M. Earle and K. Seddon, Ionic liquids. Green solvents for the future, Pure and Applied Chemistry, vol.72, issue.7, pp.1391-1398, 2000.
DOI : 10.1351/pac200072071391

J. G. Huddleston, A. E. Visser, W. M. Reichert, H. D. Willauer, G. A. Broker et al., Characterization and comparison of hydrophilic and hydrophobic room temperature ionic liquids incorporating the imidazolium cation, Green Chemistry, vol.3, issue.4, pp.156-164, 2001.
DOI : 10.1039/b103275p

K. R. Seddon, A. Stark, and M. J. Torres, Influence of chloride, water, and organic solvents on the physical properties of ionic liquids, Pure and Applied Chemistry, vol.72, issue.12, pp.72-2275, 2000.
DOI : 10.1351/pac200072122275

L. C. Branco, J. N. Rosa, J. J. Ramos, and C. A. Afonso, Preparation and Characterization of New Room Temperature Ionic Liquids, Chemistry - A European Journal, vol.8, issue.16, pp.3671-3677, 2002.
DOI : 10.1002/1521-3765(20020816)8:16<3671::AID-CHEM3671>3.0.CO;2-9

H. S. Schrekker, M. P. Stracke, C. M. Schrekker, and J. Dupont, Ether-functionalized imidazolium hexaflurophosphate ionic liquids for improved water miscibilities

Y. Fukaya, K. Hayashi, M. Wada, and H. Ohno, Cellulose dissolution with polar ionic liquids under mild conditions: required factors for anions, Green Chem., vol.4, issue.1, pp.44-46, 2008.
DOI : 10.1039/b417745b

Z. F. Fei, D. B. Zhao, R. Scopelliti, and P. J. Dyson, Organometallic Complexes Derived from Alkyne-Functionalized Imidazolium Salts, Organometallics, vol.23, issue.7, pp.23-1622, 2004.
DOI : 10.1021/om034248j

D. R. Macfarlane, J. M. Pringle, K. M. Johansson, S. A. Forsyth, and M. Forsyth, Lewis base ionic liquids, Chem. Commun, vol.18, pp.1905-1917, 2006.

T. L. Greaves and C. J. Drummond, Protic Ionic Liquids:?? Properties and Applications, Chemical Reviews, vol.108, issue.1, pp.206-237, 2008.
DOI : 10.1021/cr068040u

A. Bosmann, L. Datsevich, A. Jess, A. Lauter, C. Schmitz et al., Deep desulfurization of diesel fuel by extraction with ionic liquids, Chem. Commun, pp.2494-2495, 2001.

J. Esser, P. Wasserscheid, and A. Jess, Deep desulfurization of oil refinery streams by extraction with ionic liquids, Green Chem., vol.4, issue.17, pp.316-322, 2004.
DOI : 10.1039/b204469b

L. Alonso, A. Arce, M. Francisco, O. Rodríguez, and A. Soto, ] ionic liquid, AIChE Journal, vol.8, issue.12, pp.53-3108, 2007.
DOI : 10.1002/aic.11337

J. D. Holbrey, I. Lopez-martin, G. Rothenberg, K. R. Seddon, G. Silvero et al., Desulfurisation of oils using ionic liquids: selection of cationic and anionic components to enhance extraction efficiency, Green Chem., vol.4, issue.1, pp.87-92, 2008.
DOI : 10.1039/b204469b

L. D. Simoni, A. Chapeaux, J. F. Brennecke, and M. A. Stadtherr, Extraction of biofuels and biofeedstocks from aqueous solutions using ionic liquids, Computers & Chemical Engineering, vol.34, issue.9, pp.34-1406, 2010.
DOI : 10.1016/j.compchemeng.2010.02.020

G. W. Meindersma, A. J. Podt, and A. B. De-haan, Ternary liquid???liquid equilibria for mixtures of toluene+n-heptane+an ionic liquid, Fluid Phase Equilibria, vol.247, issue.1-2, pp.247-158, 2006.
DOI : 10.1016/j.fluid.2006.07.002

L. D. Simoni, Y. Lin, J. F. Brennecke, and M. A. Stadtherr, Modeling liquid-liquid equilibrium of ionic liquid systems with NRTL

S. Park and R. J. Kazlauskas, Improved Preparation and Use of Room-Temperature Ionic Liquids in Lipase-Catalyzed Enantio- and Regioselective Acylations, The Journal of Organic Chemistry, vol.66, issue.25, pp.66-8395, 2001.
DOI : 10.1021/jo015761e

N. Kimizuka and T. Nakashima, Spontaneous Self-Assembly of Glycolipid Bilayer Membranes in Sugar-philic Ionic Liquids and Formation of Ionogels, Langmuir, vol.17, issue.22, pp.17-6759, 2001.
DOI : 10.1021/la015523e

M. Matsumoto, K. Ueba, K. Kondo, A. Chapeaux, L. D. Simoni et al., Separation of sugar by solvent [25] Extraction of alcohols from water with 1-hexyl-3-methylimidazolium bis(trifluromethylsulfonyl)imide, Sep. Purif. Technol. Green Chem, vol.10, pp.1301-1306, 2008.

L. Feng and Z. Chen, Research progress on dissolution and functional modification of cellulose in ionic liquids, Journal of Molecular Liquids, vol.142, issue.1-3, pp.1421-1426, 2008.
DOI : 10.1016/j.molliq.2008.06.007

C. Graenacher, cellulose solution, US Patent 1, 943, p.176, 1934.

R. P. Swatloski, S. K. Spear, J. D. Holbrey, and R. D. Rogers, Dissolution of cellulose with ionic liquids, J. Am. Chem. Soc, pp.124-4974, 2002.

J. Vitz, T. Erdmenger, C. Haensch, and U. S. Schubert, Extended dissolution studies of cellulose in imidazolium based ionic liquids, Green Chemistry, vol.9, issue.3, pp.417-424, 2009.
DOI : 10.15227/orgsyn.082.0166

R. D. Holbrey and . Rogers, Controlling the aqueous miscibility of ionic liquids: aqueous biphasic systems of water-miscibile ionic liquids and water-stucturing salts of recycle, metathesis and separations, J. Am. Chem. Soc, pp.125-6632, 2003.

Y. Cao, J. Wu, J. Zhang, H. Li, Y. Zhang et al., Room temperature ionic liquids (RTILs): A new and versatile platform for cellulose processing and derivatization, Chemical Engineering Journal, vol.147, issue.1
DOI : 10.1016/j.cej.2008.11.011

W. Van-der, Over de Continuiteit van den Gas-en Vloeistoftoestand (on the continuity of the gas and liquid state, J. D, 1873.

M. C. Kroon, E. K. Karakatsani, I. G. Economou, G. J. Witkamp, and C. J. Peters, Modeling of the Carbon Dioxide Solubility in Imidazolium-Based Ionic Liquids with the tPC-PSAFT Equation of State, The Journal of Physical Chemistry B, vol.110, issue.18, pp.110-9262, 2006.
DOI : 10.1021/jp060300o

L. F. Vega and J. S. Andreu, The Solubility Behavior of CO2 in Ionic Liquids by a Simple Model, J. Phys. Chem. C, pp.111-16028, 2007.

D. Y. Peng and D. B. Robinson, A New Two-Constant Equation of State, Industrial & Engineering Chemistry Fundamentals, vol.15, issue.1, pp.59-64, 1976.
DOI : 10.1021/i160057a011

J. N. Jaubert and F. Mutelet, VLE predictions with the Peng???Robinson equation of state and temperature dependent kij calculated through a group contribution method, Fluid Phase Equilibria, vol.224, issue.2, pp.285-304, 2004.
DOI : 10.1016/j.fluid.2004.06.059

URL : https://hal.archives-ouvertes.fr/hal-01706080

S. Vitu, R. Privat, J. N. Jaubert, and F. Mutelet, Predicting the phase equilibria of CO2+hydrocarbon systems with the PPR78 model (PR EOS and kij calculated through a group contribution method), The Journal of Supercritical Fluids, vol.45, issue.1, pp.45-46, 2008.
DOI : 10.1016/j.supflu.2007.11.015

J. O. Valderrama and R. E. Rojas, Critical Properties of Ionic Liquids. Revisited, Industrial & Engineering Chemistry Research, vol.48, issue.14, pp.6890-6900, 2009.
DOI : 10.1021/ie900250g

M. S. Manic, A. J. Queimada, E. A. Macedo, and V. J. , Najdanovic-Visak, High-pressure solubilities of carbon dioxide in ionic liquids based on bis(trifluoromethylsulfonyl)imide and chloride, pp.65-66, 2012.

S. H. Huang and M. Radosz, Equation of state for small, large, polydisperse, and associating molecules, Industrial & Engineering Chemistry Research, vol.29, issue.11, pp.29-2284, 1990.
DOI : 10.1021/ie00107a014

J. Gross and G. Sadowski, Perturbed-Chain SAFT:?? An Equation of State Based on a Perturbation Theory for Chain Molecules, Industrial & Engineering Chemistry Research, vol.40, issue.4, pp.40-1244, 2001.
DOI : 10.1021/ie0003887

F. Llovell, E. Valente, O. Vilaseca, and L. F. Vega, N] Ionic Liquids: Predictions from the Soft-SAFT Equation, The Journal of Physical Chemistry B, vol.115, issue.15
DOI : 10.1021/jp112315b

K. Paduszynski and U. Domanska, Thermodynamic Modeling of Ionic Liquid Systems: Development and Detailed Overview of Novel Methodology Based on the PC-SAFT, The Journal of Physical Chemistry B, vol.116, issue.16
DOI : 10.1021/jp3009207

Y. Chen, F. Mutelet, and J. N. Jaubert, Modeling the Solubility of Carbon Dioxide in Imidazolium-Based Ionic Liquids with the PC-SAFT Equation of State, The Journal of Physical Chemistry B, vol.116, issue.49
DOI : 10.1021/jp309944t

URL : https://hal.archives-ouvertes.fr/hal-00776881

H. Renon and J. M. Prausnitz, Local compositions in thermodynamic excess functions for liquid mixtures, AIChE Journal, vol.14, issue.1, pp.135-144, 1968.
DOI : 10.1002/aic.690140124

D. S. Abrams and J. M. Prausnitz, Statistical thermodynamics of liquid mixtures: A new expression for the excess Gibbs energy of partly or completely miscible systems, AIChE Journal, vol.21, issue.1, pp.116-128, 1975.
DOI : 10.1002/aic.690210115

U. Domanska, A. Pobudkowska, and Z. , Zolek-Tryznowska, Effect of an Ionic Liquid (IL) Cation on Ternary System (UL + p-Xylene + Hexane) at T = 298, J. Chem. Eng. Data, vol.15, pp.52-2345, 2007.

L. Alonso, A. Arce, M. Francisco, and A. Soto, Thiophene separation from aliphatic hydrocarbons using the 1-ethyl-3-methylimidazolium ethylsulfate ionic liquid, Fluid Phase Equilibria, vol.270, issue.1-2, pp.97-102, 2008.
DOI : 10.1016/j.fluid.2008.06.012

H. Tadesse and R. Luque, Advances on biomass pretreatment using ionic liquids: An overview, Energy & Environmental Science, vol.11, issue.108, pp.3913-3929, 2011.
DOI : 10.1039/b905388c

R. Henry, Evaluation of plant biomass resources available for replacement of fossil oil, Plant Biotechnology Journal, vol.13, issue.3, pp.288-293, 2010.
DOI : 10.1111/j.1467-7652.2009.00482.x

M. Balat, H. Balat, and C. Oz, Progress in bioethanol processing, Progress in Energy and Combustion Science, vol.34, issue.5, pp.551-573, 2008.
DOI : 10.1016/j.pecs.2007.11.001

V. B. Agbor, N. Cicek, R. Sparling, A. Berlin, and D. B. Levin, Biomass pretreatment: Fundamentals toward application, Biotechnology Advances, vol.29, issue.6, pp.29-675, 2011.
DOI : 10.1016/j.biotechadv.2011.05.005

K. Nakashima, K. Yamaguchi, N. Taniguchi, S. Arai, R. Yamada et al., Direct bioethanol production from cellulose by the combination of cellulase-displaying yeast and ionic liquid pretreatment, Green Chemistry, vol.101, issue.10, pp.13-2948, 2011.
DOI : 10.1016/j.biortech.2009.10.066

C. E. Wyman, What is (and is not) vital to advancing cellulosic ethanol, Trends in Biotechnology, vol.25, issue.4, pp.153-157, 2007.
DOI : 10.1016/j.tibtech.2007.02.009

. Singh, Transition of cellulose crystalline structure and surface morphology of biomass as a function of ionic liquid pretreatment and its relation to enzymatic hydrolysis, Biomacromolecules, pp.12-933, 2011.

H. Wang, G. Gurau, and R. D. Rogers, Ionic liquid processing of cellulose, Chemical Society Reviews, vol.5, issue.4, pp.41-1519, 2012.
DOI : 10.1002/bbb.303

A. T. Hendriks and G. Zeeman, Pretreatments to enhance the digestibility of lignocellulosic biomass, Pretreatments to enhance the digestibility of lignocellulosic biomass, pp.10-18, 2009.
DOI : 10.1016/j.biortech.2008.05.027

A. P. Dadi, C. A. Schall, and S. Varanasi, Mitigation of cellulose recalcitrance to enzymatic hydrolysis by ionic liquid pretreatment, Appl. Biochem. Biotechnol, pp.136-140, 2007.

]. N. Sun, M. Rahman, Y. Qin, M. L. Maxim, H. Rodríguez et al., Complete dissolution and partial delignification of wood in the ionic liquid 1-ethyl-3-methylimidazolium acetate, Green Chemistry, vol.12, issue.5, pp.11-646, 2009.
DOI : 10.1021/cen-v076n013.p032

S. Simmons and . Singh, Transition of cellulose crystalline structure and surface morphology of biomass as a function of ionic liquid pretreatment and its relation to enzymatic hydrolysis, Bioresour. Technol, vol.101, pp.4900-4906, 2010.

I. P. Samayam and C. A. Schall, Ionic-Liquid Induced Changes in Cellulose Structure Associated with Enhanced Biomass Hydrolysis, Biomacromolecules, vol.12, issue.8, pp.3561-3566, 2010.
DOI : 10.1021/bm200736a

K. R. Magee, J. A. Seddon, and . Widegren, The distillation and volatility of ionic liquids, Nature, pp.439-831, 2006.

H. S. Gao, C. Guo, J. M. Xing, J. M. Zhao, and H. Z. Liu, Extraction and oxidative desulfurization of diesel fuel catalyzed by a Br??nsted acidic ionic liquid at room temperature, Green Chemistry, vol.23, issue.7, pp.12-1220, 2010.
DOI : 10.1039/c002108c

Y. Y. Jiang, H. S. Xia, C. Guo, I. Mahmood, and H. Z. Liu, Enzymatic Hydrolysis of Penicillin for 6-APA Production in Three-Liquid-Phase System, Applied Biochemistry and Biotechnology, vol.39, issue.109, pp.144-145, 2010.
DOI : 10.1016/0300-9467(84)85015-7

]. R. Hagiwara, T. Nohira, K. Matsumoto, Y. Andrea, A. H. Wesley et al., A Fluorohydrogenate Ionic Liquid Fuel Cell Operating Without Humidification, Electrochemical and Solid-State Letters, vol.16, issue.4, pp.231-233, 2005.
DOI : 10.1016/S0167-2738(02)00399-5

H. A. Weingaertner, Understanding Ionic Liquids at the Molecular Level: Facts, Problems, and Controversies, Angewandte Chemie International Edition, vol.3, issue.4, pp.47-654, 2008.
DOI : 10.1002/bbpc.19910951201

Y. Y. Jiang, C. Guo, H. S. Xia, I. Mahmood, and C. Z. Liu, Magnetic nanoparticles supported ionic liquids for lipase immobilization: Enzyme activity in catalyzing esterification, Journal of Molecular Catalysis B: Enzymatic, vol.58, issue.1-4, pp.58-103, 2009.
DOI : 10.1016/j.molcatb.2008.12.001

X. M. Hou, F. Zhou, Y. B. Sun, and W. M. Liu, Ultrasound-assisted synthesis of dentritic ZnO nanostructure in ionic liquid, Materials Letters, vol.61, issue.8-9, pp.61-1789, 2007.
DOI : 10.1016/j.matlet.2006.07.133

R. P. Swatloski, S. K. Spear, J. D. Holbrey, and R. D. Rogers, Dissolution of cellulose with ionic liquids, J. Am. Chem. Soc, pp.124-4974, 2002.

]. S. Murugesan and R. J. Linhardt, Ionic Liquids in Carbohydrate Chemistry - Current Trends and Future Directions, Current Organic Synthesis, vol.2, issue.4, pp.437-451, 2005.
DOI : 10.2174/157017905774322640

F. Ganske and U. T. Bornscheuer, Lipase-Catalyzed Glucose Fatty Acid Ester Synthesis in Ionic Liquids, Organic Letters, vol.7, issue.14, pp.3097-3098, 2005.
DOI : 10.1021/ol0511169

O. A. Seoud, A. Koschella, L. C. Fidale, S. Dorn, and T. Heinze, Applications of ionic liquids in carbohydrate chemistry: a window of opportunities, Biomacromolecules, pp.8-2629, 2007.

]. A. Pinkert, K. N. Marsh, S. S. Pang, and M. P. Staiger, Ionic Liquids and Their Interaction with Cellulose, Chemical Reviews, vol.109, issue.12, pp.6712-6728, 2009.
DOI : 10.1021/cr9001947

E. Z. Malgorzata, B. L. Ewa, and B. L. , Solubility of carbohydrates in ionic liquids, pp.24-737, 2010.

A. A. Rosatella, L. C. Branco, and C. A. Afonso, Studies on dissolution of carbohydrates in ionic liquids and extraction from aqueous phase, Green Chemistry, vol.51, issue.9, pp.1406-1413, 2009.
DOI : 10.1039/b900678h

A. P. Carneiro, O. Rodriguez, and E. A. Macedo, Solubility of monosaccharides in ionic liquids ? Experimental data and modeling, Fluid Phase Equil, pp.314-336, 2012.

S. Park and R. J. Kazlauskas, Improved Preparation and Use of Room-Temperature Ionic Liquids in Lipase-Catalyzed Enantio- and Regioselective Acylations, The Journal of Organic Chemistry, vol.66, issue.25, pp.66-8395, 2001.
DOI : 10.1021/jo015761e

N. Kimizuka and T. Nakashima, Spontaneous Self-Assembly of Glycolipid Bilayer Membranes in Sugar-philic Ionic Liquids and Formation of Ionogels, Langmuir, vol.17, issue.22, pp.17-6759, 2001.
DOI : 10.1021/la015523e

S. A. Forsyth, D. R. Macfarlane, R. J. Thomson, and M. Von-itzstein, Rabid, clean and mild O-acetylation of alcohols and carbohydrates in an ionic liquid, Chem. Commun, vol.7, pp.714-715, 2002.

D. R. Macfarlane, J. Golding, S. Forsyth, M. Forsyth, and G. B. , Deacon, Low viscosity ionic liquids based on organic salts of the dicyanamide anion, Chem. Commun, pp.1430-1431, 2001.

Q. B. Liu, M. H. Janssen, F. Van-rantwijk, and R. A. Sheldon, Room-temperature ionic liquids that dissolve carbohydrates in high concentrations, Green Chemistry, vol.7, issue.1, pp.39-42, 2005.
DOI : 10.1039/b412848f

W. Liu, Y. Hou, W. Wu, S. Ren, Y. Jing et al., Solubility of Glucose in Ionic Liquid + Antisolvent Mixtures, Industrial & Engineering Chemistry Research, vol.50, issue.11, pp.50-6952, 2011.
DOI : 10.1021/ie102586u

Y. Fukaya, K. Hayashi, M. Wada, and H. Ohno, Cellulose dissolution with polar ionic liquids under mild conditions: required factors for anions, Green Chem., vol.4, issue.1, pp.44-46, 2008.
DOI : 10.1039/b417745b

C. Reichardt and T. Welton, Solvents and Solvent effects in Organic Chemistry, fourth edn, 2010.

J. Lee, Solvent properties of piperidinium ionic liquids, Chemical Engineering Journal, vol.172, issue.2-3, pp.1066-1071, 2011.
DOI : 10.1016/j.cej.2011.06.030

S. Zhang, X. Qi, X. Ma, L. Lu, Q. Zhang et al., Investigation of cation-anion interaction in 1-(2-hydroxyethyl)-3-methylimidazolium-based ion pairs by density functional theory calculations and experiments, Journal of Physical Organic Chemistry, vol.8, issue.3, pp.25-248, 2012.
DOI : 10.1002/cphc.200600725

J. Lee and J. M. Prausntiz, Polarity and hydrogen-bond-donor strength for some ionic liquids: Effect of alkyl chain length on the pyrrolidinium cation, Chemical Physics Letters, vol.492, issue.1-3, pp.492-55, 2010.
DOI : 10.1016/j.cplett.2010.03.086

G. J. Philip, A. J. David, and F. Dongbao, Solvatochromic parameters for solvents of interest in green chemistry, Green Chem, vol.14, pp.1245-1259, 2012.

A. Oehlke, K. Hofmann, and S. Spange, New aspects on polarity of 1-alkyl-3-methylimidazolium salts as measured by solvatochromic probes, New Journal of Chemistry, vol.9, issue.74, pp.533-536, 2006.
DOI : 10.1039/b516709d

L. J. Conceiçao, E. Bogel-lukasik, and R. , A new outlook on solubility of carbohydrates and sugar alcohols in ionic liquids, RSC Advances, vol.81, issue.5, pp.1846-1855, 2012.
DOI : 10.1007/BF00912664

D. A. Fort, R. P. Swatolski, P. Moyna, R. D. Rogers, and G. Moyna, Use of ionic liquids in the study of fruit ripening by high-resolution 13C NMR spectroscopy: ???green??? solvents meet green bananas, Chemical Communications, vol.7, issue.7, pp.714-716, 2006.
DOI : 10.1039/b515177p

H. Zhang, G. Gurau, and R. D. Rogers, Ionic liquid processing of cellulose, Chem Soc Rev, pp.41-1519, 2012.

V. M. Egorov, S. V. Smirnova, A. A. Formanovsky, I. V. Pletnev, and Y. A. Zolotov, Dissolution of cellulose in ionic liquids as a way to obtain test materials for metal-ion detection, Analytical and Bioanalytical Chemistry, vol.59, issue.6, pp.387-2263, 2007.
DOI : 10.1007/s00216-006-1114-x

H. Renon and J. M. Prausnitz, Local compositions in thermodynamic excess functions for liquid mixtures, AIChE Journal, vol.14, issue.1, pp.135-144, 1968.
DOI : 10.1002/aic.690140124

D. S. Abrams and J. M. Prausnitz, Statistical thermodynamics of liquid mixtures: A new expression for the excess Gibbs energy of partly or completely miscible systems, AIChE Journal, vol.21, issue.1, pp.116-128, 1975.
DOI : 10.1002/aic.690210115

J. M. Prausnitz, R. N. Lichtenthaler, and E. G. Azevedo, Molecular thermodynamics of fluid-phase equilibria, 1986.

A. Khelassi-sefaoui, F. Mutelet, I. Mokbel, J. Jose, and L. Negadi, Measurement and correlation of vapour pressures of pyridine and thiophene with [EMIM][SCN] ionic liquid, The Journal of Chemical Thermodynamics, vol.72, pp.72-134, 2014.
DOI : 10.1016/j.jct.2013.12.033

URL : https://hal.archives-ouvertes.fr/hal-00957537

H. A. Weingaertner, Understanding Ionic Liquids at the Molecular Level: Facts, Problems, and Controversies, Angewandte Chemie International Edition, vol.3, issue.4, pp.47-654, 2008.
DOI : 10.1002/bbpc.19910951201

F. Mutelet, R. E. El-sayed, T. W. Hassan, W. E. Stephens, G. A. Acree et al., Activity Coefficients at Infinite Dilution for Organic Solutes Dissolved in Three 1-Alkyl-1-methylpyrrolidinium Bis(trifluoromethylsulfonyl)imide Ionic Liquids Bearing Short Linear Alkyl Side Chains of Three to Five Carbons, Journal of Chemical & Engineering Data, vol.58, issue.8, pp.58-2210, 2013.
DOI : 10.1021/je4001894

URL : https://hal.archives-ouvertes.fr/hal-01282096

W. Leitner, A greener solution, Nature, vol.40, issue.6943, pp.423-930, 2003.
DOI : 10.1002/1521-3773(20010716)40:14<2697::AID-ANIE2697>3.0.CO;2-W

W. L. Wong, P. Chan, Z. Zhou, K. Lee, K. Cheung et al., A Robust Ionic Liquid as Reaction Medium and Efficient Organocatalyst for Carbon Dioxide Fixation, ChemSusChem, vol.29, issue.1-2, pp.1-67, 2008.
DOI : 10.1107/S0567740873005236

C. Thurier, C. Fischmeister, C. Bruneau, H. Olivier-bourbigou, and P. H. Dixneuf, Ethenolysis of Methyl Oleate in Room-Temperature Ionic Liquids, ChemSusChem, vol.690, issue.1-2, pp.118-122, 2008.
DOI : 10.1002/cssc.200700002

URL : https://hal.archives-ouvertes.fr/hal-00341702

E. R. Cooper, C. D. Andrews, P. S. Wheatley, P. B. Webb, P. Wormald et al., Ionic liquids and eutectic mixtures as solvent and template in synthesis of zeolite analogues, Nature, pp.430-1012, 2004.

W. Xu, E. I. Cooper, and C. A. Angell, Ionic Liquids:?? Ion Mobilities, Glass Temperatures, and Fragilities, The Journal of Physical Chemistry B, vol.107, issue.25, pp.6170-6178, 2003.
DOI : 10.1021/jp0275894

J. Kiefer, K. Obert, A. Bçsmann, T. Seeger, P. Wasserscheid et al., Quantitative Analysis of Alpha-D-glucose in an Ionic Liquid by Using Infrared Spectroscopy, ChemPhysChem, vol.9, issue.132, pp.1317-1322, 2008.
DOI : 10.1524/zpch.2006.220.10.1439

P. A. Hunt and I. R. Gould, Structural Characterization of the 1-Butyl-3-methylimidazolium Chloride Ion Pair Using ab Initio Methods, The Journal of Physical Chemistry A, vol.110, issue.6, pp.110-2269, 2006.
DOI : 10.1021/jp0547865

W. Ji, Z. Ding, J. Liu, Q. Song, X. Xia et al., Mechanism of Lignin Dissolution and Regeneration in Ionic Liquid, Energy & Fuels, vol.26, issue.10, pp.26-6393, 2012.
DOI : 10.1021/ef301231a

F. Van-rantwijkl, R. M. Lau, and R. A. Sheldon, Biocatalytic transformations in ionic liquids, Trends in Biotechnology, vol.21, issue.3, pp.131-138, 2003.
DOI : 10.1016/S0167-7799(03)00008-8

S. Park and R. J. Kazlauskas, Biocatalysis in ionic liquids ??? advantages beyond green technology, Current Opinion in Biotechnology, vol.14, issue.4, pp.432-437, 2003.
DOI : 10.1016/S0958-1669(03)00100-9

U. Kragl, M. Eckstein, and N. Kaftzik, Enzyme catalysis in ionic liquids, Current Opinion in Biotechnology, vol.13, issue.6, pp.565-571, 2002.
DOI : 10.1016/S0958-1669(02)00353-1

R. A. Sheldon, R. M. Lau, M. J. Sorgedrager, F. Van-rantwijk, and K. R. Seddon, Biocatalysis in ionic liquids, Biocatalysis in ionic liquids, pp.147-151, 2002.
DOI : 10.1039/b110008b

Z. Yang and W. B. Pan, Ionic liquids: Green solvents for nonaqueous biocatalysis, Enzyme and Microbial Technology, vol.37, issue.1, pp.19-28, 2005.
DOI : 10.1016/j.enzmictec.2005.02.014

S. H. Lee, D. T. Dang, S. H. Ha, W. Chang, and Y. Koo, Lipase-catalyzed synthesis of fatty acid sugar ester using extremely supersaturated sugar solution in ionic liquids, Biotechnology and Bioengineering, vol.76, issue.1, pp.99-100, 2008.
DOI : 10.1021/cen-v076n013.p032

R. P. Swatloski, S. K. Spear, J. D. Holbrey, and R. D. Rogers, Dissolution of cellulose with ionic liquids, J. Am. Chem. Soc, pp.124-4974, 2002.

B. Kosan, C. Michels, and F. Meister, Dissolution and forming of cellulose with ionic liquids, Cellulose, vol.8, issue.6, pp.15-59, 2008.
DOI : 10.1007/s10570-007-9160-x

Y. Fukaya, K. Hayashi, M. Wada, and H. Ohno, Cellulose dissolution with polar ionic liquids under mild conditions: required factors for anions, Green Chem., vol.4, issue.1, pp.44-46, 2008.
DOI : 10.1039/b417745b

M. B. Turner, S. K. Spear, J. D. Holbrey, D. T. Daly, and R. D. Rogers, Ionic liquidreconstituted cellulose composites as solid support matrices for biocatalyst immobilization, Biomacromolecules, pp.6-2497, 2005.

M. Bagheri, H. Rodriguez, R. P. Swatloski, S. K. Spear, D. T. Daly et al., Ionic Liquid-Based Preparation of Cellulose???Dendrimer Films as Solid Supports for Enzyme Immobilization, Biomacromolecules, vol.9, issue.1, pp.381-387, 2008.
DOI : 10.1021/bm701023w

I. Kilpeläinen, H. Xie, A. King, M. Granstrom, S. Heikkinen et al., Dissolution of Wood in Ionic Liquids, Journal of Agricultural and Food Chemistry, vol.55, issue.22, pp.55-9142, 2007.
DOI : 10.1021/jf071692e

D. A. Fort, R. C. Remsing, R. P. Swatloski, P. Moyna, G. Moyna et al., Can ionic liquids dissolve wood? Processing and analysis of lignocellulosic materials with 1-n-butyl-3-methylimidazolium chloride, Green Chem., vol.3, issue.1, pp.63-69, 2007.
DOI : 10.1039/b103275p

Y. Pu, N. Jiang, and A. J. Ragauskas, Ionic Liquid as a Green Solvent for Lignin, Journal of Wood Chemistry and Technology, vol.5, issue.1, pp.23-33, 2007.
DOI : 10.1039/b412633e

P. Kolle and R. Dronskowski, Hydrogen Bonding in the Crystal Structures of the Ionic Liquid Compounds Butyldimethylimidazolium Hydrogen Sulfate, Chloride, and Chloroferrate(II,III), Inorganic Chemistry, vol.43, issue.9, pp.43-2803, 2004.
DOI : 10.1021/ic035237l

A. Wulf, K. Fumino, and R. Ludwig, Spectroscopic evidence for an enhanced anion-cation interaction due to hydrogen bonding in pure imidazolium Ionic Liquids, Angew. Chem. Int. Ed, pp.49-449, 2010.

R. C. Remsing, J. L. Wildin, A. L. Rapp, and G. Moyna, Hydrogen-bonding in ionic liquids revisited: An NMR study of deuterium isotope effects in 1-n-butyl-3-methylimidazolium Chloride, J. Phys. Chem. B, pp.111-11619, 2007.

K. Dong, S. J. Zhang, D. X. Wang, and X. Q. Yao, Hydrogen Bonds in Imidazolium Ionic Liquids, The Journal of Physical Chemistry A, vol.110, issue.31, pp.110-9775, 2006.
DOI : 10.1021/jp054054c

K. Fumino, A. Wulf, and R. Ludwig, The Cation???Anion Interaction in Ionic Liquids Probed by Far-Infrared Spectroscopy, Angewandte Chemie International Edition, vol.19, issue.20, pp.47-3830, 2008.
DOI : 10.1021/jp040199s

H. Ohno and Y. Fukaya, Task Specific Ionic Liquids for Cellulose Technology, Chemistry Letters, vol.38, issue.1, pp.2-7, 2009.
DOI : 10.1246/cl.2009.2

S. Zhang, X. Qi, X. Ma, L. Lu, Q. Zhang et al., Investigation of cation-anion interaction in 1-(2-hydroxyethyl)-3-methylimidazolium-based ion pairs by density functional theory calculations and experiments, Journal of Physical Organic Chemistry, vol.8, issue.3, pp.25-248, 2012.
DOI : 10.1002/cphc.200600725

H. Xu, W. Pan, R. Wang, D. Zhang, and C. Liu, Understanding the mechanism of cellulose dissolution in 1-butyl-3-methyl imidazolium chloride ionic liquid via quantum chemistry calculations and molecular dynamics simulations, J Comput Aided Mol Des, pp.26-329, 2012.

. Pople, Gaussian 03, revision E.01, 2003.

A. D. Becke, Density???functional thermochemistry. III. The role of exact exchange, The Journal of Chemical Physics, vol.98, issue.7, pp.5648-5652, 1993.
DOI : 10.1063/1.460205

C. Lee, W. Yang, and R. G. Parr, Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density, Physical Review B, vol.20, issue.2, pp.37-785, 1988.
DOI : 10.1103/PhysRevA.20.397

S. H. Vosko, L. Wilk, and M. Nusair, Accurate spin-dependent electron liquid correlation energies for local spin density calculations: a critical analysis, Canadian Journal of Physics, vol.58, issue.8, pp.58-1200, 1980.
DOI : 10.1139/p80-159

P. J. Stephens, F. J. Devlin, C. F. Chabalowski, and M. J. Frisch, Ab Initio Calculation of Vibrational Absorption and Circular Dichroism Spectra Using Density Functional Force Fields, The Journal of Physical Chemistry, vol.98, issue.45, pp.98-11623, 1994.
DOI : 10.1021/j100096a001

Z. D. Ding, Z. Chi, W. X. Gu, S. M. Gu, J. H. Liu et al., Theoretical and experimental investigation on dissolution and regeneration of cellulose in ionic liquid, Carbohydrate Polymers, vol.89, issue.1, pp.89-96, 2012.
DOI : 10.1016/j.carbpol.2012.01.080

X. L. Zhang, W. H. Yang, and W. Blasiak, Modeling Study of Woody Biomass: Interactions of Cellulose, Hemicellulose, and Lignin, Energy & Fuels, vol.25, issue.10, pp.25-4786, 2011.
DOI : 10.1021/ef201097d

C. M. Breneman and K. B. Wiberg, Determining atom-centered monopoles from molecular electrostatic potentials. The need for high sampling density in formamide conformational analysis, Journal of Computational Chemistry, vol.109, issue.3, pp.11-361, 1990.
DOI : 10.1002/jcc.540110311

J. Zhou, J. Mao, and S. Zhang, Ab initio calculations of the interaction between thiophene and ionic liquids, Fuel Processing Technology, vol.89, issue.12, pp.1456-1460, 2008.
DOI : 10.1016/j.fuproc.2008.07.006

C. Chiappe and D. Pieraccini, Ionic liquids: solvent properties and organic reactivity, Journal of Physical Organic Chemistry, vol.5, issue.155, pp.275-297, 2005.
DOI : 10.1021/cen-v076n013.p032

J. S. Wilkes and M. J. Zaworotko, Air and water stable 1-ethyl-3-methylimidazolium based ionic liquids, Journal of the Chemical Society, Chemical Communications, vol.13, issue.13, pp.965-967, 1992.
DOI : 10.1039/c39920000965

P. B. Hitchcock, K. R. Seddon, and T. Welton, Hydrogen-bond acceptor abilities of tetrachlorometallate (II) complexes in ionic liquids, J. Chem. Soc, pp.17-2639, 1993.

G. A. Jeffrey, The ups and downs of C???H hydrogen bonds, Journal of Molecular Structure, vol.485, issue.486, pp.485-486, 1999.
DOI : 10.1016/S0022-2860(99)00049-6

A. Casas, J. Palomar, M. V. Alonso, M. Oliet, S. Omar et al., Comparison of lignin and cellulose solubilities in ionic liquids by COSMO-RS analysis and experimental validation, Industrial Crops and Products, vol.37, issue.1, pp.37-155, 2012.
DOI : 10.1016/j.indcrop.2011.11.032

R. E. El-sayed, F. Hassan, S. Mutelet, J. Pontvianne, and . Moise, Studies on the dissolution of glucose in ionic liquids and extraction using the antisolvent method, Environ. Sci. Technol, pp.47-2809, 2013.

R. E. El-sayed, F. Hassan, J. Mutelet, and . Moise, From the dissolution to the extraction of carbohydrates using ionic liquids, RSC Adv, vol.49, issue.3, pp.20219-20226, 2013.

H. Wang, G. Gurau, and R. D. Rogers, Ionic liquid processing of cellulose, Chemical Society Reviews, vol.5, issue.4, pp.41-1519, 2012.
DOI : 10.1002/bbb.303

D. Ciolacu, F. Ciolacu, and V. I. Popa, Amorphus cellulose-structure and characterization, Cellulose Chem. Technol, vol.45, pp.13-21, 2011.

W. Li, M. Ju, Y. Wang, L. Liu, and Y. Jiang, Separation and recovery of cellulose from Zoysia japonica by 1-allyl-3-methylimidazolium chloride, Carbohydrate Polymers, vol.92, issue.1, pp.92-228, 2013.
DOI : 10.1016/j.carbpol.2012.09.075

P. Mansikkamaki, M. Lahtinen, and K. Rissanen, Structural Changes of Cellulose Crystallites Induced by Mercerisation in Different Solvent Systems; Determined by Powder X-ray Diffraction Method, Cellulose, vol.30, issue.3, pp.12-233, 2005.
DOI : 10.1007/s10570-004-3132-1

X. Wanga, H. Li, Y. Cao, and Q. Tang, Cellulose extraction from wood chip in an ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl), Bioresource Technology, vol.102, issue.17, pp.7959-7965, 2011.
DOI : 10.1016/j.biortech.2011.05.064

R. H. Newman, Homogeneity in cellulose crystallinity between samples of Pinus radiata wood, Holzforschung, vol.28, issue.4, pp.58-91, 2004.
DOI : 10.1515/hfsg.1974.28.3.91

H. Lateef, S. Grimes, P. Kewcharoenwong, and B. Feinberg, Separation and recovery of cellulose and lignin using ionic liquids: a process for recovery from paper-based waste, Journal of Chemical Technology & Biotechnology, vol.27, issue.132
DOI : 10.1504/IJETM.2004.004624

H. Tadesse and R. Luque, Advances on biomass pretreatment using ionic liquids: An overview, Energy & Environmental Science, vol.11, issue.108, pp.3913-3929, 2011.
DOI : 10.1039/b905388c

J. Frederick, J. P. Hallett, D. J. Leak, C. L. Liotta, J. R. Mielenz et al., The path forward for biofuels and biomaterials, Science, pp.311-484, 2006.

J. H. Clark, Green chemistry for the second generation biorefinery???sustainable chemical manufacturing based on biomass, Journal of Chemical Technology & Biotechnology, vol.23, issue.7, pp.603-609, 2007.
DOI : 10.1002/0470014202

H. Tadesse and R. Luque, Advances on biomass pretreatment using ionic liquids: An overview, Energy & Environmental Science, vol.11, issue.108, pp.3913-3929, 2011.
DOI : 10.1039/b905388c

R. L. Howard, E. Abotsi, E. L. Rensburg, and S. Howard, Lignocellulose biotechnology: issues of bioconversion and enzyme production, African Journal of Biotechnology, vol.2, issue.12, pp.602-619, 2003.
DOI : 10.5897/AJB2003.000-1115

P. Kang, W. Qin, Z. Zheng, C. Dong, and Y. Yang, Theoretical study on the mechanisms of cellulose dissolution and precipitation in the phosphoric acid???acetone process, Carbohydrate Polymers, vol.90, issue.4, pp.90-1771, 2012.
DOI : 10.1016/j.carbpol.2012.07.068

R. Wooley, M. F. Ruth, D. Glassner, and J. Sheehan, Process Design and Costing of Bioethanol Technology: A Tool for Determining the Status and Direction of Research and Development, Biotechnology Progress, vol.15, issue.5, pp.15-794, 1999.
DOI : 10.1021/bp990107u

T. Vancov, A. Alston, T. Brown, and S. Mcintosh, Use of ionic liquids in converting lignocellulosic material to biofuels Renewable Energy, pp.45-46, 2012.

M. Galbe and G. Zacchi, Pretreatment of Lignocellulosic Materials for Efficient Bioethanol Production, Biofuels, vol.108, pp.41-65, 2007.
DOI : 10.1007/10_2007_070

P. Kumar, D. M. Barrett, M. J. Delwiche, and P. Stroeve, Methods for Pretreatment of Lignocellulosic Biomass for Efficient Hydrolysis and Biofuel Production, Industrial & Engineering Chemistry Research, vol.48, issue.8, pp.48-3713, 2009.
DOI : 10.1021/ie801542g

J. R. Himmel, L. R. Mcmillan, and . Lynd, Fractionating recalcitrant lignocellulose at modest reaction conditions, Biotechnol Bioeng, pp.97-214, 2007.

N. Brosse, P. Sannigrahi, and A. Ragauskas, Pretreatment of miscanthus x giganteus using the ethanol organosolv process for ethanol production, Ind. Eng. Chem. Res, pp.48-8328, 2009.

N. Brosse, A. Dufour, X. Meng, Q. Sun, and A. Ragauskas, : a fast-growing crop for biofuels and chemicals production, Biofuels, Bioproducts and Biorefining, vol.6, issue.4, pp.580-598, 2012.
DOI : 10.1016/j.procbio.2010.02.015

T. De-vrije, G. G. De-haas, G. B. Tan, E. R. Keijsers, and P. A. Claassen, Pretreatment of miscanthus for hydrogen production by Thermotoga elfii, Int. J. Hydrogen Energy, pp.27-1381, 2002.

H. K. Murnen, V. Balan, S. P. Chundawat, B. Bals, L. Da et al., Optimization of Ammonia Fiber Expansion (AFEX) Pretreatment and Enzymatic Hydrolysis of Miscanthus x giganteus to Fermentable Sugars, Biotechnology Progress, vol.23, issue.4, pp.846-850, 2007.
DOI : 10.1021/bp070098m

A. Sørensen, P. J. Teller, T. Hilstrom, and B. K. Ahring, Hydrolysis of miscanthus for bioethanol production using dilute acid presoaking combined with wet explosion pretreatment and enzymatic treatment, Bioresour. Technol, pp.99-6602, 2008.

. Fukuda, Effects of cellulose crystallinity, hemicellulose, and lignin on the enzymatic hydrolysis of miscanthus sinensis to monosaccharides, Biosci. Biotechnol. Biochem, vol.72, pp.805-810, 2008.

J. J. Villaverde, J. Li, M. Ek, P. Ligero, and A. Vega, and Its Changes during Acetic and Formic Acid Fractionation, Journal of Agricultural and Food Chemistry, vol.57, issue.14, pp.6262-6270, 2009.
DOI : 10.1021/jf900483t

L. Ngoc-huyen, C. Rémond, R. M. Dheilly, and B. Chabbert, Effect of harvesting date on the composition and saccharification of Miscanthus x giganteus, Bioresource Technology, vol.101, issue.21, pp.8224-8231, 2010.
DOI : 10.1016/j.biortech.2010.05.087

C. Reichardt, Polarity of ionic liquids determined empirically by means of solvatochromic pyridinium N-phenolate betaine dyes, Green Chemistry, vol.33, issue.1, pp.339-351, 2005.
DOI : 10.1039/b408334b

M. E. Zakrzewska, E. Bogel-lukasik, and R. , Solubility of Carbohydrates in Ionic Liquids, Energy & Fuels, vol.24, issue.2, pp.737-745, 2010.
DOI : 10.1021/ef901215m

. Macfarlane, Lithium electrochemistry and cycling behaviour of ionic liquids using cyano based anions, Energy Environ. Sci, vol.6, pp.979-986, 2013.

D. Fu, G. Mazza, and Y. Tamaki, Lignin Extraction from Straw by Ionic Liquids and Enzymatic Hydrolysis of the Cellulosic Residues, Journal of Agricultural and Food Chemistry, vol.58, issue.5, pp.58-2915, 2010.
DOI : 10.1021/jf903616y

J. Sim, Pretreatment of rice straw with ammonia and ionic liquid for lignocellulose conversion to fermentable sugars, Bioresour. Technol, vol.101, pp.7432-7438, 2010.

M. Pringle and J. L. Scott, Extraction of lignin from lignocellulose at atmospheric pressure using alkylbenzenesulfonate ionic liquid, Green Chem, vol.11, pp.339-345, 2009.

H. Wu, M. Mora-pale, J. Miao, T. V. Doherty, R. J. Linhardt et al., Facile pretreatment of lignocellulosic biomass at high loadings in room temperature ionic liquids, Biotechnology and Bioengineering, vol.103, issue.1, pp.2865-2875, 2011.
DOI : 10.1002/bit.22307

R. C. Remsing, R. P. Swatloski, R. D. Rogers, and G. Moyna, Mechanism of cellulose dissolution in the ionic liquid 1-n-butyl-3-methylimidazolium chloride: a 13C and 35/37Cl NMR relaxation study on model systems, Chemical Communications, vol.3, issue.12, pp.1271-1273, 2006.
DOI : 10.1039/b600586c

S. H. Lee, T. V. Doherty, R. J. Linhardt, and J. S. Dordick, Ionic liquid-mediated selective extraction of lignin from wood leading to enhanced enzymatic cellulose hydrolysis, Biotechnology and Bioengineering, vol.99, issue.140, pp.1368-1376, 2009.
DOI : 10.1021/cen-v076n013.p032

A. M. Da-costa-lopes, K. Joao, D. Rubik, E. Bogel-lukasik, L. C. Duarte et al., Pre-treatment of lignocellulosic biomass using ionic liquids: Wheat straw fractionation, Bioresource Technology, vol.142, pp.142-198, 2013.
DOI : 10.1016/j.biortech.2013.05.032

S. P. Magalhaes-da-silva, A. M. Da-costa-lopes, L. B. Roseiro, and R. , Novel pre-treatment and fractionation method for lignocellulosic biomass using ionic liquids, RSC Advances, vol.108, issue.93, pp.16040-16050, 2013.
DOI : 10.1002/bit.23014

K. Shill, S. Padmanabhan, Q. Xin, J. M. Prausnitz, D. S. Clark et al., Ionic liquid pretreatment of cellulosic biomass: Enzymatic hydrolysis and ionic liquid recycle, Biotechnology and Bioengineering, vol.8, issue.4, pp.511-520, 2011.
DOI : 10.1039/b601395c

H. Rodríguez, S. Padmanabhan, G. Poon, and J. M. Prausnitz, Addition of ammonia and/or oxygen to an ionic liquid for delignification of miscanthus, Bioresource Technology, vol.102, issue.17, p.7952, 2011.
DOI : 10.1016/j.biortech.2011.05.039

S. Padmanabhan, M. Kim, H. W. Blanch, and J. M. Prausnitz, Solubility and rate of dissolution for Miscanthus in hydrophilic ionic liquids, Fluid Phase Equilibr, pp.309-89, 2011.

S. Padmanabhan, E. Zaia, K. Wu, H. W. Blanch, D. S. Clark et al., Delignification of miscanthus by extraction, Separation Science and Technology, p.47, 2012.

Ø. Vessia, Biofuels from lignocellulosic material: In the Norwegian context 2010- technology, potential and costs, department of electrical engineering, 2005.

Y. Sun, Enzymatic hydrolysis of rye straw and Bermudagrass for ethanol production, 2002.

C. N. Hamelinck, G. Van-hooijdonk, and A. P. Faaij, Ethanol from lignocellulosic biomass: techno-economic performance in short-, middle- and long-term, Biomass and Bioenergy, vol.28, issue.4, pp.28-384, 2005.
DOI : 10.1016/j.biombioe.2004.09.002

X. Pan, C. Arato, N. Gilkes, D. Gregg, W. Mabee et al., Biorefining of softwoods using ethanol organosolv pulping: Preliminary evaluation of process streams for manufacture of fuel-grade ethanol and co-products, Biotechnology and Bioengineering, vol.77, issue.4, pp.90-473, 2005.
DOI : 10.1007/978-3-642-74065-7_35

M. Balat, H. Balat, and C. Oz, Progress in bioethanol processing, Progress in Energy and Combustion Science, pp.551-573, 2008.
DOI : 10.1016/j.pecs.2007.11.001

A. A. Diiorio, Ethanol Production by an Isogenic Series of Saccharomyces Cerevisiae, Worcester Polytechnic Institute, Biotechnology. Worcester: WPI, 1986.

T. K. Ghose, Measurement of cellulase activities, Pure and Applied Chemistry, vol.59, issue.2, pp.257-268, 1987.
DOI : 10.1351/pac198759020257

D. A. Fort, R. C. Remsing, R. P. Swatloski, P. Moyna, G. Moyna et al., Can ionic liquids dissolve wood? Processing and analysis of lignocellulosic materials with 1-n-butyl-3-methylimidazolium chloride, Green Chem., vol.3, issue.1, pp.63-69, 2007.
DOI : 10.1039/b103275p

N. Sun, M. Rahman, Y. Qin, M. L. Maxim, H. Rodríguez et al., Complete dissolution and partial delignification of wood in the ionic liquid 1-ethyl-3-methylimidazolium acetate, Green Chemistry, vol.12, issue.5, pp.11-646, 2009.
DOI : 10.1021/cen-v076n013.p032

D. Templeton and T. Ehrman, LAP 003-Standard Method for the Determination of Acid- Insoluble Lignin in Biomass Available from World Wide Web, 1995.

H. T. Tan and K. T. Lee, Understanding the impact of ionic liquid pretreatment on biomass and enzymatic hydrolysis, Chemical Engineering Journal, vol.183, pp.448-458, 2012.
DOI : 10.1016/j.cej.2011.12.086

J. X. Sun, X. F. Sun, H. Zhao, and R. C. Sun, Isolation and characterization of cellulose from sugarcane bagasse, Polymer Degradation and Stability, vol.84, issue.2, pp.331-339, 2004.
DOI : 10.1016/j.polymdegradstab.2004.02.008

Y. Teramoto, S. Lee, and T. Endo, Cost reduction and feedstock diversity for sulfuric acid-free ethanol cooking of lignocellulosic biomass as a pretreatment to enzymatic saccharification, Bioresource Technology, vol.100, issue.20, pp.4783-4789, 2009.
DOI : 10.1016/j.biortech.2009.04.054

L. Segal, J. J. Creely, A. E. Martin-jr, and C. M. Conrad, An Empirical Method for Estimating the Degree of Crystallinity of Native Cellulose Using the X-Ray Diffractometer, Textile Research Journal, vol.49, issue.10, pp.29-786, 1959.
DOI : 10.1177/004051755002000601

S. Park, J. O. Baker, M. E. Himmel, P. A. Parilla, and D. K. Johnson, Cellulose crystallinity index: measurement techniques and their impact on interpreting cellulase performance, Biotechnology for Biofuels, vol.3, issue.1, 2010.
DOI : 10.1186/1754-6834-3-10

R. H. Newman, Homogeneity in cellulose crystallinity between samples of Pinus radiata wood, Holzforschung, vol.28, issue.4, pp.58-91, 2004.
DOI : 10.1515/hfsg.1974.28.3.91

Y. Lin, W. Zhang, C. Li, K. Sakakibara, S. Tanaka et al., Factors affecting ethanol fermentation using Saccharomyces cerevisaie BY4742, Biomass and Bioenergy, pp.47-395, 2012.

C. D. Skory, Lactic acid production by Saccharomyces cerevisiae expressing a Rhizopus oryzae lactate dehydrogenase gene, Journal of Industrial Microbiology & Biotechnology, vol.30, issue.1, pp.22-27, 2003.
DOI : 10.1007/s10295-002-0004-2

K. Kasemets and I. Nisamedtinov, Growth characteristics of Saccharomyces serevisiae S288C in changing environmental conditions: auxo-accelerostat study, Anton Leeuw, pp.92-109, 2007.

R. P. Swatloski, S. K. Spear, J. D. Holbrey, and R. D. Rogers, Dissolution of cellulose with ionic liquids, J. Am. Chem. Soc, pp.124-4974, 2002.

H. Xie, S. Li, and S. Zhang, Ionic liquids as novel solvents for the dissolution and blending of wool keratin fibers, Green Chemistry, vol.27, issue.8, pp.606-608, 2005.
DOI : 10.1039/b502547h

X. Wanga, H. Li, Y. Cao, and Q. Tang, Cellulose extraction from wood chip in an ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl), Bioresource Technology, vol.102, issue.17, pp.7959-7965, 2011.
DOI : 10.1016/j.biortech.2011.05.064

T. Yuan, W. Wan, F. Xu, and R. Sun, Synergistic benefits of ionic liquid and alkaline pretreatments of poplar wood. Part 1: Effect of integrated pretreatment on enzymatic hydrolysis, Bioresource Technology, vol.144, pp.144-429, 2013.
DOI : 10.1016/j.biortech.2012.12.034

W. Li, M. Ju, Y. Wang, L. Liu, and Y. Jiang, Separation and recovery of cellulose from Zoysia japonica by 1-allyl-3-methylimidazolium chloride, Carbohydrate Polymers, vol.92, issue.1, pp.92-228, 2013.
DOI : 10.1016/j.carbpol.2012.09.075

P. Mäki-arvela, I. Anugwom, P. Virtanen, R. Sjöholm, and J. P. Mikkola, Dissolution of lignocellulosic materials and its constituents using ionic liquids???A review, Industrial Crops and Products, vol.32, issue.3, pp.32-175, 2010.
DOI : 10.1016/j.indcrop.2010.04.005

M. Zavrel, D. Bross, M. Funke, J. Büchs, and A. C. Spiess, High-throughput screening for ionic liquids dissolving (ligno-)cellulose, Bioresource Technology, vol.100, issue.9, pp.2580-2587, 2009.
DOI : 10.1016/j.biortech.2008.11.052

A. Brandt, J. P. Hallett, D. J. Leak, R. J. Murphy, and T. Welton, The effect of the ionic liquid anion in the pretreatment of pine wood chips, Green Chemistry, vol.4, issue.4, p.12, 2010.
DOI : 10.1039/b918787a

G. E. Box and D. W. Behnken, Some New Three Level Designs for the Study of Quantitative Variables, Technometrics, vol.31, issue.4, pp.455-475, 1960.
DOI : 10.1214/aoms/1177706093

R. E. El-sayed, F. Hassan, S. Mutelet, J. Pontvianne, and . Moise, Studies on the dissolution of glucose in ionic liquids and extraction using the antisolvent method, Environ. Sci. Technol, pp.47-2809, 2013.

R. E. El-sayed, F. Hassan, J. Mutelet, and . Moise, From the dissolution to the extraction of carbohydrates using ionic liquids, RSC Adv, vol.3, pp.20219-20226, 2013.

D. Ciolacu, F. Ciolacu, and V. I. Popa, Amorphus cellulose-structure and Characterization, Cellulose Chem. Technol, vol.45, pp.13-21, 2011.

P. Mansikkamaki, M. Lahtinen, and K. Rissanen, Structural Changes of Cellulose Crystallites Induced by Mercerisation in Different Solvent Systems; Determined by Powder X-ray Diffraction Method, Cellulose, vol.30, issue.3, pp.12-233, 2005.
DOI : 10.1007/s10570-004-3132-1

Z. G. Wang, T. Yokoyama, H. M. Chang, and Y. Matsumoto, Dissolution of Beech and Spruce Milled Woods in LiCl/DMSO, Journal of Agricultural and Food Chemistry, vol.57, issue.14, pp.6167-6170, 2009.
DOI : 10.1021/jf900441q

M. Matulova, R. Nouaille, P. Cappek, M. Péan, E. Forano et al., Degradation of Wheat Straw by Fibrobacter succinogenes S85: a Liquid- and Solid-State Nuclear Magnetic Resonance Study, Applied and Environmental Microbiology, vol.71, issue.3, pp.71-1247, 2005.
DOI : 10.1128/AEM.71.3.1247-1253.2005

URL : https://hal.archives-ouvertes.fr/hal-00125723

E. Locci, S. Laconi, R. Pompei, P. Scano, A. Lai et al., Wheat bran biodegradation by Pleurotus ostreatus: A solid-state Carbon-13 NMR study, Bioresource Technology, vol.99, issue.10, pp.99-4279, 2006.
DOI : 10.1016/j.biortech.2007.08.048

G. Cheng, P. Varanasi, C. Li, H. Liu, Y. B. Melnichenko et al., Transition of Cellulose Crystalline Structure and Surface Morphology of Biomass as a Function of Ionic Liquid Pretreatment and Its Relation to Enzymatic Hydrolysis, Biomacromolecules, vol.12, issue.4, pp.12-933, 2011.
DOI : 10.1021/bm101240z

Y. Zheng, Z. Pan, and R. Zhang, Overview of biomass pretreatment for cellulosic ethanol production, International Journal of Agricultural and Biological Engineering, vol.2, pp.51-68, 2009.

T. Bauchop and S. R. Elsden, The Growth of Micro-organisms in Relation to their Energy Supply, Microbiology, vol.23, issue.3, pp.457-469, 1960.
DOI : 10.1099/00221287-23-3-457

S. J. Coppella and P. Dhurjati, A detailed analysis of Saccharomyces cerevisiae growth kinetics in batch, fed-batch, and hollow-fiber bioreactors, The Chemical Engineering Journal, vol.41, issue.2, pp.41-68, 1989.
DOI : 10.1016/0300-9467(89)80080-2

N. G. Cheng, M. Hasan, A. C. Kumoro, C. F. Ling, and M. Tham, Production of ethanol by fed-batch fermentation, Pertanika J. Sci. & Technol, pp.17-399, 2009.

Z. Yue, C. Teater, J. Maclellan, Y. Liu, and W. Liao, Development of a new bioethanol feedstock-Anaerobically digested fiber from confined dairy operations using different digestion configurations, biomass and bioenergy, pp.35-1946, 2011.

Z. Yue, C. Teater, Y. Liu, J. Maclellan, and W. Liao, A sustainable pathway of cellulosic ethanol production integrating anaerobic digestion with biorefining, Biotechnology and Bioengineering, vol.84, issue.12, pp.1031-1039, 2010.
DOI : 10.2172/885984

L. Tan, Y. Tang, H. Nishimura, S. Takei, S. Morimura et al., Eficcient production of bioethanol from corn stover by pretreatment with a combination of sulfuric acid and sodium hydroxide, Preparative Biochemistry & Biotechnology, pp.43-682, 2013.