T. M. Allen, E. M. Mccauley, P. 8. Kelly, and A. D. Jones, Negative ion laser desorption ionization time-of-flight mass spectrometry of nitrated Polycyclic Aromatic Hydrocarbons, Chapitre III: Etude des HAP et des composés hétérocycliques aromatiques par FTICRMS Références du chapitre III fBezabeh, pp.630-636, 1997.

A. D. Jones, L. L. Ashbaugh, and P. Kelly, Screening of aerosol filter samples for PAHs and nitro-PAHs by laser desorption ionization TOF mass spectrometry, Aerosol Science & Technology, vol.8, issue.30, pp.288-299, 1999.

*. Bjarnason, A. Reactions, *. Sc, *. Ti, V. *. et al., Con, and Ni* with 1- fluoronaphthalene in the gas phase. Metal-catalyzed oligomer formation and observation of unusual ring fragmentation, Rapid, Comm. Mass Spectrom, issue.8, pp.366-403, 1994.

P. Boisson, M. Decouzon, J. F. Gal, P. C. Maria, and A. Pagliardini, Volatile and semivolatile organic compound analysis using Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry, pp.441-447, 1995.

P. Boisson, Applications analytiques de la spectrométrie de masse FT- ICR : diagnostics de sols pollués, Thèse de l'Université de Nice- Sophia Antipohs, 1998.

R. Brown, Compound Types in Gasoline by Mass Spectrometer Analysis, Analytical Chemistry, vol.23, issue.3, pp.430-437, 1951.
DOI : 10.1021/ac60051a012

H. Budzkiewicz, T. Cvitas, S. Rkazazic, L. Klasinc, and D. Srzic, Gas phase reaction rate measurements in Fourier transform mass spectrometry, Rapid Communications in Mass Spectrometry, vol.84, issue.12, 1999.
DOI : 10.1021/j100458a012

M. T. Butterfield, R. A. Agbaria, and I. M. Warner, Extraction of Volatil PAHS from air by use of solid cyclodextrin, Anal. Chem, issue.68, 1993.

M. J. Dale, A. C. Jones, S. J. Pollard, P. R. Langridge-smith, and A. G. Rowley, Application of two-step laser mass spectrometry to the analysis of polynuclear aromatic hydrocarbons in contaminated soils, Environmental Science & Technology, vol.27, issue.8, pp.693-694, 1993.
DOI : 10.1021/es00045a029

M. J. Dale, A. C. Jones, S. J. Pollard, and P. R. Langridge-smith, Direct determination of polycyclic aromatic hydrocarbons in environmental matrices using laser desorption laser photoionization time-of-flight mass spectrometry, The Analyst, vol.119, issue.4, pp.1-57
DOI : 10.1039/an9941900571

, Chapitre III: Etude des IIAP et des composés hétérocycliques aromatiques par FTICRMS [Dale, 1995.

M. J. Dale, O. H. Downs, K. F. Costello, S. J. Wright, P. R. Langridge-smith et al., Direct analysis of Polycyclic Aromatic Hydrocarbons in cloud after aerosol filtrates using laser desorption mass spectrometry, Environmental P ollution, pp.123-129

P. Deparseval, Analyse par spectrométrie de masse de la photofragmentation d'ions aromatiques isolés dans un piège. Applications en astrophysique et en chimie analytique, Thèse de l, pp.26-7997

S. Delmas, Caractérisation organique et minérale des particules individuelles de I'environnement sidérurgique. Etude des synergies entre la matière organique et la nature des espèces minérales des particules, Thèse de l, 1991.

L. Dotter, R. N. Dotter, C. H. Smith, M. K. Young, P. 8. Kelly et al., Laser desorption/ionization time-offlight mass spectrometry of nitrated Polycyclic Aromatic Hydrocarbons, Anal. Chem, issue.68, pp.2319-2324, 1996.

N. 8. Elliot, T. T. Ndou, A. J. Prenni, and I. M. Warner, Size-exclusion extraction of PAH from a microemulsion system using cyclodextrins, Colloid Interface Sci, issue.159, pp.359-364, 1993.

F. H. Field and S. H. Hastings, Determination of Unsaturated Hydrocarbons by Low Voltage Mass Spectrometry, Analytical Chemistry, vol.28, issue.8, pp.1248-1255, 1956.
DOI : 10.1021/ac60116a005

S. Guan, A. G. Marshall, and S. Scheppele, Resolution and Chemical Formula Identification of Aromatic Hydrocarbons and Aromatic Compounds Containing Sulfur, Nitrogen, or Oxygen in Petroleum Distillates and Refinery Streams, Analytical Chemistry, vol.68, issue.1, pp.46-71, 1996.
DOI : 10.1021/ac9507855

. Haefliger, O. P. Haefliger, and R. Zenobi, Laser Mass Spectrometric Analysis of Polycyclic Aromatic Hydrocarbons with Wide Wavelength Range Laser Multiphoton Ionization Spectroscopy, Analytical Chemistry, vol.70, issue.13, pp.2660-2265, 1998.
DOI : 10.1021/ac971264f

O. P. Haefliger, R. Zenobi, O. P. Haefliger, T. D. Buchetli, and R. Zenobi, New sample preparation for quantitative laser desorption mass spectrometry and optical spectroscopy, Rev. Sc. Inst Time resolved identification of aerosol emission source using organic tracers, Oral communication, The dh European Meeting on Mass Spectrometry in Occupational and Environmental H ealth, p.173, 1828.
DOI : 10.1063/1.1148849

, Chapitre III: Etude des HAP et des composés hétérocycliques aromatiques par FTICRMS [Hsu, 1994.

, Analysis of complex mixtures of aromatic compounds by high resolution mass spectrometry at low ionizing voltages, fJohnson Anal. Chem, issue.39, pp.682-685, 1967.

S. M. Hankin, P. John, A. W. Simpson, and G. P. Smith, Spatially resolved time-oÊflight mass spectrometry of Polycyclic Aromatic Hydrocarbons: Quantification studies, Anal. Chem, issue.68, pp.3238-3243, 1996.

S. M. Hankin, P. John, and G. P. Smith, Laser Time-of-Flight Mass Spectrometry of PAH???Picrate Complexes, Analytical Chemistry, vol.69, issue.15, pp.2927-2930, 1997.
DOI : 10.1021/ac970222o

S. H. Hastings, J. 8. Lumpkin, and H. , Analysis of Aromatic Fraction of Virgin Gas Oils by Mass Spectrometer, Analytical Chemistry, vol.28, issue.8, pp.243-1247, 1956.
DOI : 10.1021/ac60116a004

C. S. Hsu, . Liang-2, and J. Campana, Hydrocarbon characterizationby ultrahigh resolution Fourier transform ion cyclotron resonance mass spectrometry, Anal. Chem, vol.8, issue.466

C. Joblin, C. Masselon, P. Boissel, P. Parseval, S. Martinovic et al., Simulation of interstellar aromatic hydrocarbons using ion cyclotron resonance. Preliminary results, Rapid Comm, Mass Spectrom, pp.1619-1623, 1997.

J. Co-boissel, P. Deparseval, and P. , Polycyclic Aromatic Hydrocarbon lifetime in cometary environments, Planetary and Space Science A mass scale based on CHz:14.000 for high resolution mass spectrometry of organic compoturds, Anal. Chem, vol.8, issue.36, pp.2146-2154, 1963.

, Identification of compound types in a heavy petroleum gas oil, Anal. Chem, issue.26, pp.1719-1722, 1954.

H. Lumpkin, Analysis of a Trinuclear Aromatic Petroleum Fraction by High Resolution Mass Spectrometry., Analytical Chemistry, vol.36, issue.13, pp.2399-240, 1964.
DOI : 10.1021/ac60219a006

P. Marty, P. Deparseval, A. Klotz, B. Chaudret, G. Serra et al., Gas phase formation and reactivity of iron naphthylene cations: a route for polycyclic aromatic hydrocarbon growth, Chemical Physics Letters, vol.256, issue.6, pp.669-67, 1996.
DOI : 10.1016/0009-2614(96)00501-5

, chapitre IV : Etude des HAP et des alkytdibenzothiophènes par Gç4IyS fBurrows, 1995.

I. Références-du-chapitre, . Brodbelt, J. Brodbelt, C. Liou, and T. Donovan, Selective adduct formation by dimethylether chemical ionization in a quadrupole ion trap mass spectrorneter and a conventional ion source, Anal. Chem, issue.63, pp.205-1209, 1991.

E. P. Burrows, Dimethyl ether and dimethyl-do ether chemical ionization mass spectrometry of Polynuclear Aromatic Hydrocarbons, J. Mass Spectrom, issue.30, pp.312-318, 1995.

H. Campbell, R. G. Cooks, K. Jr, and R. , Théorie génêral de l'équation de Mathieu et de quelques autrei équations differentielles de la mécanique Quadruple ion trap mass spectrometry, Acc. Chem. Res, issue.23, pp.213-215, 1955.

F. Krokos, K. E. O-'neill, M. J. Smith, and . G. Mcdowell-p, Selective chemical ionization of nitrogen and sulfur heterocycles in petroleum fractions by ion trap mass spectrometry, 19761.

. Spectrom, , pp.322-326, 1993.

P. H. Dawson, Quadrupole Mass Spectrometry and Its Applications

. F. Huntrd, Progress in Analytical Chemistry: Applications of New techniques of analysis, 1973.

E. P. Hunter and S. G. Lias, Proton affinities evaluation" in NIST chemistry webbook, NIST Standard reference database Number 69, p.20899, 1988.

, Dimethyl ether as a reagent gas for organic functional group"determination by chemical ionization mass spectrometry, Anal. Chem, issue.54, pp.2540-2547, 1982.

D. C. Lane and M. Mcguire, Gas phase electrophilic aromatic reactions with methylene chloride positive ions, org. Mass spectrom, pp.494-495, 1983.

, ;"i3ii"i'i'"-"riJ",'#i'Jihiï[iil

S. Spec, . Pubt, . Us-government-printing-office, and D. C. Washington, , p.731, 1979.

R. March and R. Hughes, Quadrupole storage mass spectrometry, Analytica Chimica Acta, vol.243, 1989.
DOI : 10.1016/S0003-2670(00)82582-9

, chapitre rv : Etude des IrAP et des alkyldibenzothiophènes par GC/ITMS, 1995.

R. E. March and J. F. Todd, Practical aspects of ion trap mass spectrometry, 1995.

R. March, An Introduction to Quadrupole Ion Trap Mass Spectrometry, Journal of Mass Spectrometry, vol.32, issue.4, pp.35-369, 1997.
DOI : 10.1002/(SICI)1096-9888(199704)32:4<351::AID-JMS512>3.0.CO;2-Y

R. 8. March, Quadrupole ion trap mass spectrometry : Theory, simulation, recent developments and applications, Rapid Com, Mass Spectrom, issue.12, 1998.
DOI : 10.1002/0471717983

E. Mathieu and . Rj, Math. Pure AppL, issue.13, 1868.

A. Milliet, M. F. Renou-gonnord, and K. Pointet, Ionisation chimique d'Hydrocarbures Aromatiques Polycycliques (HAP) par le diméthylsulfure, C. R. Acad. Sci. Paris Série II b, pp.347-352, 1996.

G. Moneti, G. Pieraccini, F. R. Dani, S. Catinella, and . Traldi-p, Acetonitrile as an effective reactant species for positive-ion chemical ionization of hydrocarbons by ion-trap mass spectrometry, Rapid Com, Mass Spectrom, issue.10, pp.167-70, 1996.

G. Moneti, G. Pieraccini, F. R. Dani, S. Turillazzi, D. Favretto et al., Ion-molecule reactions of ionic species from acetonitrile with unsaturated hydrocarbons for the identification of the double-bond position using an ion trap, Journal of Mass Spectrometry, vol.32, issue.12, pp.37-373, 1997.
DOI : 10.1002/(SICI)1096-9888(199712)32:12<1371::AID-JMS588>3.0.CO;2-E

G. Moneti, G. Pieraccini, D. Favretto, and . Traldi-p, Acetonitrile in chemical ionization of monosatured hydrocarbons : A l3C and 2H labeling study, J. Mass Spectrom, issue.33, pp.48-52, 1998.

M. 4. Cullen, W. R. Eigendorf, and G. K. , Ion-molecule reactions of halocarbon cations with Polycyclic Aromatic Hydrocarbons in a quadrupole ion frap. Part l-Differentiation of structural isomers, J. Mass Spectrom, vol.32, pp.864-87, 1997.

M. 4. Cullen, W. R. Eigendorf, and G. K. , Ion-molecule reactions of halocarbon cations with Polycyclic Aromatic Hydrocarbons in a quadrupole ion trap. Part Il-Applications to environmental analysis, -[ Mass Spectrom, pp.250-263, 1998.

W. R. Cullen and G. K. Eigendorf, Ion-molecule reactions of perfluorotributylamine (FC43) cations with polycyclic aromatic hydrocarbons in a quadrupole ion trap, Int. J. Mass Spectrom, issue.190, pp.9-207, 1999.

S. Môssner and S. A. Wise, Determination of Polycyclic Aromatic Sulfur Heterocycles in Fossil Fuel-Related Samples, Analytical Chemistry, vol.71, issue.1, pp.58-69, 1999.
DOI : 10.1021/ac980664f

I. Chapitre, I. Etude-des, G. Môssner, S. Môssner, M. J. Lopez-de-alda et al., Gas chromatographic retention behavior of polycyclic aromatic sulfur heterocyclic compounds, (dibenzothiophene, naphthoIb]thiophenes, benzo[b]naphthothiophenes and alkylsubstitued derivatives) on stationary phases of different selectivity, J. of Chromatographia A, issue.841, pp.207-228, 1999.

D. Cooks and R. G. , Aspects of recent developments in ion trap mass spectrometry, Anal. Chim. Acta, issue.228, p.22, 1990.

K. Trouk-pointet, A. Mitliet, and M. F. Renou-gonnord, Mass spectrometric and theoritical determination of polynuclear aromatic hydrocarbon proton af{inities, J. Mass. Spectrom, issue.32, pp.1495-504, 1995.
DOI : 10.1002/jms.1190301016

K. Pointet, Nouveaux modes d'ionisation chimique pour la détection d'HAP par GCAvIS: Application à des mesures d'environnements, Thèse de l', 1997.

. Pointet, K. Pointet, . Miltiet-4, S. Hoyau, and M. F. Renou-gonnord, Proton affinities of polybenzenoid aromatic hydrocarbons and those with five-membered rings, Journal of Computational Chemistry, vol.322, issue.5, pp.629-637, 1997.
DOI : 10.1002/jcc.540150406

I. Rp-o, I e e7 ct ffii1rh#t'#: tilÏî"i' ".'Î,i"ii'*#;k i:li:i:'T:' ","*,k hydrocarbons by chemical ionization with diethylether, tetrahydrofuran and dimethylcarbonate, Eur. Mass Spectrom, issue.3, pp.281-290, 1997.

. M. Pyle-s and L. D. Betowski, Marcus 4.8., Winnick w., Analysis of Polycyclic Aromatic Hydrocarbons by ion trap tandem mass spectrometry, J. Am. Soc. Mass Spectrom, issue.8, pp.183-190, 1997.

K. , Riahi Iio Sellier N., Separation of isomeric polycyclic aromatic hydrocarbons by GC-MS : Differentiation between isomers by positive chemical ionization with ammonia and dimethyl ether as reagent gases' Chromatographia, pp.309-312, 1998.

. Roussis, S. G. Roussis, and J. W. Fedora, Determination of alkenes in hydrocarbon matrices by acetone chemical ionization mass specttometry, Anal. Chem, vol.1, issue.69, pp.550-551, 1997.

R. Srinivas, A. R. Devi, and G. K. Viswanadha-rao, Tetramethylsilane chemical ionization mass spechometry of mono-substituted aromatic compounds : Gas-phase trimethylsilylation, Rapid Comm' Mass Spectrom, pp.2-3, 1996.

G. C. Stafford, P. E. Kelley, J. E. Syka, W. E. Reynolds, T. J. Traldi et al., Int. J. Mass Spectrom. Ion Proces's', issue.60, pp.85-222, 1934.

J. F. Todd, Ion trap mass spectrometer, Mass Spectrometry Reviews, issue.10, pp.3-53, 1991.

J. F. Todd and A. D. Penman, The recent evolution of the quadrupole ion trap mass spectrometer???an overview, International Journal of Mass Spectrometry and Ion Processes, vol.106, issue.106, p.20, 1991.
DOI : 10.1016/0168-1176(91)85009-B

, AI\NEXE II Formulaire et constantes physiques

I. Mills, C. T. Homann, K. Kallay, N. Kuchitsu, and K. , Quantitieso Units and Symbols in Physical Chemistry, Constantes physiques fondamentales, 1993.

, Constante de Planck : hx6.626075 5(40). I 0-34 J's

. Vitesse-de-la-lumière-dans-le-vide, 108 m/s Charge élémentair e : exl, pp.2-99792458

. Unité-de-masse-atomique, , pp.1-1

, Constante Pi : ae=3, p.14159265359

. Constante-de-boltzmann, k-1.380662.10-23 JtK Conversions d'unités : r Energie/longueur d'onde/nombre d'onde : 1r 'n 1239, p.841

. E=hv=-'^-e-(-e\lae,

, E(eV) x 1

, r Conversion d'unités de pression

*. Torr, 3 Pa Bar: 10s Pa Afin: 101 325 Pa Densité et masse molaire de solvants : Klo o Klo .#, p666:1.3r8 2gtrnl Ma;ç51q=84.93, pshls:I.48 g/ml M"61o, pp.19-38

S. Llv and /. Visible,

T. Io-lumière-incidente-lo-a-=-logt and =. ,