Organolithium : reactivity for synthesis, Tetrahedron, vol.46, pp.87-89, 1990. ,
Aggregative Activation and Heterocyclic Chemistry III. Unusual regioselective lithiation of 2-alkoxy-pyridines, Tetrahedron Letters, vol.36, issue.27, pp.4791-4794, 1995. ,
DOI : 10.1016/00404-0399(50)0867C-
Aryl???Aryl Bond Formation by Transition-Metal-Catalyzed Direct Arylation, 3 Quelques revues traitant du sujet, pp.174-238, 2007. ,
DOI : 10.1021/cr0509760
Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by C??????H Bond Cleavage, Angewandte Chemie International Edition, vol.44, issue.52, pp.9792-9826, 2009. ,
DOI : 10.1007/b94643
Palladium(II)-Catalyzed C???H Activation/C???C Cross-Coupling Reactions: Versatility and Practicality, Angewandte Chemie International Edition, vol.45, issue.28, pp.5094-5115, 2009. ,
DOI : 10.1002/recl.19650841006
URL : http://europepmc.org/articles/pmc2722958?pdf=render
Recent advances in the synthesis of (hetero)aryl-substituted heteroarenes via transition metal-catalysed direct (hetero)arylation of heteroarene C???H bonds with aryl halides or pseudohalides, diaryliodonium salts, and potassium aryltrifluoroborates, Tetrahedron, vol.65, issue.50, pp.10269-10310, 2009. ,
DOI : 10.1016/j.tet.2009.10.015
Iron-Catalyzed Arylation of Heterocycles via Directed C???H Bond Activation, Organic Letters, vol.16, issue.3, pp.868-871, 2014. ,
DOI : 10.1021/ol403634b
] 2-pyran-l-ones from cuprous acetylides, Journal of Heterocyclic Chemistry, vol.527, issue.2, pp.227-230, 1968. ,
DOI : 10.1002/bscb.19620710913
Photoreactions of 1-(3-hydroxy-2-pyridyl)-2-(pentamethyldisilanyl)ethyne, aza analogue of 1-o-hydroxyphenyl-2-(pentamethyldisilanyl)ethyne, Journal of Photochemistry and Photobiology A: Chemistry, vol.157, issue.1, pp.15-22, 2003. ,
DOI : 10.1016/S1010-6030(03)00011-X
Solid-Phase Syntheses of Furopyridine and Furoquinoline Systems, Organic Letters, vol.6, issue.9, pp.1405-1408, 2004. ,
DOI : 10.1021/ol049762f
N-Induced Demethylation???Annulation of 3-Alkynyl-4-methoxy-2-pyridones and Structurally Related Compounds in the Synthesis of Furan-Fused Heterocycles, The Journal of Organic Chemistry, vol.73, issue.21, pp.8619-8622, 2008. ,
DOI : 10.1021/jo8014038
Furo[3,2-b]pyridine: a convenient unit for the synthesis of polyheterocycles, Tetrahedron, vol.64, issue.48, pp.10867-10873, 2008. ,
DOI : 10.1016/j.tet.2008.09.008
]pyridones by One-Pot Coupling of 3-Iodopyridones, Alkynes, and Organic Halides, Organic Letters, vol.5, issue.14, pp.2441-2444, 2003. ,
DOI : 10.1021/ol034644y
]furan Synthesis from 2-Chlorophenols. Bifunctional Ligand Strategy for Cross-Coupling of Chloroarenes, The Journal of Organic Chemistry, vol.75, issue.15, pp.5340-5342, 2010. ,
DOI : 10.1021/jo1007948
A convenient route to functionalized 3-amino-6-bromofuro[3,2-b]pyridine-2-carboxamides, Tetrahedron, vol.66, issue.25, pp.4490-4494, 2010. ,
DOI : 10.1016/j.tet.2010.04.071
25 Par exemple : a), Chem. Heterocycl. Compd, vol.40, pp.1442-1453, 2004. ,
]furans via CuI-Catalyzed Ring Closure, The Journal of Organic Chemistry, vol.70, issue.17, pp.6964-6967, 2005. ,
DOI : 10.1021/jo050788+
)-Nicotine, The Journal of Organic Chemistry, vol.75, issue.5, pp.1706-1716, 2010. ,
DOI : 10.1021/jo9026929
Annelation of perfluorinated heteroaromatic systems by 1,3-dicarbonyl derivatives, Tetrahedron, vol.66, issue.17, pp.3222-3227, 2010. ,
DOI : 10.1016/j.tet.2010.02.083
Synthesis of benzofurans via palladium-promoted cyclization of ortho-substituted aryl allyl ethers, Tetrahedron Letters, vol.29, issue.37, pp.4687-4690, 1988. ,
DOI : 10.1016/S0040-4039(00)80581-X
One-pot sequential and cascade formation of triazoles via palladium catalysed azide capture-1,3-dipolar cycloaddition, Tetrahedron, vol.57, issue.36, pp.7729-7735, 2001. ,
DOI : 10.1016/S0040-4020(01)00737-2
Novel heteroaromatic C???H insertion of alkylidenecarbenes. A new entry to furopyridine synthesis, Tetrahedron Letters, vol.39, issue.30, pp.5375-5376, 1998. ,
DOI : 10.1016/S0040-4039(98)01034-X
Tandem furo[3,4-b]pyridine formation???Diels???Alder reaction: an approach to the synthesis of nitrogen containing heterocyclic analogues of 1-arylnaphthalene lignans, Tetrahedron, vol.63, issue.48, pp.12015-12025, 2007. ,
DOI : 10.1016/j.tet.2007.09.007
Synthesis of Annulated Pyridines by Intramolecular Inverse-Electron-Demand Hetero-Diels-Alder Reaction under Superheated Continuous Flow Conditions, European Journal of Organic Chemistry, vol.13, issue.1, pp.47-52 ,
DOI : 10.1021/op800244m
! 39 Par exemple : a) Miyazaki, pp.1207-1209, 1982. ,
Der Chemica Sinica, J. ; Galleway, F. P, vol.4, pp.17-23, 2013. ,
! 43 Par exemple : a) Willemann, Chem. Pap. C. ; Grünert, R. ; Bednarski, P. J, vol.63, pp.586-591, 2009. ,
Name reactions A collection of detailed mechanisms and synthetic applications Fourth edition, Bull. Soc. Chim. Fr, vol.49, pp.1888-89, 2009. ,
Solvent-free microwave synthesis of 4-hydroxy-3-phenylquinolin-2(1H)-ones and variants using activated arylmalonates, Tetrahedron Letters, vol.47, issue.14, pp.2395-2398, 2006. ,
DOI : 10.1016/j.tetlet.2006.01.148
Reaction of heteroaromatic o-aminothioaldehydes with alkynes: a novel entry to b-fused pyridines, Tetrahedron Letters, vol.38, issue.12, pp.2171-2174, 1997. ,
DOI : 10.1016/S0040-4039(97)00274-8
! 50 Voznyi, I, Z, vol.31, issue.6, pp.7839-7843, 2005. ,
-Vinyl-??-Lactams, Organic Letters, vol.11, issue.6, pp.1281-1284, 2009. ,
DOI : 10.1021/ol900118d
Polycyclic N-heterocyclic compounds. Part 61: A novel Truce???Smiles type rearrangement reaction of 4-(2-cyanovinyloxy)butanenitriles to give cycloalkeno[1,2-d]furo[2,3-b]pyridines, Tetrahedron Letters, vol.51, issue.6, pp.903-906, 2010. ,
DOI : 10.1016/j.tetlet.2009.12.010
Multi-component anion relay cascade of 1-acetylcyclopropanecarboxamides, aldehydes and acrylonitrile: access to biscyanoethylated furo[3,2-c]pyridinones, Organic & Biomolecular Chemistry, vol.12, issue.23, pp.4571-4576, 2012. ,
DOI : 10.1002/chem.200600914
Lithiated heterocycles in modern synthesis dans Lithium compounds in organic synthesis ? From fundamentals to applications, 58 Clayden, J. Organolithiums : Selectivity for synthesis 2002, pp.423-462, 1939. ,
??ber das Verhalten der halogenierten Anisole gegen Phenyl-lithium (V. Mitteil. ??ber die Reaktionsweise des Phenyl-lithiums), Berichte der deutschen chemischen Gesellschaft (A and B Series), vol.36, issue.11, pp.1197-1218, 1940. ,
DOI : 10.1002/jlac.19073540203
Untersuchungen ??ber alkaliorganische Verbindungen, VII. Mitteil.: Alkalimetallalkyle und Pyridin (Vorl??ufige Mitteilung), Berichte der deutschen chemischen Gesellschaft (A and B Series), vol.40, issue.I, pp.1847-1851, 1930. ,
DOI : 10.1002/cber.19070400214
Enantioselective addition of organolithium reagents on isoquinoline, Tetrahedron: Asymmetry, vol.13, issue.19, pp.2117-2122, 2002. ,
DOI : 10.1016/S0957-4166(02)00531-1
68 Par exemple : a) Collum, Acc. Chem. Res, vol.40, issue.25, pp.569-574, 1975. ,
Organometallic ??-complexes XII. The metalation of benzene and ferrocene by n-butyllithium-N,N,N???,N???-tetramethylethylenediamine, Journal of Organometallic Chemistry, vol.10, issue.1, pp.127-136, 1967. ,
DOI : 10.1016/S0022-328X(00)81725-8
Enantioselective synthesis via sparteine-induced asymmetric deprotonation, Pure and Applied Chemistry, vol.102, issue.7, pp.1479-1486, 1994. ,
DOI : 10.1351/pac199466071479
Superbases for organic synthesis, Pure and Applied Chemistry, vol.94, issue.11, pp.1627-1634, 1988. ,
DOI : 10.1351/pac198860111627
77 a) Clayden, J. Organolithium : reactivity for synthesis, J. Organomet. Chem. Tetrahedron Tetrahedron Lett, vol.6, issue.36, pp.9-16, 1967. ,
BuLi/Lithium Aminoalkoxide Aggregation in Hexane and THF, The Journal of Organic Chemistry, vol.73, issue.23, pp.9393-9402, 2002. ,
DOI : 10.1021/jo8019434
New efficient access to thieno[3,2-b]pyridine derivatives via regioselective lithiation of 3-methylthiopyridine, Tetrahedron, vol.62, issue.25, pp.6036-6041, 2006. ,
DOI : 10.1016/j.tet.2006.04.008
Directed ortho metalation. Tertiary amide and O-carbamate directors in synthetic strategies for polysubstituted aromatics, Chemical Reviews, vol.90, issue.6, pp.879-933, 1990. ,
DOI : 10.1021/cr00104a001
URL : https://hal.archives-ouvertes.fr/hal-00443872
Stereo- and regiocontrol by complex induced proximity effects: reactions of organolithium compounds, Accounts of Chemical Research, vol.19, issue.11, pp.356-363, 1986. ,
DOI : 10.1021/ar00131a005
)-trione, a Key Intermediate for the Synthesis of Irinotecan and Other Camptothecin Analogs, The Journal of Organic Chemistry, vol.62, issue.19, pp.6588-6597, 1997. ,
DOI : 10.1021/jo970173f
Direct metalation of pyrimidine. Synthesis of some 4-substituted pyrimidines, The Journal of Organic Chemistry, vol.44, issue.13, pp.2081-2082, 1979. ,
DOI : 10.1021/jo01327a007
Kinetic Resolution of Secondary Alcohols. Enantioselective Acylation Mediated by a Chiral (Dimethylamino)pyridine Derivative, Journal of the American Chemical Society, vol.118, issue.7, pp.1809-1810, 1996. ,
DOI : 10.1021/ja953631f
Organolithiums : selectivity for synthesis, pp.2892-2897, 1995. ,
??ber die Austauschbarkeit von aromatisch gebundenem Wasserstoff gegen Lithium mittels Phenyl-lithiums, Berichte der deutschen chemischen Gesellschaft (A and B Series), vol.48, issue.9, pp.1903-1912, 1938. ,
DOI : 10.1002/cber.187801101273
Metalation as a Side Reaction in the Preparation of Organolithium Compounds, Journal of the American Chemical Society, vol.61, issue.1, pp.106-109, 1939. ,
DOI : 10.1021/ja01870a036
! 96 a) Zefirov, Chem. Soc. N. S. ; Makhanolov, D. I. Chem. Rev, vol.82, pp.1603-1610, 1956. ,
Tetrabromothiophene from 2-Bromothiophene by means of Sodium Acetylide in Liquid Ammonia, Nature, vol.18, issue.4281, pp.875-876, 1951. ,
DOI : 10.1002/cber.18850180199
Nouvelles r??actions d'halogenopyridines avec le n-butyllithium. proposition d'un m??canisme par m??tallation et migration du brome, Tetrahedron, vol.35, issue.13, pp.1625-1631, 1979. ,
DOI : 10.1016/0040-4020(79)80026-5
Metalation of diazines X, Tetrahedron, vol.50, issue.34, pp.10299-10308, 1994. ,
DOI : 10.1016/S0040-4020(01)81762-2
A HIGH-YIELD SYNTHESIS OF 3-PENTADECYLPYRIDINE, Organic Preparations and Procedures International, vol.73, issue.6, pp.677-678, 1994. ,
DOI : 10.1021/ic50198a023
Complex-Induced Proximity Effect in the Regioselective Lithiation of Pyridine Derivatives, European Journal of Organic Chemistry, vol.658, issue.9, pp.1746-1752 ,
DOI : 10.1016/S0022-328X(02)01627-3
First Regioselective Ortho-Lithiation Induced by a 2-Chloropyridyl Group Complexation, The Journal of Organic Chemistry, vol.68, issue.12, pp.4918-4922, 2003. ,
DOI : 10.1021/jo026788g
Synthèse et fonctionnalisation des furo, Thèse de doctorat de l'Université Henri Poincaré, 2010. ,
A new method for benzylic deprotonative lithiation: synthesis of 1- and 1,3-disubstituted (aza)phthalans, Tetrahedron Letters, vol.43, issue.22, pp.4045-4048, 2002. ,
DOI : 10.1016/S0040-4039(02)00685-8
Lithiation of 2-Heterosubstituted Pyridines with BuLi???LiDMAE:?? Evidence for Regiospecificity at C-6, The Journal of Organic Chemistry, vol.67, issue.1, pp.234-237, 2002. ,
DOI : 10.1021/jo015855o
]pyridine, The Journal of Organic Chemistry, vol.75, issue.7, pp.2227-2235, 2010. ,
DOI : 10.1021/jo902666w
]pyridines, The Journal of Organic Chemistry, vol.78, issue.11, pp.5618-5626, 2004. ,
DOI : 10.1021/jo400748n
URL : https://hal.archives-ouvertes.fr/hal-01493935
in Handbook of organopalladium chemistry for organic synthesis, 2002. ,
USA. c) Ackermann, L. in Modern arylation methods, KGaA, Weinheim. d) Stille, J. K. Pure Appl. Chem, vol.57, pp.1771-1780, 1985. ,
Palladium-Catalyzed Coupling Reactions of Aryl Chlorides, Angewandte Chemie International Edition, vol.41, issue.22, pp.4176-4211, 2002. ,
DOI : 10.1002/1521-3773(20021115)41:22<4176::AID-ANIE4176>3.0.CO;2-U
Click Chemistry: Diverse Chemical Function from a Few Good Reactions, Angewandte Chemie International Edition, vol.36, issue.6, pp.2004-2021, 2001. ,
DOI : 10.1016/B978-008096518-5.00095-2
How I came across the silicon-based cross-coupling reaction, Journal of Organometallic Chemistry, vol.653, issue.1-2, pp.58-61, 2002. ,
DOI : 10.1016/S0022-328X(02)01157-9
Palladium-Catalyzed Cross-Coupling Reactions of DiazineN-Oxides with Aryl Chlorides, Bromides, and Iodides, Angewandte Chemie International Edition, vol.28, issue.46, pp.7781-7786, 1980. ,
DOI : 10.1002/anie.200602773
étude de la métallation régiosélective d'un bicycle fusionné: la furo[3,2-b]pyridine. L'influence de la nature du système basique sur le cours de la réaction et sur la régiosélectivité de la lithiation a été étudiée avec différentes bases ,
cette étude nous a permis d'établir quelques règles pour la fonctionnalisation des furopyidines, ce qui nous a conduit à l'obtention efficace et rapide d'une vaste chimiothèque de furo ,