T. Li, V. A. Topolkaraev, A. Hiltner, E. Baer, X. Z. Ji et al., Block copolymers as compatibilizers for blends of linear low density polyethylene and polystyrene, Journal of Polymer Science Part B: Polymer Physics, vol.33, issue.4, pp.667-683, 1995.
DOI : 10.1002/polb.1995.090330416

H. Li, G. H. Hu, and J. A. Sousa, Morphology development of immiscible polymer blends during melt blending: Effects of interfacial agents on the liquid-solid interfacial heat transfer, Journal of Polymer Science Part B: Polymer Physics, vol.38, issue.23, pp.3368-3384, 1999.
DOI : 10.1515/POLYENG.1991.10.1-3.123

P. Cigana, B. D. Favis, and R. Jerome, Diblock copolymers as emulsifying agents in polymer blends: Influence of molecular weight, architecture, and chemical composition, Journal of Polymer Science Part B: Polymer Physics, vol.34, issue.9, pp.1691-1700, 1996.
DOI : 10.1002/(SICI)1099-0488(19960715)34:9<1691::AID-POLB18>3.0.CO;2-2

P. Cigana and B. D. Favis, The relative efficacy of diblock and triblock copolymers for a polystyrene/ethylene-propylene rubber interface, Polymer, vol.39, issue.15, pp.3373-3378, 1998.
DOI : 10.1016/S0032-3861(97)10041-6

C. Harrats, R. Fayt, and R. Jérôme, Effect of block copolymers of various molecular architecture on the phase morphology and tensile properties of LDPE rich (LDPE/PS) blends, Polymer, vol.43, issue.3, pp.863-873, 2002.
DOI : 10.1016/S0032-3861(01)00633-4

P. Jannasch, H. Hassander, and B. Wesslén, On the macro- and microphase separation of compatibilizers in immiscible polymer blends, Journal of Polymer Science Part B: Polymer Physics, vol.34, issue.7, p.1289, 1996.
DOI : 10.1002/(SICI)1099-0488(199605)34:7<1289::AID-POLB11>3.0.CO;2-6

B. D. Edgecombe, J. A. Stein, J. M. Fréchet, Z. Xu, and E. J. Kramer, The Role of Polymer Architecture in Strengthening Polymer???Polymer Interfaces:?? A Comparison of Graft, Block, and Random Copolymers Containing Hydrogen-Bonding Moieties, Macromolecules, vol.31, issue.4, pp.1292-1304, 1998.
DOI : 10.1021/ma970832q

Z. Starý, I. Fortelný, Z. Kruli?, and M. ?louf, Effect of the molecular structure of ethene???propene and styrene???butadiene copolymers on their compatibilization efficiency in low-density polyethylene/polystyrene blends, Journal of Applied Polymer Science, vol.66, issue.1, pp.174-186, 2008.
DOI : 10.3139/217.0060

N. Vranje?, F. Lednický, J. Kotek, J. Baldrian, V. Rek et al., Compatibilization efficiency of styrene-butadiene block copolymers as a function of their block number, Journal of Applied Polymer Science, vol.23, issue.1, pp.466-472, 2008.
DOI : 10.1007/978-3-662-04556-5

M. Matos, B. D. Favis, and P. Lomellini, Interfacial modification of polymer blends???the emulsification curve: 1. Influence of molecular weight and chemical composition of the interfacial modifier, Polymer, vol.36, issue.20, pp.3899-3907, 1995.
DOI : 10.1016/0032-3861(95)99784-R

W. M. Chio, O. O. Park, and J. G. Lim, Effect of diblock copolymers on morphology and mechanical properties for syndiotactic polystyrene/ethylene-propylene copolymer blends, Journal of Applied Polymer Science, vol.35, issue.6, pp.3618-3626, 2004.
DOI : 10.1122/1.550166

B. K. Hong and W. Jo, Effects of molecular weight of SEBS triblock copolymer on the morphology, impact strength, and rheological property of syndiotactic polystyrene/ethylene???propylene rubber blends, Polymer, vol.41, issue.6, pp.2069-2079, 2004.
DOI : 10.1016/S0032-3861(99)00372-9

D. Bourry and B. D. Favis, Cocontinuity and phase inversion in HDPE/PS blends: Influence of interfacial modification and elasticity, Journal of Polymer Science Part B: Polymer Physics, vol.36, issue.11, pp.1889-1899, 1998.
DOI : 10.1002/(SICI)1099-0488(199808)36:11<1889::AID-POLB10>3.0.CO;2-3

B. G. Soares, A. C. Moreira, A. S. Sirqueira, R. V. Barbosa, and R. A. Simão, Effect of the molecular architecture of graft copolymers on the phase morphology and tensile properties of PS/EVA blends, Journal of Applied Polymer Science, vol.7, issue.2, pp.930-938, 2008.
DOI : 10.5254/1.3538766

H. Retsos, S. H. Anastasiadis, S. Pispas, J. W. Mays, and N. Hadjichristidis, Interfacial Tension in Binary Polymer Blends in the Presence of Block Copolymers. 2. Effects of Additive Architecture and Composition, Macromolecules, vol.37, issue.2, pp.524-537, 2004.
DOI : 10.1021/ma035463e

Y. Lyatskaya, D. Gersappe, N. A. Gross, and A. C. Balazs, Designing Compatibilizers To Reduce Interfacial Tension in Polymer Blends, The Journal of Physical Chemistry, vol.100, issue.5, pp.1449-1458, 1996.
DOI : 10.1021/jp952422e

Y. Lyatskaya, S. H. Jacobson, and A. C. Balazs, Effect of Composition on the Compatibilizing Activity of Comb Copolymers, Macromolecules, vol.29, issue.3, pp.1059-1061, 1996.
DOI : 10.1021/ma950615u

S. Schwarz and D. G. Peiffer, The use of graft copolymers to bind immiscible blends, Science, vol.265, pp.1072-1074, 1994.

R. Israels, D. P. Foster, and A. C. Balazs, Designing Optimal Comb Compatibilizers: AC and BC Combs at an A/B Interface, Macromolecules, vol.28, issue.1, pp.218-224, 1995.
DOI : 10.1021/ma00105a028

L. Kvist, H. Bertilsson, and P. Meuller, Poly(styrene-g-ethylene oxide) copolymers as interfacial agents in immiscible polymer blends, Polymer Engineering & Science, vol.34, issue.8, pp.1303-1312, 1998.
DOI : 10.1002/pen.10301

A. Adedeji, S. D. Hudson, and A. M. Jamieson, Effect of Exothermic Interfacial Mixing on Interfacial Activity of a Block Copolymer, Macromolecules, vol.29, issue.7, pp.2449-2456, 1996.
DOI : 10.1021/ma951298u

S. Kim, J. K. Kim, and C. E. Park, Effect of molecular architecture of in situ reactive compatibilizer on the morphology and interfacial activity of an immiscible polyolefin/polystyrene blend, Polymer, vol.38, issue.8, pp.1809-1815, 1997.
DOI : 10.1016/S0032-3861(96)00714-8

N. Kitayama, H. Keskkula, and D. R. Paul, Reactive compatibilization of nylon 6/styrene???acrylonitrile copolymer blends. Part 2. Dispersed phase particle size, Polymer, vol.41, issue.22, pp.8053-8060, 2000.
DOI : 10.1016/S0032-3861(00)00157-9

M. F. Zhang and H. E. Müller, Cylindrical polymer brushes, Journal of Polymer Science Part A: Polymer Chemistry, vol.252, issue.16, pp.3461-3481, 2005.
DOI : 10.1146/annurev.bb.13.060184.000505

A. Bhattacharya and B. N. Misra, Grafting: a versatile means to modify polymersTechniques, factors and applications, Progress in Polymer Science, vol.29, issue.8, pp.767-814, 2004.
DOI : 10.1016/j.progpolymsci.2004.05.002

M. Pitsikalis, S. Pispas, J. W. Mays, and N. Hadjichristidis, Nonlinear block copolymer architectures Advances in Polymer Science, pp.1-137, 1998.

H. G. Börner and K. Matyjasewski, Graft copolymer by atom transfer polymerization. Macromolecular Symposium, pp.1-15, 2002.

A. V. Vivek and R. Dhamodharan, Grafting of methacrylates and styrene on to polystyrene backbone via a ???grafting from??? ATRP process at ambient temperature, Journal of Polymer Science Part A: Polymer Chemistry, vol.38, issue.17, pp.3818-3832, 2007.
DOI : 10.1016/S0921-5107(01)00570-0

Z. Li, P. Li, and J. Huang, Synthesis of amphiphilic copolymer brushes: Poly(ethylene oxide)-graft-polystyrene, Journal of Polymer Science Part A: Polymer Chemistry, vol.31, issue.15, pp.4361-4371, 2006.
DOI : 10.1002/pola.21515

J. Ruokolainen, J. Tanner, O. Ikkala, G. T. Brinke, and E. L. Thomas, Direct Imaging of Self-Organized Comb Copolymer-like Systems Obtained by Hydrogen Bonding:?? Poly(4-vinylpyridine)???4-Nonadecylphenol, Macromolecules, vol.31, issue.11, pp.3532-3536, 1998.
DOI : 10.1021/ma971747l

C. G. Bazuin and A. Tork, Generation of Liquid Crystalline Polymeric Materials from Non Liquid Crystalline Components via Ionic Complexation, Macromolecules, vol.28, issue.26, pp.8877-8880, 1995.
DOI : 10.1021/ma00130a027

K. Matyjaszewski and J. Xia, Atom transfer radical polymerization. Chemical References reviews, pp.2921-2990, 2001.
URL : https://hal.archives-ouvertes.fr/hal-01564110

Y. Tsukahara, K. Mizuno, A. Segawa, and Y. Yamashita, Study on the radical polymerization behavior of macromonomers, Macromolecules, vol.22, issue.4, pp.1546-1552, 1989.
DOI : 10.1021/ma00194a007

H. A. Al-muallem and D. M. Knauss, Graft copolymers from star-shaped and hyperbranced polystyrene macromonomers, Journal of Polymer Science Part A: Polymer Chemistry, vol.29, pp.3547-3555, 2001.

K. Matyjaszewski, K. L. Beers, A. Kern, and S. G. Gaynor, Hydrogels by atom transfer radical polymerization. I. Poly(N-vinylpyrrolidinone-g-styrene) via the macromonomer method, Journal of Polymer Science Part A: Polymer Chemistry, vol.36, issue.5, pp.823-830, 1998.
DOI : 10.1002/(SICI)1099-0518(19980415)36:5<823::AID-POLA15>3.0.CO;2-I

B. D. Edgecombe, J. A. Stein, J. M. Fréchet, Z. Xu, and E. J. Kramer, The Role of Polymer Architecture in Strengthening Polymer???Polymer Interfaces:?? A Comparison of Graft, Block, and Random Copolymers Containing Hydrogen-Bonding Moieties, Macromolecules, vol.31, issue.4, pp.1292-1304, 1998.
DOI : 10.1021/ma970832q

H. Shinoda, P. J. Miller, and K. Matyjaszewski, Improving the Structural Control of Graft Copolymers by Combining ATRP with the Macromonomer Method, Macromolecules, vol.34, issue.10, pp.3186-3194, 2001.
DOI : 10.1021/ma001943j

J. Rieger, P. Dubois, and C. Jérôme, -PEO Copolymers, Langmuir, vol.22, issue.18, pp.7471-7479, 2006.
DOI : 10.1021/la0602261

S. G. Roos, A. H. Müller, and K. Matyjaszewski, -Butyl Acrylate with Methyl Methacrylate and PMMA Macromonomers:?? Comparison of Reactivity Ratios in Conventional and Atom Transfer Radical Copolymerization, Macromolecules, vol.32, issue.25, pp.8331-8335, 1999.
DOI : 10.1021/ma9819337

Y. Z. You, C. Y. Hong, W. P. Wang, P. H. Wang, W. Q. Lu et al., A Novel Strategy To Synthesize Graft Copolymers with Controlled Branch Spacing Length and Defined Grafting Sites, Macromolecules, vol.37, issue.19, pp.7140-7145, 2004.
DOI : 10.1021/ma0493123

J. Roovers and P. Toporowski, Synthesis and characterization of multiarm star polybutadienes, Macromolecules, vol.22, issue.4, pp.1897-1903, 1989.
DOI : 10.1021/ma00194a064

K. L. Beers, S. G. Gaynor, K. Matyjaszewski, S. S. Sheiko, and M. Möller, The Synthesis of Densely Grafted Copolymers by Atom Transfer Radical Polymerization, Macromolecules, vol.31, issue.26, pp.9413-9415, 1998.
DOI : 10.1021/ma981402i

M. Zhang, T. Breiner, H. Mori, and A. H. Müller, Amphiphilic cylindrical brushes with poly(acrylic acid) core and poly(n-butyl acrylate) shell and narrow length distribution, Polymer, vol.44, issue.5, pp.1449-1458, 2003.
DOI : 10.1016/S0032-3861(02)00774-7

R. Venkatesh, L. Yajjou, C. E. Koning, and B. Klumperman, Novel brush copolymers via controlled radical polymerization. Macromolecular chemistry and physics, pp.2161-2168, 2004.
DOI : 10.1002/macp.200400252

X. S. Wang, N. Luo, and S. K. Ying, Synthesis of EPDM-g-PMMA through atom transfer radical polymerization, Polymer, vol.40, issue.16, pp.4515-4520, 1999.
DOI : 10.1016/S0032-3861(98)00693-4

C. Cao, J. Y. Dong, Y. Hu, and T. C. Chung, Synthesis of polypropylene graft copolymers by the combination of a polypropylene copolymer containing pendant vinylbenzene groups and atom transfer radical polymerization, Journal of Polymer Science Part A: Polymer Chemistry, vol.63, issue.2, pp.429-437, 2005.
DOI : 10.1002/pola.20509

Y. Inoue, T. Matsugi, N. Kashiwa, and K. Matyjaszewski, Graft Copolymers from Linear Polyethylene via Atom Transfer Radical Polymerization, Macromolecules, vol.37, issue.10, pp.3651-3658, 2004.
DOI : 10.1021/ma0359887

K. Matyjaszewski, M. Teodorescu, P. J. Miller, and M. L. Peterson, Graft copolymers of polyethylene by atom transfer radical polymerization, Journal of Polymer Science Part A: Polymer Chemistry, vol.37, issue.13, pp.2440-2448, 2000.
DOI : 10.1002/(SICI)1099-0518(19991215)37:24<4610::AID-POLA19>3.0.CO;2-O

Y. Pae, Preparation of polyimide/nylon 6 graft copolymers from polyimides containing ester moieties: Synthesis and characterization, Journal of Applied Polymer Science, vol.4, issue.1, pp.309-318, 2006.
DOI : 10.1002/app.22481

G. Koutalas, D. J. Lohse, and N. Hadjichristidis, Novel block-comb/graft copolymers with the macromonomer strategy and anionic polymerization, Journal of Polymer Science Part A: Polymer Chemistry, vol.18, issue.18, pp.4040-4049, 2005.
DOI : 10.1002/pola.20891

H. Cartier and G. Hu, Morphology development ofin situ compatibilized semicrystalline polymer blends in a co-rotating twin-screw extruder, Polymer Engineering & Science, vol.37, issue.6, pp.996-1013, 1999.
DOI : 10.1002/masy.19880160103

W. Y. Su, Y. Wang, K. Min, and R. P. Quirk, In situ copolymerization and compatibilization of polyester and polystyrene blends. I. Synthesis of functionalized polystyrenes and the reactions with polyester, Polymer, vol.42, issue.12, pp.5107-5119, 2001.
DOI : 10.1016/S0032-3861(00)00776-X

M. Maric, N. Ashurov, and C. W. Macosko, Reactive blending of poly (dimethylsiloxane) with nylon 6 and poly (styrene):Effect of reactivity on morphology, Polymer Engineering & Science, vol.41, issue.4, pp.631-642, 2001.
DOI : 10.1007/978-1-4899-3533-5

Y. Seo and T. H. Ninh, Enhanced interfacial adhesion between polypropylene and nylon 6 by in situ reactive compatibilization, Polymer, vol.45, issue.25, pp.8573-8581, 2004.
DOI : 10.1016/j.polymer.2004.10.006

S. Jose, B. Francis, and S. Thomas, Morphology and mechanical properties of polyamide 12/polypropylene blends in presence and absence of reactive compatibiliser, Polymer, vol.47, issue.11, pp.3874-3888, 2006.
DOI : 10.1016/j.polymer.2006.03.046

H. K. Jeon, J. Zhang, and C. W. Macosko, Premade vs. reactively formed compatibilizers for PMMA/PS melt blends, Polymer, vol.46, issue.26, pp.12422-12429, 2005.
DOI : 10.1016/j.polymer.2005.10.125

H. K. Jeon, B. J. Feist, S. B. Koh, K. Chang, C. W. Macosko et al., Reactively formed block and graft copolymers as compatibilizers for polyamide 66/PS blends, Polymer, vol.45, issue.1, pp.197-206, 2004.
DOI : 10.1016/j.polymer.2003.10.099

X. Yu, Y. Wu, B. Li, and Y. Han, Studies on interfacial reaction kinetics and properties at a reactive compatibilization interface, Polymer, vol.46, issue.10, pp.3337-3342, 2005.
DOI : 10.1016/j.polymer.2005.02.079

G. Moad, The synthesis of polyolefin graft copolymers by reactive extrusion, Progress in Polymer Science1999, pp.81-142
DOI : 10.1016/S0079-6700(98)00017-3

G. H. Hu and H. Cartier, Reactive Extrusion:?? Toward Nanoblends, Macromolecules, vol.32, issue.14, pp.32-4713, 1999.
DOI : 10.1021/ma981924y

H. Cartier and G. H. Hu, A novel reactive extrusion process for compatibilizing immiscible polymer blends, Polymer, vol.42, issue.21, pp.8807-8816, 2001.
DOI : 10.1016/S0032-3861(01)00317-2

G. H. Hu and L. Feng, Extrusion processing for nanoblends and nanocomposites. Macromolecular symposia, pp.303-308, 2003.
DOI : 10.1002/masy.200390139

J. Teng, J. U. Otaigbe, and E. P. Taylor, Reactive blending of functionalized polypropylene and polyamide 6:In situ polymerization andin situ compatibilization, Polymer Engineering and Science, vol.267, issue.4, pp.648-659, 2004.
DOI : 10.1002/pen.20059

S. Datta and D. J. Lohse, Polymeric compatibilizers: uses and benefits in polymer blends, Hanser, 1996.

C. W. Macosko, H. K. Jeon, and T. R. Hoye, Reactions at polymer-polymer interfaces for blend compatibilization. Progress in polymer science, pp.939-947, 2005.

N. C. Tan, S. K. Tai, and R. M. Briber, Morphology control and interfacial reinforcement in reactive polystyrene/amorphous polyamide blends, Polymer, vol.37, pp.3509-3519, 1996.

H. K. Jeon and J. K. Kim, Effect of Reaction Rate on Morphological Change of Reactive Blends, Macromolecules, vol.33, issue.22, pp.8200-8210, 2000.
DOI : 10.1021/ma000842i

K. Dedecker and G. Groeninckx, Interfacial Graft Copolymer Formation during Reactive Melt Blending of Polyamide 6 and Styrene???Maleic Anhydride Copolymers, Macromolecules, vol.32, issue.8, pp.2472-2479, 1999.
DOI : 10.1021/ma980642v

B. Moon, T. R. Hoye, and C. W. Macrosko, Synthesis and application of fluorescently labeled phthalic anhydride (PA) functionalized polymers by ATRP, Polymer, vol.43, issue.20, pp.5501-5509, 2002.
DOI : 10.1016/S0032-3861(02)00406-8

B. Moon, T. R. Hoye, and C. W. Macosko, Anionic synthesis and detection of fluorescence-labeled polymers with a terminal anhydride group, Journal of Polymer Science Part A: Polymer Chemistry, vol.25, issue.12, pp.2177-2185, 2000.
DOI : 10.1021/ma00027a080

G. H. Hu, H. Li, and L. F. Feng, A Two-Step Reactive Extrusion Process for the Synthesis of Graft Copolymers with Polyamides as Grafts, Macromolecules, vol.35, issue.22, pp.8247-8250, 2002.
DOI : 10.1021/ma020641+

G. H. Hu, H. Li, and L. Feng, Rate of the activated anionic polymerisation of ??-caprolactam onto an isocyanate bearing polypropylene in the melt, Polymer, vol.46, issue.13, pp.4562-4570, 2005.
DOI : 10.1016/j.polymer.2005.03.075

URL : https://hal.archives-ouvertes.fr/hal-00068847

Y. Ji, W. Li, J. Ma, and B. Liang, A Novel Approach to the Preparation of Nanoblends of Poly(2,6-dimethyl-1,4-phenylene oxide)/Polyamide 6, Macromolecular rapid communications, pp.116-120, 2005.
DOI : 10.1002/marc.200400561

M. Matzer, D. L. Schober, and J. Mcgrath, Polystyrene-nylon 6 graft copolymers, European Polymer Journal, vol.9, issue.6, pp.469-480, 1973.
DOI : 10.1016/0014-3057(73)90030-X

D. Petit, R. Jerome, and P. Teyssie, Anionic block copolymerization of ??-caprolactam, Journal of Polymer Science: Polymer Chemistry Edition, vol.17, issue.9, pp.2903-2916, 1979.
DOI : 10.1002/pol.1979.170170926

Y. Yamashita, H. Matsui, and K. Ito, Block copolymerization. V. Block anionic polymerization of lactams, Journal of Polymer Science Part A-1: Polymer Chemistry, vol.10, issue.12, pp.3577-3587, 1972.
DOI : 10.1002/pol.1972.170101212

G. H. Hu, H. Li, and L. Feng, Follow-up of the course of the anionic ring-opening polymerization of lactams onto an isocyanate-bearing polymer backbone in the melt, Journal of Applied Polymer Science, vol.3, issue.5, pp.4394-4403, 2006.
DOI : 10.1007/978-94-009-1449-0_1

URL : https://hal.archives-ouvertes.fr/hal-00280875

J. ?ebenda, Lactam Polymerization, Journal of Macromolecular Science: Part A - Chemistry, vol.29, issue.6, pp.1145-1199, 1972.
DOI : 10.1002/app.1968.070120913

K. Udipi, R. S. Davé, R. L. Kruse, and L. R. Stebbins, Polyamides from lactams via anionic ring-opening polymerization: 1. Chemistry and some recent findings, Polymer, vol.38, issue.4, pp.927-938, 1997.
DOI : 10.1016/S0032-3861(96)00566-6

J. ?ebenda and V. Kou?il, Anionic polymerization of caprolactam???XL. Estimation of the content of active base from the rate of polymerization and from the increase of the number of polymer molecules in activated polymerization, European Polymer Journal, vol.8, issue.3, pp.437-447, 1972.
DOI : 10.1016/0014-3057(72)90108-5

J. ?ebenda and V. Kou?il, Anionic polymerization of caprolactam???XXXIX. Number of polymer molecules formed per molecule of acyl caprolactam in high-temperature polymerization, European Polymer Journal, vol.7, issue.12, pp.1637-1648, 1971.
DOI : 10.1016/0014-3057(71)90067-X

R. S. Davé, L. K. Robert, R. S. Linonel, and K. Udipi, Polyamides from lactams via anionic ring-opening polymerization: 2. Kinetics, Polymer, vol.38, issue.4, pp.939-947, 1997.
DOI : 10.1016/S0032-3861(96)00567-8

J. Marelová, J. Roda, and J. Stehlí?ek, Anionic polymerization of ??-caprolactam in the presence of symmetrically substituted ureas, European Polymer Journal, vol.35, issue.1, pp.145-155, 1999.
DOI : 10.1016/S0014-3057(98)00101-3

R. Mateva, O. Ishtinakova, R. N. Nikolov, and C. Djambova, Kinetics of polymerization of ??-caprolactam in the presence of inorganic dispersed additives, European Polymer Journal, vol.34, issue.8, pp.1061-1067, 1998.
DOI : 10.1016/S0014-3057(98)00105-0

G. H. Hu and I. Kadri, Preparation of macromolecular tracers and their use for studying the residence time distribution of polymeric systems, Polymer Engineering & Science, vol.61, issue.2, pp.299-311, 1999.
DOI : 10.3139/217.950003

H. S. Wu, M. H. Chuang, and J. W. Hwang, Kinetics and thermal analysis of copolymerization ofm-isopropenyl-?,??-dimethylbenzyl isocyanate with styrene, Journal of Applied Polymer Science, vol.1, issue.13, pp.2763-2770, 1999.
DOI : 10.1002/polc.5070010109

L. Barner, C. Barner-kowollik, and T. P. Davis, Free-radical copolymerization of styrene andm-isopropenyl-?,??-dimethylbenzyl isocyanate studied by1H NMR kinetic experiments, Journal of Polymer Science Part A: Polymer Chemistry, vol.39, issue.8, pp.1064-1074, 2002.
DOI : 10.1002/1099-0518(20010301)39:5<597::AID-POLA1030>3.0.CO;2-Q

G. H. Hu, H. Li, L. F. Feng, and L. A. Pessan, Strategies for maximizing free-radical grafting reaction yields, Journal of Applied Polymer Science, vol.35, issue.7, pp.1799-1807, 2003.
DOI : 10.1023/A:1004730822600

L. Ricco, S. Russo, G. Orefice, and F. Riva, Anionic Poly(??-caprolactam):?? Relationships among Conditions of Synthesis, Chain Regularity, Reticular Order, and Polymorphism, Macromolecules, vol.32, issue.23, pp.7726-7731, 1999.
DOI : 10.1021/ma9909004

R. Mateva, P. Petrov, S. Rousseva, R. Dimitrov, and G. Zolova, On the structure of poly--caprolactams, obtained with bifunctional N-carbamyl derivatives of lactams, European Polymer Journal, vol.36, issue.4, pp.813-821, 2000.
DOI : 10.1016/S0014-3057(99)00132-9

G. Rusu, K. Ueda, E. Rusu, and M. Rusu, Polyamides from lactams by centrifugal molding via anionic ring-opening polymerization, Polymer, vol.42, issue.13, pp.5669-5678, 2001.
DOI : 10.1016/S0032-3861(01)00059-3

G. C. Ongemach and A. C. Moody, Determination of caprolactam monomer content in nylon 6 extractables by gas chromatography, Analytical Chemistry, vol.39, issue.8, pp.1005-1006, 1967.
DOI : 10.1021/ac60252a047

F. Zilio-grandi, G. M. Sassu, and P. Callegaro, Direct determination or residual caprolactam in nylon 6 by gas chromatography, Analytical Chemistry, vol.41, issue.13, pp.1847-1849, 1969.
DOI : 10.1021/ac60282a055

E. Heberstroh, L. Jakisch, E. Henßge, and P. Schwarz, Real-Time Monitoring of Reactive Extrusion Processes by Means of In-Line Infrared Spectroscopy and Infrared Temperature Measurement, Macromolecular Materials and Engineering, vol.287, issue.3, pp.203-208, 2002.
DOI : 10.1002/1439-2054(20020301)287:3<203::AID-MAME203>3.0.CO;2-8

E. Jacobi, R. C. Schuttenberg, and R. C. Schulz, A new method for gel permeation chromatography of polyamides, Die Makromolekulare Chemie, Rapid Communications, vol.1, issue.6, p.397, 1980.
DOI : 10.1002/marc.1980.030010609

M. A. Dudley, Characterization of nylon 66 by gel permeation chromatography, Journal of Applied Polymer Science, vol.16, issue.2, pp.493-504, 1972.
DOI : 10.1002/app.1972.070160218

G. Pastuska and U. Just, Zur analyse von polyamiden. Bestimmung der molekülmassen und ihre verteilung. Angewandte Makromolekulare chemie, pp.173-184, 1982.

G. Marot and J. Lesec, Size Exclusion Chromatography of Polyamides, Journal of Liquid Chromatography, vol.11, issue.16, pp.3305-3319, 1988.
DOI : 10.1002/app.1982.070271231

R. Panaris and G. Pallas, Caracterisation des polyamides par chromatographie sur gel (GPC) en milieu hexamethylphosphorotriamide, Journal of Polymer Science Part B: Polymer Letters, vol.8, issue.6, p.441, 1970.
DOI : 10.1002/pol.1970.110080610

V. Girardon, M. Tessier, and E. Maréchal, Characterization of functional aliphatic oligoamides using N-trifluoroacetylation???II. size exclusion chromatography, European Polymer Journal, vol.34, issue.9
DOI : 10.1016/S0014-3057(97)00267-X

H. Schuttenberg and R. C. Schulz, Trifluoracetylierung von Aminen mitN-Trifluoracetyl-Nylon 66, Angewandte Chemie, vol.1952, issue.24, pp.848-849, 1976.
DOI : 10.1016/S0021-9673(73)30078-4

K. Weisskopf and G. Meyerhoff, Molecular weight determinations of polyamides by N-trifluoroacetylation, Polymer, vol.24, issue.1, pp.72-76, 1983.
DOI : 10.1016/0032-3861(83)90083-6

E. Biagini, G. Costa, E. Gattiglia, A. Imperato, and S. Russo, Gel permeation chromatographic analysis of N-trifluoroacetylated poly(??-caprolactam): Calibration procedures, Polymer, vol.28, issue.1, pp.114-118, 1987.
DOI : 10.1016/0032-3861(87)90325-9

G. Z. Li, L. F. Feng, X. P. Gu, Z. B. Xu, G. H. Hu et al., Synthesis of PSt-TMI copolymer and studies of the copolymerization kinetics, Journal of Functional Polymers, vol.18, pp.127-133, 2005.

G. H. Hu and I. Kadri, Modeling reactive blending: An experimental approach, Journal of Polymer Science Part B: Polymer Physics, vol.36, issue.12, pp.2153-2163, 1998.
DOI : 10.1002/(SICI)1099-0488(19980915)36:12<2153::AID-POLB13>3.0.CO;2-Z

G. H. Hu, I. Kadri, and C. Picot, One-line measurement of the residence time distribution in screw extruders, Polymer Engineering & Science, vol.61, issue.5, pp.930-939, 1999.
DOI : 10.3139/217.950003

J. ?ebenda, Comprehesive lactams kinetics, Elevies, vol.115, p.379, 1976.

J. Havlice, J. Bro?ek, M. ?áchová, V. Nováková, and J. Roda, Non-activated anionic polymerization of ?-caprolactam initiated with the sodium salt of ?-caprolactam. Macromolecular Chemistry and Physics, pp.1200-1207, 1999.

S. R. Shukla, A. M. Harad, and D. Mahato, Depolymerization of nylon 6 waste fibers, Journal of Applied Polymer Science, vol.86, issue.1, pp.186-190, 2006.
DOI : 10.1002/app.22775

. Abastari, T. Sakai, H. Sembokuya, M. Kubouchi, and K. Tsuda, The reciprocal influence between ion transport and degradation of PA66 in acid solution, Polymer Degradation and Stability, vol.91, issue.11, pp.2595-2604, 2006.
DOI : 10.1016/j.polymdegradstab.2006.05.018

. Abastari, T. Sakai, H. Sembokuya, M. Kubouchi, and K. Tsuda, Study on permeation behavior and chemical degradation of PA66 in acid solution, Polymer Degradation and Stability, vol.92, issue.3, pp.379-388, 2007.
DOI : 10.1016/j.polymdegradstab.2006.12.002

N. Chaupart, G. Serpe, and J. Verdu, Molecular weight distribution and mass changes during polyamide hydrolysis, Polymer, vol.39, issue.6-7, pp.1375-1380, 1998.
DOI : 10.1016/S0032-3861(97)00414-X

U. Klun and A. Kr?an, Degradation of polyamide-6 by using metal salts as catalyst. Polymers for Advanced Technologies, pp.817-822, 2002.

G. Serpe and N. Chaupart, Ageing of polyamide 11 in acid solutions, Polymer, vol.38, issue.8, pp.1911-1917, 1997.
DOI : 10.1016/S0032-3861(96)00705-7

R. S. Lehrle, I. W. Parsons, and M. P. Rollinson, Thermal degradation mechanisms of Nylon 6 deduced from kinetic studies by pyrolysis-g.c. Polymer Degradation References and Stability, pp.21-33, 2000.

Y. Zhang, K. Cheng, and J. Xu, Thermal stability studies of polyamides and their block copolymers, Thermochimica Acta, vol.425, issue.1-2, pp.137-141, 2005.
DOI : 10.1016/j.tca.2004.06.013

M. J. Oliveira and G. Botelho, Degradation of polyamide 11 in rotational moulding, Polymer Degradation and Stability, vol.93, issue.1, pp.139-146, 2008.
DOI : 10.1016/j.polymdegradstab.2007.10.004

T. D. Fornes, P. J. Yoon, and D. R. Paul, Polymer matrix degradation and color formation in melt processed nylon 6/clay nanocomposites, Polymer, vol.44, issue.24, pp.7545-7556, 2003.
DOI : 10.1016/j.polymer.2003.09.034

G. M. Russo, V. Nicolais, L. D. Maio, S. Montesano, and L. Incarnato, Rheological and mechanical properties of nylon 6 nanocomposites submitted to reprocessing with single and twin screw extruders, Polymer Degradation and Stability, vol.92, issue.10, pp.1925-1933, 2007.
DOI : 10.1016/j.polymdegradstab.2007.06.010

J. Martinez-salazar and C. G. Cannon, Transmission electron microscopy of polyamides, Journal of Materials Science Letters, vol.16, issue.8, pp.693-694, 1984.
DOI : 10.1007/BF00719925

D. Forsström and B. Terselius, Thermo oxidative stability of polyamide 6 films I. Mechanical and chemical characterization. Polymer Degradation and stability, pp.69-78, 2000.

M. Guaita, O. Chiantore, and M. P. Luda, Monte Carlo simulations of polymer degradations. 1. Degradations without volatilization, Macromolecules, vol.23, issue.7, pp.2087-2092, 1990.
DOI : 10.1021/ma00209a035

E. S. Gonçalves, L. Poulsen, and P. Ogilby, Mechanism of the temperature-dependent degradation of polyamide 66 films exposed to water, Polymer Degradation and Stability, vol.92, issue.11, pp.1977-1985, 2007.
DOI : 10.1016/j.polymdegradstab.2007.08.007

D. Gersappe, P. K. Harm, D. Irvine, and A. C. Balazs, Contrasting the compatibilizing activity of comb and linear copolymers, Macromolecules, vol.27, issue.3, pp.720-724, 1994.
DOI : 10.1021/ma00081a015

Y. Zhu, Z. Ma, Y. Li, J. Cui, and W. Jiang, Monte Carlo simulation of the compatibility of graft copolymer compatibilized two incompatible homopolymer blends: Effect of graft structure, Journal of Applied Polymer Science, vol.21, issue.3, pp.1591-1596, 2007.
DOI : 10.1007/978-3-662-08854-8

R. Asaletha, S. Thomas, and M. Kumaran, -Polystyrene, Rubber Chemistry and Technology, vol.68, issue.4, p.671, 1995.
DOI : 10.5254/1.3538766

H. Feng, C. Ye, J. Tian, Z. Feng, and B. Huang, Compatibilization effect of graft copolymer on immiscible polymer blends: 1. LLDPE/SBS/LLDPE-g-PS systems, Polymer, vol.39, issue.10, pp.1787-1792, 1998.
DOI : 10.1016/S0032-3861(97)00269-3

R. C. Willemse, A. P. Boer, J. V. Dam, and A. D. Gotsis, Co-continuous morphologies in polymer blends: the influence of the interfacial tension, Polymer, vol.40, issue.4, p.827, 1999.
DOI : 10.1016/S0032-3861(98)00307-3

P. A. Bhadane, M. F. Champagne, M. A. Huneault, F. Tofan, and B. Favis, Continuity development in polymer blends of very low interfacial tension, Polymer, vol.47, issue.8, pp.2760-2771, 2006.
DOI : 10.1016/j.polymer.2006.01.065

J. Li, P. L. Ma, and B. D. Favis, The Role of the Blend Interface Type on Morphology in Cocontinuous Polymer Blends, Macromolecules, vol.35, issue.6, pp.2005-2016, 2002.
DOI : 10.1021/ma010104+

P. Sarazin and B. Favis, Influence of temperature-induced coalescence effects on co-continuous morphology in poly(??-caprolactone)/polystyrene blends, Polymer, vol.46, issue.16, pp.5966-5978, 2005.
DOI : 10.1016/j.polymer.2005.04.064

H. Pernot, M. Baumert, F. Court, and L. Leibler, Design and properties of co-continuous nanostructured polymers by reactive blending, Nature Materials, vol.1, issue.1, pp.54-58, 2002.
DOI : 10.1038/nmat711

N. Bhanu, L. D. Kandpal, and G. N. Mathur, Poly(ether ether Ketone)/poly(aryl ether sulfone) blends: Relationships between morphology and mechanical properties, Journal of Applied Polymer Science, vol.90, pp.2887-2905, 2003.

C. H. Arns, M. A. Knackstedt, A. P. Roberts, and V. W. Pinczewski, Morphology, Cocontinuity, and Conductive Properties of Anisotropic Polymer Blends, Macromolecules, vol.32, issue.18, p.5964, 1999.
DOI : 10.1021/ma981476u

O. Meincke, D. Kaempfer, H. Weickmann, C. Friedrich, M. Vathauer et al., Mechanical properties and electrical conductivity of carbon-nanotube filled polyamide-6 and its blends with acrylonitrile/butadiene/styrene, Polymer, vol.45, issue.3, pp.739-748, 2004.
DOI : 10.1016/j.polymer.2003.12.013

Y. Li and S. Hiroshi, Co-continuous Polyamide 6 (PA6)/Acrylonitrile-Butadiene-Styrene (ABS) Nanocomposites, Macromolecular Rapid Communications, vol.42, issue.9, pp.710-715, 2005.
DOI : 10.1080/00222358008080917

J. K. Lee and C. Han, Evolution of a dispersed morphology from a co-continuous morphology in immiscible polymer blends, Polymer, vol.40, issue.10, pp.2521-2536, 1999.
DOI : 10.1016/S0032-3861(98)00496-0

R. C. Willemse, Co-continuous morphologies in polymer blends: stability, Polymer, vol.40, issue.8, pp.2175-2178, 1999.
DOI : 10.1016/S0032-3861(98)00430-3

N. Mekhilef, B. D. Favis, and P. J. Carreau, Morphological stability, interfacial tension, and dual-phase continuity in polystyrene-polyethylene blends, Journal of Polymer Science Part B: Polymer Physics, vol.35, issue.2, pp.293-308, 1997.
DOI : 10.1002/(SICI)1099-0488(19970130)35:2<293::AID-POLB7>3.0.CO;2-T

Z. Yuan and B. D. Favis, Coarsening of immiscible co-continuous blends during quiescent annealing, AIChE Journal, vol.38, issue.1, pp.271-280, 2005.
DOI : 10.1098/rspa.1935.0104

Z. Yuan and B. D. Favis, Influence of the efficacy of interfacial modification on the coarsening of cocontinuous PS/HDPE blends during quiescent annealing, Journal of Polymer Science Part B: Polymer Physics, vol.74, issue.4
DOI : 10.1103/PhysRevA.20.595

K. Dedecher and G. Groeninchx, Reactive compatibilisation of A/(B/C) polymer blends. Part 2. Analysis of the phase inversion region and the co-continuous phase morphology, Polymer, vol.39, issue.21, pp.4993-5000, 1998.
DOI : 10.1016/S0032-3861(97)10089-1

C. Z. Chuai, K. Almdal, and J. Lyngaae-jørgensen, Phase continuity and inversion in polystyrene/poly(methyl methacrylate) blends. Polymer, pp.481-493, 2003.

J. A. Galloway, H. K. Jeon, J. R. Bell, and C. W. Macosko, Block copolymer compatibilization of cocontinuous polymer blends, Polymer, vol.46, issue.1, pp.183-191, 2005.
DOI : 10.1016/j.polymer.2004.10.061

C. Harrats, S. Blacher, R. Fayt, and R. Jérôme, Molecular design of multicomponent polymer systems XIX: Stability of cocontinuous phase morphologies in low-density polyethylene???polystyrene blends emulsified by block copolymers, Journal of Polymer Science Part B: Polymer Physics, vol.33, issue.5, pp.801-811, 1995.
DOI : 10.1002/polb.1995.090330509

C. Harrats, R. Fayt, R. Jérôme, and S. Blacher, Stabilization of a cocontinuous phase morphology by a tapered diblock or triblock copolymer in polystyrene-rich low-density polyethylene/polystyrene blends, Journal of Polymer Science Part B: Polymer Physics, vol.39, issue.2, pp.202-216, 2003.
DOI : 10.1002/pen.11566

I. Vinckier and H. M. Laun, Assessment of the Doi???Ohta theory for co-continuous blends under oscillatory flow, Journal of Rheology, vol.45, issue.6, pp.1373-1385, 2001.
DOI : 10.1122/1.1410373

S. H. Jafari, P. Pötschke, M. Stephan, H. Warth, and H. Alberts, Multicomponent blends based on polyamide 6 and styrenic polymers: morphology and melt rheology, Polymer, vol.43, issue.25, pp.6985-6992, 2002.
DOI : 10.1016/S0032-3861(02)00614-6

R. C. Willemse, A. P. Boer, J. V. Dam, and A. D. Gotsis, Co-continuous morphologies in polymer blends: a new model, Polymer, vol.39, issue.24, pp.5879-5887, 1998.
DOI : 10.1016/S0032-3861(97)10200-2

J. Noolandi and M. K. Hong, Interfacial properties of immiscible homopolymer blends in the presence of block copolymers, Macromolecules, vol.15, issue.2, pp.482-492, 1982.
DOI : 10.1021/ma00230a054

J. Noolandi and K. M. Hong, Effect of block copolymers at a demixed homopolymer interface, Macromolecules, vol.17, issue.8, pp.1531-1537, 1984.
DOI : 10.1021/ma00138a019

K. H. Kim and W. Jo, Effect of chain architecture of graft copolymer on the structure of adsorbed layer: a Monte Carlo simulation approach, Polymer, vol.42, issue.7, pp.3205-3211, 2001.
DOI : 10.1016/S0032-3861(00)00728-X

S. Cimmino, F. Coppola, L. Orazio, R. Greco, G. Maglio et al., Ternary nylon-6/rubber/modified rubber blends: Effect of the mixing procedure on morphology, mechanical and impact properties, Polymer, vol.27, issue.12, pp.1874-1884, 1986.
DOI : 10.1016/0032-3861(86)90175-8

J. M. Willis and B. Favis, Processing-morphology relationships of compatibilized polyolefin/polyamide blends. Part I: The effect of an lonomer compatibilizer on blend morphology, Polymer Engineering and Science, vol.1, issue.21, pp.1416-1426, 1988.
DOI : 10.1002/pol.1986.140240105

J. D. Lee and S. M. Yang, Effects of mixing porcedures on properties of compatibilized polypropylene/nylon 6 blends, Polymer Engineering and Science, vol.26, issue.23, pp.1821-1833, 1995.
DOI : 10.1002/pen.760352302

G. H. Hu, Y. J. Sun, and M. Lambla, Devolatilization: A critical sequential operation forin situ compatibilization of immiscible polymer blends by one-step reactive extrusion, Polymer Engineering & Science, vol.57, issue.5, pp.676-684, 1996.
DOI : 10.1002/pen.10455

Y. J. Sun, G. H. Hu, M. Lambla, and H. K. Kotlar, In situ compatibilization of polypropylene and poly(butylene terephthalate) polymer blends by one-step reactive extrusion, Polymer, vol.37, issue.18, pp.4119-4127, 1996.
DOI : 10.1016/0032-3861(96)00229-7

H. Li and G. H. Hu, The early stage of the morphology development of immiscible polymer blends during melt blending: Compatibilized vs. uncompatibilized blends, Journal of Polymer Science Part B: Polymer Physics, vol.30, issue.5, pp.601-610, 2001.
DOI : 10.1002/1099-0488(20010301)39:5<601::AID-POLB1034>3.0.CO;2-V

D. Wolf and D. White, Experimental study of the residence time distribution in plasticating screw extruders, AIChE Journal, vol.22, issue.1, pp.122-131, 1976.
DOI : 10.1002/aic.690220115

L. Chen, Z. Pan, and G. H. Hu, Residence time distribution in screw extruders, AIChE Journal, vol.8, issue.9, pp.1455-1464, 1993.
DOI : 10.1016/0260-8774(88)90058-1

E. B. Nauman and B. A. Buffham, Mixing in continuous flow system, 1983.

E. Unlu and J. Faller, Geometric mean vs. Arithmetic mean in extrusion residence time studies, Polymer Engineering & Science, vol.63, issue.5, pp.743-751, 2001.
DOI : 10.1002/pen.10770

J. Gao, G. C. Walsh, D. Bigio, R. M. Briber, and M. D. Wetzel, Residence-time distribution model for twin-screw extruders, AIChE Journal, vol.22, issue.12, pp.2541-2549, 1999.
DOI : 10.3139/217.950111

O. S. Carneiro, J. A. Covas, J. A. Ferreira, and M. F. Cerqueira, On-line monitoring of the residence time distribution along a kneading block of a twin-screw extruder, Polymer Testing, vol.23, issue.8, pp.925-937, 2004.
DOI : 10.1016/j.polymertesting.2004.05.001

X. M. Zhang, Z. B. Xu, L. F. Feng, X. B. Song, and G. H. Hu, Assessing local residence time distributions in screw extruders through a new in-line measurement instrument, Polymer Engineering & Science, vol.43, issue.4, pp.510-519, 2006.
DOI : 10.3139/217.1842

URL : https://hal.archives-ouvertes.fr/hal-00281188

X. M. Zhang, L. F. Feng, S. Hoppe, and G. H. Hu, Local residence time, residence revolution, and residence volume distributions in twin-screw extruders, Polymer Engineering & Science, vol.43, issue.1, pp.19-28, 2008.
DOI : 10.3139/217.1664