:. Favennec, Géopolitique de l'énergie-Besoins, ressources, échanges mondiaux, 2007.

:. F. Mermoud, Gazéification de charbon de bois à la vapeur d'eau : de la particule isolée au lit fixe continu, Thèse de doctorat à l'Institut National Polytechnique de Toulouse, 2006.

. Athanassiou, Investigating the potential for energy, fuel, materials and chemicals production from corn residues (cobs and stalks) by non-catalytic and catalytic pyrolysis in two reactor configuration, press [11]: S. Yaman, Pyrolysis of biomass to produce fuels and chemical feedstocks, Energy Conversion and Management, pp.651-671, 2004.

:. R. Radmanesh, Y. Courbariaux, J. Chaouki, and C. Guy, A unified lumped approach in kinetic modeling of biomass pyrolysis, Fuel, vol.85, issue.9, pp.1211-1220, 2006.
DOI : 10.1016/j.fuel.2005.11.021

A. Subramanian and . Review, Influence of mineral matter on biomass pyrolysis characteristics, Renewable and Sustainable Energy Reviews Fuel, vol.14, issue.74, pp.1812-1822, 1995.

A. Rapport, Pyrolyse et Gazéification de la biomasse pour la production d'électricité-Procédés et acteurs, 2001.

:. F. Agblevor, S. Besler, and A. E. , Fast Pyrolysis of Stored Biomass Feedstocks, Energy & Fuels, vol.9, issue.4, pp.635-640, 1995.
DOI : 10.1021/ef00052a010

:. C. Di-blasi, G. Signorelli, C. Di-russo, and G. Rea, Product Distribution from Pyrolysis of Wood and Agricultural Residues, Industrial & Engineering Chemistry Research, vol.38, issue.6, pp.2216-2224, 1999.
DOI : 10.1021/ie980711u

:. B. Jenkins, R. R. Bakker, and J. B. Wei, On the properties of washed straw, Biomass and Bioenergy, vol.10, issue.4, pp.177-200, 1996.
DOI : 10.1016/0961-9534(95)00058-5

:. B. Jenkins, L. L. Baxter, T. R. Miles-jr, and T. R. Miles, Combustion properties of biomass, Fuel Processing Technology, vol.54, issue.1-3, pp.17-46, 1998.
DOI : 10.1016/S0378-3820(97)00059-3

:. P. Mckendry, Energy production from biomass (part 1): overview of biomass, Bioresource Technology, vol.83, issue.1, pp.37-46, 2002.
DOI : 10.1016/S0960-8524(01)00118-3

:. W. Hillis, Wood and biomass ultrastructure, Fundamentals of biomass thermochemical conversion, pp.1-33, 1985.

:. W. Glasser, Lignin, Fundamentals of biomass thermochemical conversion, pp.61-76, 1985.

:. G. Barton, Definition of biomass samples involving wood, bark and foliages, Fundamentals of biomass thermochemical conversion, pp.1137-1344, 1985.

:. H. Goyal, D. Seal, and R. C. Saxena, Bio-fuels from thermochemical conversion of renewable resources: A review, Renewable and Sustainable Energy Reviews, vol.12, issue.2, pp.504-517, 2008.
DOI : 10.1016/j.rser.2006.07.014

:. A. Bridgewater, Principles and practice of biomass fast pyrolysis processes for liquids, Journal of Analytical and Applied Pyrolysis, vol.51, issue.1-2, pp.3-22, 1999.
DOI : 10.1016/S0165-2370(99)00005-4

:. F. Ana-rita and W. D. Ian, Pyrolysis of sugarcane bagasse in a wire mesh reactor, Industrial and Engineering Chemical Research, vol.35, pp.1263-1268, 1996.

:. Chang, Harnessing energy from plant biomass, Current Opinion in Chemical Biology, vol.11, issue.6, pp.677-684, 2007.
DOI : 10.1016/j.cbpa.2007.08.039

:. J. Wooten, J. I. Seeman, and M. R. Hajaligol, C CPMAS NMR. A New Mechanistic Model, Energy & Fuels, vol.18, issue.1, pp.1-15, 2004.
DOI : 10.1021/ef0300601

:. E. Sjostrom, Wood Chemistry : Fundamentals and Applications, 1993.

:. E. Antonakou, A. Lappas, M. Nilsen, A. Bouzga, and M. Stöcker, Evaluation of various types of Al-MCM-41 materials as catalysts in biomass pyrolysis for the production of biofuels and chemicals, Fuel, vol.85, pp.2206-2212, 2006.

:. I. Boukis, P. Grammelis, S. Bezergianni, and A. V. Bridgwater, CFB air-blown flash pyrolysis. Part I: Engineering design and cold model performance, Fuel, vol.86, issue.10-11, pp.1372-1386, 2007.
DOI : 10.1016/j.fuel.2006.11.002

:. E. Apaydin-varol, E. Pütün, and A. E. Pütün, Slow pyrolysis of pistachio shell, Fuel, vol.86, issue.12-13, pp.1892-1899, 2007.
DOI : 10.1016/j.fuel.2006.11.041

:. A. Pütün, A. Ozcan, H. F. Gercel, and E. Pütün, Production of biocrudes from biomass in a fixed-bed tubular reactor: product yields and compositions, Fuel, vol.80, issue.10, pp.1371-1378, 2001.
DOI : 10.1016/S0016-2361(01)00021-7

:. N. Özbay, A. E. Pütün, B. V. Uzun, and E. Pütün, Biocrude from biomass: pyrolysis of cotton seed cake, Renewable Energy, pp.24-615, 2001.

:. O. Onay and O. M. Koçkar, Fixed-bed pyrolysis of rapeseed (Brassica napus L.), Biomass and Bioenergy, vol.26, issue.3, pp.289-299, 2004.
DOI : 10.1016/S0961-9534(03)00123-5

:. N. Özbay, B. B. Uzun, E. Apayd?n-varol, and A. E. Pütün, Comparative analysis of pyrolysis oils and its subfractions under different atmospheric conditions, Fuel Processing Technology, vol.87, issue.11, pp.1013-1019, 2006.
DOI : 10.1016/j.fuproc.2006.07.009

:. S. Beis, O. Onay, and O. M. Koçkar, Fixed-bed pyrolysis of sufflower seed: influence of pyrolysis parameters on product yields and compositions, Renweable Energy, pp.26-47, 2002.

:. Z. Luo, S. Wang, Y. Liao, J. Zhou, Y. Gu et al., Research on biomass fast pyrolysis for liquid fuel, Biomass and Bioenergy, vol.26, issue.5, pp.26-455, 2004.
DOI : 10.1016/j.biombioe.2003.04.001

:. O. Onay, S. H. Beis, and O. M. Koçkar, Fast pyrolysis of rape seed in a well-swept fixed-bed reactor, Journal of Analytical and Applied Pyrolysis, vol.58, issue.59, pp.58-59, 2001.
DOI : 10.1016/S0165-2370(00)00133-9

:. O. Onay and O. M. Koçkar, Slow, fast and flash pyrolysis of rapeseed, Renewable Energy, vol.28, issue.15, pp.2417-2433, 2003.
DOI : 10.1016/S0960-1481(03)00137-X

:. W. Tsai, M. K. Lee, and Y. M. Chang, Fast pyrolysis of rice straw, sugarcane bagasse and coconut shell in an induction-heating reactor, Journal of Analytical and Applied Pyrolysis, vol.76, issue.1-2, pp.76-230, 2006.
DOI : 10.1016/j.jaap.2005.11.007

:. T. Cornelissen, M. Jans, J. Yperman, G. Reggers, S. Schreurs et al., Flash co-pyrolysis of biomass with polyhydroxybutyrate: Part 1. Influence on bio-oil yield, water content, heating value and the production of chemicals, Fuel, vol.87, issue.12, pp.2523-2532, 2008.
DOI : 10.1016/j.fuel.2008.02.024

:. A. Demirbas and G. , An Overview of Biomass Pyrolysis, Energy Sources, vol.1, issue.5, pp.471-482, 2002.
DOI : 10.1016/0960-8524(93)90071-I

:. F. Beall and H. W. Eickner, Thermal degradation of wood components: a review of the literature, FPL Research Paper N°, vol.130, 1970.

:. A. Roberts, A review of kinetics data for the pyrolysis of wood and related substances, Combustion and Flame, vol.14, issue.2, pp.261-272, 1970.
DOI : 10.1016/S0010-2180(70)80037-2

:. M. Gronli and M. J. , A Round-Robin Study of Cellulose Pyrolysis Kinetics by Thermogravimetry, Industrial & Engineering Chemistry Research, vol.38, issue.6, pp.2238-2244, 1999.
DOI : 10.1021/ie980601n

:. A. Lappas, M. C. Samolada, D. K. Iatridis, S. S. Voutetakis, and I. A. Vasalos, Biomass pyrolysis in a circulating fluid bed reactor for the production of fuels and chemicals, Fuel, vol.81, issue.16, pp.2087-2095, 2002.
DOI : 10.1016/S0016-2361(02)00195-3

:. M. Müller-hagedorn, H. Bockhorn, L. Krebs, and U. Müller, A comparative kinetic study on the pyrolysis of three different wood species, Journal of Analytical and Applied Pyrolysis, vol.68, issue.69, pp.69-231, 2003.
DOI : 10.1016/S0165-2370(03)00065-2

:. B. Babu and A. S. Chaurasia, Pyrolysis of biomass: improved models for simultaneous kinetics and transport of heat, mass and momentum, Energy Conversion and Management, pp.45-1297, 2004.

:. E. Cetin, B. Moghtaderi, R. Gupta, and T. F. Wall, Influence of pyrolysis conditions on the structure and gasification reactivity of biomass chars, Fuel, vol.83, issue.16, pp.2139-2150, 2004.
DOI : 10.1016/j.fuel.2004.05.008

:. S. Seidelt, M. Müller-hagedorn, and H. Bockhorn, Description of tire pyrolysis by thermal degradation behaviour of main components, Journal of Analytical and Applied Pyrolysis, vol.75, issue.1, pp.11-18, 2006.
DOI : 10.1016/j.jaap.2005.03.002

:. A. Sadhukhan, P. Gupta, T. Goyal, and R. K. Saha, Modelling of pyrolysis of coal???biomass blends using thermogravimetric analysis, Bioresource Technology, vol.99, issue.17, pp.99-8022, 2008.
DOI : 10.1016/j.biortech.2008.03.047

:. Blasi, Modeling and simulation of combustion processes of charring and non-charring solid fuels, Progress in Energy and Combustion Science, vol.19, issue.1, pp.71-104, 1993.
DOI : 10.1016/0360-1285(93)90022-7

:. A. Bridgwater, Principles and practice of biomass fast pyrolysis processes for liquids, Journal of Analytical and Applied Pyrolysis, vol.51, issue.1-2, pp.3-22, 1999.
DOI : 10.1016/S0165-2370(99)00005-4

:. D. Scott, P. Majerski, J. Piskorz, and D. Radlein, A second look at fast pyrolysis of biomass???the RTI process, Journal of Analytical and Applied Pyrolysis, vol.51, issue.1-2, pp.23-37, 1999.
DOI : 10.1016/S0165-2370(99)00006-6

:. A. Bridgwater, D. Meier, and D. Radlein, An overview of fast pyrolysis of biomass, Organic Geochemistry, vol.30, issue.12, pp.1479-1493, 1999.
DOI : 10.1016/S0146-6380(99)00120-5

:. A. Bridgwater and G. V. Peacocke, Fast pyrolysis processes for biomass, Renewable and Sustainable Energy Reviews, vol.4, issue.1, pp.1-73, 2000.
DOI : 10.1016/S1364-0321(99)00007-6

:. A. Bridgwater, Renewable fuels and chemicals by thermal processing of biomass, Chemical Engineering Journal, vol.91, issue.2-3, pp.91-87, 2003.
DOI : 10.1016/S1385-8947(02)00142-0

:. M. Antal, W. S. Mok, T. Varhegyi, and . Szekely, Review of methods for improving the yield of charcoal from biomass, Energy & Fuels, vol.4, issue.3, pp.4-221, 1990.
DOI : 10.1021/ef00021a001

:. S. Czernik and A. V. Bridgwater, Overview of Applications of Biomass Fast Pyrolysis Oil, Energy & Fuels, vol.18, issue.2, pp.590-598, 2004.
DOI : 10.1021/ef034067u

:. M. Ramiah, Thermogravimetric and differential thermal analysis of cellulose, hemicellulose, and lignin, Journal of Applied Polymer Science, vol.14, issue.5, pp.1323-1337, 1970.
DOI : 10.1002/app.1970.070140518

:. Blasi, Modeling chemical and physical processes of wood and biomass pyrolysis, Progress in Energy and Combustion Science, vol.34, pp.47-90, 2008.

:. S. Ward and J. Braslaw, Experimental weight loss kinetics of wood pyrolysis under vacuum, Combustion and Flame, vol.61, issue.3, pp.61-261, 1985.
DOI : 10.1016/0010-2180(85)90107-5

:. C. Koufopanos, G. Maschio, and A. Lucchesi, Kinetic modelling of the pyrolysis of biomass and biomass components, The Canadian Journal of Chemical Engineering, vol.61, issue.1, pp.75-84, 1989.
DOI : 10.1002/polc.5070060109

:. P. Williams and S. Besler, The pyrolysis of rice husks in a thermogravimetric analyser and static batch reactor, Fuel, vol.72, issue.2, pp.151-159, 1993.
DOI : 10.1016/0016-2361(93)90391-E

:. J. Caballero, R. Font, and A. Marcilla, Comparative study of the pyrolysis of almond shells and their fractions, holocellulose and lignin. Product yields and kinetics, Thermochimica Acta, vol.276, pp.276-57, 1996.
DOI : 10.1016/0040-6031(95)02794-7

:. A. Shebani, A. J. Van-reenen, and M. Meincken, The effect of wood extractives on the thermal stability of different wood species, Thermochimica Acta, vol.471, issue.1-2, pp.471-514, 2008.
DOI : 10.1016/j.tca.2008.02.020

:. M. Antal and G. Varhegyi, Cellulose Pyrolysis Kinetics:?? Revisited, Industrial & Engineering Chemistry Research, vol.37, issue.4, pp.1267-1275, 1998.
DOI : 10.1021/ie970144v

URL : http://real.mtak.hu/21646/1/CELLULOSE_REVISITED_1997-10-07.PDF

:. V. Mamleev, S. Bourbigot, and J. Yvon, Kinetic analysis of the thermal decomposition of cellulose: The main step of mass loss, Journal of Analytical and Applied Pyrolysis, vol.80, issue.1, pp.151-165, 2007.
DOI : 10.1016/j.jaap.2007.01.013

V. Mamleev, S. Bourbigot, and J. Yvon, Kinetic analysis of the thermal decomposition of cellulose: The change of the rate limitation, Journal of Analytical and Applied Pyrolysis, vol.80, issue.1, pp.141-150, 2007.
DOI : 10.1016/j.jaap.2007.01.012

:. F. Shafizadeh and A. G. Bradbury, Thermal degradation of cellulose in air and nitrogen at low temperatures, Journal of Applied Polymer Science, vol.23, issue.5, pp.1431-1441, 1979.
DOI : 10.1002/app.1979.070230513

:. J. Banyasz, S. Li, J. L. Lyons-hart, and K. H. Shafer, Gas evolution and the mechanism of cellulose pyrolysis, Fuel, vol.80, issue.12, pp.1757-1763, 2001.
DOI : 10.1016/S0016-2361(01)00060-6

:. T. Mcgrath, W. G. Chan, and M. R. Hajaligol, Low temperature mechanism for the formation of polycyclic aromatic hydrocarbons from the pyrolysis of cellulose, Journal of Analytical and Applied Pyrolysis, vol.66, issue.1-2, pp.51-70, 2003.
DOI : 10.1016/S0165-2370(02)00105-5

:. I. Milosavljevic and E. Suuberg, Cellulose Thermal Decomposition Kinetics: Global Mass Loss Kinetics, Industrial & Engineering Chemistry Research, vol.34, issue.4, pp.1081-1091, 1995.
DOI : 10.1021/ie00043a009

:. M. Antal and G. Varhegyi, Cellulose Pyrolysis Kinetics: The Current State of Knowledge, Industrial & Engineering Chemistry Research, vol.34, issue.3, pp.703-717, 1995.
DOI : 10.1021/ie00042a001

:. A. Bradbury, Y. Sakai, and F. Shafizadeh, A kinetic model for pyrolysis of cellulose, Journal of Applied Polymer Science, vol.23, issue.11, pp.3271-3280, 1979.
DOI : 10.1002/app.1979.070231112

:. G. Jakab and M. J. , Is the Broido-Shafizadeh model for cellulose pyrolysis true?, Energy & Fuels, vol.8, pp.1345-1352, 1994.

:. C. Branca, A. Albano, and C. D. Blasi, Critical evaluation of global mechanisms of wood devolatilization, Thermochimica Acta, vol.429, issue.2, pp.429-133, 2005.
DOI : 10.1016/j.tca.2005.02.030

:. O. Boutin, M. Ferrer, and J. Lédé, Radiant flash pyrolysis of cellulose???Evidence for the formation of short life time intermediate liquid species, Journal of Analytical and Applied Pyrolysis, vol.47, issue.1, pp.13-31, 1998.
DOI : 10.1016/S0165-2370(98)00088-6

:. J. Scheirs, G. Camino, and W. Tumiatti, Overview of water evolution during the thermal degradation of cellulose, European Polymer Journal, vol.37, issue.5, pp.933-942, 2001.
DOI : 10.1016/S0014-3057(00)00211-1

:. F. Shafizadeh, Introduction to pyrolysis of biomass, Journal of Analytical and Applied Pyrolysis, vol.3, issue.4, pp.283-305, 1982.
DOI : 10.1016/0165-2370(82)80017-X

:. F. Shafizadeh, R. H. Furneaux, T. G. Cochran, J. P. Scholl, and Y. Sakai, Production of levoglucosan and glucose from pyrolysis of cellulosic materials, Journal of Applied Polymer Science, vol.23, issue.12, pp.3525-3539, 1979.
DOI : 10.1002/app.1979.070231209

:. D. Radlein, A. Grinshpun, J. Piskorz, and D. S. Scott, On the presence of anhydro-oligosaccharides in the sirups from the fast pyrolysis of cellulose, Journal of Analytical and Applied Pyrolysis, vol.12, issue.1, pp.39-49, 1987.
DOI : 10.1016/0165-2370(87)80013-X

:. P. Arisz, J. A. Lomax, and J. J. Boon, High-performance liquid chromatography/chemical ionization mass spectrometric analysis of pyrolysates of amylase and cellulose, Analytical Chemistry, pp.62-1519, 1990.

:. F. Kilzer and A. Broido, The nature of cellulose pyrolysis, Pyrodynamics, vol.2, pp.151-163, 1965.

:. D. Nowakowski and J. M. Jones, Uncatalysed and potassium-catalysed pyrolysis of the cell-wall constituents of biomass and their model compounds, Journal of Analytical and Applied Pyrolysis, vol.83, issue.1, 2008.
DOI : 10.1016/j.jaap.2008.05.007

:. J. Banyasz, S. Li, J. L. Lyons-hart, and K. H. Shafer, Cellulose pyrolysis: the kinetics of hydroxyacetaldehyde evolution, Journal of Analytical and Applied Pyrolysis, vol.57, issue.2, pp.223-248, 2001.
DOI : 10.1016/S0165-2370(00)00135-2

:. J. Piskorz, D. Radlein, D. S. Scott, and S. Czernik, Liquid Products from the Fast Pyrolysis of Wood and Cellulose, Research in thermochemical biomass conversion, pp.557-571, 1988.
DOI : 10.1007/978-94-009-2737-7_43

:. M. Jr, G. Várhegyi, and E. Jakab, Cellulose pyrolysis kinetics: Revisited, Industrial and Engineering Chemistry Research, vol.37, pp.1267-1275, 1998.

:. A. Broido and M. A. Nelson, Char yield on pyrolysis of cellulose, Combustion and Flame, vol.24, pp.263-268, 1975.
DOI : 10.1016/0010-2180(75)90156-X

:. R. Kotilanen, Chemical changes in wood during heating at 150-260°C, p.51, 2000.

:. A. Pavlath and K. S. Gregorski, Thermoanalytical studies of carbohydrate pyrolysis- Fundementals of thermochemical Biomass Conversion

:. P. Williams and S. Besler, Thermogravimetric analysis of the component of Biomass- Advances in thermochimical biomass conversion, A.V. Bridgewater. London, Blackie Academic & Professional, 1994.

:. J. Bourgois and R. Guyonnet, Characterization and analysis of torrefied wood, Wood Science and Technology, vol.29, issue.291, pp.143-155, 1988.
DOI : 10.1007/BF00355850

URL : https://hal.archives-ouvertes.fr/emse-00447463

:. J. Bourgois and M. C. Bartholin, Thermal treatment of wood: analysis of the obtained product, Wood Science and Technology, vol.155, issue.291, pp.303-310, 1989.
DOI : 10.1007/978-94-011-6017-9

URL : https://hal.archives-ouvertes.fr/emse-00447276

:. B. Tjeerdsma and M. Boonstra, Charakterisieren von thermisch behandeltem Holz: Molekulare Ursachen f??r die Verbesserung der Holzstabilit??t, Holz als Roh- und Werkstoff, vol.48, issue.5, pp.149-153, 1998.
DOI : 10.1021/ie51398a022

:. F. Avat, Contribution à l'étude des traitements thermiques du bois (20-300°C): transformations chimiques et caractérisations physico-chimiques, Saint-Etienne, p.237, 1993.

:. D. Gardner and T. P. Schulz, The Pyrolytic Behavior of Selected Lignin Preparations, Journal of Wood Chemistry and Technology, vol.62, issue.2, pp.85-110, 1985.
DOI : 10.1021/j150562a003

:. E. Jakab and O. Faix, Thermogravimetry/mass spectrometry study of six lignins within the scope of an international round robin test, Journal of Analytical and Applied Pyrolysis, vol.35, issue.2, pp.167-179, 1995.
DOI : 10.1016/0165-2370(95)00907-7

:. F. Kacik and D. Kacikova, Changes of maple wood lignin (Acer pseudoplatanus L.) due to hydrothermal treatment, Drevarsky Vyskum/Wood Research, vol.44, issue.1, pp.31-40, 1999.

:. B. Pollet and I. Mila, Pine wood retification: Relationships between lignin structural alterations and wood performances, Sixth European workshop on lignocellulosics and pulp: advances in lignocellulosics chemistry towards high quality processes and products, 2000.

:. J. Blazek and P. Buryan, Study of the thermal degradation of lignin in the inert atmosphere, Entropie, vol.235236, pp.6-11, 2001.

:. S. Baumberger and P. Dole, Using Transgenic Poplars to Elucidate the Relationship between the Structure and the Thermal Properties of Lignins, Journal of Agricultural and Food Chemistry, vol.50, issue.8, pp.2450-2453, 2002.
DOI : 10.1021/jf0113530

:. E. Jakab and O. Faix, Thermal decomposition of milled wood lignins studied by thermogravimetry/mass spectrometry, Journal of Analytical and Applied Pyrolysis, vol.40, issue.41, pp.40-41, 1997.
DOI : 10.1016/S0165-2370(97)00046-6

:. S. Baumberger and I. Mila, Lignines et environnement : de la préservation du bois à l'élaboration des plastiques biodégradables, Grignon, Les rencontres de l, pp.9-10, 2002.

:. E. Van-der-hage and M. M. Mulder, Structural characterization of lignin polymers by temperature-resolved in-source pyrolysis???mass spectrometry and Curie-point pyrolysis???gas chromatography/mass spectrometry, Journal of Analytical and Applied Pyrolysis, vol.25, pp.149-183, 1993.
DOI : 10.1016/0165-2370(93)80038-2

:. F. Shafizadeh-overend, R. Milne, T. Mudge, and L. , Pyrolytic Reactions and Products of Biomass, Fundamentals of biomass thermochemical conversion, pp.183-217, 1985.
DOI : 10.1007/978-94-009-4932-4_11

:. A. Jensen, K. Dam-johansen, M. A. Wojtowicz, and M. A. Serio, TG-FTIR Study of the Influence of Potassium Chloride on Wheat Straw Pyrolysis, Energy & Fuels, vol.12, issue.5, pp.929-938, 1998.
DOI : 10.1021/ef980008i

:. P. Williams and P. A. Horne, The role of metal salts in the pyrolysis of biomass, Renewable Energy, vol.4, issue.1, pp.1-13, 1994.
DOI : 10.1016/0960-1481(94)90058-2

:. G. Dobele, G. Rossinskaja, T. Dizhbite, G. Telysheva, D. Meier et al., Application of catalysts for obtaining 1,6-anhydrosaccharides from cellulose and wood by fast pyrolysis, Journal of Analytical and Applied Pyrolysis, vol.74, issue.1-2, pp.74-401, 2005.
DOI : 10.1016/j.jaap.2004.11.031

:. K. Raveendran, A. K. Ganesh, and C. Khilar, Influence of mineral matter on biomass pyrolysis characteristics, Fuel, vol.74, issue.12, pp.1812-1822, 1995.
DOI : 10.1016/0016-2361(95)80013-8

:. P. Szabo, G. Varhegyi, F. Till, and O. Faix, Thermogravimetric/mass spectrometric characterization of two energy crops, Arundo donax and Miscanthus sinensis, Journal of Analytical and Applied Pyrolysis, vol.36, issue.2, pp.179-190, 1996.
DOI : 10.1016/0165-2370(96)00931-X

:. D. Nowakowski, J. M. Jones, R. M. Brydson, and A. B. Ross, Potassium catalysis in the pyrolysis behaviour of short rotation willow coppice, Fuel, vol.86, issue.15, pp.2389-2402, 2007.
DOI : 10.1016/j.fuel.2007.01.026

:. Y. Tsuchiya and K. Sumi, Thermal decomposition products of cellulose, Journal of Applied Polymer Science, vol.14, issue.8, pp.2003-2013, 1970.
DOI : 10.1002/app.1970.070140808

:. F. Shafizadeh and Y. Sekiguchi, Development of aromaticity in cellulosic chars, Carbon, vol.21, issue.5, pp.511-516, 1983.
DOI : 10.1016/0008-6223(83)90144-6

:. Y. Halpern and S. Patai, , in the Presence of Additives, Israel Journal of Chemistry, vol.13, issue.5, p.685, 1969.
DOI : 10.1016/S0008-6215(00)81239-2

:. S. Madorsky, V. E. Hart, and S. Straus, Pyrolysis of cellulose in a vacuum, Journal of Research of the National Bureau of Standards, vol.56, issue.6, p.343, 1956.
DOI : 10.6028/jres.056.045

:. H. Wu, D. M. Quyn, and C. Z. Li, Volatilisation and catalytic effects of alkali and alkaline earth metallic species during the pyrolysis and gasification of Victorian brown coal. Part III. The importance of the interactions between volatiles and char at high temperature, Fuel, vol.81, issue.8, pp.1033-1039, 2001.
DOI : 10.1016/S0016-2361(02)00011-X

:. W. Pan and G. N. Richards, Influence of metal ions on volatile products of pyrolysis of wood, Journal of Analytical and Applied Pyrolysis, vol.16, issue.2, pp.117-126, 1989.
DOI : 10.1016/0165-2370(89)85011-9

:. H. Kawamoto, D. Yamamoto, and S. Saka, Influence of neutral inorganic chlorides on primary and secondary char formation from cellulose, Journal of Wood Science, vol.342, issue.3, pp.242-246, 2008.
DOI : 10.1016/j.carres.2007.04.009

:. N. Shimada, H. Kawamoto, and S. Saka, Different action of alkali/alkaline earth metal chlorides on cellulose pyrolysis, Journal of Analytical and Applied Pyrolysis, vol.81, issue.1, pp.80-87, 2008.
DOI : 10.1016/j.jaap.2007.09.005

:. C. Sathe, Y. Pang, and C. Z. Li, Effects of Heating Rate and Ion-Exchangeable Cations on the Pyrolysis Yields from a Victorian Brown Coal, Energy & Fuels, vol.13, issue.3, p.748, 1999.
DOI : 10.1021/ef980240o

:. W. Tang and W. K. Neill, Effect of flame retardants on pyrolysis and combustion of alpha cellulose, Journal of Polymer Science, vol.6, pp.65-81, 1964.

:. A. Broido and M. Weinstein, Thermogravimetric Analysis of Ammonia-Swelled Cellulose, Combustion Science and Technology, vol.1, issue.4, pp.243-251, 1970.
DOI : 10.1177/004051755902901003

F. Shafizadeh, Chemical composition and thermal analysis of cottonwood, Carbohydrate Research, vol.16, issue.2, pp.273-277, 1971.
DOI : 10.1016/S0008-6215(00)81161-1

:. G. Varhegyi and M. J. Antal, Kinetics of the thermal decomposition of cellulose, hemicellulose, and sugarcane bagasse, Energy & Fuels, vol.3, issue.3, pp.329-335, 1989.
DOI : 10.1021/ef00015a012

:. M. Gronli and G. Varhegyi, Thermogravimetric Analysis and Devolatilization Kinetics of Wood, Industrial & Engineering Chemistry Research, vol.41, issue.17, pp.4201-4208, 2002.
DOI : 10.1021/ie0201157

:. J. Reina and E. Velo, Thermogravimetric study of the pyrolysis of waste wood, Thermochimica Acta, vol.320, issue.1-2, pp.161-167, 1998.
DOI : 10.1016/S0040-6031(98)00427-4

:. L. Helsen, E. Van-den-bulck, S. Mullens, and J. , Low-temperature pyrolysis of CCA-treated wood: thermogravimetric analysis, Journal of Analytical and Applied Pyrolysis, vol.52, issue.1, pp.65-86, 1999.
DOI : 10.1016/S0165-2370(99)00034-0

:. L. Helsen, E. Van-den, and . Bulck, Kinetics of the low-temperature pyrolysis of chromated copper arsenate-treated wood, Journal of Analytical and Applied Pyrolysis, vol.53, issue.1, pp.51-79, 2000.
DOI : 10.1016/S0165-2370(99)00050-9

:. C. Hindsgaul, J. Schramm, L. Gratz, U. Henriksen, and J. D. Bentzen, Physical and chemical characterization of particles in producer gas from wood chips, Bioresource Technology, vol.73, issue.2, pp.73-147, 2000.
DOI : 10.1016/S0960-8524(99)00153-4

:. A. Zabaniotou, O. Ioannidou, E. Antonakou, and A. Lappas, Experimental study of pyrolysis for potential energy, hydrogen and carbon material production from lignocellulosic biomass, International Journal of Hydrogen Energy, vol.33, issue.10, pp.2433-2444, 2008.
DOI : 10.1016/j.ijhydene.2008.02.080

:. P. Luangkiattikhun, C. Tangsathitkulchai, and M. Tangsathitkulchai, Non-isothermal thermogravimetric analysis of oil-palm solid wastes, Bioresource Technology, vol.99, issue.5, pp.986-997, 2008.
DOI : 10.1016/j.biortech.2007.03.001

. Athanassiou, Investigating the potential for energy, fuel, materials and chemicals production from corn residues (cobs and stalks) by non-catalytic and catalytic pyrolysis in two reactor configurations The differentiel thermal analysis of wood, Renewable and Sustainable Energy Reviews The Canadian Journal of Chemical Engineering, vol.13, issue.39, pp.1915-1919, 1961.

:. M. Sefain and S. F. El-kalyoubi, Thermal behavior of holo- and hemicellulose obtained from rice straw and bagasse, Journal of Polymer Science: Polymer Chemistry Edition, vol.23, issue.5, pp.1569-1577, 1985.
DOI : 10.1002/pol.1985.170230527

:. E. Jakab and O. Faix, Thermogravimetry/mass spectrometry study of six lignins within the scope of an international round robin test, Journal of Analytical and Applied Pyrolysis, vol.35, issue.2, pp.167-179, 1995.
DOI : 10.1016/0165-2370(95)00907-7

:. P. Ghetti, L. Ricca, and L. Angelini, Thermal analysis of biomass and corresponding pyrolysis products, Fuel, vol.75, issue.5, pp.565-573, 1996.
DOI : 10.1016/0016-2361(95)00296-0

:. V. Cozzani and A. Lucchesi, A new method to determine the composition of biomass by thermogravimetric analysis, The Canadian Journal of Chemical Engineering, vol.65, issue.1, pp.127-133, 1997.
DOI : 10.1080/10473289.1994.10467308

:. M. Safi, I. M. Mishra, and B. Prasad, Global degradation kinetics of pine needles in air, Thermochimica Acta, vol.412, issue.1-2, pp.155-162, 2004.
DOI : 10.1016/j.tca.2003.09.017

:. F. Beall, Differential calometric analysis of wood and wood components, Wood Science and Technology, vol.6, issue.3, pp.159-175, 1971.
DOI : 10.1002/polc.5070060109

:. I. Simkovic and K. Balog, Thermal Degradation and Thermooxidation of O-Acetyl-(4-O-methyl-D-glucurono)-D-xylan and Related Derivatives, Holzforschung, vol.13, issue.6, pp.512-516, 1995.
DOI : 10.1016/0961-9534(93)90054-8

:. M. Statheropoulosa and S. Liodakisa, Thermal degradation of Pinus halepensis pine-needles using various analytical methods, Journal of Analytical and Applied Pyrolysis, vol.43, issue.2, pp.115-123, 1997.
DOI : 10.1016/S0165-2370(97)00064-8

:. M. Antal and G. Varhegyi, Cellulose pyrolysis kinetics: revisited, Industrialia and Engineering, Chemistry Research, vol.37, pp.1267-1275, 1998.
DOI : 10.1021/ie970144v

URL : http://real.mtak.hu/21646/1/CELLULOSE_REVISITED_1997-10-07.PDF

:. J. Weiland and R. Guyonnet, Analyse de la pyrolyse menagee du bois par un couplage TG-DSC-IRTF, Journal of Thermal Analysis and Calorimetry, vol.7, issue.1, pp.51-265, 1998.
DOI : 10.1007/BF02719028

URL : https://hal.archives-ouvertes.fr/emse-00447977

:. S. Tsujiyama and A. Miyamori, Assignment of DSC thermograms of wood and its components, Thermochimica Acta, vol.351, issue.1-2, pp.177-181, 2000.
DOI : 10.1016/S0040-6031(00)00429-9

:. F. He, W. Yi, and X. Bai, Investigation on caloric requirement of biomass pyrolysis using TG-DSC analyzer, Energy Conversion and Management, pp.47-2461, 2006.

:. A. Ross, J. M. Jones, M. L. Kubacki, and T. Bridgeman, Classification of macroalgae as fuel and its thermochemical behaviour, Bioresource Technology, vol.99, issue.14, pp.99-6494, 2008.
DOI : 10.1016/j.biortech.2007.11.036

:. T. Fisher, M. Hajaligol, B. Waymack, and D. Kellogg, Pyrolysis behavior and kinetics of biomass derived materials, Journal of Analytical and Applied Pyrolysis, vol.62, issue.2, pp.331-349, 2002.
DOI : 10.1016/S0165-2370(01)00129-2

:. H. Lam, Y. L. Bigot, M. Delmas, and G. Avignon, A new procedure for the destructuring of vegetable matter at atmospheric pressure by a catalyst/solvent system of formic acid/acetic acid. Applied to the pulping of triticale straw, Industrial Crops and Products, vol.14, pp.139-144, 2001.

:. J. Banoub and M. Delmas, Structural elucidation of the wheat straw lignin polymer by atmospheric pressure chemical ionization tandem mass spectrometry and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry, Journal of Mass Spectrometry, vol.42, issue.8, pp.900-903, 2003.
DOI : 10.1016/S0032-3861(01)00216-6

:. M. Low and C. Morterra, IR studies of carbons???V Effects of nacl on cellulose pyrolysis and char oxidation??????Part IV: Ref. 4., Carbon, vol.23, issue.3, pp.311-316, 1985.
DOI : 10.1016/0008-6223(85)90116-2

:. C. Zaror, I. S. Hutchings, D. L. Pyle, H. N. Stiles, and R. Kandiyoti, Secondary char formation in the catalytic pyrolysis of biomass, Fuel, vol.64, issue.7, pp.990-994, 1985.
DOI : 10.1016/0016-2361(85)90156-5

:. G. Richards, Glycolaldehyde from pyrolysis of cellulose, Journal of Analytical and Applied Pyrolysis, vol.10, issue.3, pp.251-255, 1987.
DOI : 10.1016/0165-2370(87)80006-2

P. T. Williams and P. A. Horne, The role of metal salts in the pyrolysis of biomass, Renewable Energy, vol.4, issue.1, pp.1-13, 1994.
DOI : 10.1016/0960-1481(94)90058-2

:. G. Dobele, G. Rossinskaja, G. Telysheva, D. Meier, and O. Faix, Cellulose dehydration and depolymerization reactions during pyrolysis in the presence of phosphoric acid, Journal of Analytical and Applied Pyrolysis, vol.49, issue.1-2, pp.307-317, 1999.
DOI : 10.1016/S0165-2370(98)00126-0

:. G. Dobele, D. Meier, O. Faix, S. Radtke, G. Rossinskaja et al., Volatile products of catalytic flash pyrolysis of celluloses, Journal of Analytical and Applied Pyrolysis, vol.58, issue.59, pp.58-59, 2001.
DOI : 10.1016/S0165-2370(00)00128-5

:. I. Tanczos, G. Pokol, J. Borsa, T. Toth, and H. Schmidt, The effect of tetramethylammonium hydroxide in comparison with the effect of sodium hydroxide on the slow pyrolysis of cellulose, Journal of Analytical and Applied Pyrolysis, vol.68, issue.69, pp.68-69, 2003.
DOI : 10.1016/S0165-2370(03)00071-8

:. G. Dobele, T. Dizhbite, G. Rossinskaja, G. Telysheva, D. Meier et al., Pre-treatment of biomass with phosphoric acid prior to fast pyrolysis, Journal of Analytical and Applied Pyrolysis, vol.68, issue.69, pp.68-69, 2003.
DOI : 10.1016/S0165-2370(03)00063-9

:. G. Dobele, G. Rossinskaja, T. Dizhbite, G. Telysheva, D. Meier et al., Application of catalysts for obtaining 1,6-anhydrosaccharides from cellulose and wood by fast pyrolysis, Journal of Analytical and Applied Pyrolysis, vol.74, issue.1-2, pp.401-405, 2005.
DOI : 10.1016/j.jaap.2004.11.031

:. E. Iniesta, F. Sanchez, A. N. Garcia, and A. Marcilla, Yields and CO 2 reactivity of chars from almond shells obtained by a two heating step carbonisation process-Effect of different chemical pre-treatments and ash content, Journal of Analytical and Applied Pyrolysis, pp.58-59, 2001.

:. F. Marquez-montesinos, T. Cordero, J. Rodriguez-mirasol, and J. J. Rodriguez, CO2 and steam gasification of a grapefruit skin char, Fuel, vol.81, issue.4, pp.423-429, 2002.
DOI : 10.1016/S0016-2361(01)00174-0

:. D. Ye, J. B. Agnew, and D. K. Zhang, Gasification of a South Australian low-rank coal with carbon dioxide and steam: kinetics and reactivity studies, Fuel, vol.77, issue.11, pp.1209-1219, 1998.
DOI : 10.1016/S0016-2361(98)00014-3

:. J. Encinar, J. F. Gonzalez, J. J. Rodriguez, and M. J. Ramiro, Catalysed and uncatalysed steam gasification of eucalyptus char: influence of variables and kinetic study, Fuel, vol.80, issue.14, pp.2025-2036, 2001.
DOI : 10.1016/S0016-2361(01)00073-4

:. R. Struis, C. Von-scala, S. Stucki, and R. Prins, Gasification reactivity of charcoal with CO 2 . Part II: Metal catalysis as a function of conversion, Chemical Engineering Science, pp.57-3593, 2002.

:. G. Loffler, V. J. Wargadalam, and F. Winter, Catalytic effect of biomass ash on CO, CH 4 and HCN oxidation under fluidised bed combustor conditions, Fuel, vol.81, issue.6, pp.711-717, 2002.
DOI : 10.1016/S0016-2361(01)00203-4

:. C. Di-blasi, C. Branca, and G. D. Errico, Degradation characteristics of straw and washed straw, Thermochimica Acta, vol.364, issue.1-2, pp.133-142, 2000.
DOI : 10.1016/S0040-6031(00)00634-1

:. K. Raveendran, A. K. Ganesh, and C. Khilar, Influence of mineral matter on biomass pyrolysis characteristics, Fuel, vol.74, issue.12, pp.1812-1822, 1995.
DOI : 10.1016/0016-2361(95)80013-8

:. P. Szabo, G. Varhegyi, F. Till, and O. Faix, Thermogravimetric/mass spectrometric characterization of two energy crops, Arundo donax and Miscanthus sinensis, Journal of Analytical and Applied Pyrolysis, vol.36, issue.2, pp.179-190, 1996.
DOI : 10.1016/0165-2370(96)00931-X

:. R. Fahmi, A. V. Bridgwater, I. Donnison, N. Yates, and J. M. Jones, The effect of lignin and inorganic species in biomass on pyrolysis oil yields, quality and stability, Fuel, vol.87, issue.7, pp.1230-1240, 2008.
DOI : 10.1016/j.fuel.2007.07.026

:. J. Han and H. Kim, The reduction and control technology of tar during biomass gasification/pyrolysis: An overview, Renewable and Sustainable Energy Reviews, vol.12, issue.2, pp.397-416, 2008.
DOI : 10.1016/j.rser.2006.07.015

A. Subramanian and . Review, Pyrolysis?gas chromatography/mass spectrometry of Quercus sp. Wood Application to structural elucidation of macromolecules and aromatic profiles of different species, Renewable and Sustainable Energy Reviews Journal of Analytical Applied Pyrolysis, vol.51, issue.75, pp.181-193, 2006.

:. C. Saiz-jimenez and J. W. De-leeuw, Chemical structure of a soil humic acid as revealed by analytical pyrolysis, Journal of Analytical and Applied Pyrolysis, vol.11, pp.367-376, 1987.
DOI : 10.1016/0165-2370(87)85042-8

:. C. Saiz-jimenez, Analytical Pyrolysis of Humic Substances: Pitfalls, Limitations, and Possible Solutions, Environmental Science & Technology, vol.28, issue.11, pp.1773-1780, 1994.
DOI : 10.1021/es00060a005

:. C. Saiz-jimenez, Production of alkylbenzenes and alkylnaphtalenes upon pyrolysis of unsaturated fatty acids A model reaction to understand the origin of some pyrolysis products from humic substances?, Naturwissenschaften, vol.81, pp.451-453, 1994.

:. C. Saiz-jimenez, The origin of alkylbenzenes and thiophenes in pyrolysates of geochemical samples, Organic Geochemistry, vol.23, issue.1, pp.81-85, 1995.
DOI : 10.1016/0146-6380(94)00102-7

:. M. Gronli and G. Varhegyi, Thermogravimetric analysis and devolatilization kinetics of wood, Industrial and engineering chemistry research, pp.41-4201, 2002.

:. L. Helsen, E. Van-den, and . Bulck, Kinetics of the low-temperature pyrolysis of chromated copper arsenate-treated wood, Journal of Analytical and Applied Pyrolysis, vol.53, issue.1, pp.51-79, 2000.
DOI : 10.1016/S0165-2370(99)00050-9

:. C. Hindsgaul, J. Schramm, L. Gratz, U. Henriksen, and J. D. Bentzen, Physical and chemical characterization of particles in producer gas from wood chips, Bioresource Technology, vol.73, issue.2, pp.73-147, 2000.
DOI : 10.1016/S0960-8524(99)00153-4

:. J. Manyà and J. Arauzo, An alternative kinetic approach to describe the isothermal pyrolysis of micro-particles of sugar cane bagasse, Chemical Engineering Journal, vol.139, issue.3, pp.549-561, 2008.
DOI : 10.1016/j.cej.2007.09.005

:. A. Zabaniotou, O. Ioannidou, E. Antonakou, and A. Lappas, Experimental study of pyrolysis for potential energy, hydrogen and carbon material production from lignocellulosic biomass, International Journal of Hydrogen Energy, vol.33, issue.10, pp.2433-2444, 2008.
DOI : 10.1016/j.ijhydene.2008.02.080

:. P. Luangkiattikhun, C. Tangsathitkulchai, and M. Tangsathitkulchai, Non-isothermal thermogravimetric analysis of oil-palm solid wastes, Bioresource Technology, vol.99, issue.5, pp.986-997, 2008.
DOI : 10.1016/j.biortech.2007.03.001

. Athanassiou, Investigating the potential for energy, fuel, materials and chemicals production from corn residues (cobs and stalks) by non-catalytic and catalytic pyrolysis in two reactor configurations, Renewable and Sustainable Energy Reviews, 2008.

:. Y. Park, J. Kim, S. S. Kim, and Y. K. Park, Pyrolysis characteristics and kinetics of oak trees using thermogravimetric analyzer and micro-tubing reactor, Press [9]: A.J. Stamm, Wood and cellulose science, p.48, 1956.
DOI : 10.1016/j.biortech.2008.06.040

:. D. Arseneau, THE DIFFERENTIAL THERMAL ANALYSIS OF WOOD, Canadian Journal of Chemistry, vol.1, issue.6, pp.1915-1919, 1961.
DOI : 10.1021/ac60099a002

:. W. Tang, Effect of Inorganic Salts on Pyrolysis of Wood

:. F. Shafizadeh, Chemical composition and thermal analysis of cottonwood, Carbohydrate Research, vol.16, issue.2, pp.273-277, 1971.
DOI : 10.1016/S0008-6215(00)81161-1

:. S. Gaur and T. Reed, Thermal Data for Natural and Synthetic Fuels, 1998.

:. S. Moldoveanu, Analytical pyrolysis of natural organic polymers, 1998.

:. M. Antal and G. Varhegyi, Cellulose Pyrolysis Kinetics: The Current State of Knowledge, Industrial & Engineering Chemistry Research, vol.34, issue.3, pp.703-717, 1995.
DOI : 10.1021/ie00042a001

:. E. Sanders, A. I. Goldsmith, and J. I. Seeman, A model that distinguishes the pyrolysis of d-glucose, d-fructose, and sucrose from that of cellulose. Application to the understanding of cigarette smoke formation, Journal of Analytical and Applied Pyrolysis, vol.66, issue.1-2, pp.29-50, 2003.
DOI : 10.1016/S0165-2370(02)00104-3

:. M. Hajaligol, B. Waymack, and D. Kellogg, Low temperature formation of aromatic hydrocarbon from pyrolysis of cellulosic materials, Fuel, vol.80, issue.12, pp.1799-1807, 2001.
DOI : 10.1016/S0016-2361(01)00063-1

:. M. Low and C. Morterra, IR studies of carbons???V Effects of nacl on cellulose pyrolysis and char oxidation??????Part IV: Ref. 4., Carbon, vol.23, issue.3, pp.311-316, 1985.
DOI : 10.1016/0008-6223(85)90116-2

:. C. Zaror, I. S. Hutchings, D. L. Pyle, H. N. Stiles, and R. Kandiyoti, Secondary char formation in the catalytic pyrolysis of biomass, Fuel, vol.64, issue.7, pp.990-994, 1985.
DOI : 10.1016/0016-2361(85)90156-5

:. G. Richards, Glycolaldehyde from pyrolysis of cellulose, Journal of Analytical and Applied Pyrolysis, vol.10, issue.3, pp.251-255, 1987.
DOI : 10.1016/0165-2370(87)80006-2

:. P. Williams and P. A. Horne, The role of metal salts in the pyrolysis of biomass, Renewable Energy, vol.4, issue.1, pp.1-13, 1994.
DOI : 10.1016/0960-1481(94)90058-2

:. G. Dobele, G. Rossinskaja, G. Telysheva, D. Meier, and O. Faix, Cellulose dehydration and depolymerization reactions during pyrolysis in the presence of phosphoric acid, Journal of Analytical and Applied Pyrolysis, vol.49, issue.1-2, pp.307-317, 1999.
DOI : 10.1016/S0165-2370(98)00126-0

:. G. Dobele, D. Meier, O. Faix, S. Radtke, G. Rossinskaja et al., Volatile products of catalytic flash pyrolysis of celluloses, Journal of Analytical and Applied Pyrolysis, vol.58, issue.59, pp.58-59, 2001.
DOI : 10.1016/S0165-2370(00)00128-5

:. I. Tanczos, G. Pokol, J. Borsa, T. Toth, and H. Schmidt, The effect of tetramethylammonium hydroxide in comparison with the effect of sodium hydroxide on the slow pyrolysis of cellulose, Journal of Analytical and Applied Pyrolysis, vol.68, issue.69, pp.68-69, 2003.
DOI : 10.1016/S0165-2370(03)00071-8

:. G. Dobele, T. Dizhbite, G. Rossinskaja, G. Telysheva, D. Meier et al., Pre-treatment of biomass with phosphoric acid prior to fast pyrolysis, Journal of Analytical and Applied Pyrolysis, vol.68, issue.69, pp.68-69, 2003.
DOI : 10.1016/S0165-2370(03)00063-9

:. G. Dobele, G. Rossinskaja, T. Dizhbite, G. Telysheva, D. Meier et al., Application of catalysts for obtaining 1,6-anhydrosaccharides from cellulose and wood by fast pyrolysis, Journal of Analytical and Applied Pyrolysis, vol.74, issue.1-2, pp.401-405, 2005.
DOI : 10.1016/j.jaap.2004.11.031

:. J. Blazek and P. Buryan, Study of the thermal degradation of lignin in the inert atmosphere, pp.235-236, 2001.

:. M. Ramiah, Thermogravimetric and differential thermal analysis of cellulose, hemicellulose, and lignin, Journal of Applied Polymer Science, vol.14, issue.5, pp.1323-1337, 1970.
DOI : 10.1002/app.1970.070140518

:. T. Hosoya, H. Kawamoto, and S. Saka, Cellulose???hemicellulose and cellulose???lignin interactions in wood pyrolysis at gasification temperature, Journal of Analytical and Applied Pyrolysis, vol.80, issue.1, pp.118-125, 2007.
DOI : 10.1016/j.jaap.2007.01.006

:. K. Mansaray and A. E. Ghaly, Thermal degradation of rice husks in nitrogen atmosphere, Bioresource Technology, vol.65, issue.1-2, pp.13-20, 1998.
DOI : 10.1016/S0960-8524(98)00031-5

:. M. Müller-hagedorn, H. Bockhorn, L. Krebs, and U. Müller, A comparative kinetic study on the pyrolysis of three different wood species, Journal of Analytical and Applied Pyrolysis, vol.68, issue.69, pp.69-231, 2003.
DOI : 10.1016/S0165-2370(03)00065-2

:. V. Mamleev, S. Bourbigot, and J. Yvon, Kinetic analysis of the thermal decomposition of cellulose: The main step of mass loss, Journal of Analytical and Applied Pyrolysis, vol.80, issue.1, pp.151-165, 2007.
DOI : 10.1016/j.jaap.2007.01.013

V. Mamleev, S. Bourbigot, and J. Yvon, Kinetic analysis of the thermal decomposition of cellulose: The change of the rate limitation, Journal of Analytical and Applied Pyrolysis, vol.80, issue.1, pp.141-150, 2007.
DOI : 10.1016/j.jaap.2007.01.012

:. G. Varhegyi, Aims and methods in non-isothermal reaction kinetics, Journal of Analytical and Applied Pyrolysis, vol.79, issue.1-2, pp.278-288, 2007.
DOI : 10.1016/j.jaap.2007.01.007

:. J. Conesa, A. Marcilla, J. A. Caballero, and R. Font, Comments on the validity and utility of the different methods for kinetic analysis of thermogravimetric data, Journal of Analytical and Applied Pyrolysis, vol.58, issue.59, pp.58-59, 2001.
DOI : 10.1016/S0165-2370(00)00130-3

:. Blasi, Modeling chemical and physical processes of wood and biomass pyrolysis, Progress in Energy and Combustion Science, vol.34, pp.47-90, 2008.

:. Blasi, Modeling and simulation of combustion processes of charring and non-charring solid fuels, Progress in Energy and Combustion Science, vol.19, issue.1, pp.71-104, 1993.
DOI : 10.1016/0360-1285(93)90022-7

:. C. Di-blasi, C. Branca, and G. D. Errico, Degradation characteristics of straw and washed straw, Thermochimica Acta, vol.364, issue.1-2, pp.133-142, 2000.
DOI : 10.1016/S0040-6031(00)00634-1

:. S. Collura, B. Azambre, and J. Weber, Kinetic modelling of the pyrolysis of Miscanthus ?? Giganteus from the thermogravimetric analysis of its fractionated components, Environmental Chemistry Letters, vol.9, issue.69, pp.95-99, 2005.
DOI : 10.1007/s10311-005-0007-0

:. A. Shebani, A. J. Van-reenen, and M. Meincken, The effect of wood extractives on the thermal stability of different wood species, Thermochimica Acta, vol.471, issue.1-2, pp.471-514, 2008.
DOI : 10.1016/j.tca.2008.02.020

:. A. Khelfa, G. Finqueneisel, M. Auber, J. V. Weber, and C. Lig, Influence of some minerals on the cellulose thermal degradation mechanisms, Journal of Thermal Analysis and Calorimetry, vol.40, issue.41, pp.795-79983, 2008.
DOI : 10.1007/s10973-007-8649-8

:. M. Statheropoulos and S. A. Kyriakou, Quantitative thermogravimetric-mass spectrometric analysis for monitoring the effects of fire retardants on cellulose pyrolysis, Analytica Chimica Acta, vol.409, issue.1-2, pp.203-214, 2000.
DOI : 10.1016/S0003-2670(99)00859-4

:. A. Izumi and K. Kuroda, Pyrolysis-mass spectrometry analysis of dehydrogenation lignin polymers with various syringyl/guaiacyl ratios, Rapid Communications in Mass Spectrometry, vol.11, issue.15, pp.1709-1715, 1997.
DOI : 10.1002/(SICI)1097-0231(19971015)11:15<1709::AID-RCM5>3.0.CO;2-J

:. M. Nonier, N. Vivasa, N. Vivas-de-gaulejac, C. Absalon, . Ph et al., Pyrolysis???gas chromatography/mass spectrometry of Quercus sp. wood, Journal of Analytical and Applied Pyrolysis, vol.75, issue.2, pp.181-193, 2006.
DOI : 10.1016/j.jaap.2005.05.006

:. F. Ate?, A. E. Pütün, and E. Pütün, Pyrolysis of two different biomass samples in a fixed-bed reactor combined with two different catalysts, Fuel, vol.85, issue.12-13, pp.1851-1859, 2006.
DOI : 10.1016/j.fuel.2006.01.015

:. A. Pappa, K. Mikedi, N. Tzamtzis, and M. Statheropoulos, TG-MS analysis for studying the effects of fire retardants on the pyrolysis of pine-needles and their components, Journal of Thermal Analysis and Calorimetry, vol.75, issue.3, pp.655-661, 2006.
DOI : 10.1007/978-3-662-22455-7

:. A. Khelfa, G. Finqueneisel, M. Auber, and J. V. Weber, Influence of some minerals on the cellulose thermal degradation mechanisms, Journal of Thermal Analysis and Calorimetry, vol.40, issue.41, pp.795-799, 2008.
DOI : 10.1007/s10973-007-8649-8

:. K. Miyazaki, A New Compound, 4-Hydroxy-5,6-dihydro-2H-pyran-2-one, from Xylan on Heating, Mokuzai Gakkaishi, vol.21, p.120, 1975.

:. D. Gomez-pardo and J. Angelo, Revision of structure of a ???C56O3??? substance generated in the pyrolysis of biomass materials, Tetrahedron Letters, vol.32, issue.26, pp.32-3067, 1991.
DOI : 10.1016/0040-4039(91)80690-8

:. A. Herring, J. T. Mckinnon, D. E. Petrick, K. W. Gneshin, J. Filley et al., Detection of reactive intermediates during laser pyrolysis of cellulose char by molecular beam mass spectroscopy, implications for the formation of polycyclic aromatic hydrocarbons, Journal of Analytical and Applied Pyrolysis, vol.66, issue.1-2, pp.165-182, 2003.
DOI : 10.1016/S0165-2370(02)00112-2

:. R. Evans and T. A. Milne, Molecular characterization of the pyrolysis of biomass, Energy & Fuels, vol.1, issue.2, pp.123-137, 1987.
DOI : 10.1021/ef00002a001

:. E. Mészáros, E. Jakab, G. Várhegyi, P. Szepesváry, and B. Marosvölgyi, Comparative study of the thermal behavior of wood and bark of young shoots obtained from an energy plantation, Journal of Analytical and Applied Pyrolysis, vol.72, issue.2, pp.317-328, 2004.
DOI : 10.1016/j.jaap.2004.07.009

:. M. Statheropoulos and K. Mikedi, PCA???ContVarDia: an improvement of the PCA???VarDia technique for curve resolution in GC???MS and TG???MS analysis, Analytica Chimica Acta, vol.446, issue.1-2, pp.351-368, 2001.
DOI : 10.1016/S0003-2670(01)01097-2

:. A. Pappa, K. Mikedi, N. Tzamtzis, and M. Statheropoulos, Chemometric methods for studying the effects of chemicals on cellulose pyrolysis by thermogravimetry???mass spectrometry, Journal of Analytical and Applied Pyrolysis, vol.67, issue.2, pp.221-235, 2003.
DOI : 10.1016/S0165-2370(02)00063-3

:. J. Jackson, A User's Guide to Principal Components, Statistics, J. Wiley, Sons, 2003.
DOI : 10.1002/0471725331

:. H. Yang, R. Yan, H. Chen, D. H. Lee, and C. Zheng, Characteristics of hemicellulose, cellulose and lignin pyrolysis, Fuel, vol.86, issue.12-13, pp.1781-1788, 2007.
DOI : 10.1016/j.fuel.2006.12.013

:. Q. Wu, N. Pan, K. Deng, and D. , Pan, Thermogravimetry?mass spectrometry on the pyrolysis process of Lyocell fibers with and without catalyst, Carbohydrate Polymers, pp.72-222, 2008.

:. S. Collura, B. Azambre, and J. V. Weber, Kinetic modelling of the pyrolysis of Miscanthus ?? Giganteus from the thermogravimetric analysis of its fractionated components, Environmental Chemistry Letters, vol.9, issue.69, pp.95-99, 2005.
DOI : 10.1007/s10311-005-0007-0

:. T. Hosoya, H. Kawamoto, and S. Saka, Pyrolysis behaviors of wood and its constituent polymers at gasification temperature, Journal of Analytical and Applied Pyrolysis, vol.78, issue.2, pp.328-336, 2007.
DOI : 10.1016/j.jaap.2006.08.008

:. F. Modugno, E. Ribechini, M. Calderisi, G. Giachi, and M. P. Colombini, Analysis of lignin from archaeological waterlogged wood by direct exposure mass spectrometry (DE-MS) and PCA evaluation of mass spectral data, Microchemical Journal, vol.88, issue.2, pp.186-193, 2008.
DOI : 10.1016/j.microc.2007.11.010

:. M. Baratieri, P. Baggio, L. Fiori, and M. Grigiante, Biomass as an energy source: Thermodynamic constraints on the performance of the conversion process, Bioresource Technology, vol.99, issue.15, pp.99-7063, 2008.
DOI : 10.1016/j.biortech.2008.01.006

:. D. Fabbri, C. Torri, and V. Baravelli, Effect of zeolites and nanopowder metal oxides on the distribution of chiral anhydrosugars evolved from pyrolysis of cellulose: An analytical study, Journal of Analytical and Applied Pyrolysis, vol.80, issue.1, pp.24-29, 2007.
DOI : 10.1016/j.jaap.2006.12.025

:. P. Principi, F. Villa, M. Bernasconi, and E. Zanardini, Metal toxicity in municipal wastewater activated sludge investigated by multivariate analysis and in situ hybridization, Water Research, vol.40, issue.1, pp.40-99, 2006.
DOI : 10.1016/j.watres.2005.10.028

:. V. Mamleev, S. Bourbigot, and J. Yvon, Kinetic analysis of the thermal decomposition of cellulose: The main step of mass loss, Journal of Analytical and Applied Pyrolysis, vol.80, issue.1, pp.151-165, 2007.
DOI : 10.1016/j.jaap.2007.01.013

:. D. Hayesj, J. M. Nowakowski, and . Jones, An examination of biorefining processes, catalysts and challenges Uncatalysed and potassium-catalysed pyrolysis of the cell-wall constituents of biomass and their model compounds, Catalysis Today Journal of Analytical and Applied Pyrolysis, vol.25, issue.83, pp.12-25, 2008.

:. H. Kawamoto, H. Morisaki, S. Saka-adama, M. Blazsó, E. Mészáros et al., Secondary decomposition of levoglucosan in pyrolytic production from cellulosic biomass, Pyrolysis of biomass in the presence of Al-MCM-41 type catalysts, pp.1494-1502, 2005.
DOI : 10.1016/j.jaap.2008.08.009

T. Hosoya, H. Kawamoto, and S. Saka, Different pyrolytic pathways of levoglucosan in vapor- and liquid/solid-phases, Journal of Analytical and Applied Pyrolysis, vol.83, issue.1, pp.64-70, 2008.
DOI : 10.1016/j.jaap.2008.06.008

:. J. Lédé, F. Blachard, and O. Boutin, Radiant flash pyrolysis of cellulose pellets: products and mechanisms involved in transient and steady state conditions, Fuel, vol.81, issue.10, pp.1269-1279, 2002.
DOI : 10.1016/S0016-2361(02)00039-X

:. O. Boutin, M. Ferrer, and J. Lédé, Flash pyrolysis of cellulose pellets submitted to a concentrated radiation: experiments and modelling, Chemical Engineering Science, vol.57, issue.1, pp.15-25, 2002.
DOI : 10.1016/S0009-2509(01)00360-8

:. D. Scott, J. Piskorz, D. Radlein-in, H. Kawamoto, D. Yamamoto et al., Influence of neutral inorganic chlorides on primary and secondary char formation from cellulose, Levoglucosenone and Levoglucosans, pp.242-246, 1994.

D. J. Nowakowski, J. M. Jones, R. M. Brydson, and A. B. Ross, Potassium catalysis in the pyrolysis behaviour of short rotation willow coppice, Diméthyle furane, pp.2389-2402, 2007.
DOI : 10.1016/j.fuel.2007.01.026

:. D. Nowakowski, C. R. Woodbridge, and J. M. Jones, Phosphorus catalysis in the pyrolysis behaviour of biomass, Journal of Analytical and Applied Pyrolysis, vol.83, issue.2, pp.197-204, 2008.
DOI : 10.1016/j.jaap.2008.08.003

:. J. Wooten, J. I. Seeman, and M. R. Hajaligol, C CPMAS NMR. A New Mechanistic Model, Energy & Fuels, vol.18, issue.1, pp.1-15, 2004.
DOI : 10.1021/ef0300601

:. K. Bru, J. Blin, A. Julbe, and G. Volle, Pyrolysis of metal impregnated biomass: An innovative catalytic way to produce gas fuel, Journal of Analytical and Applied Pyrolysis, vol.78, issue.2, pp.291-300, 2007.
DOI : 10.1016/j.jaap.2006.08.006

URL : https://hal.archives-ouvertes.fr/hal-00165774

:. M. Najmi, DMF plus fort que le bioéthanol, Magazine nature « high-tech, 2007.

:. S. Collura, B. Azambre, and J. Weber, Thermal behaviour of Miscanthus grasses, an alternative biological fuel, Environmental Chemistry Letters, vol.5, issue.1, pp.95-99, 2005.
DOI : 10.1007/s10311-006-0077-7

:. S. Collura, B. Azambre, G. Finqueneisel, T. Zimny, and J. Weber, Miscanthus ?? Giganteus straw and pellets as sustainable fuels, Environmental Chemistry Letters, vol.31, issue.2, pp.75-78, 2006.
DOI : 10.1007/s10311-006-0036-3

:. I. Rowlands, The European directive on renewable electricity: conflicts and compromises, Energy Policy, vol.33, issue.8, pp.965-974, 2005.
DOI : 10.1016/j.enpol.2003.10.019

:. A. Caputo, M. Palumbo, P. M. Pelagagge, and F. Scacchia, Economics of biomass energy utilization in combustion and gasification plants: effects of logistic variables, Biomass and Bioenergy, vol.28, issue.1, pp.35-51, 2005.
DOI : 10.1016/j.biombioe.2004.04.009

:. G. Huber and J. A. Dumesic, An overview of aqueous-phase catalytic processes for production of hydrogen and alkanes in a biorefinery, Catalysis Today, vol.111, issue.1-2, pp.119-132, 2006.
DOI : 10.1016/j.cattod.2005.10.010

:. G. Fischer, S. Prieler, and H. Van-velthuizen, Biomass potentials of miscanthus, willow and poplar: results and policy implications for Eastern Europe, Northern and Central Asia, Biomass and Bioenergy, vol.28, issue.2, pp.119-132, 2005.
DOI : 10.1016/j.biombioe.2004.08.013

:. M. Khanna, B. Dhungana, and J. Clifton-brown, Costs of producing miscanthus and switchgrass for bioenergy in Illinois, Biomass and Bioenergy, vol.32, issue.6, pp.482-493, 2008.
DOI : 10.1016/j.biombioe.2007.11.003

:. A. Sørensen, P. J. Teller, T. Hilstrøm, and B. K. Ahring, Hydrolysis of Miscanthus for bioethanol production using dilute acid presoaking combined with wet explosion pretreatment and enzymatic treatment, Bioresource Technology, pp.99-6602, 2008.

:. B. Jenkins, L. L. Baxter, T. R. Miles, and T. R. Miles, Combustion properties of biomass, Fuel Processing Technology, vol.54, issue.1-3, pp.17-46, 1998.
DOI : 10.1016/S0378-3820(97)00059-3

:. S. Yorgun and Y. E. ?im?ek, Catalytic pyrolysis of Miscanthus??giganteus over activated alumina, Bioresource Technology, vol.99, issue.17, pp.8095-8100, 2008.
DOI : 10.1016/j.biortech.2008.03.036

:. Y. Matsumura, T. Minowa, B. Potic, S. R. Kersten, W. Prins et al., Biomass gasification in near- and super-critical water: Status and prospects, Biomass and Bioenergy, vol.29, issue.4, pp.269-292, 2005.
DOI : 10.1016/j.biombioe.2005.04.006

:. L. Wei, S. Xu, J. Liu, C. Lu, . Sh et al., A Novel Process of Biomass Gasification for Hydrogen-Rich Gas with Solid Heat Carrier:??? Preliminary Experimental Results, Energy & Fuels, vol.20, issue.5, pp.2266-2273, 2006.
DOI : 10.1021/ef060137w

:. M. Baratieri, P. Baggio, L. Fiori, and M. Grigiante, Biomass as an energy source: Thermodynamic constraints on the performance of the conversion process, Bioresource Technology, vol.99, issue.15, pp.99-7063, 2008.
DOI : 10.1016/j.biortech.2008.01.006

. Baryshnikov, Modification of iron ore catalysts for lignite hydrogenation and hydrocracking of coal-derived liquids, Fuel, vol.75, pp.39-42, 1996.

:. V. Sharypov, N. G. Beregovtsova, B. N. Kuznetsov, S. V. Baryshnikov, V. L. Cebolla et al., Co-pyrolysis of wood biomass and synthetic polymers mixtures, Journal of Analytical and Applied Pyrolysis, vol.76, issue.1-2, pp.265-270, 2006.
DOI : 10.1016/j.jaap.2005.12.006

:. T. Hosoya, H. Kawamoto, and S. Saka, Pyrolysis behaviors of wood and its constituent polymers at gasification temperature, Journal of Analytical and Applied Pyrolysis, vol.78, issue.2, pp.328-336, 2007.
DOI : 10.1016/j.jaap.2006.08.008

:. T. Nordgreen, T. Liliedahl, and K. Sjöström, Elemental Iron as a Tar Breakdown Catalyst in Conjunction with Atmospheric Fluidized Bed Gasification of Biomass: A Thermodynamic Study, Energy & Fuels, vol.20, issue.3, pp.890-895, 2006.
DOI : 10.1021/ef0502195

:. A. Uddin, H. Tsuda, S. Wu, and E. Sasaoka, Catalytic decomposition of biomass tars with iron oxide catalysts, Fuel, vol.87, pp.451-459, 2008.

:. M. Nakazawa and G. A. Somorjai, Coadsorption of water and selected aromatic molecules to model the adhesion of epoxy resins on hydrated surfaces of zinc oxide and iron oxide, Applied Surface Science, vol.84, issue.3, pp.309-323, 1995.
DOI : 10.1016/0169-4332(94)00537-0

:. K. Polychronopoulou, A. Bakandritos, V. Tzitzios, J. L. Fierro, and A. M. Efstathiou, Absorption-enhanced reforming of phenol by steam over supported Fe catalysts, Journal of Catalysis, vol.241, issue.1, pp.132-148, 2006.
DOI : 10.1016/j.jcat.2006.04.015

:. K. Polychronopoulou, C. N. Costa, and A. M. Efstathiou, The role of oxygen and hydroxyl support species on the mechanism of H2 production in the steam reforming of phenol over metal oxide-supported-Rh and -Fe catalysts, Catalysis Today, vol.112, issue.1-4, pp.89-93, 2006.
DOI : 10.1016/j.cattod.2005.11.037