Nous proposons ici d'en rappeler les principaux résultats ComméCommé enoncé précédemment, le Cu(111) possède unétatunétat de Shockley caractérisé par une dispersion parabolique dont le bas de bande est mesurémesuréà -440 meV sous le niveau de Fermi (` a 80K), avec une largeur spectralè a ? d'environ 40 meV et une masse effective de m * = 0.41 m e . Après le dépôt d'Ag, pour des taux de couverture inférieursinférieursà la monocouche, on observe l'atténuation de l'intensité de l ,
Electronic states at the surfaces of crystals, Math. Proc. Cambridge Phil. Soc. 35, p.205, 1939. ,
On the Surface States Associated with a Periodic Potential, Physical Review, vol.50, issue.4, p.317, 1939. ,
DOI : 10.1103/PhysRev.50.760
Die Oberfl???chenwellen in der Elektronentheorie der Metalle, Zeitschrift f???r Physik, vol.94, issue.11-12, p.717, 1935. ,
DOI : 10.1007/BF01330080
Zur frage nach der elektronenbewegung im beschrankten kristallgitter, Z. Physik, vol.89, issue.806, 1934. ,
-gap surface states on the (111) face of noble metals by photoelectron spectroscopy, Physical Review B, vol.83, issue.333, p.195411, 2001. ,
DOI : 10.1103/PhysRevLett.83.5551
Temperature dependence of Shockley-type surface energy bands on Cu(111), Ag(111) and Au(111), Surface Science, vol.336, issue.1-2, p.113, 1995. ,
DOI : 10.1016/0039-6028(95)00509-9
Ultraviolet photoemission for intrinsic surface states of the noble metals, Journal of Physics C: Solid State Physics, vol.10, issue.1, p.17, 1977. ,
DOI : 10.1088/0022-3719/10/1/004
Effective-mass theory of simple surface states, Physical Review B, vol.31, issue.23, p.6713, 1986. ,
DOI : 10.1103/PhysRevB.31.6815
Image potential states on metal surfaces: binding energies and wave functions, Surface Science, vol.437, issue.3, p.330, 1999. ,
DOI : 10.1016/S0039-6028(99)00668-8
-gap surface state on Au(111) and Ag(111), Physical Review B, vol.43, issue.3, p.33407, 2001. ,
DOI : 10.1103/PhysRevA.43.13
Direct observation of standing wave formation at surface steps using scanning tunneling spectroscopy, Physical Review Letters, vol.28, issue.7, p.1071, 1993. ,
DOI : 10.1103/PhysRevB.28.4267
Etude par spectroscopies d'´ electrons d'interfaces métalliques et semiconductrices, Thèse de doctorat, 2011. ,
Quantum coherence and lifetimes of surface-state electrons, Journal of Electron Spectroscopy and Related Phenomena, vol.109, issue.1-2, pp.33-49, 2000. ,
DOI : 10.1016/S0368-2048(00)00105-5
Confinement of Surface State Electrons in Fabry-P??rot Resonators, Physical Review Letters, vol.73, issue.24, p.5370, 1998. ,
DOI : 10.1103/PhysRevLett.73.1015
Scattering of surface electrons by isolated steps versus periodic step arrays, Physical Review B, vol.87, issue.11, p.115425, 2013. ,
DOI : 10.1103/PhysRevB.43.3821
Etude des propriétéspropriétésélectroniques desétatsdesétats de Shockley dans les surfaces nanostruturées auto-organisées, Thèse de doctorat, 2007. ,
Scanning tunneling microscopy and kinetic Monte Carlo investigation of cesium superlattices on Ag(111), Physical Review B, vol.133, issue.24, p.245427, 2008. ,
DOI : 10.1016/j.susc.2005.06.080
Thermal damping of quantum interference patterns of surface-state electrons, Physical Review B, vol.28, issue.24, p.15926, 1998. ,
DOI : 10.1103/PhysRevB.28.4267
Scanning tunneling microscopy as local probe of electron density, dynamics, and transport et metal surfaces ,
Theory of the local density of surface states on a metal: Comparison with scanning tunneling spectroscopy of a Au(111) surface, Physical Review B, vol.33, issue.5, p.3821, 1991. ,
DOI : 10.1103/PhysRevB.33.2256
Direct Imaging of Adsorption Sites and Local Electronic Bond Effects on a Metal Surface: C/Al(111), Europhysics Letters (EPL), vol.13, issue.2, p.123, 1990. ,
DOI : 10.1209/0295-5075/13/2/005
Long-Range Electronic Interactions at a High Temperature: Bromine Adatom Islands on Cu(111), Physical Review Letters, vol.50, issue.20, p.206108, 2007. ,
DOI : 10.1088/1367-2630/7/1/139
Long-ranged adsorbate-adsorbate interactions mediated by a surface-state band, Journal of Physics: Condensed Matter, vol.12, issue.1, pp.13-19, 2000. ,
DOI : 10.1088/0953-8984/12/1/103
ARPES and STS investigation of noble metal Shockley states: Confinement in vicinal Au(111) surfaces and self-organized nanostructures, Surface Science, vol.601, issue.18, p.4029, 2007. ,
DOI : 10.1016/j.susc.2007.04.205
Scanning tunneling microscopy observations on the reconstructed Au(111) surface: Atomic structure, long-range superstructure, rotational domains, and surface defects, Physical Review B, vol.40, issue.15, pp.9307-9318, 1990. ,
DOI : 10.1103/PhysRevB.40.11973
Steps on surfaces: experiment and theory, Surface Science Reports, vol.34, issue.6-8 ,
DOI : 10.1016/S0167-5729(98)00010-7
Etude des propriétéspropriétésélectroniques et structurales des films ultra minces d, Thèse de doctorat, 2003. ,
on the surface electronic structure: Quantitative analysis of the induced band gap, Physical Review B, vol.331, issue.333, p.75407, 2005. ,
DOI : 10.1016/0039-6028(95)00283-9
Lateral engineering of surface states ??? towards surface-state nanoelectronics, Nanoscale, vol.316, issue.5, pp.717-721, 2010. ,
DOI : 10.1103/PhysRevB.73.155416
Modification of Shockley states induced by surface reconstruction in epitaxial Ag films on Cu(111), Physical Review B, vol.251, issue.12, p.165412, 2003. ,
DOI : 10.1016/S0301-0104(99)00313-4
Les surfaces solides : concepts et méthodes, EDP Sciences, 2005. ,
Ag/Cu(111) structure revisited through an extended mechanism for stress relaxation, Physical Review B, vol.75, issue.62, p.10910, 1998. ,
DOI : 10.1103/PhysRevLett.75.489
An Incommensurate Reconstruction Studied with Scanning Tunnelling Microscopy and Surface X-Ray Diffraction, Microscopy Microanalysis Microstructures, vol.75, issue.288, p.167, 1997. ,
DOI : 10.1103/PhysRevLett.75.489
Fermi Gap Stabilization of an Incommensurate Two-Dimensional Superstructure, Physical Review Letters, vol.94, issue.1, p.16103, 2005. ,
DOI : 10.1103/PhysRevB.46.16018
Comment on ???Fermi Gap Stabilization of an Incommensurate Two-Dimensional Superstructure???, Physical Review Letters, vol.96, issue.2, p.29701, 2006. ,
DOI : 10.1209/epl/i2003-00216-4
Surface state in epitaxial Ag ultrathin films on Cu(), Surface state in epitaxial ag ultrathin films on cu, p.43, 2002. ,
DOI : 10.1016/S0039-6028(01)01670-3
Phase analysis of image states and surface states associated with nearly-free-electron band gaps, Physical Review B, vol.31, issue.6, p.3549, 1985. ,
DOI : 10.1016/0038-1098(79)90025-5
Self-consistent approach for spectral properties of single alkali adatoms on Cu(111), Physical Review B, vol.85, issue.4, p.45408, 2012. ,
DOI : 10.1103/PhysRevLett.80.3571
The structure of na overlayers on Cu (111) at room temperature, Surf. Sci. Lett, vol.255, p.497, 1991. ,
Interplay of electronic structure and atomic ordering on surfaces: Momentum-resolved measurements of Cs atoms adsorbed on a Ag(111) substrate, Physical Review B, vol.85, issue.12, p.121412, 2012. ,
DOI : 10.1103/PhysRevLett.106.097201
Symmetry breaking and gap opening in two-dimensional hexagonal lattices, New Journal of Physics, vol.13, issue.1, p.13026, 2011. ,
DOI : 10.1088/1367-2630/13/1/013026
Dirac Cones and Minigaps for Graphene on Ir(111), Physical Review Letters, vol.102, issue.5, p.56808, 2009. ,
DOI : 10.1103/PhysRevLett.101.026803
Effect of Symmetry Breaking on Electronic Band Structure: Gap Opening at the High Symmetry Points, Symmetry, vol.5, issue.4, 2013. ,
DOI : 10.1088/1367-2630/9/10/391
URL : https://hal.archives-ouvertes.fr/hal-01273659
Noble metal surface states: deviations from parabolic dispersion, Surface Science, vol.447, issue.1-3, pp.157-161, 2000. ,
DOI : 10.1016/S0039-6028(99)01102-4
ARPES and STS investigation of Shockley states in thin metallic films and periodic nanostructures, New Journal of Physics, vol.9, issue.10, p.391, 2007. ,
DOI : 10.1088/1367-2630/9/10/391
Electronic surface potential from angle-resolved photoemission, Physical Review B, vol.89, issue.12, p.121409, 2014. ,
DOI : 10.1103/PhysRevB.85.121412
URL : https://hal.archives-ouvertes.fr/hal-01273341
84 1.2.1 Mécanismes réactionnels sur les surfaces métalliques, 1.2.4 Contrôle du processus de polymérisation, p.89 ,
92 1.4.1 Mesures XPS en fonction de la température, p.94 ,
99 2.2.1 Influence du taux de recouvrement sur la reconstruction, 99 2.2.2 Structure détaillée de la phase organométallique saturée " S-OM " . . . . . . 99 ,
102 2.3.1 Structure des dépôts non saturés ,
110 3.2.1 Structure du polymère U " aligné, 110 3.2.2 Structure du polymère S " transverse " . . . . . . . . . . . . . . . . . . . . 111 ,
114 3.3.1 Polymérisation en fonction du recouvrement, 114 3.3.2 Structure des polymères transverses, p.114 ,
120 4.2.1 Dispersion de la bande, p.122 ,
124 4.4 ´ Etude du confinement desétatsdesétats LUMOs, p.126 ,
De l'assemblage?Aassemblage? assemblage?A la fonctionnalisation, Clefs CEA, vol.52, pp.61-66, 2005. ,
Quantum phase transition in a single-molecule quantum dot, Nature, vol.131, issue.7195, pp.633-637, 2008. ,
DOI : 10.1038/nature06930
URL : https://hal.archives-ouvertes.fr/hal-00700040
Coherent Tunneling Transport in Molecular Junctions, The Journal of Physical Chemistry C, vol.114, issue.48, pp.20431-20435, 2010. ,
DOI : 10.1021/jp104760b
Cramming More Components Onto Integrated Circuits, Proceedings of the IEEE, vol.86, issue.1, 1965. ,
DOI : 10.1109/JPROC.1998.658762
A 22nm IA multi-CPU and GPU System-on-Chip, 2012 IEEE International Solid-State Circuits Conference, 2012. ,
DOI : 10.1109/ISSCC.2012.6176876
Why is CMOS scaling coming to an END?, 2008 3rd International Design and Test Workshop, 2010. ,
DOI : 10.1109/IDT.2008.4802475
There's plenty of room at the bottom, Engineering and Science, 1960. ,
Manipulation of Matter at the Atomic and Molecular Levels, Accounts of Chemical Research, vol.28, issue.3, pp.95-102, 1995. ,
DOI : 10.1021/ar00051a002
Quantum corrals, Physica D: Nonlinear Phenomena, vol.83, issue.1-3, pp.98-108, 1995. ,
DOI : 10.1016/0167-2789(94)00254-N
Manipulating the Conformation of Single Organometallic Chains on Au(111), The Journal of Physical Chemistry C, vol.118, issue.3, pp.1719-1728, 2014. ,
DOI : 10.1021/jp409323g
URL : https://hal.archives-ouvertes.fr/hal-01712433
Low-Frequency Current Fluctuations in Individual Semiconducting Single-Wall Carbon Nanotubes, Nano Letters, vol.6, issue.5, pp.930-936, 2006. ,
DOI : 10.1021/nl052528d
Energy Band-Gap Engineering of Graphene Nanoribbons, Physical Review Letters, vol.98, issue.20, p.206805, 2007. ,
DOI : 10.1126/science.1125925
Understanding and tuning the epitaxy of large aromatic adsorbates by molecular design, Nature, vol.188, issue.503, pp.602-605, 2003. ,
DOI : 10.1002/1521-396X(200112)188:4<1297::AID-PSSA1297>3.0.CO;2-X
Rectification and stability of a single molecular diode with controlled orientation, Nature Chemistry, vol.5, issue.8, pp.635-641, 2009. ,
DOI : 10.1038/nchem.392
Single Molecule Electronic Devices, Advanced Materials, vol.22, issue.14, pp.1583-1608, 2011. ,
DOI : 10.1002/adma.200901834
Molecular scale electronic devices using single molecules and molecular monolayers, Current Applied Physics, vol.13, issue.7, pp.1157-1171, 2013. ,
DOI : 10.1016/j.cap.2013.06.014
Single Layer of Polymeric Fe-Phthalocyanine: An Organometallic Sheet on Metal and Thin Insulating Film, Journal of the American Chemical Society, vol.133, issue.5, pp.1203-1205, 2011. ,
DOI : 10.1021/ja108628r
-butylcorannulene Molecules Inserted in Phthalocyanine Networks Studied by Low-Temperature Scanning Tunneling Microscopy, The Journal of Physical Chemistry C, vol.113, issue.50, pp.21169-21176, 2009. ,
DOI : 10.1021/jp906905h
Bicomponent Supramolecular Packing in Flexible Phthalocyanine Networks, Angewandte Chemie International Edition, vol.46, issue.37, pp.6994-6998, 2008. ,
DOI : 10.1002/anie.200802628
Two-Dimensional Polymer as a Mask for Surface Nanopatterning, Advanced Materials, vol.78, issue.9, pp.1252-1254, 2012. ,
DOI : 10.1063/1.2432410
Surface mediated synthesis of 2d covalent organic frameworks : 1,3,5-tris(4-bromophenyl)benzene on graphite, p.cu ,
Nano-architectures by covalent assembly of molecular building blocks, Nature Nanotechnology, vol.128, issue.11, pp.687-691, 2007. ,
DOI : 10.1038/35098059
Electronic Structure of Atomically Precise Graphene Nanoribbons, ACS Nano, vol.6, issue.8, pp.6930-6935, 2012. ,
DOI : 10.1021/nn3021376
Two-Dimensional Polymer Formation on Surfaces: Insight into the Roles of Precursor Mobility and Reactivity, Journal of the American Chemical Society, vol.132, issue.46, pp.16669-16676, 2010. ,
DOI : 10.1021/ja107947z
Exceptional ballistic transport in epitaxial graphene nanoribbons, Nature, vol.506, issue.7488, pp.349-354, 2014. ,
DOI : 10.1038/nnano.2011.138
URL : https://hal.archives-ouvertes.fr/hal-00911209
Light-triggered self-construction of supramolecular organic nanowires as metallic interconnects, Nature Chemistry, vol.130, issue.6, pp.485-490, 2012. ,
DOI : 10.1021/ja8037307
The Hierarchical Self-Assembly of Charge Nanocarriers: A Highly Cooperative Process Promoted by Visible Light, Angewandte Chemie International Edition, vol.97, issue.39, pp.6974-6978, 2010. ,
DOI : 10.1002/3527607439
URL : https://hal.archives-ouvertes.fr/hal-00530803
Toward Self-Constructing Materials: A Systems Chemistry Approach, Accounts of Chemical Research, vol.45, issue.12, pp.2178-2188, 2012. ,
DOI : 10.1021/ar2002655
Advances in Supramolecular Electronics - From Randomly Self-assembled Nanostructures to Addressable Self-Organized Interconnects, Advanced Materials, vol.45, issue.3, pp.477-487, 2013. ,
DOI : 10.1021/ar2002655
Building Supramolecular Nanostructures at Surfaces by Hydrogen Bonding, Angewandte Chemie International Edition, vol.39, issue.7, pp.1230-1234, 2000. ,
DOI : 10.1002/(SICI)1521-3773(20000403)39:7<1230::AID-ANIE1230>3.0.CO;2-I
Aggregation and contingent metal/surface reactivity of 1, Chem. Eur. J, vol.38, issue.111, p.10, 2010. ,
Programming Supramolecular Assembly and Chirality in Two-Dimensional Dicarboxylate Networks on a Cu(100) Surface, Nano Letters, vol.5, issue.5, pp.901-904, 2005. ,
DOI : 10.1021/nl050362a
URL : https://hal.archives-ouvertes.fr/hal-01293054
A Quantitative Approach to Hydrogen Bonding at a Metal Surface, Journal of the American Chemical Society, vol.129, issue.40, pp.12056-12057, 2007. ,
DOI : 10.1021/ja0724341
Molecular lego : Bottom-up fabrication of atomically precise graphene nanostructures, 2013. ,
Molecular networks through surface-mediated reactions -from hydrogen bonds to covalent links, 2010. ,
Electric Field Effect in Atomically Thin Carbon Films, Science, vol.306, issue.5696, 2004. ,
DOI : 10.1126/science.1102896
Self-Organized and Cu-Coordinated Surface Linear Polymerization, Scientific Reports, vol.31, issue.1, p.2102, 2012. ,
DOI : 10.1103/PhysRevB.31.805
URL : http://www.nature.com/articles/srep02102.pdf
Covalently bonded networks through surface-confined polymerization, Surface Science, vol.613, pp.6-14, 2013. ,
DOI : 10.1016/j.susc.2013.03.015
A STM perspective on covalent intermolecular coupling reactions on surfaces, Journal of Physics D: Applied Physics, vol.44, issue.46, p.464011, 2011. ,
DOI : 10.1088/0022-3727/44/46/464011
Molecular self-assembly at nanometer scale modulated surfaces: trimesic acid on Ag(111), Cu(111) and Ag/Cu(111), Phys. Chem. Chem. Phys., vol.3, issue.404, p.11265, 2014. ,
DOI : 10.1002/1438-5171(200204)3:1<25::AID-SIMO25>3.0.CO;2-K
Engineering atomic and molecular nanostructures at surfaces, Nature, vol.303, issue.7059, pp.671-679, 2005. ,
DOI : 10.1126/science.1091979
Synthesis and electronic structure of a two dimensional ??-conjugated polythiophene, Chemical Science, vol.125, issue.179, p.3263, 2013. ,
DOI : 10.1021/ja034333i
URL : https://hal.archives-ouvertes.fr/hal-01273655
Effect of Halo Substitution on the Geometry of Arenethiol Films on Cu(111), Journal of the American Chemical Society, vol.126, issue.25, pp.7762-7763, 2004. ,
DOI : 10.1021/ja048660h
Novel Mechanism for Molecular Self-Assembly on Metal Substrates: Unidirectional Rows of Pentacene on Cu(110) Produced by a Substrate-Mediated Repulsion, Physical Review Letters, vol.33, issue.103 ,
DOI : 10.1016/0039-6028(95)00074-7
Low dimensional self-organization of DNA-base molecules on Cu(111) surfaces, Surface Science, vol.386, issue.1-3, pp.124-136, 1997. ,
DOI : 10.1016/S0039-6028(97)00312-9
Chiral Kagome?? Lattice from Simple Ditopic Molecular Bricks, Journal of the American Chemical Society, vol.130, issue.35, pp.11778-11782, 2008. ,
DOI : 10.1021/ja8028119
Two-Dimensional Self-Assembly of Supramolecular Clusters and Chains, Physical Review Letters, vol.107, issue.2, pp.324-327, 1999. ,
DOI : 10.1002/jcc.540020312
Supramolecular assemblies formed on an epitaxial graphene superstructure, Angew. Chem. Int. Ed, vol.49, pp.1-7, 2010. ,
Selective assembly on a surface of supramolecular aggregates with controlled size and shape, Nature, vol.77, issue.6856, pp.619-621, 2001. ,
DOI : 10.1063/1.1323546
Supramolecular Assemblies of Trimesic Acid on a Cu(100) Surface, The Journal of Physical Chemistry B, vol.106, issue.27, pp.6907-6912, 2002. ,
DOI : 10.1021/jp014214u
Controlling molecular deposition and layer structure with supramolecular surface assemblies, Nature, vol.107, issue.6952, pp.1029-1031, 2003. ,
DOI : 10.1021/ja00299a024
Bimolecular Networks and Supramolecular Traps on Au(111), Bimolecular networks and supramolecular traps on au, pp.12539-12542, 2006. ,
DOI : 10.1021/jp060062x
Tailoring molecular layers at metal surfaces, Nature Chemistry, vol.291, issue.2, pp.87-95, 2010. ,
DOI : 10.1126/science.8367724
Surface-Assisted Assembly of 2D Metal???Organic Networks That Exhibit Unusual Threefold Coordination Symmetry, Angewandte Chemie International Edition, vol.23, issue.5, pp.710-713, 2007. ,
DOI : 10.1007/s002140050239
Metal???Organic Honeycomb Nanomeshes with Tunable Cavity Size, Nano Letters, vol.7, issue.12, pp.3813-3817, 2007. ,
DOI : 10.1021/nl072466m
Engineering coordination polymers towards applications. Dalton Trans, pp.2781-2804, 2003. ,
DOI : 10.1002/chin.200406292
Self-Assembly of Discrete Cyclic Nanostructures Mediated by Transition Metals, Chemical Reviews, vol.100, issue.3, pp.853-908, 2000. ,
DOI : 10.1021/cr9601324
Grid-Type Metal Ion Architectures: Functional Metallosupramolecular Arrays, Angewandte Chemie International Edition, vol.43, issue.28, pp.3644-3662, 2004. ,
DOI : 10.1002/anie.200300636
Functional Porous Coordination Polymers, Angewandte Chemie International Edition, vol.43, issue.18, pp.2334-2375, 2004. ,
DOI : 10.1002/anie.200300610
Modular Assembly of Two-Dimensional Metal???Organic Coordination Networks at a Metal Surface, Angewandte Chemie International Edition, vol.42, issue.23, pp.2670-2673, 2003. ,
DOI : 10.1002/anie.200250610
Squaring the Interface: ?Surface-Assisted? Coordination Chemistry, Angewandte Chemie International Edition, vol.41, issue.11, pp.1594-1596, 2005. ,
DOI : 10.1002/3527607439
Surface-Confined Supramolecular Coordination Chemistry, Top. Curr. Chem, vol.287, pp.1-44, 2009. ,
DOI : 10.1007/128_2008_150
Templated Growth of Metal-Organic Coordination Chains at Surfaces, Angewandte Chemie International Edition, vol.50, issue.38, pp.6142-6145, 2005. ,
DOI : 10.1002/3527607439
Density Functional Theory Analysis of Carboxylate-Bridged Diiron Units in Two-Dimensional Metal???Organic Grids, Journal of the American Chemical Society, vol.128, issue.17, pp.5634-5635, 2006. ,
DOI : 10.1021/ja060180y
A Surface Coordination Network Based on Substrate-Derived Metal Adatoms with Local Charge Excess, Angewandte Chemie International Edition, vol.115, issue.44, pp.8442-8445, 2008. ,
DOI : 10.1002/anie.200802543
Surface-Confined Metal???Organic Nanostructures from Co-Directed Assembly of Linear Terphenyl-dicarbonitrile Linkers on Ag(111), The Journal of Physical Chemistry C, vol.114, issue.37, 2010. ,
DOI : 10.1021/jp104518h
Towards Surface-Supported Supramolecular Architectures: Tailored Coordination Assembly of 1,4-Benzenedicarboxylate and Fe on Cu(100), Chemistry - A European Journal, vol.10, issue.8, pp.1913-1919, 2004. ,
DOI : 10.1002/chem.200305589
Surface-Template Assembly of Two-Dimensional Metal???Organic Coordination Networks, The Journal of Physical Chemistry B, vol.110, issue.46, pp.23472-23477, 2006. ,
DOI : 10.1021/jp065066g
intermediate organometallic networks on Ag(111), Chem. Commun., vol.18, issue.57, pp.7680-7682, 2014. ,
DOI : 10.1021/la011534w
Graphene-based composite materials, Nature, vol.83, issue.7100, pp.282-286, 2006. ,
DOI : 10.1063/1.1616976
Room-Temperature Quantum Hall Effect in Graphene, Science, vol.315, issue.5817, p.1379, 2007. ,
DOI : 10.1126/science.1137201
Iodobenzene on Cu(111): formation and coupling of adsorbed phenyl groups, Surface Science, vol.278, issue.1-2, pp.19-32, 1992. ,
DOI : 10.1016/0039-6028(92)90580-Y
Inducing All Steps of a Chemical Reaction with the Scanning Tunneling Microscope Tip: Towards Single Molecule Engineering, Physical Review Letters, vol.110, issue.13, pp.2777-2780, 2000. ,
DOI : 10.1021/ja00211a015
Covalent Interlinking of an Aldehyde and an Amine on a Au(111) Surface in Ultrahigh Vacuum, Angewandte Chemie, vol.152, issue.48, pp.9387-9390, 2007. ,
DOI : 10.1111/j.1365-2818.1988.tb01435.x
Surface Synthesis of 2D Branched Polymer Nanostructures, Angewandte Chemie International Edition, vol.152, issue.23, pp.4406-4410, 2008. ,
DOI : 10.1111/j.1365-2818.1988.tb01435.x
Molecular Self-Assembly from Building Blocks Synthesized on a Surface in Ultrahigh Vacuum: Kinetic Control and Topo-Chemical Reactions, ACS Nano, vol.2, issue.4, pp.651-660, 2008. ,
DOI : 10.1021/nn7004365
Fabrication of Surface-Supported Low-Dimensional Polyimide Networks, Journal of the American Chemical Society, vol.130, issue.43, pp.14054-14055, 2008. ,
DOI : 10.1021/ja805342n
Organized Formation of 2D Extended Covalent Organic Frameworks at Surfaces, Journal of the American Chemical Society, vol.130, issue.21, pp.6678-6679, 2008. ,
DOI : 10.1021/ja800906f
Porous, Crystalline, Covalent Organic Frameworks, Science, vol.310, issue.5751, p.1166, 2005. ,
DOI : 10.1126/science.1120411
Ullmann-type coupling of brominated tetrathienoanthracene on copper and silver, Nanoscale, vol.43, issue.5, pp.2660-2668, 2014. ,
DOI : 10.1103/PhysRevB.43.6405
Porous graphenes: two-dimensional polymer synthesis with atomic precision, Chemical Communications, vol.100, issue.45, pp.6919-6921, 2009. ,
DOI : 10.1039/b915190g
Surface-supported 2D heterotriangulene polymers, Chemical Communications, vol.10, issue.37, pp.10239-10241, 2011. ,
DOI : 10.1021/cm980036e
Construction and repair of highly ordered 2D covalent networks by chemical equilibrium regulation, Chemical Communications, vol.57, issue.24, pp.2943-2945, 2012. ,
DOI : 10.1039/b902849h
Sequential Linking To Control Growth of a Surface Covalent Organic Framework, The Journal of Physical Chemistry C, vol.116, issue.7, pp.4819-4823, 2012. ,
DOI : 10.1021/jp300417g
URL : https://hal.archives-ouvertes.fr/hal-01020216
Charged and metallic molecular monolayers through surface-induced aromatic stabilization, Nature Chemistry, vol.135, issue.3, pp.187-194, 2013. ,
DOI : 10.1063/1.3655357
Angle-resolved photoemission of chain-like molecules: the??electronic band structure of sexithiophene and sexiphenyl, Applied Physics A, vol.92, issue.112, pp.101-105, 2009. ,
DOI : 10.1007/s00339-008-5034-9
Electronic band structure of pentacene: An experimental and theoretical study, Physical Review B, vol.16, issue.11, p.115312, 2008. ,
DOI : 10.1063/1.125632
Coherent electron???nuclear coupling in oligothiophene molecular wires, Nature Physics, vol.6, issue.12, pp.975-979, 2010. ,
DOI : 10.1103/PhysRevB.78.035445
Oligothiophene Nanorings as Electron Resonators for Whispering Gallery Modes, Physical Review Letters, vol.84, issue.5, p.56802, 2013. ,
DOI : 10.1021/ar9000179
Free-electron-like dispersion in an organic monolayer film on a metal substrate, Nature, vol.67, issue.134, pp.350-353, 2006. ,
DOI : 10.1119/1.19208
Electronic structure at highly ordered organic/metal interfaces: Pentacene on Cu(110), Physical Review B, vol.251, issue.252, p.165436, 2007. ,
DOI : 10.1016/j.susc.2007.01.020
Electronic structure and electrical properties of interfaces between metals and ?-conjugated molecular films, Journal of Polymer Science Part B: Polymer Physics, vol.94, issue.21, pp.2529-2548, 2003. ,
DOI : 10.1063/1.1577400
Energy-Level Alignment at Organic/Metal and Organic/Organic Interfaces, Advanced Materials, vol.321, issue.43, pp.1450-1472, 2009. ,
DOI : 10.1002/adma.200802893
Energy levels at interfaces between metals and conjugated organic molecules, Journal of Physics: Condensed Matter, vol.20, issue.18, p.184008, 2008. ,
DOI : 10.1088/0953-8984/20/18/184008
Complete Supramolecular Self-Assembled Adlayer on a Silicon Surface at Room Temperature, Journal of the American Chemical Society, vol.130, issue.21, pp.6670-6671, 2008. ,
DOI : 10.1021/ja8001259
URL : https://hal.archives-ouvertes.fr/hal-00281924
Noncovalent Bicomponent Self-Assemblies on a Silicon Surface, ACS Nano, vol.6, issue.8, pp.6905-6911, 2012. ,
DOI : 10.1021/nn301827e
URL : https://hal.archives-ouvertes.fr/hal-00736798
Robust and Open Tailored Supramolecular Networks Controlled by the Template Effect of a Silicon Surface, Angewandte Chemie International Edition, vol.65, issue.18, pp.4094-4098, 2011. ,
DOI : 10.1016/j.surfrep.2010.08.001
URL : https://hal.archives-ouvertes.fr/hal-00604027
The Molecular Orientation of para-Sexiphenyl on Cu(110) and Cu(110) p(2??1)O, ChemPhysChem, vol.67, issue.11, pp.1707-1712, 2007. ,
DOI : 10.1007/978-3-662-02853-7
Reconstruction of Molecular Orbital Densities from Photoemission Data, Science, vol.28, issue.5836, 2009. ,
DOI : 10.1126/science.1143239
Copper intercalation at the interface of graphene and Ir(111) studied by scanning tunneling microscopy, Applied Physics Letters, vol.289, issue.19, 2014. ,
DOI : 10.1038/srep05704
URL : https://hal.archives-ouvertes.fr/hal-01273344
Silicon layer intercalation of centimeter-scale, epitaxially grown monolayer graphene on Ru(0001), Applied Physics Letters, vol.100, issue.9, p.93101, 2012. ,
DOI : 10.1038/nphys1022
monolayer on epitaxially grown, nanostructured graphene on Ru(0001) surface, Applied Physics Letters, vol.100, issue.1, p.13304, 2012. ,
DOI : 10.1126/science.280.5364.717
Ueber Synthesen in der Biphenylreihe, Berichte der deutschen chemischen Gesellschaft, vol.141, issue.2, p.2174, 1901. ,
DOI : 10.1002/cber.190103402141
Aryl???Aryl Bond Formation One Century after the Discovery of the Ullmann Reaction, Chemical Reviews, vol.102, issue.5, pp.1359-1469, 2002. ,
DOI : 10.1021/cr000664r
Conductance of a Single Conjugated Polymer as a Continuous Function of Its Length, Science, vol.281, issue.25, p.1193, 2009. ,
DOI : 10.1073/pnas.0500075102
Synthesis of Polyphenylene Molecular Wires by Surface-Confined Polymerization, Small, vol.78, issue.5, p.592, 2009. ,
DOI : 10.1039/c39930001795
Atomically precise bottom-up fabrication of graphene nanoribbons, Nature, vol.4, issue.7305, p.470, 2010. ,
DOI : 10.1038/nature09211
Formation and Manipulation of Protopolymer Chains, Journal of the American Chemical Society, vol.126, issue.51, pp.16772-16776, 2004. ,
DOI : 10.1021/ja038930g
Electronic structures of one-dimensional metal???molecule hybrid chains studied using scanning tunneling microscopy and density functional theory, Physical Chemistry Chemical Physics, vol.133, issue.20, pp.7304-7308, 2012. ,
DOI : 10.1021/ja204956b
Interchain Interactions Mediated by Br Adsorbates in Arrays of Metal???Organic Hybrid Chains on Ag(111), The Journal of Physical Chemistry C, vol.115, issue.30, pp.14834-14838, 2011. ,
DOI : 10.1021/jp203129f
Mechanisms of Halogen-Based Covalent Self-Assembly on Metal Surfaces, Journal of the American Chemical Society, vol.135, issue.15, pp.5768-5775, 2013. ,
DOI : 10.1021/ja400304b
Single-Molecule Resolution of an Organometallic Intermediate in a Surface-Supported Ullmann Coupling Reaction, Journal of the American Chemical Society, vol.133, issue.34, pp.13264-13267, 2011. ,
DOI : 10.1021/ja204956b
Controlling on-surface polymerization by hierarchical and substrate-directed growth, Nature Chemistry, vol.82, issue.3, pp.215-220, 2012. ,
DOI : 10.1103/PhysRevB.82.161418
Insight intoorganometallic intermediate and its evolution to covalent bonding in surface-confined ullmann polymerization, ACS Nano, 2014. ,
CH3I and C2H5I on Au(100): adsorption and reaction, Surface Science, vol.325, issue.1-2, pp.102-120, 1995. ,
DOI : 10.1016/0039-6028(94)00722-5
Crystal growth of para-sexiphenyl on clean and oxygen reconstructed Cu(110) surfaces, Physical Chemistry Chemical Physics, vol.13, issue.32, pp.14675-14684, 2011. ,
DOI : 10.1039/c0cp01516d
Material- and Orientation-Dependent Reactivity for Heterogeneously Catalyzed Carbon???Bromine Bond Homolysis, The Journal of Physical Chemistry C, vol.114, issue.29, pp.12604-12609, 2010. ,
DOI : 10.1021/jp102704q
Cooperative Modulation of Electronic Structures of Aromatic Molecules Coupled to Multiple Metal Contacts, Physical Review Letters, vol.110, issue.4, p.46802, 2013. ,
DOI : 10.1021/cr60156a001
Atomic structure of chemisorbed iodine layer on Cu(110), Surface Science, vol.584, issue.2-3, pp.278-286, 2005. ,
DOI : 10.1016/j.susc.2005.04.009
In situ scanning tunneling microscopy of Cu(110): atomic structures of halide adlayers and anodic dissolution, Journal of Electroanalytical Chemistry, vol.473, issue.1-2, pp.10-18, 1999. ,
DOI : 10.1016/S0022-0728(99)00063-7
Voltage-dependent conductance of a single graphene nanoribbon, Nature Nanotechnology, vol.1, issue.11, 2012. ,
DOI : 10.1021/nl201590f
Electroluminescence of a Polythiophene Molecular Wire Suspended between a Metallic Surface and the Tip of a Scanning Tunneling Microscope, Physical Review Letters, vol.112, issue.4, p.2014 ,
DOI : 10.1063/1.1812592
Resolving Band-Structure Evolution and Defect-Induced States of Single Conjugated Oligomers by Scanning Tunneling Microscopy and Tight-Binding Calculations, Physical Review Letters, vol.106, issue.20, p.206803, 2011. ,
DOI : 10.1016/j.synthmet.2003.08.019
Emergence of localized in-gap states in conjugated polymers of branched topology, Physical Review B, vol.6, issue.4, p.45428, 2012. ,
DOI : 10.1016/0379-6779(94)03217-T
A wide-bandgap metal???semiconductor???metal nanostructure made entirely from graphene, Nature Physics, vol.9, issue.1, pp.49-54, 2013. ,
DOI : 10.1073/pnas.1105113108
Intra- and Intermolecular Band Dispersion in an Organic Crystal, Science, vol.120, issue.22, pp.351-355, 2007. ,
DOI : 10.1063/1.1651065
Substrate-mediated band-dispersion of adsorbate molecular states, Nature Comm, vol.4, p.1514, 2012. ,
Characterization of the Interface Dipole at Organic/ Metal Interfaces, Journal of the American Chemical Society, vol.124, issue.27, pp.8131-8141, 2002. ,
DOI : 10.1021/ja025673r
Renormalization of Molecular Electronic Levels at Metal-Molecule Interfaces, Physical Review Letters, vol.279, issue.21, p.216405, 2006. ,
DOI : 10.1021/jp036698v
Renormalization of Molecular Quasiparticle Levels at Metal-Molecule Interfaces: Trends across Binding Regimes, Physical Review Letters, vol.102, issue.4, p.46802, 2014. ,
DOI : 10.1103/PhysRevLett.100.166804
Photoelectric Work Function of a Copper Single Crystal for the (100), (110), (111), and (112) Faces, Physical Review Letters, vol.28, issue.12, pp.738-739, 1972. ,
DOI : 10.1063/1.1722666
Surface characterization by means of photoemission of adsorbed xenon (PAX), Surface and Interface Analysis, vol.91, issue.23, pp.15-20, 1988. ,
DOI : 10.1116/1.574320
URL : https://hal.archives-ouvertes.fr/hal-00419660
The Structure of Molecular Orbitals Investigated by Angle-Resolved Photoemission, Series in Materials Science, 2013. ,
DOI : 10.1007/978-3-642-33848-9_1
Development and character of gap states on alkali doping of molecular films, New Journal of Physics, vol.16, issue.2, p.23011, 2014. ,
DOI : 10.1088/1367-2630/16/2/023011
en fonction de la position(x,y) en maintenant la boucle de contre réaction active pour garder la composante continue de I constante Cette technique a pourénormepourénorme avantage d'? etre beaucoup plus rapide, en permettant d'obtenir sur notre dispositif expérimentale une cartographie bidimensionnelle de la conductance en une vingtaine de minute (pour une seulé energie) Elle permet de repérer facilement et rapidement les effets spectroscopiques liés liésà la localisationélectroniquelocalisationélectronique, par exemple dans le cas du confinement desétatsdesétats de Shockley 162 2 STM/STS dans des puits quantiques. Néanmoins, les données sontàsontà interpréter avec précaution car nous n'enregistrons plus dans ce cas la densité d'´ etatàetatà hauteur constante. L'expression donnée en A.17 n'est plus valable, Cet effet a ´ eté notamment discuté dans les travaux de Kliewer et coll. présentés en figure C.8 ou l'on observe sur des résonateurs formés par des atomes de Mn déposés sur Ag(111) un excellent accord entre les cartes de conductances mesurées et calculées, et un fort désaccord avec la densité d'´ etat théorique ,
Il est constitué principalement de trois chambres : ? une chambre d'´ epitaxie (a,b) pour l'´ elaboration et la caractérisation deséchantillonsdeséchantillons. ? une chambre STM (c) pour la microscopie et la spectroscopie par effet tunnel. ? une chambre de photoémission (d-f) résolue en angle pour l'´ etude spectroscopique On compté egalement un sas de petit volume (g) permettant d'introduire leséchantillonsleséchantillons dans un délai de 8 heures nécessairesnécessairesà l'´ etuvage du dispositif ainsi qu'une chambre de stockage (h) ´ equipée d'un carrousel permettant de conserver leséchantillonsleséchantillons sous vide. L'ensemble des chambres sont couplées entre elles et maintenues sous ultravidè a l'aide de pompes turbomoléculaires et/ou ioniques permettant d'atteindre un vide de l ,
Photoemission Studies of Copper and Silver: Theory, Physical Review, vol.81, issue.4A, p.1030, 1964. ,
DOI : 10.1103/PhysRev.81.612
Angular Dependence of Photoemission in Metals, Physical Review Letters, vol.2, issue.19, p.1068, 1970. ,
DOI : 10.1088/0022-3719/2/12/310
Theory of Photoemission in Simple Metals, Physical Review B, vol.74, issue.11, p.4334, 1970. ,
DOI : 10.1007/978-3-642-52803-3
Angle-resolved photoemission-theory and current application, 1992. ,
Photoemission spectroscopy : Principles and applications, 2003. ,
Photoemission in solids 1, 1978. ,
Photoelectric Work Function of a Copper Single Crystal for the (100), (110), (111), and (112) Faces, Physical Review Letters, vol.28, issue.12, pp.738-739, 1972. ,
DOI : 10.1063/1.1722666
Bulk band structure and Fermi surface of nickel: A soft x-ray angle-resolved photoemission study, Physical Review B, vol.34, issue.468, p.45127, 2006. ,
DOI : 10.1103/PhysRevB.16.3428
Films, Physical Review Letters, vol.104, issue.6, p.66407, 2010. ,
DOI : 10.1126/science.1162843
Tunneling from a many-particle point of view, Phys. Rev. Lett, vol.6, 1961. ,
Quantum corrals, Physica D: Nonlinear Phenomena, vol.83, issue.1-3, pp.98-108, 1995. ,
DOI : 10.1016/0167-2789(94)00254-N
Structural and electronic properties of self-assembled nanostructures on silicon surfaces, 2008. ,
Scanning tunnelling spectroscopy of electron resonators, New Journal of Physics, vol.3, pp.1-22, 2001. ,
DOI : 10.1088/1367-2630/3/1/322
Etude des propriétéspropriétésélectroniques et structurales des films ultra minces d, Thèse de doctorat, 2003. ,
Alkali metal generation and gas evolution from alkali metal dispensers ,
Reconstruction of Molecular Orbital Densities from Photoemission Data, Science, vol.28, issue.5836, 2009. ,
DOI : 10.1126/science.1143239
The Structure of Molecular Orbitals Investigated by Angle-Resolved Photoemission, Series in Materials Science, 2013. ,
DOI : 10.1007/978-3-642-33848-9_1
Photoemission spectroscopy???Correspondence between quantum theory and experimental phenomenology, Physical Review B, vol.18, issue.12, p.4932, 1974. ,
DOI : 10.1016/0009-2614(73)87001-0
Intra- and Intermolecular Band Dispersion in an Organic Crystal, Science, vol.120, issue.22, pp.351-355, 2007. ,
DOI : 10.1063/1.1651065