A. Volta and A. Galvani, « selected papers on animal electricity » in Nuova memoria

&. Sull, Divisa in tre lettere diretta al signor Abate Anton Maria Vassali, proffessore di fisica nella R. Université Torino. Ed. by Institute for experimental medicine of Russia, p.1794

J. C. Peltier, Nouvelles expériences sur la caloricité des courants électriques

. Chem, , vol.87, p.1834

W. Thomson, On mechanical theory of thermoelectric currents, Proceeding of the

, Royal Society of Edinburgh, p.91, 1851.

S. R. De-groot and P. Mazur, Non-Equilibrium Thermodynamics, Holl. Pblishing Co. Amst, vol.66, issue.10, pp.883-884, 1962.

I. Prigogine, Introduction à la thermodynamique des processus irréversibles, 2000.

L. Onsager, Reciprocal Relations in Irreversible Processes. I, Phys. Rev, vol.37, issue.4, pp.405-426, 1931.

D. M. Rowe, CRC Handbook of Thermoelectrics, 1995.

G. J. Snyder and T. S. Ursell, Thermoelectric Efficiency and Compatibility, Phys. Rev

. Lett, , vol.91, 2003.

H. J. Goldsmid, Theory of Thermoelectric Refrigeration and Generation, Introduction to Thermoelectricity, vol.121, pp.9-24, 2016.

B. Lenoir, Thermoélectricité : des principes aux applications', Transport, 1990.

A. G. Slack and ;. Rowe, New material and performance limits for thermoelectric cooling, CRC Handbook of Thermoelectrics, p.407, 1995.

H. J. Goldsmid, Thermoelectric Refrigeration, 1964.

L. W. Whitlow and T. Hirano, Superlattice applications to thermoelectricity, J. Appl. Phys, vol.78, issue.9, pp.5460-5466, 1995.

H. J. Goldsmid and R. W. Douglas, The use of semiconductors in thermoelectric refrigeration, Britsh Joyrnal Appl. Phys, vol.5, issue.12, p.386, 1954.

T. Stopa, J. Tobola, S. Kaprzyk, E. K. Hlil, and D. Fruchart, Resistivity and thermopower calculations in half-Heusler Ti1?x ScxNiSn alloys from the KKR-CPA method, J. Phys. Condens. Matter, vol.18, issue.27, p.6379, 2006.

N. F. Mott and H. Jones, The Theory of the Properties of Metals and Alloys, J Chem Educ, vol.14, p.99, 1937.

G. D. Mahan and J. O. Sofo, The best thermoelectric, Proc. Natl. Acad. Sci, vol.93, pp.7436-7439, 1996.

Y. Pei, A. D. Lalonde, H. Wang, and G. J. Snyder, Low effective mass leading to high thermoelectric performance, Energy Environ. Sci, vol.5, issue.7, p.7963, 2012.

A. F. Ioffe, L. S. Stil'bans, E. K. Iordanishvili, T. S. Stavitskaya, A. Gelbtuch et al.,

, Semiconductor Thermoelements and Thermoelectric Cooling, Phys. Today, vol.12, issue.5, pp.42-42, 1959.

C. H. Goodman, The prediction of semiconducting properties in inorganic compounds, J. Phys. Chem. Solids, vol.6, issue.4, pp.305-314, 1958.

G. Mahan, B. Sales, and J. Sharp, Thermoelectric Materials: New Approaches to an Old Problem, Phys. Today, vol.50, issue.3, pp.42-47, 1997.

C. Godart, Matériaux à effets thermoélectriques, 2009.

T. M. Tritt and E. , Recent trends in thermoelectric materials research, vol.1, 2001.

B. Lenoir, H. Scherrer, and T. Caillat, An overview of recent developments for BiSb alloys, Recent Trends in Thermoelectric Materials, vol.69, pp.101-137, 2001.

A. Dauscher, B. Lenoir, T. Caillat, and H. Scherrer, Thermoelectric materials, Recent Research Developments in Materials Science, vol.3, p.181, 2002.
URL : https://hal.archives-ouvertes.fr/hal-01280797

J. P. Heremans, Enhancement of Thermoelectric Efficiency in PbTe by Distortion of the Electronic Density of States, Science, vol.321, issue.5888, pp.554-557, 2008.

C. Wood, Materials for thermoelectric energy conversion, Rep Prog Phys, vol.51, pp.459-539, 1988.

G. A. Slack, Design Concepts for Improved Thermoelectric Materials, MRS Proc, vol.478, 1997.

, New Materials for Thermoelectric Applications: Theory and Experiment, 2013.

H. J. Goldsmid and G. S. Nolas, A review of the new thermoelectric materials, pp.1-6, 2001.

T. M. Tritt, Thermoelectric Phenomena, Materials, and Applications

, Mater. Res, vol.41, issue.1, pp.433-448, 2011.

X. Shi, Multiple-Filled Skutterudites: High Thermoelectric Figure of Merit through Separately Optimizing Electrical and Thermal Transports, J. Am. Chem. Soc, vol.133, issue.20, pp.7837-7846, 2011.

S. Ballikaya, G. Wang, K. Sun, and C. Uher, Thermoelectric Properties of Triple-Filled Ba x Yb y In z Co4Sb12 Skutterudites, J. Electron. Mater, vol.40, issue.5, pp.570-576, 2011.

J. Martin, H. Wang, and G. S. Nolas, Optimization of the thermoelectric properties of Ba8Ga16Ge30, Appl. Phys. Lett, vol.92, issue.22, p.222110, 2008.

G. J. Snyder, M. Christensen, E. Nishibori, T. Caillat, and B. B. Iversen, Disordered zinc in Zn 4 Sb 3 with phonon-glass and electron-crystal thermoelectric properties, Nat. Mater, vol.3, issue.7, pp.458-463, 2004.

E. S. Toberer, Traversing the Metal-Insulator Transition in a Zintl Phase: Rational Enhancement of Thermoelectric Efficiency in Yb 14 Mn 1? x Al x Sb 11, Adv. Funct. Mater, vol.18, issue.18, pp.2795-2800, 2008.

X. Yan, Stronger phonon scattering by larger differences in atomic mass and size in p-type half-Heuslers Hf1?xTixCoSb0.8Sn0.2', Energy Environ. Sci, vol.5, p.7543, 2012.

A. F. May, J. Fleurial, and G. J. Snyder, Optimizing Thermoelectric Efficiency

, La3?xTe4 via Yb Substitution, vol.22, pp.2995-2999, 2010.

L. Zhao, BiCuSeO oxyselenides: new promising thermoelectric materials, Energy Environ. Sci, vol.7, issue.9, pp.2900-2924, 2014.

G. Kim, L. Shao, K. Zhang, and K. P. Pipe, Engineered doping of organic semiconductors for enhanced thermoelectric efficiency, Nat. Mater, vol.12, issue.8, pp.719-723, 2013.

K. Suekuni, High-performance thermoelectric mineral Cu12?xNixSb4S13

, J. Appl. Phys, vol.113, issue.4, p.43712, 2013.

P. Vaqueiro, The Influence of Mobile Copper Ions on the Glass-Like Thermal Conductivity of Copper-Rich Tetrahedrites, Chem. Mater, vol.29, issue.9, pp.4080-4090, 2017.
URL : https://hal.archives-ouvertes.fr/hal-02175414

L. Zhao, C. Chang, G. Tan, and M. G. Kanatzidis, SnSe: a remarkable new thermoelectric material, Energy Environ. Sci, vol.9, issue.10, pp.3044-3060, 2016.

C. Chen, H. Wang, Y. Chen, T. Day, and G. J. Snyder, Thermoelectric properties of p-type polycrystalline SnSe doped with Ag, J. Mater. Chem. A, vol.2, issue.29, pp.11171-11176, 2014.

T. Wei, Distinct Impact of Alkali-Ion Doping on Electrical Transport Properties of Thermoelectric p-Type Polycrystalline SnSe, J. Am. Chem. Soc, vol.138, issue.28, pp.8875-8882, 2016.

D. Ibrahim, Reinvestigation of the thermal properties of single-crystalline SnSe, Appl. Phys. Lett, vol.110, issue.3, p.32103, 2017.

S. Riffat and X. Ma, Thermoelectrics: a review of present and potential applications

, Appl. Therm. Eng, vol.23, issue.8, pp.913-935, 2003.

R. L. Heacock, The voyager spacecraft, Proc. Inst. Mech. Eng, vol.194, issue.1, pp.211-224, 1980.

, Ulysses -Satellite Missions -eoPortal Directory, p.12, 2018.

G. L. Bennett, Mission of daring: the general-purpose heat source radioisotope thermoelectric generator, 4th International Energy Conversion Engineering Conference and Exhibit (IECEC), vol.4096, p.2006, 2006.

K. Matsubara, Development of a high efficient thermoelectric stack for a waste exhaust heat recovery of vehicles, Proceedings ICT'02. Twenty-First International Conference on, pp.418-423, 2002.

O. , &. Bmw, and F. , GM to Test Thermoelectric Devices on Real Cars This Summer', The Green Optimistic, vol.25, 2011.

S. Kumar, S. D. Heister, X. Xu, J. R. Salvador, and G. P. Meisner, Thermoelectric Generators for Automotive Waste Heat Recovery Systems Part I: Numerical Modeling and Baseline Model Analysis, J. Electron. Mater, vol.42, issue.4, pp.665-674, 2013.

J. A. Paradiso and T. Starner, Energy scavenging for mobile and wireless electronics, IEEE Pervasive Comput, vol.4, issue.1, pp.18-27, 2005.

, Un circuit fonctionnant à la chaleur humaine', Tom's Hardware, vol.13, 2010.

Y. L. Kharif, P. V. Kovtunenko, A. A. Maier, and I. K. Avetisov, calculation of the phase diagrams of the phase diagrams of the Sn-Te and Pb-Sn-Te Systems, Russ J Phys Chem, vol.56, pp.1414-1416, 1982.

M. J. Pool, P. J. Spencer, and J. R. Guadagno, Heats of Solution of Tellurium in Liquid Tin, vol.242, pp.1481-1482, 1968.

J. S. Harris, J. T. Longo, E. R. Gertner, and J. E. Clarke, The Pb-Sn-Te phase diagram and its application to the liquid phase epitaxial growth of Pb1-xSnxTe, J Cryst Growth, vol.28, pp.334-342, 1975.

L. E. Shelimova and N. K. Abrikosov, The Sn-Te system in the region of the compoud SnTe, Russ J Inorg Chem, vol.9, pp.1017-1020, 1964.

R. F. Brebrick and A. J. Strauss, Partial Pressures in Equilibrium with Group IV Tellurides. II. Tin Telluride, J. Chem. Phys, vol.41, issue.1, pp.197-205, 1964.

B. B. Houston, R. F. Bis, and E. Gubner, Bull Am Phys Soc, vol.6, p.436, 1961.

V. M. Glazov, N. N. Glagoleva, and N. M. Makhmudova, Izv. Akad. Nauk SSSR', Neorg Mater, vol.5, pp.1508-1512, 1969.

H. Krebs, K. Grun, D. Kallen, and W. Lippert, Mixed crystal between As and Sb and semi-conducting chalcogenides of group IV, Z Anorg Chem, vol.308, pp.200-211, 1961.

J. Umeda, M. Jeong, and T. Okada, Tin-Tellurium Phase Diagram in the Vicinity of

. Stannous-telluride-snte, Jpn. J. Appl. Phys, vol.1, issue.5, p.277, 1962.

L. E. Glukhikh and N. K. Abrikosov, Th Sn-Te system in the region of the compound

&. Snte and J. Russ, Inorg Chem, vol.8, pp.930-931, 1963.

R. F. Brebrick, Composition stability limits for the rocksalt-structure phase, p.1

, Sny)1-xTex from lattice parameter measurements, J. Phys. Chem. Solids, vol.32, p.551

R. F. Brebrick, Analysis of the solidus lines for PbTe and SnTe, J. Electron. Mater, vol.6, issue.6, pp.659-692, 1977.

E. Rogacheva, Nonstoichiometry and Properties of SnTe Semiconductor Phase of Variable Composition, p.41

E. H. Putley, Materials used in semiconductors device, C.A. Hogarth, p.77, 1956.

M. Gomez, Depart. Of Materials', Sci. Rep, p.64, 1964.

R. F. Brebrick, Solid State Physics and Chemistry : an introduction, Solid State and Chemistry, 1966.

R. F. Brebrick, J Appl Phys, vol.30, p.811, 1959.

R. Mazelsky and M. S. Lubell, Nonstoichiometry in Some Group IV Tellurides, Nonstoichiometric Compounds, vol.39, pp.210-217, 1963.

B. B. Houston, R. S. Allgaier, J. Babiskin, and P. G. Siebenmann, Relationship between real and nominal carrier concentration in p-type SnTe, Bull Am Phys Soc, vol.9, p.60, 1964.

R. F. Bis and J. R. Dixon, Applicability of Vegard's Law to the PbxSn1?xTe Alloy System, J. Appl. Phys, vol.40, issue.4, 1918.

L. A. Sagar and R. C. Miller, Report of the International Conference on the Physics of Semiconductors, 1962.

G. Lucovsky and R. M. White, Effects of resonance bonding on the properties of crystalline and amorphous semiconductors, Phys. Rev. B, vol.8, issue.2, p.660, 1973.

I. Lefebvre, M. A. Szymanski, J. Olivier-fourcade, and J. C. Jumas, Electronic structure of tin monochalcogenides from SnO to SnTe, Phys. Rev. B, vol.58, issue.4, p.1896, 1998.

I. Lefebvre, M. Lannoo, G. Allan, and L. Martinage, Theoretical Mössbauer isomer shift of antimony chalcogenides, Phys. Rev. B, vol.38, issue.13, p.8593, 1988.

A. Null-sferco and . Lefebvre,

. Hollinger, Electronic structure of semiconductor oxides: InPO4, In(PO3)3, P2O5, SiO2, AlPO4, and Al(PO3)3', Phys. Rev. B Condens. Matter, vol.42, issue.17, pp.11232-11239

W. B. Pearson, A Handbook of Lattice Spacings and Structures of Metals and Alloys, vol.3, 1976.

A. N. Mariano and K. L. Chopra, Polymorphism in some IV-VI compounds induced by high pressure and thin-film epitaxial growth, Appl. Phys. Lett, vol.10, issue.10, pp.282-284, 1967.

R. J. Cava, H. Ji, M. K. Fuccillo, Q. D. Gibson, and Y. S. Hor, Crystal structure and chemistry of topological insulators, J. Mater. Chem. C, vol.1, issue.19, p.3176, 2013.

S. S. Kabalkina, L. F. Vereshchagin, and N. R. Serebryanaya,

, Germanium Telluride at High Pressures', Sov, J. Exp. Theor. Phys, vol.24, p.917, 1967.

J. N. Bierly, L. Muldawer, and O. Beckman, The continuous rhombohedral-gubic transformation in GeTe-SnTe alloys, Acta Metall, vol.11, issue.5, pp.447-454, 1963.

S. S. Kabalkina, N. R. Serebryanaya, and L. F. Vereshchagin, Sov. Phys-Solid State, vol.9, p.2527, 1968.

I. Lefkowitz, M. Shields, G. Dolling, and W. J. Buyers, Proc. 2nd Int. Meeting Ferroelectricity, vol.28, p.249, 1969.

G. S. Pawley, evidence for ferroelectricity in IV-VIcompounds, J. Phys. Colloq, vol.29, issue.C4, pp.4-145, 1968.

W. Paul, summary paper at paris conference on IV-VI compounds, J. Phys. Colloq, vol.29, issue.C4, pp.4-171, 1968.
URL : https://hal.archives-ouvertes.fr/jpa-00213631

S. I. Novikova and L. E. Shelimova, Phase transition in SnTe, Sov. Phys-Solid State, vol.7, p.2052, 1966.

O. Valassiades and N. A. Economou, On the phase transformation of SnTe, Phys. Status Solidi A, vol.30, issue.1, pp.187-195, 1975.

J. D. Wasscher, Philips Res Rept Suppl, vol.8, 1969.

M. Iizumi, Y. Hamaguchi, K. F. Komatsubara, and Y. Kato, Phase Transition in SnTe with Low Carrier Concentration, J. Phys. Soc. Jpn, vol.38, issue.2, pp.443-449, 1975.

K. L. Kobayashi, Y. Kato, Y. Katayama, and K. F. Komatsubara, CarrierConcentration-Dependent Phase Transition in SnTe, Phys. Rev. Lett, vol.37, issue.12, pp.772-774, 1976.

L. Muldawer, New studies of the low temperature transformation in SnTe, J Nonmetals, vol.1, p.177, 1973.

L. J. Brillson, E. Burstein, and L. Muldawer, Raman observation of the ferroelectric phase transition in SnTe, Phys. Rev. B, vol.9, issue.4, p.1547, 1974.

I. Hatta and K. L. Kobayashi, A mean-field behavior of the specific heat at the phase transition of SnTe with a low carrier concentration, Solid State Commun, vol.22, issue.12, pp.775-777, 1977.

J. A. Kafalas and A. N. Mariano, High-Pressure Phase Transition in Tin Telluride, Science, vol.143, issue.3609, p.952, 1964.

O. Madelung, U. Rössler, and M. Schulz, Non-Tetrahedrally Bonded Elements and Binary Compounds I, vol.41, 1998.

P. B. Littlewood, Band Structure of SnTe Studied by Photoemission Spectroscopy, Phys. Rev. Lett, vol.105, issue.8, 2010.

L. Pauling, The Nature of the Chemical Bond and the Structure of Molecules and Crystals: An Introduction to Modern Structural Chemistry, 1960.

J. C. Phillips, Bonds and bands in semiconductors, 1973.

J. John and A. N. Bloch, Quantum-Defect Electronegativity Scale for Nontransition Elements, Phys. Rev. Lett, vol.33, issue.18, pp.1095-1098, 1974.

P. B. Littlewood, The crystal structure of IV-VI compounds. I. Classification and description, J. Phys. C Solid State Phys, vol.13, issue.26, p.4855, 1980.

W. Cochran, Crystal stability and the theory of ferroelectricity, Adv. Phys, vol.9, issue.36, pp.387-423, 1960.

&. 'ferroélectricité and W. , , 2017.

K. F. Komatsubara, Y. Kato, K. L. Kobayashi, M. Iizumi, and Y. Hamaguchi, The Displacive Phase Transition in SnTe and Pbl?xSnxTe, Proceedings of the Twelfth International Conference on the Physics of Semiconductors, pp.602-606, 1974.

R. Clarke, X-ray study of the structural phase transition in Sn x Ge 1-x Te, Phys. Rev

B. , , vol.18, p.4920, 1978.

G. S. Pawley, W. Cochran, R. A. Cowley, and G. Dolling, Diatomic Ferroelectrics, Phys. Rev. Lett, vol.17, issue.14, pp.753-755, 1966.

C. W. Li, Phonon Self-Energy and Origin of Anomalous Neutron Scattering Spectra in SnTe and PbTe Thermoelectrics, Phys. Rev. Lett, vol.112, issue.17, 2014.

G. Dolling and W. J. Bruyers, Effect of Lattice Anharmonicity on Displacive Phase Transition in Narrow-Gap Semiconductors, J Nonmetals, vol.1, p.159, 1973.

C. D. O'neill, D. A. Sokolov, A. Hermann, A. Bossak, C. Stock et al., Inelastic x-ray investigation of the ferroelectric transition in SnTe, Phys. Rev. B, vol.95, issue.14, 2017.

K. L. Kobayashi, Y. Kato, Y. Katayama, and K. F. Komatsubara, Resistance anomaly due to displacive phase transition in SnTe, Solid State Commun, vol.17, issue.7, pp.875-878, 1975.

A. D. Grassie, J. A. Agapito, and P. Gonzalez, Anomalous resistivity at the structural phase transition of polycrystalline SnTe, J. Phys. C Solid State Phys, vol.12, issue.24, p.925, 1979.

E. R. Cowley, J. K. Darby, and G. S. Pawley, The lattice dynamics of tin telluride, J. Phys. C Solid State Phys, vol.2, issue.11, p.1916, 1969.

E. K. Salje, Tin telluride: A weakly co-elastic metal, Phys. Rev. B, vol.82, issue.18, 2010.

A. G. Beattie, Temperature Dependence of the Elastic Constants of Tin Telluride

, Appl. Phys, vol.40, issue.12, pp.4818-4821, 1969.

J. O. Dimmock, I. Melngailis, and A. J. Strauss, Band Structure and Laser Action

. Pbxsn1?xte, Phys. Rev. Lett, vol.16, issue.26, pp.1193-1196, 1966.

L. M. Rogers, Valence band structure of SnTe, J. Phys. Appl. Phys, vol.1, issue.7, p.845, 1968.

N. Wang, Microscopic origin of the p -type conductivity of the topological crystalline insulator SnTe and the effect of Pb alloying, Phys. Rev. B, vol.89, issue.4, 2014.

G. Tan, Extraordinary role of Hg in enhancing the thermoelectric performance of p-type SnTe, Energy Environ. Sci, vol.8, issue.1, pp.267-277, 2015.

R. F. Brebrick and A. J. Strauss, Anomalous thermoelectric power as evidence for twovalence bands in SnTe, Phys. Rev, vol.131, issue.1, p.104, 1963.

X. J. Tan, Mdoped SnTe, vol.18, pp.7141-7147, 2016.

Y. Pei, H. Wang, and G. J. Snyder, Band Engineering of Thermoelectric Materials, Adv. Mater, vol.24, issue.46, pp.6125-6135, 2012.

R. P. Chasmar and R. Stratton, The Thermoelectric Figure of Merit and its Relation to Thermoelectric Generators ?, J. Electron. Control, vol.7, issue.1, pp.52-72, 1959.

H. J. Goldsmid, Thermoelectric Refrigeration, 1964.

W. Li, Advances in Environment-Friendly SnTe Thermoelectrics, ACS Energy Lett, vol.2, issue.10, pp.2349-2355, 2017.

K. V. Klitzing, G. Dorda, and M. Pepper, New method for high-accuracy determination of the fine-structure constant based on quantized Hall resistance, Phys. Rev. Lett, vol.45, issue.6, p.494, 1980.

R. B. Laughlin, H. L. Störmer, and D. C. Tsui, The 1998 Nobel Prize in Physics : a new form of quantum fluid with fractionally charged excitations, vol.13, 1998.

D. Hsieh, A topological Dirac insulator in a quantum spin Hall phase (experimental realization of a 3D Topological Insulator)', ArXiv09102420 Cond-Mat

J. E. Moore and L. Balents, Topological invariants of time-reversal-invariant band structures, Phys. Rev. B, vol.75, issue.12, 2007.

M. Z. Hasan and C. L. Kane, Colloquium: Topological insulators, Rev. Mod. Phys, vol.82, issue.4, pp.3045-3067, 2010.

X. Qi and S. Zhang, Topological insulators and superconductors, Rev. Mod. Phys, vol.83, issue.4, pp.1057-1110, 2011.

L. Fu and C. L. Kane, Topological insulators with inversion symmetry, Phys. Rev. B, vol.76, issue.4, 2007.

M. Konig, Quantum Spin Hall Insulator State in HgTe Quantum Wells, Science, vol.318, issue.5851, pp.766-770, 2007.

B. A. Bernevig, T. L. Hughes, and S. Zhang, Quantum Spin Hall Effect and Topological Phase Transition in HgTe Quantum Wells, Science, vol.314, issue.5806, pp.1757-1761, 2006.

A. P. Schnyder, S. Ryu, A. Furusaki, and A. W. Ludwig, Classification of topological insulators and superconductors in three spatial dimensions, Phys. Rev. B, vol.78, issue.19, 2008.

A. Kitaev, Periodic table for topological insulators and superconductors', ArXiv09012686 Cond-Mat Physicshep-Th Physicsmath-Ph, pp.22-30, 2009.

Y. Ran, Weak indices and dislocations in general topological band structures', ArXiv10065454 Cond-Mat, 2010.

R. S. Mong, A. M. Essin, and J. E. Moore, Antiferromagnetic topological insulators, Phys. Rev. B, vol.81, issue.24, 2010.

R. Li, J. Wang, X. Qi, and S. Zhang, Dynamical axion field in topological magnetic insulators, Nat. Phys, vol.6, issue.4, pp.284-288, 2010.

T. H. Hsieh, H. Lin, J. Liu, W. Duan, A. Bansil et al., Topological crystalline insulators in the SnTe material class, Nat. Commun, vol.3, issue.1, 2012.

L. Fu, Topological Crystalline Insulators, Phys. Rev. Lett, vol.106, issue.10, 2011.

Y. Tanaka, Experimental realization of a topological crystalline insulator in

. Snte, Nat. Phys, vol.8, issue.11, pp.800-803, 2012.

S. Xu, Observation of a topological crystalline insulator phase and topological phase transition in Pb(1-x)Sn(x)Te', Nat. Commun, vol.3, p.1192, 2012.

A. S. Erickson, J. Chu, M. F. Toney, T. H. Geballe, and I. R. Fisher, Enhanced superconducting pairing interaction in indium-doped tin telluride, Phys. Rev. B, vol.79, issue.2, 2009.

R. D. Zhong, Optimizing the superconducting transition temperature and upper critical field of Sn 1 ? x In x Te, Phys. Rev. B, vol.88, issue.2, 2013.

M. Novak, S. Sasaki, M. Kriener, K. Segawa, and Y. Ando, Unusual nature of fully gapped superconductivity in In-doped SnTe, Phys. Rev. B, vol.88, issue.14, 2013.

V. K. Maurya, P. Shruti, S. Srivastava, and . Patnaik, Superconducting properties of indium-doped topological crystalline insulator SnTe, EPL Europhys. Lett, vol.108, issue.3, p.37010, 2014.

G. Balakrishnan, L. Bawden, S. Cavendish, and M. R. Lees, Superconducting properties of the In-substituted topological crystalline insulator SnTe, Phys. Rev. B, vol.87, issue.14, 2013.

N. Haldolaarachchige, Q. Gibson, W. Xie, M. B. Nielsen, S. Kushwaha et al., Anomalous composition dependence of the superconductivity in In-doped SnTe, Phys. Rev

B. , , vol.93, 2016.

K. Kobayashi, Y. Ai, H. O. Jeschke, and J. Akimitsu, Enhanced superconducting transition temperatures in the rocksalt-type superconductors In 1 ? x Sn x Te ( x ? 0.5 ), Phys. Rev. B, vol.97, issue.10, 2018.

Y. Pei, X. Shi, A. Lalonde, H. Wang, L. Chen et al., Convergence of electronic bands for high performance bulk thermoelectrics, Nature, vol.473, issue.7345, pp.66-69, 2011.

K. Biswas, High-performance bulk thermoelectrics with all-scale hierarchical architectures, Nature, vol.489, issue.7416, pp.414-418, 2012.

J. P. Heremans, Enhancement of Thermoelectric Efficiency in PbTe by Distortion of the Electronic Density of States, Science, vol.321, issue.5888, pp.554-557, 2008.

K. Biswas, Strained endotaxial nanostructures with high thermoelectric figure of merit, Nat. Chem, vol.3, issue.2, pp.160-166, 2011.

L. Yang, n-type Bi-doped PbTe Nanocubes with Enhanced Thermoelectric Performance, Nano Energy, vol.31, pp.105-112, 2017.

R. Orabi, Band Degeneracy, Low Thermal Conductivity, and High Thermoelectric Figure of Merit in SnTe-CaTe Alloys, Chem. Mater, vol.28, issue.1, pp.376-384, 2016.

A. Banik and K. Biswas, AgI alloying in SnTe boosts the thermoelectric performance via simultaneous valence band convergence and carrier concentration optimization, J. Solid State Chem, vol.242, pp.43-49, 2016.

G. Tan, Codoping in SnTe: Enhancement of Thermoelectric Performance through Synergy of Resonance Levels and Band Convergence, J. Am. Chem. Soc, vol.137, issue.15, pp.5100-5112, 2015.

A. Banik and K. Biswas, Lead-free thermoelectrics: promising thermoelectric performance in p-type SnTe1?xSex system, J. Mater. Chem. A, vol.2, issue.25, pp.9620-9625, 2014.

A. Banik, B. Vishal, S. Perumal, R. Datta, and K. Biswas, The origin of low thermal conductivity in Sn 1?x Sb x Te: phonon scattering via layered intergrowth nanostructures, Energy Environ. Sci, vol.9, issue.6, pp.2011-2019, 2016.

H. Wu, Synergistically optimized electrical and thermal transport properties of SnTe via alloying high-solubility MnTe, Energy Environ. Sci, vol.8, issue.11, pp.3298-3312, 2015.

Q. Zhang, High thermoelectric performance by resonant dopant indium in nanostructured SnTe, Proc. Natl. Acad. Sci, vol.110, pp.13261-13266, 2013.

L. Zhang, J. Wang, Z. Cheng, Q. Sun, Z. Li et al., Lead-free SnTe-based thermoelectrics: enhancement of thermoelectric performance by doping with Gd/Ag, J. Mater

, Chem. A, vol.4, issue.20, pp.7936-7942, 2016.

W. Li, Promoting SnTe as an Eco-Friendly Solution for p-PbTe Thermoelectric via Band Convergence and Interstitial Defects, Adv. Mater, vol.29, issue.17, p.1605887, 2017.

M. Han, J. Androulakis, S. Kim, and M. G. Kanatzidis, Lead-Free Thermoelectrics: High Figure of Merit in p-type AgSnmSbTem+2, Adv. Energy Mater, vol.2, issue.1, pp.157-161, 2012.

Z. Zhou, Multiple effects of Bi doping in enhancing the thermoelectric properties of SnTe, J. Mater. Chem. A, vol.4, issue.34, pp.13171-13175, 2016.

T. Liang, Ultra-fast non-equilibrium synthesis and phase segregation in In x Sn

?. , Te thermoelectrics by SHS-PAS processing, J. Mater. Chem. C, vol.3, issue.33, pp.8550-8558, 2015.

J. He, Enhanced thermopower in rock-salt SnTe-CdTe from band convergence, RSC Adv, vol.6, issue.38, pp.32189-32192, 2016.

W. Li, Band and scattering tuning for high performance thermoelectric

, Sn1?xMnxTe alloys, J. Materiomics, vol.1, issue.4, pp.307-315, 2015.

Z. Li, Systhesizing SnTe nanocrystals leading to thermoelectric performance enhancement via an ultra-fast microwave hydrothermal method, Nano Energy, vol.28, pp.78-86, 2016.

M. Zhou, Z. M. Gibbs, H. Wang, Y. Han, L. Li et al., Thermoelectric performance of co-doped SnTe with resonant levels, Appl. Phys. Lett, vol.109, issue.4, p.42102, 2016.

D. K. Bhat, S. Shenoy, and U. , High Thermoelectric Performance of Co-Doped Tin

, Telluride Due to Synergistic Effect of Magnesium and Indium, J. Phys. Chem. C, vol.121, issue.13, pp.7123-7130, 2017.

L. Zheng, W. Li, S. Lin, J. Li, Z. Chen et al., Interstitial Defects Improving Thermoelectric SnTe in Addition to Band Convergence, ACS Energy Lett, vol.2, issue.3, pp.563-568, 2017.

Y. Pei, Interstitial Point Defect Scattering Contributing to High Thermoelectric Performance in SnTe, Adv. Electron. Mater, vol.2, issue.6, p.1600019, 2016.

R. Moshwan, L. Yang, J. Zou, and Z. Chen, Eco-Friendly SnTe Thermoelectric Materials: Progress and Future Challenges, Adv. Funct. Mater, vol.27, issue.43, p.1703278, 2017.

A. Banik, U. S. Shenoy, S. Anand, U. V. Waghmare, and K. Biswas, Mg Alloying

, SnTe Facilitates Valence Band Convergence and Optimizes Thermoelectric Properties, Chem. Mater, vol.27, issue.2, pp.581-587, 2015.

A. Banik, U. S. Shenoy, S. Saha, U. V. Waghmare, and K. Biswas, High Power Factor and Enhanced Thermoelectric Performance of SnTe-AgInTe 2 : Synergistic Effect of Resonance Level and Valence Band Convergence, J. Am. Chem. Soc, vol.138, issue.39, pp.13068-13075, 2016.

J. He, Valence band engineering and thermoelectric performance optimization in SnTe by Mn-alloying via a zone-melting method, J. Mater. Chem. A, vol.3, issue.39, pp.19974-19979, 2015.

G. Tan, Valence Band Modification and High Thermoelectric Performance in

, SnTe Heavily Alloyed with MnTe, J. Am. Chem. Soc, vol.137, issue.35, pp.11507-11516

G. Tan, SnTe-AgBiTe 2 as an efficient thermoelectric material with low thermal conductivity, J Mater Chem A, vol.2, issue.48, pp.20849-20854, 2014.

G. Tan, High Thermoelectric Performance SnTe-In 2 Te 3 Solid Solutions Enabled by Resonant Levels and Strong Vacancy Phonon Scattering, Chem. Mater, vol.27, issue.22, pp.7801-7811, 2015.

G. Tan, High Thermoelectric Performance of p-Type SnTe via a Synergistic Band Engineering and Nanostructuring Approach, J. Am. Chem. Soc, vol.136, issue.19, pp.7006-7017, 2014.

X. J. Tan, G. Q. Liu, J. T. Xu, H. Z. Shao, J. Jiang et al., Element-selective resonant state in M-doped SnTe (M = Ga, vol.18, pp.20635-20639, 2016.

L. Zhao, Enhanced Thermoelectric Properties in the Counter-Doped SnTe System with Strained Endotaxial SrTe, J. Am. Chem. Soc, vol.138, issue.7, pp.2366-2373, 2016.

M. Zhou, Optimization of thermoelectric efficiency in SnTe: the case for the light band, Phys. Chem. Chem. Phys, vol.16, issue.38, pp.20741-20748, 2014.

R. F. Brebrick, Deviations from stoichiometry and electrical properties in SnTe, J. Phys. Chem. Solids, vol.24, issue.1, pp.27-36, 1963.

J. He, S. N. Girard, M. G. Kanatzidis, and V. P. Dravid,

, Thermoelectric Materials, Adv. Funct. Mater, vol.20, issue.5, pp.764-772, 2010.

Z. Chen, Vacancy-induced dislocations within grains for high-performance PbSe thermoelectrics, Nat. Commun, vol.8, p.13828, 2017.

Z. Chen, Lattice Dislocations Enhancing Thermoelectric PbTe in Addition to Band Convergence, Adv. Mater, vol.29, issue.23, p.1606768, 2017.

Y. Pei, H. Wang, Z. M. Gibbs, A. D. Lalonde, and G. J. Snyder, Thermopower enhancement in Pb1?xMn x Te alloys and its effect on thermoelectric efficiency, NPG Asia Mater, vol.4, issue.9, pp.28-28, 2012.

Y. Pei, A. D. Lalonde, N. A. Heinz, and G. J. Snyder, High Thermoelectric Figure of Merit in PbTe Alloys Demonstrated in PbTe-CdTe, Adv. Energy Mater, vol.2, issue.6, pp.670-675, 2012.

X. Dong, H. Yu, W. Li, Y. Pei, and Y. Chen, First-principles study on band structures and electrical transports of doped-SnTe, J. Materiomics, vol.2, issue.2, pp.158-164, 2016.

G. D. Mahan and J. O. Sofo, The best thermoelectric, Proc. Natl. Acad. Sci, vol.93, pp.7436-7439, 1996.

M. Cutler and N. F. Mott, Observation of Anderson localization in an electron gas, Phys. Rev, vol.181, issue.3, p.1336, 1969.

J. Korringa and A. N. Gerritsen, The cooperative electron phenomenon in dilute alloys, Physica, vol.19, issue.1-12, pp.457-507, 1953.

V. A. Kulbachinskii, N. B. Brandt, P. A. Cheremnykh, S. A. Azou, J. Horak et al.,

. Lo?ták, Magnetoresistance and Hall Effect in Bi2Te3?Sn? in Ultrahigh Magnetic Fields and under Pressure, Phys. Status Solidi B, vol.150, issue.1, pp.237-243, 1988.

Q. Zhang, Enhancement of thermoelectric figure-of-merit by resonant states of aluminium doping in lead selenide, Energy Env. Sci, vol.5, issue.1, pp.5246-5251, 2012.

J. J. Gong, Investigation of the bipolar effect in the thermoelectric material CaMg

, Bi 2 using a first-principles study, Phys. Chem. Chem. Phys, vol.18, issue.24, pp.16566-16574, 2016.

A. F. Ioffe, L. S. Stil'bans, E. K. Iordanishvili, T. S. Stavitskaya, A. Gelbtuch et al.,

, Semiconductor Thermoelements and Thermoelectric Cooling, Phys. Today, vol.12, issue.5, pp.42-42, 1959.

H. J. Goldsmid, Introduction to Thermoelectricity, 2010.

Y. Pei, Stabilizing the Optimal Carrier Concentration for High Thermoelectric Efficiency, Adv. Mater, vol.23, issue.47, pp.5674-5678, 2011.

Y. Pei, N. A. Heinz, and G. J. Snyder, Alloying to increase the band gap for improving thermoelectric properties of Ag2Te, J. Mater. Chem, vol.21, issue.45, pp.18256-18260

H. J. Goldsmid, Applications of thermoelectricity. London

. Wiley, , 1960.

M. K. Jana, K. Pal, U. V. Waghmare, and K. Biswas, The Origin of Ultralow Thermal Conductivity in InTe: Lone-Pair-Induced Anharmonic Rattling, Angew. Chem. Int. Ed, vol.55, issue.27, pp.7792-7796, 2016.

X. Shi, Multiple-Filled Skutterudites: High Thermoelectric Figure of Merit through Separately Optimizing Electrical and Thermal Transports, J. Am. Chem. Soc, vol.133, issue.20, pp.7837-7846, 2011.

H. Euchner, Phononic filter effect of rattling phonons in the thermoelectric clathrate Ba 8 Ge 40 + x Ni 6 ? x, Phys. Rev. B, vol.86, issue.22, 2012.

C. J. Vineis, A. Shakouri, A. Majumdar, and M. G. Kanatzidis, Nanostructured Thermoelectrics: Big Efficiency Gains from Small Features, Adv. Mater, vol.22, issue.36, pp.3970-3980, 2010.

J. Androulakis, Nanostructuring and High Thermoelectric Efficiency in p-Type Ag(Pb1 -ySny)mSbTe2 +m, Adv. Mater, vol.18, issue.9, pp.1170-1173, 2006.

K. F. Hsu, Cubic AgPbmSbTe2+m: Bulk Thermoelectric Materials with High Figure of Merit, Science, vol.303, issue.5659, pp.818-821, 2004.

P. F. Poudeu, J. Angelo, A. D. Downey, J. L. Short, T. P. Hogan et al.,

. Kanatzidis, High Thermoelectric Figure of Merit and Nanostructuring in Bulk p-type

, Angew. Chem. Int. Ed, vol.45, issue.23, pp.3835-3839, 2006.

M. G. Kanatzidis, Nanostructured Thermoelectrics: The New Paradigm? ? ', Chem

. Mater, , vol.22, pp.648-659, 2010.

B. A. Cook, M. J. Kramer, J. L. Harringa, M. Han, D. Chung et al.,

. Kanatzidis, Analysis of Nanostructuring in High Figure-of-Merit Ag1-x Pb m SbTe2+ m Thermoelectric Materials, vol.19, pp.1254-1259, 2009.

S. N. Girard, Situ Nanostructure Generation and Evolution within a Bulk Thermoelectric Material to Reduce Lattice Thermal Conductivity, Nano Lett, vol.10, issue.8, pp.2825-2831, 2010.

J. R. Sootsman, Large Enhancements in the Thermoelectric Power Factor of Bulk PbTe at High Temperature by Synergistic Nanostructuring, Angew. Chem. Int. Ed, vol.47, issue.45, pp.8618-8622, 2008.

P. F. Poudeu, Nanostructures versus Solid Solutions: Low Lattice Thermal Conductivity and Enhanced Thermoelectric Figure of Merit in Pb9.6Sb0.2Te10-xSex Bulk Materials, J. Am. Chem. Soc, vol.128, issue.44, pp.14347-14355, 2006.

E. Quarez, K. Hsu, R. Pcionek, N. Frangis, E. K. Polychroniadis et al.,

. Kanatzidis, Nanostructuring, Compositional Fluctuations, and Atomic Ordering in the Thermoelectric Materials AgPb m SbTe 2+ m . The Myth of Solid Solutions, J. Am. Chem

. Soc, , vol.127, pp.9177-9190, 2005.

J. He, On the Origin of Increased Phonon Scattering in Nanostructured PbTe Based Thermoelectric Materials, J. Am. Chem. Soc, vol.132, issue.25, pp.8669-8675

J. R. Sootsman, R. J. Pcionek, H. Kong, C. Uher, and M. G. Kanatzidis, Strong Reduction of Thermal Conductivity in Nanostructured PbTe Prepared by Matrix Encapsulation, Chem. Mater, vol.18, issue.21, pp.4993-4995, 2006.

M. Han, Substitution of Bi for Sb and its Role in the Thermoelectric Properties and Nanostructuring in Ag 1? x Pb, Chem. Mater, vol.18, issue.20, pp.3512-3520, 2008.

A. Guéguen, Thermoelectric Properties and Nanostructuring in the p-Type Materials NaPb 18? x Sn x MTe 20 (M = Sb, Bi, vol.21, pp.1683-1694, 2009.

C. B. Lioutas, N. Frangis, I. Todorov, D. Y. Chung, and M. G. Kanatzidis, Understanding Nanostructures in Thermoelectric Materials: An Electron Microscopy Study of AgPb 18 SbSe 20 Crystals, Chem. Mater, vol.22, issue.19, pp.5630-5635, 2010.

M. Zhou, J. Li, and T. Kita, Nanostructured AgPb m SbTe m +2 System Bulk Materials with Enhanced Thermoelectric Performance, J. Am. Chem. Soc, vol.130, issue.13, pp.4527-4532, 2008.

G. Joshi, Enhanced Thermoelectric Figure-of-Merit in Nanostructured p-type Silicon Germanium Bulk Alloys, Nano Lett, vol.8, issue.12, pp.4670-4674, 2008.

X. W. Wang, Enhanced thermoelectric figure of merit in nanostructured n-type silicon germanium bulk alloy, Appl. Phys. Lett, vol.93, issue.19, p.193121, 2008.

D. G. Cahill, S. K. Watson, and R. O. Pohl, Lower limit to the thermal conductivity of disordered crystals, Phys. Rev. B, vol.46, issue.10, p.6131, 1992.

R. Orabi, Ultralow Lattice Thermal Conductivity and Enhanced Thermoelectric Performance in SnTe:Ga Materials, Chem. Mater, vol.29, issue.2, pp.612-620, 2017.
URL : https://hal.archives-ouvertes.fr/hal-01500409

J. G. Park and Y. H. Lee, High thermoelectric performance of Bi-Te alloy: Defect engineering strategy, Curr. Appl. Phys, vol.16, issue.9, pp.1202-1215, 2016.

G. Tan, L. Zhao, and M. G. Kanatzidis, Rationally Designing High-Performance Bulk Thermoelectric Materials, Chem. Rev, vol.116, issue.19, pp.12123-12149, 2016.

G. Tan, Codoping in SnTe: Enhancement of Thermoelectric Performance through Synergy of Resonance Levels and Band Convergence, J. Am. Chem. Soc, vol.137, issue.15, pp.5100-5112, 2015.

C. Fu, Realizing high figure of merit in heavy-band p-type half-Heusler thermoelectric materials, Nat. Commun, vol.6, p.8144, 2015.

K. Kurosaki, A. Kosuga, H. Muta, M. Uno, and S. Yamanaka, Ag9TlTe5: A highperformance thermoelectric bulk material with extremely low thermal conductivity, Appl. Phys. Lett, vol.87, issue.6, p.61919, 2005.

L. Zhao, BiCuSeO oxyselenides: new promising thermoelectric materials, Energy Environ. Sci, vol.7, issue.9, pp.2900-2924, 2014.

E. S. Toberer, Traversing the Metal-Insulator Transition in a Zintl Phase: Rational Enhancement of Thermoelectric Efficiency in Yb 14 Mn 1? x Al x Sb 11, Adv. Funct. Mater, vol.18, issue.18, pp.2795-2800, 2008.

L. Zhou, P. Qiu, C. Uher, X. Shi, and L. Chen, Thermoelectric properties, pp.p-type
URL : https://hal.archives-ouvertes.fr/hal-00821960

, YbxLayFe2.7Co1.3Sb12 double-filled skutterudites', Intermetallics, vol.32, pp.209-213

, Chapitre II : propriétés structurales, physico-chimiques et physiques de composés à base de SnTe VII. Références

Z. Zhang, Z. Liu, J. Lu, X. Shen, F. Wang et al., The sintering mechanism in spark plasma sintering -Proof of the occurrence of spark discharge, Scr. Mater, vol.81, pp.56-59, 2014.

J. R. Taylor, Apparatus for Making Hard Metal Compositions', US Patent, pp.896-854, 1933.

M. Nygren and Z. Shen, On the preparation of bio-, nano-and structural ceramics and composites by spark plasma sintering, Solid State Sci, vol.5, issue.1, pp.125-131, 2003.

C. Estournes, Mise en forme de matériaux par frittage flash', in Techniques de l?ingénieur Innovations en matériaux avancés, p.56, 2006.

H. Sherrer, , 1980.

B. Tuck, Introduction to diffusion in semiconductors, IEE Monograph series, p.16, 1974.

H. A. Davies, Rapidly Quenched Metals

. Warlimont, , p.101, 1985.

B. Cantor, Rapidly Quenched Metals Ill, Metals Society, 1978.

H. Li, X. Tang, Q. Zhang, and C. Uher, High performance InxCeyCo4Sb12 thermoelectric materials with in situ forming nanostructured InSb phase, Appl. Phys. Lett, vol.94, issue.10, p.102114, 2009.

S. Fan, J. Zhao, J. Guo, Q. Yan, J. Ma et al., p-type Bi0.4Sb1.6Te3 nanocomposites with enhanced figure of merit, Appl. Phys. Lett, vol.96, issue.18, p.182104, 2010.

V. Ohorodniichuk, Influence de la nanostructuration sur les propriétés thermoélectriques de matériaux massifs de type p à base de (Bi, 2014.

. Ue-ondes-matière and . Rayonnement, , p.15, 2018.

J. Rodríguez, AN INTRODUCTION TO THE PROGRAM, p.139

G. Tan, Extraordinary role of Hg in enhancing the thermoelectric performance of p-type SnTe, Energy Environ. Sci, vol.8, issue.1, pp.267-277, 2015.

G. Tan, High Thermoelectric Performance of p-Type SnTe via a Synergistic Band Engineering and Nanostructuring Approach, J. Am. Chem. Soc, vol.136, issue.19, pp.7006-7017, 2014.

Q. Zhang, High thermoelectric performance by resonant dopant indium in nanostructured SnTe, Proc. Natl. Acad. Sci, vol.110, pp.13261-13266, 2013.

M. Zhou, Optimization of thermoelectric efficiency in SnTe: the case for the light band, Phys. Chem. Chem. Phys, vol.16, issue.38, pp.20741-20748, 2014.

A. Banik, U. S. Shenoy, S. Anand, U. V. Waghmare, and K. Biswas, Mg Alloying

, SnTe Facilitates Valence Band Convergence and Optimizes Thermoelectric Properties, Chem. Mater, vol.27, issue.2, pp.581-587, 2015.

J. He, Valence band engineering and thermoelectric performance optimization in SnTe by Mn-alloying via a zone-melting method, J. Mater. Chem. A, vol.3, issue.39, pp.19974-19979, 2015.

L. Zheng, W. Li, S. Lin, J. Li, Z. Chen et al., Interstitial Defects Improving Thermoelectric SnTe in Addition to Band Convergence, ACS Energy Lett, vol.2, issue.3, pp.563-568, 2017.

R. Orabi, Band Degeneracy, Low Thermal Conductivity, and High Thermoelectric Figure of Merit in SnTe-CaTe Alloys, Chem. Mater, vol.28, issue.1, pp.376-384, 2016.

L. Zhang, J. Wang, Z. Cheng, Q. Sun, Z. Li et al., Lead-free SnTe-based thermoelectrics: enhancement of thermoelectric performance by doping with Gd/Ag, J. Mater

, Chem. A, vol.4, issue.20, pp.7936-7942, 2016.

W. Li, Promoting SnTe as an Eco-Friendly Solution for p-PbTe Thermoelectric via Band Convergence and Interstitial Defects, Adv. Mater, vol.29, issue.17, p.1605887, 2017.

Z. Zhou, Multiple effects of Bi doping in enhancing the thermoelectric properties of SnTe, J. Mater. Chem. A, vol.4, issue.34, pp.13171-13175, 2016.

G. Zhang, Y. Zhan, and C. Li, Phase diagram of Er-Sn-Te system for diluted magnetic semiconductor developments, J. Rare Earths, vol.31, issue.8, pp.800-803, 2013.

. Vii and . Références,

O. Maldonado, Pulse method for simultaneous measurement of electric thermopower and heat conductivity at low temperatures, Cryogenics, vol.31, pp.908-912, 1992.

W. J. Parker, R. J. Jenkins, C. P. Butler, and G. L. Abbott, Flash Method of Determining Thermal Diffusivity, Heat Capacity, and Thermal Conductivity, J. Appl. Phys, vol.32, issue.9, pp.1679-1684, 1961.

B. Hay, J. Filtz, and J. Batsale, Mesure de la diffusivité thermique par la méthode flash, Méthodes surfaciques, p.42, 2004.

R. D. Cowan, Proposed Method of Measuring Thermal Diffusivity at High Temperatures, J. Appl. Phys, vol.32, issue.7, pp.1363-1370, 1961.

R. D. Cowan, Pulse Method of Measuring Thermal Diffusivity at High Temperatures

, J. Appl. Phys, vol.34, issue.4, pp.926-927, 1963.

J. A. Cape and G. W. Lehman, Temperature and Finite Pulse-Time Effects in the Flash Method for Measuring Thermal Diffusivity, J. Appl. Phys, vol.34, issue.7, pp.1909-1913

D. Josell, J. Warren, and A. Cezairliyan, Analysis for determining thermal diffusivity from thermal pulse experiments, J. Appl. Phys, vol.78, issue.11, pp.6867-6869, 1995.

J. Faure, Determination de la diffusivite thermique des isolants par la methode du signal tres bref, 1964.

J. Jamet and R. Jalin, Etude expérimentale de la dégradation thermique d'un matériau ablatif. Recherche aérospatiale, Recherche aérospatiale, vol.4, pp.233-244, 1974.

L. Clark and R. Taylor, Radiation loss in the flash method for thermal diffusivity, Journal of Applied Physics, pp.714-719, 1975.

J. Blumm and J. Opfermann, Improvement of the mathematical modeling of flash measurements, High Temperatures. High Pressures, vol.34, pp.515-521, 2002.

, Influence de la stoechiométrie chimique sur les propriétés de transport de Sn 1+x Te avec x =

, Influence de la technique de synthèse sur les propriétés de transport de SnTe

, Propriétés électriques et galvano-magnétiques

, Modèle à deux bandes de valence

, Propriétés thermiques à basses température

, Composés substitués à l'iode et à l'antimoine

, Avec ces deux mécanismes, le temps de relaxation totale est égal à : ?? ?~

. Db,

G. Tan, High Thermoelectric Performance of p-Type SnTe via a Synergistic Band Engineering and Nanostructuring Approach, J. Am. Chem. Soc, vol.136, issue.19, pp.7006-7017, 2014.

Y. Pei, X. Shi, A. Lalonde, H. Wang, L. Chen et al., Convergence of electronic bands for high performance bulk thermoelectrics, Nature, vol.473, issue.7345, pp.66-69, 2011.

J. Androulakis, Thermoelectric enhancement in PbTe with K or Na codoping from tuning the interaction of the light-and heavy-hole valence bands, Phys. Rev. B, vol.82, issue.11, 2010.

R. F. Brebrick, Deviations from stoichiometry and electrical properties in SnTe

, Phys. Chem. Solids, vol.24, issue.1, pp.27-36, 1963.

G. Nimtz and B. Schlicht, Narrow-Gap Semiconductors

. Verlag, , 1983.

J. He, S. N. Girard, M. G. Kanatzidis, and V. P. Dravid,

, Thermoelectric Materials, Adv. Funct. Mater, vol.20, issue.5, pp.764-772, 2010.

Z. Chen, Vacancy-induced dislocations within grains for high-performance PbSe thermoelectrics, Nat. Commun, vol.8, p.13828, 2017.

H. Sherrer, , 1980.

B. B. Houston, R. S. Allgaier, J. Babiskin, and P. G. Siebenmann, Relationship between real and nominal carrier concentration in p-type SnTe, Bull Am Phys Soc, vol.9, p.60, 1964.

N. K. Abrikosov, A. Tybulewicz, I. Semiconducting, V. Iv-vi, and . Compounds, , 1969.

Y. G. Sha and R. F. Brebrick, Explicit incorporation of the energy-band structure into an analysis of the defect chemistry of PbTe and SnTe, J. Electron. Mater, vol.18, issue.3, pp.421-443, 1989.

J. R. Burke, R. S. Allgaier, B. B. Houston, J. Babiskin, and P. G. Siebenmann, Shubnikov-de Haas Effect in SnTe, Phys. Rev. Lett, vol.14, issue.10, pp.360-361, 1965.

Y. W. Tung and M. L. Cohen, Relativistic Band Structure and Electronic Properties of

G. Snte and P. , Phys. Rev, vol.180, issue.3, pp.823-826, 1969.

R. S. Allgaier and B. Houston, Weak-field magnetoresistance and the valence-band structure of SnTe, Phys. Rev. B, vol.5, issue.6, p.2186, 1972.

J. S. Melvin and D. C. Hendry, Self-consistent relativistic energy bands for tin telluride, J. Phys. C Solid State Phys, vol.12, issue.15, p.3003, 1979.

L. M. Rogers, Valence band structure of SnTe, J. Phys. Appl. Phys, vol.1, issue.7, p.845, 1968.

J. O. Dimmock, I. Melngailis, and A. J. Strauss, Band Structure and Laser Action

. Pbxsn1?xte, Phys. Rev. Lett, vol.16, issue.26, pp.1193-1196, 1966.

M. Gomez, Depart. Of Materials', Sci. Rep, p.64, 1964.

R. F. Brebrick, Solid State Physics and Chemistry : an introduction, Solid State and Chemistry, 1966.

R. F. Brebrick, J Appl Phys, vol.30, p.811, 1959.

N. Wang, Microscopic origin of the p -type conductivity of the topological crystalline insulator SnTe and the effect of Pb alloying, Phys. Rev. B, vol.89, issue.4, 2014.

R. F. Brebrick and A. J. Strauss, Anomalous thermoelectric power as evidence for twovalence bands in SnTe, Phys. Rev, vol.131, issue.1, p.104, 1963.

H. Wang, E. Schechtel, Y. Pei, and G. J. Snyder, High Thermoelectric Efficiency of ntype PbS, Adv. Energy Mater, vol.3, issue.4, pp.488-495, 2013.

T. Seddon, S. C. Gupta, and G. A. Saunders, Hole contribution to the elastic constants of SnTe, Solid State Commun, vol.20, issue.1, pp.69-72, 1976.

C. Herring and E. Vogt, Transport and Deformation-Potential Theory for Many-Valley Semiconductors with Anisotropic Scattering, Phys. Rev, vol.101, issue.3, pp.944-961

J. He, Valence band engineering and thermoelectric performance optimization in SnTe by Mn-alloying via a zone-melting method, J. Mater. Chem. A, vol.3, issue.39, pp.19974-19979, 2015.

R. W. Mckinney, P. Gorai, V. Stevanovi?, and E. S. Toberer, Search for new thermoelectric materials with low Lorenz number, J. Mater. Chem. A, vol.5, issue.33, pp.17302-17311, 2017.

M. Puyet, Low-temperature thermal properties of n-type partially filled calcium skutterudites, J. Phys. Condens. Matter, vol.18, issue.49, p.11301, 2006.

A. Banik, B. Vishal, S. Perumal, R. Datta, and K. Biswas, The origin of low thermal conductivity in Sn 1?x Sb x Te: phonon scattering via layered intergrowth nanostructures, Energy Environ. Sci, vol.9, issue.6, 2011.

, Te (Figure VI

V. I. Figure, Dépendance en température de la concentration de porteur de charge, p H des échantillons Sn 1,03-x Na x Te non trempés

A. Banik, B. Vishal, S. Perumal, R. Datta, and K. Biswas, The origin of low thermal conductivity in Sn 1?x Sb x Te: phonon scattering via layered intergrowth nanostructures, Energy Environ. Sci, vol.9, issue.6, 2011.

S. Vyazovkin and C. A. Wight, KINETICS IN SOLIDS, Annu. Rev. Phys. Chem, vol.48, issue.1, pp.125-149, 1997.

A. K. Galwey and M. E. Brown, Application of the Arrhenius equation to solid state kinetics: can this be justi®ed?, Thermochim. Acta, issue.8, 2002.

T. P. Prasad, S. B. Kanungo, and H. S. Ray, Non-isothermal kinetics: some merits and limitations, p.12

S. Vyazovkin, A unified approach to kinetic processing of nonisothermal data, Int. J

, Chem. Kinet, vol.28, issue.2, pp.95-101, 1996.

J. W. Connell, J. G. Smith, and P. M. Hergenrother, High Temperature Transfer Molding Resins: Status of PETI-298 and PETI-330, p.15

, TG) of polymers --General principles, p.29