. Plasticseurope, Une Industrie Performante et Contestée, 'industrie Des Matières Plastiques

J. R. White, Polymer Ageing: Physics, Chemistry or Engineering? Time to Reflect, Comptes Rendus Chim, vol.9, pp.1396-1408, 2006.

, Norme ISO 10-640, Methodology for Assessing Polymer Photoageing by FTIR and UV-Visible Spectrometry, 2011.

, Norme EN 16472, Plastics, Method for Artificial Accelerated Photoageing Using Medium Pressure Mercury Vapour Lamps, 2014.

H. Vahabi, R. Sonnier, and L. Ferry, Effects of Ageing on the Fire Behaviour of Flame-Retarded Polymers: A Review, Polym. Int, vol.64, issue.3, pp.313-328, 2015.
URL : https://hal.archives-ouvertes.fr/hal-01117185

D. E. Henton, P. Gruber, J. Lunt, and . Randall, J. Polylactic Acid Technology. Nat. Fibers Biopolym. Biocomposites, vol.16, pp.527-577, 2005.

M. Jamshidian, E. A. Tehrany, M. Imran, M. Jacquot, S. Desobry et al., Acid: Production, Applications, Nanocomposites, and Release Studies, Compr. Rev. Food Sci. Food Saf, vol.2010, issue.5, pp.552-571

E. Castro-aguirre, F. Iñiguez-franco, H. Samsudin, X. Fang, R. Auras et al., Lactic Acid)-Mass Production, Processing, Industrial Applications, and End of Life, Adv. Drug Deliv. Rev, vol.107, pp.333-366, 2016.

Y. Chen, L. M. Geever, J. A. Killion, J. G. Lyons, C. L. Higginbotham et al., Review of Multifarious Applications of Poly (Lactic Acid), Polym.-Plast. Technol. Eng, vol.55, issue.10, pp.1057-1075, 2016.

, European Bioplastics, nova-Institute. Global Production Capacities of Bioplastics, 2017.

. Arkema, Biopolymers Rnew -Altuglas® resins

B. Fayolle and J. Verdu, Vieillissement Physique Des Matériaux Polymères, 2005.

J. Verdu, Différents Types de Vieillissement Chimique Des Plastiques

N. Nagai, T. Matsunobe, and T. Imai, Infrared Analysis of Depth Profiles in UV-Photochemical Degradation of Polymers, Polym. Degrad. Stab, vol.88, issue.2, pp.224-233, 2005.

E. Richaud and J. Verdu, Vieillissement Chimique Des Polymères -Cinétique de Dégradation, 2011.

S. Bagherpour, Fibre Reinforced Polyester Composites, 2012.

M. M. Qayyum and J. R. White, Effect of Water Absorption and Temperature Gradients on Polycarbonate Injection Moldings, J. Appl. Polym. Sci, vol.43, issue.1, pp.129-144, 1991.

G. Xian, H. Li, and X. Su, Water Absorption and Hygrothermal Ageing of Ultraviolet Cured GlassFiber Reinforced Acrylate Composites, Polym. Compos, vol.2012, issue.7, pp.1120-1128

A. S. Maxwell, Review of Accelerated Ageing Methods and Lifetime Prediction Techniques for Polymeric Materials, vol.16, 2005.

J. Lopez-cuesta and L. Ferry, Retardateurs de Flammes RF Des Matériaux Polymères, 2016.

E. Richaud and J. Verdu, Vieilllissement Chimique Des Polymères -Mécanismes de Dégradation

J. Verdu, Vieillissement Chimique Des Plastiques : Aspects Généraux, 2002.

J. Verdu, Vieillissement Des Plastiques; AFNOR technique, 1984.

E. Richaud and J. Verdu, Vieillissement Chimique Des Polymères -Physicochimie de La Stabilisation

G. Wypych and . Polymethylmethacrylate, Handbook of Polymers, pp.450-454, 2012.

D. Wyart, Polyméthylméthacrylates (PMMA) : Élaboration et Propriétés, 2012.

F. Pardos, Polyméthacrylate de Méthyle (PMMA) -Aspects Économiques, 2013.

. Oleinik;-salamatina;-rudnev;-shenogin, A New Approach to the Plastic Deformation of Vitreous Polymers, 1993.

J. M. Cheriere, L. Belec, and J. L. Gacougnolle, The Three Successive Stages of Creep of PMMA between 55 C and 90 C, Polym. Eng. Sci, vol.37, issue.10, pp.1664-1671, 1997.

M. M. Santore, R. S. Duran, and G. B. Mckenna, Volume Recovery in Epoxy Glasses Subjected to Torsional Deformations: The Question of Rejuvenation, Polymer, vol.32, issue.13, pp.2377-2381, 1991.

J. J. Martinez-vega, H. Trumel, and J. L. Gacougnolle, Plastic Deformation and Physical Ageing in PMMA, Polymer, vol.43, issue.18, pp.4979-4987, 2002.

H. Lee and M. D. Ediger, Mechanical Rejuvenation in Poly(Methyl Methacrylate) Glasses? Molecular Mobility after Deformation, Macromolecules, issue.13, pp.5863-5873, 2010.

C. Ishiyama and Y. Higo, Effects of Humidity on Young's Modulus in Poly(Methyl Methacrylate), J. Polym. Sci. Part B Polym. Phys, vol.40, issue.5, pp.460-465, 2002.

L. Smith and V. Schmitz, The Effect of Water on the Glass Transition Temperature of Poly(Methyl Methacrylate), Polymer, vol.29, issue.10, pp.1871-1878, 1988.

M. Unemori, Y. Matsuya, S. Matsuya, A. Akashi, and A. Akamine, Water Absorption of Poly (Methyl Methacrylate) Containing 4-Methacryloxyethyl Trimellitic Anhydride, Biomaterials, vol.24, issue.8, pp.1381-1387, 2003.

E. Moghbelli, R. Banyay, and H. Sue, Effect of Moisture Exposure on Scratch Resistance of PMMA, Tribol. Int, vol.69, pp.46-51, 2014.

R. C. Estler and N. S. Nogar, Mass Spectroscopic Identification of Wavelength Dependent UV Laser Photoablation Fragments from Polymethylmethacrylate, Appl. Phys. Lett, issue.18, p.1175, 1986.

H. Hiraoka, Radiation Chemistry of Poly(Methacrylates), IBM J. Res. Dev, vol.21, issue.2, pp.121-130, 1977.

J. M. Taguenang, A. Kassu, P. B. Ruffin, C. Brantley, E. Edwards et al., Reversible UV Degradation of PMMA Plastic Optical Fibers, Opt. Commun, issue.8, pp.2089-2092, 2008.

E. Yousif, G. El-hiti, R. Haddad, and A. Balakit, Photochemical Stability and Photostabilizing Efficiency of Poly(Methyl Methacrylate) Based on 2-(6-Methoxynaphthalen-2-Yl)Propanoate Metal Ion Complexes, Polymers, vol.7, issue.6, pp.1005-1019, 2015.

S. Eve and J. Mohr, Study of the Surface Modification of the PMMA by UV-Radiation. Procedia Eng, vol.1, pp.237-240, 2009.

W. R. Zeng, S. F. Li, and W. K. Chow, Review on Chemical Reactions of Burning Poly(Methyl Methacrylate) PMMA. J. Fire Sci, vol.20, issue.5, pp.401-433, 2002.

T. Kashiwagi, A. Inaba, J. E. Brown, K. Hatada, T. Kitayama et al., Effects of Weak Linkages on the Thermal and Oxidative Degradation of Poly (Methyl Methacrylates), Macromolecules, vol.19, issue.8, pp.2160-2168, 1986.

A. Gentilhomme, Synthèse et Caractérisation de Polymères Méthacryliques Phosphorés à Propriétés Retardatrices de Flamme, 2003.

L. E. Manring, Thermal Degradation of Poly (Methyl Methacrylate). 2. Vinyl-Terminated Polymer, Macromolecules, vol.22, issue.6, pp.2673-2677, 1989.

L. E. Manring, D. Y. Sogah, and G. M. Cohen, Thermal Degradation of Poly (Methyl Methacrylate). 3. Polymer with Head-to-Head Linkages, Macromolecules, vol.22, issue.12, pp.4652-4654, 1989.

L. E. Manring, Thermal Degradation of Poly (Methyl Methacrylate). 4. Random Side-Group Scission, Macromolecules, vol.24, issue.11, pp.3304-3309, 1991.

M. Ferriol, A. Gentilhomme, M. Cochez, N. Oget, and J. L. Mieloszynski, Thermal Degradation of Poly (Methyl Methacrylate)(PMMA): Modelling of DTG and TG Curves, Polym. Degrad. Stab, vol.79, issue.2, pp.271-281, 2003.

J. E. Brown and T. Kashiwagi, Gas Phase Oxygen Effect on Chain Scission and Monomer Content in Bulk Poly(Methyl Methacrylate) Degraded by External Thermal Radiation, Polym. Degrad. Stab, vol.52, issue.1, pp.1-10, 1996.

J. D. Peterson, S. Vyazovkin, and C. A. Wight, Kinetic Study of Stabilizing Effect of Oxygen on Thermal Degradation of Poly(Methyl Methacrylate), J. Phys. Chem. B, issue.38, pp.8087-8092, 1999.

G. P. Castellan and . Biodégradables,

D. Wyart, Les Polymères Biodégradables Polylactides (PLA) et Polyvinyliques (PVA) : Élaboration et Propriétés, 2014.

J. Quentin, Polycondensation Des Polyesters Saturés

J. Wertz, . -l.-l'amidon, and P. Le, Deux Biopolymères Sur Le Marché, 2011.

W. Groot, J. Van-krieken, O. Sliekersl, S. De-vos, . Poly-;-lim et al., Lactic Acid): Synthesis, Structures, Properties, Processing, and Applications; Auras, pp.3-18, 2010.

. Penu,

. Helou, Acide Polylactique (PLA), 2017.

V. Berthé, Développement de Mélanges à Base de Polylactide à Durée de Vie Contrôlée, 2010.

M. Hirata and Y. Kimura, Thermomechanical Properties of Stereoblock Poly(Lactic Acid)s with Different PLLA/PDLA Block Compositions, Polymer, vol.49, issue.11, pp.2656-2661, 2008.

C. Bastioli, Handbook of Biodegradable Polymers; Rapra Technology, 2005.

;. Kalish, . Aou, and . Yang,

. Hsu, Spectroscopic and Thermal Analyses of ?? and ? Crystalline Forms of Poly(l-Lactic Acid), Polymer, vol.52, pp.814-821, 2011.

S. Rathi, J. P. Kalish, E. B. Coughlin, and S. L. Hsu, Utilization of Oligo(Lactic Acid) for Studies of Chain Conformation and Chain Packing in Poly(Lactic Acid), Macromolecules, vol.44, issue.9, pp.3410-3415, 2011.

J. Huang, M. S. Lisowski, J. Runt, E. S. Hall, R. T. Kean et al., Crystallization and Microstructure of Poly (l-Lactide-Co-Meso-Lactide) Copolymers, Macromolecules, issue.8, pp.2593-2599, 1998.

. Miyata,

. Masuko, Crystallization Behaviour of Poly(l-Lactide), Pdf. Polymer, vol.39, issue.22, pp.5515-5521

;. Loomis and . Murdoch,

P. Gardner and . Stereocomplexes, Polym. Prepr. Am. Chem. Soc. Div. Polym. Chem, issue.2, p.55, 1990.

E. W. Fischer, H. J. Sterzel, and G. Wegner, Investigation of the Structure of Solution Grown Crystals of Lactide Copolymers by Means of Chemical Reactions, Kolloid-Z. Z. Für Polym, issue.11, pp.980-990, 1973.

H. Tsuji, R. Okino, H. Daimon, and K. Fujie, Water Vapor Permeability of Poly(Lactide)s: Effects of Molecular Characteristics and Crystallinity, J. Appl. Polym. Sci, vol.99, issue.5, pp.2245-2252, 2006.

, European Bioplastics, nova-Institute. Global Production Capacities of Bioplastics, 2016.

D. Wyart, Les Polymères Biodégradables Polylactides (PLA) et Polyvinyliques Alcools (PVA) : Transformation, Façonnage, Recyclage; Ed. Techniques Ingénieur, 2014.

J. R. Rocca-smith, N. Chau, D. Champion, C. Brachais, E. Marcuzzo et al., Effect of the State of Water and Relative Humidity on Ageing of PLA Films, vol.236, pp.109-119, 2017.
URL : https://hal.archives-ouvertes.fr/hal-01509779

J. Rydz, W. Sikorska, M. Kyulavska, and D. Christova, Polyester-Based (Bio)Degradable Polymers as Environmentally Friendly Materials for Sustainable Development, Int. J. Mol. Sci, vol.16, issue.1, pp.564-596, 2014.

H. Tsuji, A. Mizuno, and Y. Ikada, Properties and Morphology of Poly (L-Lactide). III. Effects of Initial Crystallinity on Long-Term in Vitro Hydrolysis of High Molecular Weight Poly (L-Lactide) Film in Phosphate-Buffered Solution, J. Appl. Polym. Sci, vol.77, issue.7, pp.1452-1464, 2000.

;. Tsuji and . Nakahara,

. Ikarashi and . Poly, L-Lactide) High-Temperature Hydrolysis of Poly(L-Lactide) Films with Different Crystallinities and Crystalline Thicknesses in Phosphate-Buffered Solution, Macromol Mater Eng, vol.286, pp.398-406, 2001.

. Tsuji,

. Ikada, Properties and Morphology of Poly(l-Lactide) 4 Effects of Structural Parameters on Long-Term Hydrolysis of Poly(l-Lactide) in Phosphate-Buffered Solution, Polym. Degrad. Stab, vol.67, pp.179-189, 2000.

H. Tsuji, In Vitro Hydrolysis of Poly(?-Lactide) Crystalline Residues as Extended-Chain Crystallites. Part I: Long-Term Hydrolysis in Phosphate-Buffered Solution at 37°C, Biomaterials, vol.25, issue.24, pp.5449-5455, 2004.

H. Tsuji, K. Ikarashi, and N. Fukuda, Poly(l-Lactide): XII. Formation, Growth, and Morphology of Crystalline Residues as Extended-Chain Crystallites through Hydrolysis of Poly(l-Lactide) Films in Phosphate-Buffered Solution, Polym. Degrad. Stab, vol.84, issue.3, pp.515-523, 2004.

A. Copinet, C. Bertrand, S. Govindin, V. Coma, and Y. Couturier, Effects of Ultraviolet Light (315 Nm), Temperature and Relative Humidity on the Degradation of Polylactic Acid Plastic Films, Chemosphere, vol.55, issue.5, pp.763-773, 2004.

M. Aressy, Etude et Modélisation de La Cristallisation Du Polylactide (PLA) En Vue de l'optimisation Du Procédé de Rotomoulage, Ecole nationale supérieure d'arts et métiers-ENSAM, 2013.

. Jamshidi;-hyon;-ikada, Thermal Caracterisation of Polylactides, Polymer, vol.29, issue.12, pp.2229-2234, 1988.

N. Najafi, M. C. Heuzey, P. J. Carreau, and P. Wood-adams, Control of Thermal Degradation of Polylactide (PLA)-Clay Nanocomposites Using Chain Extenders, Polym. Degrad. Stab, vol.2012, issue.4, pp.554-565

Q. Meng, M. Heuzey, and P. Carreau, Control of Thermal Degradation of Polylactide/Clay Nanocomposites during Melt Processing by Chain Extension Reaction, Polym. Degrad. Stab, vol.2012, issue.10, pp.2010-2020

F. Iñiguez-franco, R. Auras, J. Ahmed, S. Selke, M. Rubino et al., Control of Hydrolytic Degradation of Poly(Lactic Acid) by Incorporation of Chain Extender: From Bulk to Surface Erosion, Polym. Test, vol.67, pp.190-196, 2018.

J. Cailloux, R. N. Hakim, O. O. Santana, J. Bou, T. Abt et al., Reactive Extrusion: A Useful Process to Manufacture Structurally Modified PLA/o-MMT Composites, Compos. Part Appl. Sci. Manuf, vol.88, pp.106-115, 2016.

M. Alapetite, PLA : Caractéristiques, Utilisations, Voies de Synthèse et Traitement, 2015.

T. Wu and C. Wu, Biodegradable Poly(Lactic Acid)/Chitosan-Modified Montmorillonite Nanocomposites: Preparation and Characterization, Polym. Degrad. Stab, vol.91, issue.9, pp.2198-2204, 2006.

K. Fukushima, A. Fina, F. Geobaldo, A. Venturello, and G. Camino, Properties of Poly(Lactic Acid) Nanocomposites Based on Montmorillonite, Sepiolite and Zirconium Phosphonate, Express Polym. Lett, vol.2012, issue.11, pp.914-926

M. Fontanille, Structure Morphologique Des Polymeres, 2009.

V. Massardier, Etat de l'art Concernant La Compatibilité Des Matières Plastiques. Rapp. Final Lab. Matér. Macromoléculaires INSA LYON Fr, 2001.

P. Pötschke and D. R. Paul, Formation of Co-Continuous Structures in Melt-Mixed Immiscible Polymer Blends, J. Macromol. Sci. Part C Polym. Rev, vol.43, issue.1, pp.87-141, 2003.

F. Teyssandier, Formulation et Morphologies de Mélanges de Polymères Thermoplastiques à Base d'amidon, 2011.

J. Gonzalez and C. Albano, Dynamic Thermal Decomposition of Blends of Polyamide 6 with Functionalized and Non-Functionalized PP, Polym. Degrad. Stab, vol.68, pp.9-19, 2000.

L. Mantia, F. P. Morreale, M. Botta, L. Mistretta, M. C. Ceraulo et al., Degradation of Polymer Blends: A Brief Review, Polym. Degrad. Stab, 2017.

E. Rodriguez, S. Shahbikian, B. Marcos, and M. A. Huneault, Hydrolytic Stability of Polylactide and Poly(Methyl Methacrylate) Blends, J. Appl. Polym. Sci, p.45991, 2017.

K. Ganesh, Stabilization of Thermal Degradation of Poly (Methylmethacrylate) by Polysulfide Polymers, J. Appl. Polym. Sci, vol.66, pp.2149-2156, 1997.

Z. Ahmad, N. A. Al-awadi, and F. Al-sagheer, Thermal Degradation Studies in Poly(Vinyl Chloride)/Poly(Methyl Methacrylate) Blends, Polym. Degrad. Stab, vol.93, issue.2, pp.456-465, 2008.

J. Kowalonek, Surface Studies of UV-Irradiated Poly(Vinyl Chloride)/Poly(Methyl Methacrylate) Blends, Polym. Degrad. Stab, vol.133, pp.367-377, 2016.

Y. Márquez, L. Franco, and J. Puiggalí, Thermal Degradation Studies of Poly(Trimethylene Carbonate) Blends with Either Polylactide or Polycaprolactone, Thermochim. Acta, vol.550, pp.65-75, 2012.

F. Walha, K. Lamnawar, A. Maazouz, and M. Jaziri, Morphological and Mechanical Studies of Sustainably Sourced Polymer Blends Based on Poly(Lactic Acid) and Polyamide 11, Polymers, vol.8, issue.3, p.61, 2016.

W. Dong, B. Zou, Y. Yan, P. Ma, and M. Chen, Effect of Chain-Extenders on the Properties and Hydrolytic Degradation Behavior of the Poly(Lactide)/ Poly(Butylene Adipate-CoTerephthalate) Blends, Int. J. Mol. Sci, vol.2013, issue.12, pp.20189-20203

F. Signori, M. Coltelli, and S. Bronco, Thermal Degradation of Poly(Lactic Acid) (PLA) and Poly(Butylene Adipate-Co-Terephthalate) (PBAT) and Their Blends upon Melt Processing, Polym. Degrad. Stab, vol.94, issue.1, pp.74-82, 2009.

J. L. Eguiburu, J. J. Iruin, M. J. Fernandez-berridi, and J. San-román, Blends of Amorphous and Crystalline Polylactides with Poly(Methyl Methacrylate) and Poly(Methyl Acrylate): A Miscibility Study, Polymer, vol.39, issue.26, pp.6891-6897, 1998.

G. Zhang, J. Zhang, S. Wang, and D. Shen, Miscibility and Phase Structure of Binary Blends of Polylactide and Poly(Methyl Methacrylate), J. Polym. Sci. Part B Polym. Phys, vol.41, issue.1, pp.23-30, 2003.

S. Li and E. M. Woo, Immiscibility-Miscibility Phase Transitions in Blends of Poly(L-Lactide) with Poly(Methyl Methacrylate), Polym. Int, vol.57, issue.11, pp.1242-1251, 2008.

X. Hao, J. Kaschta, Y. Pan, X. Liu, and D. W. Schubert, Intermolecular Cooperativity and Entanglement Network in a Miscible PLA/PMMA Blend in the Presence of Nanosilica, Polymer, vol.82, pp.57-65, 2016.

M. Canetti, A. Cacciamani, and F. Bertini, Miscible Blends of Polylactide and Poly(Methyl Methacrylate): Morphology, Structure, and Thermal Behavior, J. Polym. Sci. Part B Polym. Phys, vol.2014, issue.17, pp.1168-1177

C. Samuel, J. Raquez, P. Dubois, . Plla/pmma, and . Blends, A Shear-Induced Miscibility with Tunable Morphologies and Properties? Polymer, vol.54, pp.3931-3939, 2013.

K. Le, R. Lehman, J. Remmert, K. Vanness, P. M. Ward et al., Multiphase Blends from Poly(L-Lactide) and Poly(Methyl Mathacrylate), J. Biomater. Sci. Polym. Ed, vol.17, issue.1-2, pp.121-137, 2006.

T. Shirahase, Y. Komatsu, Y. Tominaga, S. Asai, and M. Sumita, Miscibility and Hydrolytic Degradation in Alkaline Solution of Poly(l-Lactide) and Poly(Methyl Methacrylate) Blends. Polymer, vol.47, pp.4839-4844, 2006.

X. Hao, J. Kaschta, X. Liu, Y. Pan, and D. W. Schubert, Entanglement Network Formed in Miscible PLA/PMMA Blends and Its Role in Rheological and Thermo-Mechanical Properties of the Blends, Polymer, vol.80, pp.38-45, 2015.

B. Imre, K. Renner, and B. Pukanszky, Interactions, Structure and Properties in Poly(Lactic Acid)/Thermoplastic Polymer Blends, Express Polym. Lett, vol.8, issue.1, pp.2-14, 2014.
DOI : 10.3144/expresspolymlett.2014.2

URL : https://doi.org/10.3144/expresspolymlett.2014.2

Z. X. Teo, W. S. Chow, and . Impact, Thermal, and Morphological Properties of Poly(Lactic Acid)/Poly(Methyl Methacrylate)/Halloysite Nanotube Nanocomposites. Polym.-Plast
DOI : 10.1080/03602559.2015.1132464

. Technol and . Eng, , vol.55, pp.1474-1480, 2016.

J. Anakabe, A. M. Zaldua-huici, A. Eceiza, and A. Arbelaiz, Melt Blending of Polylactide and Poly(Methyl Methacrylate): Thermal and Mechanical Properties and Phase Morphology Characterization, J. Appl. Polym. Sci, vol.2015, issue.42
DOI : 10.1002/app.42677

M. Gonzalez-garzon, S. Shahbikian, and M. A. Huneault, Properties and Phase Structure of MeltProcessed PLA/PMMA Blends, J. Polym. Res, issue.2, p.25, 2018.
DOI : 10.1007/s10965-018-1438-1

G. Rapp, C. Samuel, J. Odent, J. Raquez, P. Dubois et al., Peculiar Effect of Stereocomplexes on the Photochemical Ageing of PLA/PMMA Blends, Polym. Degrad. Stab, 2018.
URL : https://hal.archives-ouvertes.fr/hal-01963065

J. Wu, M. C. Kuo, and C. Chen, Physical Properties and Crystallization Behavior of Poly(Lactide)/Poly(Methyl Methacrylate)/Silica Composites, J. Appl. Polym. Sci, vol.2015, issue.32
DOI : 10.1002/app.42378

B. Friederich, Développement de Nouveaux Systèmes Retardateurs de Flammes à Base de Nanocomposites plus Respectueux de l'environnement, 2011.

A. B. Morgan and J. W. Gilman, An Overview of Flame Retardancy of Polymeric Materials: Application, Technology, and Future Directions: AN OVERVIEW OF FLAME RETARDANCY OF POLYMERIC MATERIALS, Fire Mater, vol.37, issue.4, pp.259-279, 2013.

M. C. Yew, N. H. Sulong, M. K. Yew, M. A. Amalina, and M. R. Johan, Influences of FlameRetardant Fillers on Fire Protection and Mechanical Properties of Intumescent Coatings, Prog. Org. Coat, vol.78, pp.59-66, 2015.

S. Bourbigot, R. Delobel, and S. Duquesne, Comportement Au Feu Des Composites. Tech. Ing, 2006.

M. Wladyka-przybylak and R. Kozlowski, The Thermal Characteristics of Different Intumescent Coatings. Fire Mater, vol.23, pp.33-43, 1999.

K. Lim, S. Bee, L. T. Sin, T. Tee, C. T. Ratnam et al., A Review of Application of Ammonium Polyphosphate as Intumescent Flame Retardant in Thermoplastic Composites, Compos. Part B Eng, vol.84, pp.155-174, 2016.

P. K. Roy, M. Hakkarainen, and A. Albertsson, Nanoclay Effects on the Degradation Process and Product Patterns of Polylactide, Polym. Degrad. Stab, vol.2012, issue.8, pp.1254-1260

S. Hwang, P. P. Hsu, J. Yeh, K. Chang, and Y. Lai, The Mechanical/Thermal Properties of Microcellular Injection-Molded Poly-Lactic-Acid Nanocomposites, Polym. Compos, vol.30, issue.11, pp.1625-1630, 2009.

M. Lewin, E. M. Pearce, K. Levon, A. Mey-marom, M. Zammarano et al., Nanocomposites at Elevated Temperatures: Migration and Structural Changes, Polym. Adv. Technol, vol.17, issue.4, pp.226-234, 2006.
DOI : 10.1002/pat.684

R. A. Vaia, G. Price, P. N. Ruth, H. T. Nguyen, and J. Lichtenhan, Polymer Layered Silicate Nanocomposites as High Performance Ablative Materials, p.26, 1999.
DOI : 10.1016/s0169-1317(99)00013-7

Y. Yu, S. Qi, J. Zhan, Z. Wu, X. Yang et al., Polyimide/Sepiolite Nanocomposite Films: Preparation, Morphology and Properties, Mater. Res. Bull, vol.46, issue.10, pp.1593-1599, 2011.
DOI : 10.1016/j.materresbull.2011.06.009

P. Suchorska-wo?niak, O. Rac, M. Fiedot, and H. Teterycz, The Impact of Sepiolite on Sensor Parameters during the Detection of Low Concentrations of Alcohols, Sensors, vol.16, issue.11, p.1881, 2016.

J. Majesté, Renforcement Des Élastomères, 2017.

A. Laachachi, M. Cochez, E. Leroy, P. Gaudon, M. Ferriol et al., Effect of Al2O3 and TiO2 Nanoparticles and APP on Thermal Stability and Flame Retardance of PMMA, Polym. Adv. Technol, vol.17, issue.4, pp.327-334, 2006.
URL : https://hal.archives-ouvertes.fr/hal-00327253

C. Chivas-joly, C. Longuet, C. Motzkus, and J. Lopez-cuesta, Influence of the Composition of PMMA Nanocomposites on Gaseous Effluents Emitted during Combustion, Polym. Degrad. Stab, vol.113, pp.197-207, 2015.

Y. Quach, N. Cinausero, R. Sonnier, C. Longuet, and J. Lopez-cuesta, Barrier Effect of Flame Retardant Systems in Poly(Methyl Methacrylate): Study of the Efficiency of the Surface Treatment by Octylsilane of Silica Nanoparticles in Combination with Phosphorous Fire Retardant Additives, Fire Mater, vol.2012, issue.7, pp.590-602

H. Vahabi, F. Gholami, V. Karaseva, F. Laoutid, R. Mangin et al., Novel Nanocomposites Based on Poly(Ethylene-Co -Vinyl Acetate) for Coating Applications: The Complementary Actions of Hydroxyapatite, MWCNTs and Ammonium Polyphosphate on Flame Retardancy, Prog. Org. Coat, vol.113, pp.207-217, 2017.
URL : https://hal.archives-ouvertes.fr/hal-01604942

C. Motzkus, C. Chivas-joly, E. Guillaume, S. Ducourtieux, L. Saragoza et al., Aerosols Emitted by the Combustion of Polymers Containing Nanoparticles, J. Nanoparticle Res, issue.3, p.14, 2012.

J. Wang, G. Wang, Y. Liu, Y. Jiao, D. Liu et al., Combustion Behavior, and Toxic Gases in Fire Effluents of an Intumescent Flame-Retarded Polypropylene System, Ind. Eng. Chem. Res, vol.53, issue.17, pp.6978-6984, 2014.

F. Laoutid, L. Bonnaud, M. Alexandre, J. Lopez-cuesta, and P. Dubois, New Prospects in Flame Retardant Polymer Materials: From Fundamentals to Nanocomposites, Mater. Sci. Eng. R Rep, vol.63, issue.3, pp.100-125, 2009.

N. Cinausero, N. Azema, J. Lopez-cuesta, M. Cochez, and M. Ferriol, Synergistic Effect between Hydrophobic Oxide Nanoparticles and Ammonium Polyphosphate on Fire Properties of Poly(Methyl Methacrylate) and Polystyrene, Polym. Degrad. Stab, issue.8, pp.1445-1454, 2011.
URL : https://hal.archives-ouvertes.fr/hal-00772219

X. Wang, L. Wu, and J. Li, Synergistic Flame Retarded Poly(Methyl Methacrylate) by Nano-ZrO2 and Triphenylphosphate, J. Therm. Anal. Calorim, vol.103, issue.2, pp.741-746, 2011.

L. Dumazert, D. Rasselet, B. Pang, B. Gallard, S. Kennouche et al., Thermal Stability and Fire Reaction of Poly(Butylene Succinate) Nanocomposites Using Natural Clays and FR Additives, Polym. Adv. Technol, vol.29, issue.1, pp.69-83, 2018.

H. Vahabi, R. Sonnier, B. Otazaghine, G. Le-saout, and J. Lopez-cuesta, Nanocomposites of Polypropylene/Polyamide 6 Blends Based on Three Different Nanoclays: Thermal Stability and Flame Retardancy, Polimery, vol.2013, issue.5, pp.350-360
URL : https://hal.archives-ouvertes.fr/hal-00825562

H. Vahabi, Q. Lin, C. Vagner, M. Cochez, M. Ferriol et al., Investigation of Thermal Stability and Flammability of Poly(Methyl Methacrylate) Composites by Combination of APP with ZrO 2 , Sepiolite or MMT, Polym. Degrad. Stab, vol.124, pp.60-67, 2016.
URL : https://hal.archives-ouvertes.fr/hal-01255349

D. Calogine, J. Bertrand, S. Duplantier, C. Chivas-joly, E. Guillaume et al., Etude Structurale et Chimique Des Effluents Gazeux et Des Résidus de La Combustion de Nanocomposite à Matrice PMMA, Matériaux, 2010.

, Fédération Française des Matériaux, 2010.

P. A. Bonczyk, Effect of Ferrocene on Soot in a Prevaporized Iso-Octane/Air Diffusion Flame, Combust. Flame, vol.87, pp.233-244, 1991.

P. Stelmachowski, A. Kopacz, P. Legutko, P. Indyka, M. Wojtasik et al., The Role of Crystallite Size of Iron Oxide Catalyst for Soot Combustion, Catal. Today, vol.257, pp.111-116, 2015.

D. Reichert, H. Bockhorn, and S. Kureti, Study of the Reaction of NOx and Soot on Fe2O3 Catalyst in Excess of O2, Appl. Catal. B Environ, vol.80, issue.3-4, pp.248-259, 2008.

S. Wagloehner and S. Kureti, Study on the Mechanism of the Oxidation of Soot on Fe2O3 Catalyst, Appl. Catal. B Environ, vol.125, pp.158-165, 2012.

C. Chivas-joly, C. Motzkus, E. Guillaume, S. Ducourtieux, L. Saragoza et al., Influence of Carbon Nanotubes on Fire Behaviour and Aerosol Emitted during Combustion of Thermoplastics: Fire Mater, vol.38, pp.46-62, 2014.

G. Ounoughene, O. Le-bihan, C. Chivas-joly, C. Motzkus, C. Longuet et al., Behavior and Fate of Halloysite Nanotubes (HNTs) When Incinerating PA6/HNTs Nanocomposite, Environ. Sci. Technol, vol.49, issue.9, pp.5450-5457, 2015.
URL : https://hal.archives-ouvertes.fr/ineris-01855609

F. I. Beltrán-ramírez, L. F. Ramos-devalle, E. Ramírez-vargas, S. Sánchez-valdes, A. B. Espinozamartínez et al., Effect of Nanometric Metallic Hydroxides on the Flame Retardant Properties of HDPE Composites, J. Nanomater, pp.1-11, 2014.

A. Bunder?ek, B. Japelj, B. Mu?i?, N. Rajnar, S. Gyergyek et al., Influence of Al(OH)3 Nanoparticles on the Mechanical and Fire Resistance Properties of Poly(Methyl Methacrylate) Nanocomposites, Polym. Compos, vol.37, issue.6, pp.1659-1666, 2016.

C. A. Wilkie and A. B. Morgan, Fire Retardancy of Polymeric Materials, Second Edition, 2009.

D. Price, K. Pyrah, T. R. Hull, G. J. Milnes, J. R. Ebdon et al., Flame Retarding Poly (Methyl Methacrylate) with Phosphorus-Containing Compounds: Comparison of an Additive with a Reactive Approach, Polym. Degrad. Stab, vol.74, issue.3, pp.441-447, 2001.

H. Vahabi, L. Ferry, C. Longuet, R. Sonnier, C. Negrell-guirao et al., Theoretical and Empirical Approaches to Understanding the Effect of Phosphonate Groups on the Thermal Degradation for Two Chemically Modified PMMA, Eur. Polym. J, vol.2012, issue.3, pp.604-612
URL : https://hal.archives-ouvertes.fr/hal-00674367

G. Camino, N. Grassie, and I. C. Mcneill, Influence of the Fire Retardant, Ammonium Polyphosphate, on the Thermal Degradation of Poly (Methyl Methacrylate), J. Polym. Sci. Part Polym. Chem, vol.16, issue.1, pp.95-106, 1978.

S. Rabe,

B. Schartel, Exploring the Modes of Action of Phosphorus-Based Flame Retardants in Polymeric Systems, Materials, vol.2017, issue.5, p.455

Y. Guo, J. Qiu, H. Tang, and C. Liu, High Transmittance and Environment-Friendly Flame-Resistant Optical Resins Based on Poly(Methyl Methacrylate) and Cyclotriphosphazene Derivatives, J. Appl. Polym. Sci, vol.121, issue.2, pp.727-734, 2011.

G. Krala, A. Ubowska, and K. Kowalczyk, Mechanical and Thermal Analysis of Injection Molded Poly(Methyl Methacrylate) Modified with 9,10-Dihydro-9-Oxa-10-Phosphaphenanthrene-10-Oxide (DOPO) Fire Retarder, Polym. Eng. Sci, vol.2014, issue.5, pp.1030-1037

S. Jiang, Y. Zhu, Y. Hu, G. Chen, X. Shi et al., Situ Synthesis of a Novel Transparent Poly (Methyl Methacrylate) Resin with Markedly Enhanced Flame Retardancy: Synthesis of New Flame-Retardant Transparent Poly(Methyl Methacrylate), Polym. Adv. Technol, vol.27, issue.2, pp.266-272, 2016.

A. Laachachi, E. Leroy, M. Cochez, M. Ferriol, and J. M. Lopez-cuesta, Use of Oxide Nanoparticles and Organoclays to Improve Thermal Stability and Fire Retardancy of Poly(Methyl Methacrylate), Polym. Degrad. Stab, vol.89, issue.2, pp.344-352, 2005.

M. Liu, Z. Jia, D. Jia, and C. Zhou, Recent Advance in Research on Halloysite Nanotubes-Polymer Nanocomposite, Prog. Polym. Sci, vol.39, issue.8, pp.1498-1525, 2014.

S. Liufu, H. Xiao, and Y. Li, Thermal Analysis and Degradation Mechanism of Polyacrylate/ZnO Nanocomposites, Polym. Degrad. Stab, vol.87, issue.1, pp.103-110, 2005.

N. Cinausero, N. Azema, J. L. Cuesta, M. Cochez, and M. Ferriol, Impact of Modified Alumina Oxides on the Fire Properties of PMMA and PS Nanocomposites, Polym. Adv. Technol, vol.22, issue.12, pp.1931-1939, 2011.

A. Laachachi, M. Cochez, M. Ferriol, J. M. Lopez-cuesta, and E. Leroy, Influence of TiO2 and Fe2O3 Fillers on the Thermal Properties of Poly(Methyl Methacrylate) (PMMA), Mater. Lett, vol.59, issue.1, pp.36-39, 2005.

R. Shen, L. C. Hatanaka, L. Ahmed, R. J. Agnew, M. S. Mannan et al., Cone Calorimeter Analysis of Flame Retardant Poly (Methyl Methacrylate)-Silica Nanocomposites, J. Therm. Anal. Calorim, vol.2017, issue.3, pp.1443-1451

M. C. Costache, D. Wang, M. J. Heidecker, E. Manias, and C. A. Wilkie, The Thermal Degradation of Poly(Methyl Methacrylate) Nanocomposites with Montmorillonite, Layered Double Hydroxides and Carbon Nanotubes, Polym. Adv. Technol, vol.17, issue.4, pp.272-280, 2006.

T. Kashiwagi, F. Du, K. I. Winey, K. M. Groth, J. R. Shields et al., Flammability Properties of Polymer Nanocomposites with Single-Walled Carbon Nanotubes: Effects of Nanotube Dispersion and Concentration, Polymer, vol.46, issue.2, pp.471-481, 2005.

B. Friederich, A. Laachachi, M. Ferriol, M. Cochez, R. Sonnier et al., Investigation of Fire-Resistance Mechanisms of the Ternary System (APP/MPP/TiO2) in PMMA, Polym. Degrad. Stab, vol.2012, issue.11, pp.2154-2161
URL : https://hal.archives-ouvertes.fr/hal-00772225

B. Friederich, A. Laachachi, R. Sonnier, M. Ferriol, M. Cochez et al., Comparison of Alumina and Boehmite in (APP/MPP/Metal Oxide) Ternary Systems on the Thermal and Fire Behavior of PMMA: BEHAVIORS, Polym. Adv. Technol, vol.2012, issue.10, pp.1369-1380

W. S. Chow, E. L. Teoh, and . Karger-kocsis, J. Flame Retarded Poly(Lactic Acid): A Review. Express Polym. Lett, vol.12, issue.5, pp.396-417, 2018.

. Kubokawa,

. Hatakeyama, Thermal Decomposition Behavior of Polylactide Fabrics Treated with Flame Retardants, Seni Gakkaishi, vol.55, pp.349-355, 1999.

S. Bourbigot, S. Duquesne, G. Fontaine, S. Bellayer, T. Turf et al., Characterization and Reaction to Fire of Polymer Nanocomposites with and without Conventional Flame Retardants, Mol. Cryst. Liq. Cryst, vol.486, issue.1, 2008.

L. Shumao, R. Jie, Y. Hua, Y. Tao, and Y. Weizhong, Influence of Ammonium Polyphosphate on the Flame Retardancy and Mechanical Properties of Ramie Fiber-Reinforced Poly(Lactic Acid) Biocomposites, Polym. Int, 2009.

C. Réti, M. Casetta, S. Duquesne, S. Bourbigot, and R. Delobel, Flammability Properties of Intumescent PLA Including Starch and Lignin, Polym. Adv. Technol, vol.19, issue.6, pp.628-635, 2008.

R. Zhang, X. Xiao, Q. Tai, H. Huang, J. Yang et al., Preparation of Lignin-Silica Hybrids and Its Application in Intumescent Flame-Retardant Poly(Lactic Acid) System, High Perform. Polym, vol.2012, issue.8, pp.738-746

X. Wang, Y. Hu, L. Song, S. Xuan, W. Xing et al., Flame Retardancy and Thermal Degradation of Intumescent Flame Retardant Poly (Lactic Acid)/Starch Biocomposites, Ind. Eng. Chem. Res, vol.50, issue.2, pp.713-720, 2010.

R. Zhang, X. Xiao, Q. Tai, H. Huang, J. Yang et al., The Effect of Different Organic Modified Montmorillonites (OMMTs) on the Thermal Properties and Flammability of PLA/MCAPP/Lignin Systems, J. Appl. Polym. Sci, vol.2013, issue.6, pp.4967-4973

H. Sheng, Y. Zhang, B. Wang, B. Yu, Y. Shi et al., Effect of Electron Beam Irradiation and Microencapsulation on the Flame Retardancy of Ethylene-Vinyl Acetate Copolymer Materials during Hot Water Ageing Test, Radiat. Phys. Chem, vol.133, pp.1-8, 2017.

A. Araújo, G. Botelho, M. Oliveira, and A. V. Machado, Influence of Clay Organic Modifier on the Thermal-Stability of PLA Based Nanocomposites, Appl. Clay Sci, pp.144-150, 2014.

K. Fukushima, C. Abbate, D. Tabuani, M. Gennari, and G. Camino, Biodegradation of Poly(Lactic Acid) and Its Nanocomposites, Polym. Degrad. Stab, vol.94, issue.10, pp.1646-1655, 2009.

M. Paul, C. Delcourt, M. Alexandre, P. Degée, F. Monteverde et al., Polylactide/Montmorillonite Nanocomposites: Study of the Hydrolytic Degradation, Polym. Degrad. Stab, vol.87, issue.3, pp.535-542, 2005.

N. Lesaffre, S. Bellayer, G. Fontaine, M. Jimenez, and S. Bourbigot, Revealing the Impact of Ageing on a Flame Retarded PLA, Polym. Degrad. Stab, vol.127, pp.88-97, 2016.

N. A. Isitman, M. Dogan, E. Bayramli, and C. Kaynak, The Role of Nanoparticle Geometry in Flame Retardancy of Polylactide Nanocomposites Containing Aluminium Phosphinate, Polym. Degrad. Stab, vol.2012, issue.8, pp.1285-1296

S. Bourbigot, G. Fontaine, S. Duquesne, R. Delobel, and . Nanocomposites, Quantification of Clay Nanodispersion and Reaction to Fire, Int. J. Nanotechnol, vol.5, issue.6-8, pp.683-692, 2008.

S. Solarski, F. Mahjoubi, M. Ferreira, E. Devaux, P. Bachelet et al., Plasticized) Polylactide/Clay Nanocomposite Textile: Thermal, Mechanical, Shrinkage and Fire Properties, J. Mater. Sci, vol.42, issue.13, pp.5105-5117, 2007.

S. Bourbigot, G. Fontaine, A. Gallos, and S. Bellayer, Reactive Extrusion of PLA and of PLA/Carbon Nanotubes Nanocomposite: Processing, Characterization and Flame Retardancy, Polym. Adv. Technol, vol.22, issue.1, pp.30-37, 2011.

;. Wilkie and . Morgan,

. Nelson, Fire and Polymers V: Materials and Concepts for Fire Retardancy

. Washington, , p.1013, 2009.

M. Murariu, A. L. Dechief, L. Bonnaud, Y. Paint, A. Gallos et al., The Production and Properties of Polylactide Composites Filled with Expanded Graphite, Polym. Degrad. Stab, issue.5, pp.889-900, 2010.

R. B. Valapa, G. Pugazhenthi, and V. Katiyar, Effect of Graphene Content on the Properties of Poly(Lactic Acid) Nanocomposites, RSC Adv, vol.5, issue.36, pp.28410-28423, 2015.

G. Fontaine and S. Bourbigot, Intumescent Polylactide: A Nonflammable Material, J. Appl. Polym. Sci, vol.113, issue.6, pp.3860-3865, 2009.

D. Wang, A. Leuteritz, Y. Wang, U. Wagenknecht, and G. Heinrich, Preparation and Burning Behaviors of Flame Retarding Biodegradable Poly(Lactic Acid) Nanocomposite Based on Zinc Aluminum Layered Double Hydroxide, Polym. Degrad. Stab, issue.12, pp.2474-2480, 2010.

X. Liu, D. Wang, X. Wang, L. Chen, and Y. Wang, Synthesis of Organo-Modified ?-Zirconium Phosphate and Its Effect on the Flame Retardancy of IFR Poly(Lactic Acid) Systems, Polym. Degrad. Stab, vol.96, issue.5, pp.771-777, 2011.

X. Zhou, J. Li, and Y. Wu, Synergistic Effect of Aluminum Hypophosphite and Intumescent Flame Retardants in Polylactide: SYNERGISTIC EFFECT OF AHP AND IFR IN POLYLACTIDE, Polym. Adv. Technol, vol.26, issue.3, pp.255-265, 2015.

H. Zhu, Q. Zhu, J. Li, K. Tao, L. Xue et al., Synergistic Effect between Expandable Graphite and Ammonium Polyphosphate on Flame Retarded Polylactide, Polym. Degrad. Stab, vol.96, issue.2, pp.183-189, 2011.

C. Feng, M. Liang, Y. Zhang, J. Jiang, J. Huang et al., Synergistic Effect of Lanthanum Oxide on the Flame Retardant Properties and Mechanism of an Intumescent Flame Retardant PLA Composites, J. Anal. Appl. Pyrolysis, vol.122, pp.241-248, 2016.

C. Ke, J. Li, K. Fang, Q. Zhu, J. Zhu et al., Synergistic Effect between a Novel Hyperbranched Charring Agent and Ammonium Polyphosphate on the Flame Retardant and Anti-Dripping Properties of Polylactide, Polym. Degrad. Stab, issue.5, pp.763-770, 2010.

E. L. Teoh, M. Mariatti, and W. S. Chow, Thermal and Flame Resistant Properties of Poly (Lactic Acid)/Poly (Methyl Methacrylate) Blends Containing Halogen-Free Flame Retardant, Procedia Chem, vol.19, pp.795-802, 2016.

E. L. Teoh, W. S. Chow, and M. Jaafar, ? -Cyclodextrin as a Partial Replacement of Phosphorus Flame Retardant for Poly(Lactic Acid)/Poly(Methyl Methacrylate): A More Environmental Friendly Flame-Retarded Blends, Polym.-Plast. Technol. Eng, vol.2017, pp.1-15

S. Colonna, F. Cuttica, and A. Frache, Aging of EVA/Organically Modified Clay: Effect on Dispersion, Distribution and Combustion Behavior, Polym. Degrad. Stab, vol.107, pp.184-187, 2014.

X. Zuo, H. Shao, D. Zhang, Z. Hao, and J. Guo, Effects of Thermal-Oxidative Aging on the Flammability and Thermal-Oxidative Degradation Kinetics of Tris(Tribromophenyl) Cyanurate Flame Retardant PA6/LGF Composites, Polym. Degrad. Stab, vol.98, issue.12, pp.2774-2783, 2013.

H. Inata, I. Maki, T. Ishikawa, and K. Takeda, Diffusion of Additives and Deterioration with Passage of Time in Polypropylene, J. Appl. Polym. Sci, vol.99, issue.5, pp.2152-2162, 2006.

P. Patel, Investigation of Fire Behavior of PEEK-Based Polymers and Compounds, 2011.

E. S. Oztekin, S. B. Crowley, R. E. Lyon, S. I. Stoliarov, P. Patel et al., Sources of Variability in Fire Test Data: A Case Study on Poly(Aryl Ether Ether Ketone) (PEEK), Combust. Flame, vol.2012, issue.4, pp.1720-1731

N. Safronava, R. E. Lyon, S. Crowley, and S. I. Stoliarov, Effect of Moisture on Ignition Time of Polymers, Fire Technol, vol.51, issue.5, pp.1093-1112, 2015.

S. V. Levchik, D. A. Bright, G. R. Alessio, and S. Dashevsky, New Halogen-Free Fire Retardant for Engineering Plastic Applications, J. Vinyl Addit. Technol, vol.7, issue.2, pp.98-103, 2001.

B. Wang, K. Zhao, Y. Zhang, Y. Tao, X. Zhou et al., Influence of Aging Conditions on the Mechanical Properties and Flame Retardancy of HIPS Composites, J. Appl. Polym. Sci, p.46339, 2018.

M. Jimenez, S. Bellayer, B. Revel, S. Duquesne, and S. Bourbigot, Comprehensive Study of the Influence of Different Aging Scenarios on the Fire Protective Behavior of an Epoxy Based Intumescent Coating, Ind. Eng. Chem. Res, vol.52, issue.2, pp.729-743, 2013.

L. L. Wang, Y. C. Wang, J. F. Yuan, and G. Q. Li, Thermal Conductivity of Intumescent Coating Char after Accelerated Aging: THERMAL CONDUCTIVITY OF INTUMESCENT COATING CHAR, Fire Mater, vol.37, issue.6, pp.440-456, 2013.

D. Chantegraille, S. Morlat-therias, and J. Gardette, Photochemical Behaviour of Fire-Retarded Polymers, Polym. Degrad. Stab, vol.95, issue.3, pp.274-277, 2010.
URL : https://hal.archives-ouvertes.fr/hal-00512162

M. Diagne, M. Gueye, L. Vidal, and A. Tidjani, Thermal Stability and Fire Retardant Performance of Photo-Oxidized Nanocomposites of Polypropylene-Graft-Maleic Anhydride/Clay, Polym. Degrad. Stab, vol.89, issue.3, pp.418-426, 2005.

J. Larché, G. Gallot, L. Boudiaf-lomri, C. Poulard, I. Duemmler et al., Evidence of Surface Accumulation of Fillers during the Photo-Oxidation of Flame Retardant ATH Filled EVA Used for Cable Applications, Polym. Degrad. Stab, vol.103, pp.63-68, 2014.

U. Braun, V. Wachtendorf, A. Geburtig, H. Bahr, and B. Schartel, Weathering Resistance of Halogen-Free Flame Retardance in Thermoplastics, Polym. Degrad. Stab, issue.12, pp.2421-2429, 2010.

X. Almeras, M. L. Bras, P. Hornsby, S. Bourbigot, G. Marosi et al., Artificial Weathering and Recycling Effect on Intumescent Polypropylenebased Blends, J. Fire Sci, vol.22, issue.2, pp.143-161, 2004.

Z. Wang, E. Han, and W. Ke, Effect of Nanoparticles on the Improvement in Fire-Resistant and Anti-Ageing Properties of Flame-Retardant Coating, Surf. Coat. Technol, pp.5706-5716, 0200.

A. I. Balabanovich, S. V. Levchik, G. F. Levchik, W. Schnabel, and C. A. Wilkie, Thermal Decomposition and Combustion of ?-Irradiated Polyamide 6 Containing Phosphorus Oxynitride or Phospham, Polym. Degrad. Stab, vol.64, issue.2, pp.191-195, 1999.

A. I. Balabanovich, G. F. Levchik, S. V. Levchik, and W. Schnabel, Fire Retardance in Polyamide-6. The Effects of Red Phosphorus and Radiation-Induced Cross-Links, Fire Mater, vol.25, issue.5, pp.179-184, 2001.

. Balabanovich,

. Schnabel, Fire Retardance in Polyamide-6,6. The Effects of Red Phosphorus and Radiation-Induced Cross-Links, Macromol Mater Eng, 2002.

A. I. Balabanovich, T. A. Zevaco, and W. Schnabel, Fire Retardance in Poly(Butylene Terephthalate). The Effects of Red Phosphorus and Radiation-Induced Cross-Links, Macromol. Mater. Eng, vol.289, issue.2, pp.181-190, 2004.

S. Jia, Z. Zhang, Z. Wang, X. Zhang, and Z. Du, A Study of Gamma-Radiation-Crosslinked HDPE/EPDM Composites as Flame Retardants, Polym. Int, vol.54, issue.2, pp.320-326, 2005.

H. Lu, Y. Hu, J. Xiao, Q. Kong, Z. Chen et al., The Influence of Irradiation on Morphology Evolution and Flammability Properties of Maleated Polyethylene/Clay Nanocomposite, Mater. Lett, issue.6, pp.648-651, 2005.

H. Liu, Z. Fang, M. Peng, L. Shen, and Y. Wang, The Effects of Irradiation Cross-Linking on the Thermal Degradation and Flame-Retardant Properties of the HDPE/EVA/Magnesium Hydroxide Composites, Radiat. Phys. Chem, vol.78, issue.11, pp.922-926, 2009.

A. Coudreuse, P. Noireaux, R. Noblat, and A. Basfar, Influence of Radiation Cross-Linking and Nano-Filler on the Flammability of Ethylene Vinyl Acetate and Low Density Polyethylene Blends for Wire and Cable Applications, J. Fire Sci, vol.2010, issue.6, pp.497-507

R. Sonnier, A. Caro-bretelle, L. Dumazert, M. Longerey, and B. Otazaghine, Influence of Radiation-Crosslinking on Flame Retarded Polymer Materials-How Crosslinking Disrupts the Barrier Effect, Radiat. Phys. Chem, vol.106, pp.278-288, 2015.

C. V. Mettananda, D. A. Torvi, and E. M. Crown, Characterization of the Combustion Process of Flame Resistant Thermal Protective Textiles in the Presence of Oily Contaminants: Effects of Contamination and Decontamination, Text. Res. J, issue.10, pp.917-934, 2010.

K. Yates, R. Peel, and N. Farmer, An Investigation into the Effects of Domestic Cleaning on Upholstery Covering Materials Backcoated with Fire Retardants, Int. J. Consum. Stud, vol.23, issue.1, pp.47-52, 1999.

T. Imai, S. Hamm, and K. P. Rothenbacher, Comparison of the Recyclability of Flame-Retarded Plastics, Environ. Sci. Technol, vol.37, issue.3, pp.652-656, 2003.

S. R. Raghavan, J. Hou, G. L. Baker, and S. A. Khan, Colloidal Interactions between Particles with Tethered Nonpolar Chains Dispersed in Polar Media: Direct Correlation between Dynamic Rheology and Interaction Parameters, Langmuir, vol.16, issue.3, pp.1066-1077, 2000.

J. Posp-?il, Z. Horák, J. Pila?, N. Billingham, H. Zweifel et al., Influence of Testing Conditions on the Performance and Durability of Polymer Stabilisers in Thermal Oxidation, Polym. Degrad. Stab, vol.82, issue.2, pp.145-162, 2003.

S. Nie, Y. Hu, L. Song, Q. He, D. Yang et al., Synergistic Effect between a Char Forming Agent (CFA) and Microencapsulated Ammonium Polyphosphate on the Thermal and Flame Retardant Properties of Polypropylene, Polym. Adv. Technol, vol.19, issue.8, pp.1077-1083, 2008.

M. Shen, W. Chen, C. Kuan, H. Kuan, J. Yang et al., Preparation, Characterization of Microencapsulated Ammonium Polyphosphate and Its Flame Retardancy in Polyurethane Composites, Mater. Chem. Phys, vol.173, pp.205-212, 2016.

J. Lopez-cuesta and L. Ferry, , 2013.

E. Guillaume, D. Marquis, L. Saragoza, and C. Yardin, Incertitude sur la mesure par un « cône calorimètre » du dégagement de chaleur produit lors de la combustion d'un matériau, Rev. Fr. Métrologie, issue.31, pp.3-11, 2013.

G. Ounoughene and . Thèse, Etude Des Émissions Liées à La Décomposition Thermique de Nanocomposites : Application à l'incinération, 2015.

B. R'mili, O. L. Le-bihan, C. Dutouquet, O. Aguerre-charriol, and E. Frejafon, Particle Sampling by TEM Grid Filtration, Aerosol Sci. Technol, vol.47, issue.7, pp.767-775, 2013.

N. Lesaffre, S. Bellayer, H. Vezin, G. Fontaine, M. Jimenez et al., Recent Advances on the Ageing of Flame Retarded PLA: Effect of UV-Light and/or Relative Humidity, Polym. Degrad. Stab, vol.139, pp.143-164, 2017.
URL : https://hal.archives-ouvertes.fr/hal-01509593

K. Fukushima, D. Tabuani, C. Abbate, M. Arena, and L. Ferreri, Effect of Sepiolite on the Biodegradation of Poly(Lactic Acid) and Polycaprolactone, Polym. Degrad. Stab, issue.10, pp.2049-2056, 2010.

K. Fukushima, D. Tabuani, M. Dottori, I. Armentano, J. M. Kenny et al., Effect of Temperature and Nanoparticle Type on Hydrolytic Degradation of Poly(Lactic Acid) Nanocomposites, Polym. Degrad. Stab, issue.12, pp.2120-2129, 2011.

K. Fukushima, A. Fina, F. Geobaldo, A. Venturello, and G. Camino, Properties of Poly(Lactic Acid) Nanocomposites Based on Montmorillonite, Sepiolite and Zirconium Phosphonate, Express Polym. Lett, vol.2012, issue.11, pp.914-926

K. Fukushima, D. Tabuani, and G. Camino, Nanocomposites of PLA and PCL Based on Montmorillonite and Sepiolite, Mater. Sci. Eng. C, vol.29, issue.4, pp.1433-1441, 2009.

H. C. Bidsorkhi, M. Soheilmoghaddam, R. H. Pour, H. Adelnia, and . Mohamad, Thermal and Flammability Properties of Ethylene-Vinyl Acetate (EVA)/Sepiolite Nanocomposites, Z. Mechanical, vol.37, pp.117-122, 2014.

M. Soheilmoghaddam, M. U. Wahit, A. A. Yussuf, M. A. Al-saleh, and W. T. Whye, Characterization of Bio Regenerated Cellulose/Sepiolite Nanocomposite Films Prepared via Ionic Liquid, Polym. Test, vol.33, pp.121-130, 2014.

R. Bao, W. Yang, Z. Liu, B. Xie, and M. Yang, Polymorphism of a High-MolecularWeight Racemic Poly(l-Lactide)/Poly(d-Lactide) Blend: Effect of Melt Blending with Poly(Methyl Methacrylate), RSC Adv, vol.5, issue.25, pp.19058-19066, 2015.

K. Das, D. Ray, I. Banerjee, N. R. Bandyopadhyay, S. Sengupta et al., Crystalline Morphology of PLA/Clay Nanocomposite Films and Its Correlation with Other Properties, J. Appl. Polym. Sci, vol.2010, issue.1, pp.143-151

S. Barrau, C. Vanmansart, M. Moreau, A. Addad, G. Stoclet et al., Crystallization Behavior of Carbon Nanotube?Polylactide Nanocomposites, Macromolecules, vol.44, issue.16, pp.6496-6502, 2011.
URL : https://hal.archives-ouvertes.fr/hal-00653292

G. Liu, W. Chen, and J. Yu, A Novel Process to Prepare Ammonium Polyphosphate with Crystalline Form II and Its Comparison with Melamine Polyphosphate, Ind. Eng. Chem. Res, issue.23, pp.12148-12155, 2010.

K. Wu, Y. Zhang, W. Hu, J. Lian, and Y. Hu, Influence of Ammonium Polyphosphate Microencapsulation on Flame Retardancy, Thermal Degradation and Crystal Structure of Polypropylene Composite, Compos. Sci. Technol, vol.81, pp.17-23, 2013.

A. Fujimori, N. Ninomiya, and T. Masuko, Structure and Mechanical Properties in Drawn Poly(lLactide)/Clay Hybrid Films, Polym. Adv. Technol, vol.19, issue.12, pp.1735-1744, 2008.

E. Robles, I. Urruzola, J. Labidi, and L. Serrano, Surface-Modified Nano-Cellulose as Reinforcement in Poly(Lactic Acid) to Conform New Composites, Ind. Crops Prod, vol.71, pp.44-53, 2015.

L. He, Y. Zhang, X. Zeng, D. Quan, S. Liao et al., Fabrication and Characterization of Poly(l-Lactic Acid) 3D Nanofibrous Scaffolds with Controlled Architecture by Liquid-Liquid Phase Separation from a Ternary Polymer-Solvent System, Polymer, vol.50, issue.16, pp.4128-4138, 2009.

E. M. Woo and Y. Wang, New Complex Crystals of Chiral Poly( L -Lactic Acid) and Different Tactic Poly(Methyl Methacrylate), Macromol. Chem. Phys, vol.2012, issue.16, pp.1688-1696

A. Hamins, Environmental Implications of Combustion Processes; Ischwa K. Puri, 1993.

J. Lopez-cuesta, C. Longuet, and C. Chivas-joly, Thermal Degradation, Flammability, and Potential Toxicity of Polymer Nanocomposites, In Health and Environmental Safety of Nanomaterials, pp.278-310, 2014.

B. W. Doyle, Combustion Source Evaluation, Student Manual, APTI Course 427 Third Edition, ICES Ltd, vol.318, 2003.

M. Mora, M. López, M. Ángeles-carmona, C. Jiménez-sanchidrián, and J. Rafael-ruiz, Study of the Thermal Decomposition of a Sepiolite by Mid-and near-Infrared Spectroscopies, Polyhedron, issue.16, pp.3046-3051, 2010.

J. L. Pérez-rodríguez and E. Galán, Determination of Impurity in Sepiolite by Thermal Analysis, J. Therm. Anal, vol.42, issue.1, pp.131-141, 1994.

H. C. Skinner, M. Ross, and C. Frondel, Asbestos and Other Fibrous Materials: Mineralogy, Crystal Chemistry, and Health Effects, 1988.

M. I. Habib, Thèse : Applications Des Méthodes de l'analyse Thermique à l'étude Du Vieillissement Des Polymères, 2013.

;. Yanagisawa, . Kiuchi, and . Iji, Enhanced Flame Retardancy of Polylactic Acid with Aluminum TriHydroxide and Phenolic Resins, Kobunshi Ronbunshu, vol.66, issue.2, pp.49-54, 2009.