pp.1-13, 2005.
DOI : 10.1016/j.jcs.2005.01.002

O. Grujic, D. J. Pejin, and N. M. Pruzulj, The effect of Winter barley variety and technological factors during malting on malt quality, Acta periodica technologica, vol.36, issue.36, pp.33-42, 2005.
DOI : 10.2298/APT0536033G

M. Brophy and M. , Canadian Barley Malting and Brewing Technical Guide, 2012.

S. Aastrup and K. Erdal, Quantitative determination of endosperm modification and its relationship to the content of 1,3???1,4-??-glucans during malting of barley, Carlsberg Research Communications, vol.55, issue.5, pp.45-369, 1980.
DOI : 10.1002/j.2050-0416.1952.tb02677.x

J. Wang, G. Zhang, J. Chen, and F. Wu, The changes of ??-glucan content and ??-glucanase activity in barley before and after malting and their relationships to malt qualities, Food Chemistry, vol.86, issue.2, pp.223-228, 2004.
DOI : 10.1016/j.foodchem.2003.08.020

R. B. Vis and K. Lorenz, Malting and Brewing with a High ?-Glucan Barley. LWT -Food Science and Technology, pp.31-51, 1998.

M. Gupta, Barley for brewing: characteristic changes during malting, brewing and applications of its by-products. Comprehensive reviews in food science and food safety 9, pp.318-328, 2010.

]. C. Agu, Some Links Between and Among Quality Parameters Used in Assessment of Barley Adjuncts for Food Processing, Master Brewers Associations of the Americas Technical Quarterly (MBAA TQ), pp.45-268, 2008.
DOI : 10.1094/TQ-45-3-0268

L. Munck and B. Moller, A New Germinative Classification Model of Barley for Prediction of Malt Quality Amplified by a Near Infrared Transmission Spectroscopy Calibration for Vigour ???On Line??? Both Implemented by Multivariate Data Analysis, Journal of the Institute of Brewing, vol.100, issue.1, pp.110-113, 2004.
DOI : 10.1002/j.2050-0416.1994.tb00822.x

K. J. Siebert, A. Egi, R. Mccaig, and R. , Chemometric Investigation of Barley and Malt Data, J. American societ. Brew. Chemists, vol.70, pp.163-175, 2012.

G. Downey, Estimation of moisture in undried wheat and barley by near infrared reflectance, Journal of the Science of Food and Agriculture, vol.28, issue.10, pp.951-958, 1985.
DOI : 10.1002/jsfa.2740361008

E. Roux, Near InfraRed spectroscopy for selection of malting barley in south African breeding programmes, 2011.

R. J. Henry, Near infrared reflectance analysis of carbohydrates and its application to the determination of (1? 3), (1? 4)-ß-d-glucan in barley, Carbohydrate research, vol.13, p.14119, 1985.

S. Trangoonrung, P. M. Haves, and S. L. Brorch, Near-infrared reflectance estimates of grain protein and malt extract in hill and row plot evaluations of spring malting barley

M. J. Allison, I. A. Cowe, and R. Mchale, THE USE OF INFRA RED REFLECTANCE FOR THE RAPID ESTIMATION OF THE SOLUBLE ??-GLUCAN CONTENT OF BARLEY, Journal of the Institute of Brewing, vol.54, issue.3, pp.153-155, 1978.
DOI : 10.1002/j.2050-0416.1975.tb03664.x

Z. Czuchajowska, J. Szczodrak, and Y. Pomeranz, Characterization and estimation of barley polysaccharides by near-infrared spectroscopy. I. Barleys, starches, and beta-Dglucans, J. Cereal. Chem, pp.69-413, 1992.

D. W. Lachenmeier, Rapid quality control of spirit drinks and beer using multivariate data analysis of Fourier transform infrared spectra, Food Chemistry, vol.101, issue.2, pp.825-832, 2007.
DOI : 10.1016/j.foodchem.2005.12.032

F. A. Inon, S. Garrigues, M. De, and . Guardia, Combination of mid-and near-infrared spectroscopy for the determination of the quality properties of beers, Analytica chemistry acta, pp.571-167, 2006.

P. Robert, M. Malanie, C. Barron, C. Guillon, and L. Saulnier, FT-IR Investigation of Cell Wall Polysaccharides from Cereal Grains. Arabinoxylan Infrared Assignment, Journal of Agricultural and Food Chemistry, vol.53, issue.18, pp.7014-7018, 2005.
DOI : 10.1021/jf051145y

R. Karoui, G. Downey, and C. Blecker, Mid-Infrared Spectroscopy Coupled with Chemometrics: A Tool for the Analysis of Intact Food Systems and the Exploration of Their Molecular Structure???Quality Relationships ??? A Review, Chemical Reviews, vol.110, issue.10, 2010.
DOI : 10.1021/cr100090k

H. Seefeldt, A. Blennow, B. M. Jespersen, B. Wollenweber, and S. B. Engelsen, Accumulation of mixed linkage (1???3) (1???4)-??-d-glucan during grain filling in barley: A vibrational spectroscopy study, Journal of Cereal Science, vol.49, issue.1, pp.24-31, 2009.
DOI : 10.1016/j.jcs.2008.06.012

J. P. Nielsen and L. Munck, Evaluation of malting barley quality using exploratory data analysis. I. Extraction of information from micro-malting data of spring and winter barley, Journal of Cereal Science, vol.38, issue.2, pp.173-180, 2003.
DOI : 10.1016/S0733-5210(03)00023-7

E. Polshin, B. Aernouts, W. Saeys, F. Delvaux, F. R. Delvaux et al., Beer quality screening by FT-IR spectrometry: Impact of measurement strategies, data pre-processings and variable selection algorithms, Journal of Food Engineering, vol.106, issue.3, pp.188-198, 2011.
DOI : 10.1016/j.jfoodeng.2011.05.003

R. Lleti, E. Meléndez, M. C. Ortiz, L. A. Sarabia, and M. S. Sànchez, Outliers in partial least squares regression, Analytica Chimica Acta, vol.544, issue.1-2, pp.60-70, 2005.
DOI : 10.1016/j.aca.2005.03.075

D. Cozzolino, M. Holdstock, G. Dambergs, W. U. Cynkar, and P. A. Smith, Mid infrared spectroscopy and multivariate analysis: A tool to discriminate between organic and non-organic wines grown in Australia, Food Chemistry, vol.116, issue.3, pp.761-765, 2009.
DOI : 10.1016/j.foodchem.2009.03.022

P. Yu, Molecular chemical structure of barley proteins revealed by ultra-spatially resolved synchrotron light sourced FTIR microspectroscopy: Comparison of barley varieties, Biopolymers, vol.44, issue.4, pp.308-317, 2007.
DOI : 10.1007/978-1-349-15203-2

H. Abdi, Partial least squares regression and projection on latent structure regression (PLS Regression) WIREs Comp, Stat, vol.2, pp.97-106, 2010.

D. M. Haaland and E. V. Thomas, Partial least-squares methods for spectral analyses. 1. Relation to other quantitative calibration methods and the extraction of qualitative information, Analytical Chemistry, vol.60, issue.11, pp.1193-1202, 1988.
DOI : 10.1021/ac00162a020

S. Wold, M. Sjostrom, and L. Eriksson, PLS-regression: a basic tool of chemometrics, Chemometrics and Intelligent Laboratory Systems, vol.58, issue.2, pp.109-130, 2001.
DOI : 10.1016/S0169-7439(01)00155-1

A. Pirie, B. Singh, and K. Islam, Ultra-violet, visible, near-infrared, and mid-infrared diffuse reflectance spectroscopic techniques to predict several soil properties, Australian Journal of Soil Research, vol.43, issue.6, pp.43-713, 2005.
DOI : 10.1071/SR04182

M. A. Coimbra, A. Barros, M. Barros, D. N. Rutledge, and I. Delgadillo, Multivariate analysis of uronic acid and neutral sugars in whole pectic samples by FT-IR spectroscopy, Carbohydrate Polymers, vol.37, issue.3, pp.37-241, 1998.
DOI : 10.1016/S0144-8617(98)00066-6

X. Fang, B. Jiang, and X. L. Wang, Purification and Partial Characterization of an Acidic Polysaccharide with Complement Fixing Ability from the Stems of Avicennia Marina, BMB Reports, vol.39, issue.5
DOI : 10.5483/BMBRep.2006.39.5.546