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. Le-diagramme-ni0-al2ü3, présente un spinelle pour une composition de 50 %mol. de Niü. Les solubilités mutuelles des deux oxydes sont très faibles. Le diagramme binaire Al203-Fe203 (fig 4) sous une pression partielle d'oxygène de 0,2 atm présente à basse température un large domaine biphasé hématite+corindon et de part et d'autre une faible solubilité de Al2Ü3 dans Fe203 et vice versa (environ 10%masse) Les températures de fusion sont

. Le-diagramme-al-fe, fig 6) montre une grande solubilité de l'aluminium dans le fer (18at%) à basse température alors que la solubilité du fer dans l'aluminium est quasi nulle. Entre ces deux domaines de solution solide existent plusieurs composés intermétalliques fer-aluminium, pp.2-5

. Le-diagramme-binaire-fe-cr, Entre les deux, centré sur la composition 45%at. et en dessous de 830°C existe le domaine de la phase cr (quadratique) et d'une lacune de miscibilité. Cette phase cr se décompose par une réaction eutectoïde en dessous de 475°C pour former un domaine biphasé a-Fe+a-Cr. A plus haute température existe un large domaine a-Fe,Cr. Enfin, jusqu'à une -197- Annexes composition de 13%at existe un domaine y-Fe, L'évolution du paramètre cristallin des solutions solides Fe-Cr montre un écart positif à la loi de V égard jusqu'à des teneurs en chrome de 45%at, pp.9-15

. Au-dessus-de-400°c-le-diagramme-fe-ni, fig 8) présente une large région biphasée a+y du coté pauvre en nickel Du coté riche en nickel il existe un très large domaine y-(Fe,Ni) Le diagramme présente un point tricritique pour T=460°C et x= 48 %at. Ni en dessous duquel coexistent les phases y' (paramagnétique) et

. Ni, y-Ni Uusqu'à 6 %at. Fe) et FeNi, Fe3Ni et FeNi3

. Ci-diminue, La variation du paramètre est linéaire avec la teneur en nickel pour les alliages a-FeNi

. Le-diagramme-de-phase-al-cr, fig 9) montre un large domaine de solubilité de l'aluminium dans le chrome (25%at) à basse température alors que la solubilité du chrome dans l'aluminium est très faible (<0,1 %at) Entre ces domaines coexistent plusieurs composés intermétalliques

C. Les-alliages-fe, Ni ont une structure dépendant fortement de la teneur en éléments alphagène (Cr) et gammagène (Ni) Ainsi, le diagramme de Maurer-Scherrer définit différents domaines dans le graphe %Ni=f(%Cr) au sein desquels on peut avoir soit des alliages monophasés (y) soit des alliages biphasés (a+y, a'+y, a+a') avec a' phase martensitique

. Fe-cr, Ni présente en plus des phases a et y une phase cr dans la région comprise vers 45 %atCr et 10 %at

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G. , L. Caër, F. Wolf, D. France, D. Osso et al., Osso M echanosynthesis of nanocrystalline alumina-metal composites EMRS 1992 Fall Meeting-The 3rd European East-West Conference & Exhibition on Materials and Processe~, 3-6 NovembreMatteazzi Synthesis of alumina-metal nanocomposites by mechanical alloying Euromat 93, The 3rd European Conference on Advanced Materials and Processes Mécanosynthèse de composés et de composites nanocristallins 36° Colloque de Métallurgie INSTN 22-23 juin.Mocellin Synthesis of alumina-metal nanocomposites by mechanical alloying Nanos 94, International Workshop on Nanomaterials, pp.22-24, 1992.

P. Matteazzi, M. D. Alcalà, D. Basset, D. Osso, G. Le-caër et al., Mocellin Alumina-based nanocennets obtained by reactive milling and hot isostatic pressing Powder Metallurgy World Congress & Exhibition 6-9 juinMocellin Alumina-metal nanocennets by mechanosynthesis World Ceramic Congress 3th CIMTEC, 28 juin-4 juilletMatteazzi Nanocomposites alumine-métal : élaboration et microstructure Journées d'Automne de la SF2M, 18-20 octobreMocellin Mécanosynthèse de poudres nanocomposites aluminejer: perspective Science et Technologie des Poudres, .Tillement Phase transfomzations induced by hall milling in some alloys and in some oxides Discussion Metting on Non-Linear Phenomena in Material Science III, pp.22-24, 1994.

D. Osso, G. Le-caër, S. Begin-colin, A. Mocellin, and P. , Matteazzi Synthesis of alumina-metal nanocomposites by mechanical alloying, J. de Phys. IV, vol.3, pp.7-1407, 1993.

P. Matteazzi, M. D. Alcalà, D. Basset, D. Osso, G. Le-caër et al., Mocellin Alumina-based nanocermets obtained by reactive milling and hot isostatic pressing Annexes PM'94, Congrès Mondial de Métallurgie des PoudresMocellin Alumina-metal nanocermets by mechanosynthesis Proceeding of the gth CIMTEC, Les éditions de Physique, 1994.

D. Osso, O. Tillement, A. Mocellin, G. Le-caër, O. Babushkin et al., Lindback Mechanical thermal synthesis of AZ203-Cr composite powders J

N. Institut and . Polytechnique-de-lorraine, autorise: Monsieur OSSO Dominique à soutenir devant lElaboration de nanocomposites alumine-métal (Fe, Cr, Ni) par mécanosynthèse