D. Berardan, Rare earth valence and paramagnetic properties of the skutterudites Ce1???zYbzFe4Sb12, BayFe4Sb12 and LayFe4Sb12, Journal of Magnetism and Magnetic Materials, vol.285, issue.1-2, p.245, 2005.
DOI : 10.1016/j.jmmm.2004.07.047

D. A. Gajewski, H. J. Goldsmith, and R. W. Douglas, Heavy fermion behaviour of the cerium-filled skutterudites and, Journal of Physics: Condensed Matter, vol.10, issue.31, pp.6973-386, 1954.
DOI : 10.1088/0953-8984/10/31/013

T. C. Harman, Quantum Dot Superlattice Thermoelectric Materials and Devices, Science, vol.297, issue.5590, p.2229, 2002.
DOI : 10.1126/science.1072886

K. Koumoto, I. Terasaki, and R. Funahaschi, Complex Oxide Materials for Potential Thermoelectric Applications, MRS Bulletin, vol.61, issue.03, p.206, 2006.
DOI : 10.1006/jssc.2002.9578

P. W. Lange and R. T. Littleton, Ein Vergleich zwischen Bi2Te3 und Bi2Te2S, Die Naturwissenschaften, vol.27, issue.8, pp.133-121104, 1939.
DOI : 10.1007/BF01490284

M. Ohtaki, )O, Journal of Applied Physics, vol.10, issue.3, p.1816, 1996.
DOI : 10.1063/1.349385

M. Prevel, Doctorat de l'Université de Caen, soutenu le 26 octobre, Dictionnaire des Inventeurs et des Inventions, 1999.

F. Rosi, Materials for thermoelectric refrigeration, Journal of Physics and Chemistry of Solids, vol.10, issue.2-3, pp.191-1959
DOI : 10.1016/0022-3697(59)90074-5

D. M. Rowe, V. S. Shukla, and N. Savvides, Phonon scattering at grain boundaries in heavily doped fine-grained silicon???germanium alloys, Nature, vol.8, issue.5809, p.765, 1981.
DOI : 10.1038/290765a0

D. M. Rowe, Thermoelectrics Handbook, Macro to Nano, 2006.

Q. Shen, Effects of partial substitution of Ni by Pd on the thermoelectric properties of ZrNiSn-based half-Heusler compounds, Applied Physics Letters, vol.79, issue.25, p.4165, 2001.
DOI : 10.1063/1.1388162

I. Shirotani, Electrical conductivity and superconductivity of metal phosphides with skutterudite-type structure prepared at high pressure, Journal of Physics and Chemistry of Solids, vol.57, issue.2, p.211, 1996.
DOI : 10.1016/0022-3697(95)00197-2

G. S. Snyder and E. S. Toberer, Complex thermoelectric materials, CRC Handbook of Thermoelectrics, pp.105-407, 1995.
DOI : 10.1557/mrs2006.46

M. Telkes, The Efficiency of Thermoelectric Generators. I., Journal of Applied Physics, vol.12, issue.17, p.1116, 1947.
DOI : 10.1002/andp.19324070107

T. M. Tritt, Semimetals and Semiconductors: Recent Trends in Thermoelectric, Materials Research, vol.70, 2000.

T. M. Tritt, Semimetals and Semiconductors: Recent Trends in Thermoelectric, Materials Research, vol.69, 2001.

C. Uher, =Zr, Hf), Physical Review B, vol.80, issue.107, pp.8615-587, 1999.
DOI : 10.1007/BF01323516

C. Wood, Materials for thermoelectric energy conversion, Reports on Progress in Physics, vol.51, issue.4, p.459, 1988.
DOI : 10.1088/0034-4885/51/4/001

H. Anno, Structural and electronic transport properties of polycrystalline p-type CoSb3, Journal of Applied Physics, vol.3, issue.10, p.5270, 1998.
DOI : 10.1063/1.357620

D. Berardan, Thèse de l, 2004.

L. D. Chen, -type thermoelectric performance of BayCo4Sb12, Journal of Applied Physics, vol.47, issue.4, p.1864, 2001.
DOI : 10.2497/jjspm.47.958

T. He, J. Chen, H. D. Rosenfeld, and M. A. Subramanian, Thermoelectric Properties of Indium-Filled Skutterudites, Chemistry of Materials, vol.18, issue.3, p.759, 2006.
DOI : 10.1021/cm052055b

M. Puyet, Synthesis and crystal structure of CaxCo4Sb12 skutterudites, Journal of Solid State Chemistry, vol.177, issue.6, p.2138, 2004.
DOI : 10.1016/j.jssc.2004.02.010

M. Puyet, partially filled skutterudites, Physical Review B, vol.1, issue.3, p.35126, 2006.
DOI : 10.1103/PhysRevB.61.R9209

M. Puyet, N° 245110, Phys. Rev. B Ark. KemiC., Chakoumakos B.C., Mandrus D., Phys. Rev. B.., Science Phys. Rev. B, vol.75, issue.56, pp.103-2475, 1968.

J. O. Sofo and G. D. Mahan, A narrow-band-gap semiconductor, Physical Review B, vol.43, issue.23, p.15620, 1998.
DOI : 10.1103/PhysRevB.43.6388

H. Takizawa, Atom insertion into the CoSb3 skutterudite host lattice under high pressure, Journal of Alloys and Compounds, vol.282, issue.1-2, pp.79-259, 1999.
DOI : 10.1016/S0925-8388(98)00802-0

K. T. Wojciechowski, J. Tobola, and J. Leszczynski, Thermoelectric properties and electronic structure of CoSb3 doped with Se and Te, Journal of Alloys and Compounds, vol.361, issue.1-2, p.19, 2003.
DOI : 10.1016/S0925-8388(03)00411-0

C. K. Johnson, S. Katsuyama, Y. Shichijo, M. Ito, K. Majima et al., Thermoelectric properties of the skutterudite Co 1-x Fe x Sb 3 system, Thermoelectric properties of CoSb 3, pp.1065-6708, 1998.

V. L. Kuznetsov, L. A. Kuznetsova, and D. M. Rowe, skutterudites, Journal of Physics: Condensed Matter, vol.15, issue.29, p.5035, 2003.
DOI : 10.1088/0953-8984/15/29/315

G. A. Lamberton, High figure of merit in Eu-filled CoSb 3 -based skutterudites, Applied Physics Letters, vol.80, issue.4, 2002.

D. Mandrus, A. Migliori, T. W. Darling, M. F. Hundley, E. J. Peterson et al., Electronic transport in lightly doped CoSb 3, Phys. Rev. B, vol.52, issue.7, 1995.

Y. Nagamoto, K. Tanaka, and T. Koyanagi, Transport properties of heavily doped n-type CoSb/sub 3/, Seventeenth International Conference on Thermoelectrics. Proceedings ICT98 (Cat. No.98TH8365), p.302, 1998.
DOI : 10.1109/ICT.1998.740378

G. S. Nolas, H. Takizawa, T. Endo, H. Sellinschegg, and D. C. Johnson, Thermoelectric properties of Sn-filled skutterudites, Applied Physics Letters, vol.77, issue.1, p.52
DOI : 10.1107/S0108768198018345

G. S. Nolas, M. Kaeser, R. T. Littleton, and T. M. Tritt, High figure of merit in partially filled ytterbium skutterudite materials, Applied Physics Letters, vol.61, issue.12, 2000.
DOI : 10.1103/PhysRevB.61.4608

G. S. Nolas, J. L. Cohn, and G. A. Slack, Effect of partial void filling on the lattice thermal conductivity of skutterudites, Physical Review B, vol.72, issue.1, p.164, 1998.
DOI : 10.1016/0022-5088(80)90260-X

C. Kittel, Introduction to solid state physics, traduction parue chez Dunod, 5ème édition, 1976.

B. Hay, J. Filtz, and J. Batsale, Mesure de la diffusivité thermique par la méthode flash, p.955, 2004.

A. Degiovanni, Diffusivité et méthode flash, Rev. Gén. Therm. Fr, vol.185, p.420, 1977.

A. Degiovanni and M. Laurent, Une nouvelle technique d'identification de la diffusivité thermique pour la méthode « flash », Revue Phys, Appl, vol.21, p.229, 1986.

W. J. Parker, R. J. Jenkins, C. P. Butler, and G. L. Abbott, Flash Method of Determining Thermal Diffusivity, Heat Capacity, and Thermal Conductivity, Journal of Applied Physics, vol.32, issue.9, pp.9-1679, 1961.
DOI : 10.1063/1.1728417

L. J. Van-der-pauw, A method of measuring specific resistivity and hall effect of discs of arbitrary shape, Philips research reports, 1958.

M. Puyet, Electronic, transport and magnetic properties of CaxCo4Sb12 partially filled skutterudites, Phys. Rev. B, vol.73, issue.035126, 2006.

H. Anno, Structural and electronic transport properties of polycrystalline p-type CoSb3, Journal of Applied Physics, vol.3, issue.10, pp.5270-13396, 1998.
DOI : 10.1063/1.357620

T. Caillat, J. Fleurial, and A. Borshchevski, Bridgman-solution crystal growth and characterization of the skutterudite compounds CoSb3 and RhSb3, Journal of Crystal Growth, vol.166, issue.1-4, p.722, 1996.
DOI : 10.1016/0022-0248(95)00478-5

J. Callaway, Model for Lattice Thermal Conductivity at Low Temperatures, Physical Review, vol.68, issue.4, p.1046, 1959.
DOI : 10.1088/0370-1298/68/12/303

J. Callaway, Effect of Point Imperfections on Lattice Thermal Conductivity, Physical Review, vol.106, issue.4, p.1149, 1960.
DOI : 10.1103/PhysRev.106.1175

H. J. Goldsmid, Thermoelectric refrigeration, 1964.
DOI : 10.1007/978-1-4899-5723-8

T. He, J. Chen, H. D. Rosenfeld, and M. A. Subramanian, Thermoelectric Properties of Indium-Filled Skutterudites, Chemistry of Materials, vol.18, issue.3, p.759, 2006.
DOI : 10.1021/cm052055b

S. Kaprzyk and A. Et-bansil, Green???s function and a generalized Lloyd formula for the density of states in disordered muffin-tin alloys, Physical Review B, vol.23, issue.12, p.7358, 1990.
DOI : 10.1103/PhysRevB.23.3608

G. P. Meisner, D. T. Morelli, S. Hu, J. Yang, and C. Uher, Structure and Lattice Thermal Conductivity of Fractionally Filled Skutterudites: Solid Solutions of Fully Filled and Unfilled End Members, Physical Review Letters, vol.126, issue.16, p.3551, 1998.
DOI : 10.1103/PhysRev.126.427

M. Puyet, Développement de nouveaux matériaux thermoélectriques avancés de structure skutterudite, thèse INPL, 2004.

M. Puyet, Low-temperature thermal properties of n-type partially filled calcium skutterudites, Journal of Physics: Condensed Matter, vol.18, issue.49, p.11301, 2006.
DOI : 10.1088/0953-8984/18/49/021

J. W. Sharp, E. C. Jones, R. K. Williams, P. M. Martin, and B. C. Sales, and related alloys, Journal of Applied Physics, vol.115, issue.2, p.1013, 1995.
DOI : 10.1016/0022-3115(83)90312-4

I. Shirotani, X-ray study with synchrotron radiation for P- and Sb-based skutterudite compounds at high pressures, Journal of Physics: Condensed Matter, vol.16, issue.43, pp.7853-11235, 1979.
DOI : 10.1088/0953-8984/16/43/024

J. O. Sofo and G. D. Mahan, A narrow-band-gap semiconductor, Physical Review B, vol.43, issue.23, p.15620, 1998.
DOI : 10.1103/PhysRevB.43.6388

K. T. Wojciechowski, J. Tobola, and J. Leszczynski, Thermoelectric properties and electronic structure of CoSb3 doped with Se and Te, Journal of Alloys and Compounds, vol.361, issue.1-2, p.19, 2003.
DOI : 10.1016/S0925-8388(03)00411-0