T. J. Seebeck, Ueber den magnetismus der galvenische kette, Abh. K », Akad. Wiss. Berlin, vol.289, p.1821

T. J. Seebeck and . Magnetische,

. Differenz, Abhandlungen der Königlichen Akademie der Wissenschaften in Berlin, pp.289-346, 1822.

J. C. Peltier, « Nouvelles expériences sur la caloricité des courants électrique, Ann. Chim. Phys, vol.56, pp.371-386, 1834.

W. Thomson, On a mechanical theory of thermo-electric currents, Proceedings of the Royal society of Edinburgh, vol.3, pp.91-98, 1857.

L. Onsager, Reciprocal relations in irreversible processes. I. », Physical review, vol.37, p.405, 1931.

E. Altenkirch, Über den nutzeffekt der thermosäule, vol.10, p.560, 1909.

M. Telkes, The Efficiency of Thermoelectric Generators. I. », Journal of Applied Physics, vol.18, pp.1116-1127

M. Telkes, . Solar-thermoelectric, and . Generators, Journal of Applied Physics, vol.25, issue.6, pp.765-777

A. F. Ioffe, L. S. Stil'bans, E. K. Iordanishvili, T. S. Stavitskaya, A. Gelbtuch et al., Semiconductor thermoelements and thermoelectric cooling », vol.12, p.42, 1959.

H. J. Goldsmid and R. W. Douglas, « The use of semiconductors in thermoelectric refrigeration, British Journal of Applied Physics, vol.5, issue.11, p.386, 1954.

G. A. Slack, « The thermal conductivity of nonmetallic crystals, Solid state physics, vol.34, pp.1-71, 1979.

Y. Pei, H. Wang, and G. J. Snyder, Advanced Materials, vol.24, pp.6125-6135, 2012.

X. Shi, « Band Structure Engineering and Thermoelectric Properties of Charge-Compensated Filled Skutterudites, Scientific Reports, vol.5, p.14641, 2015.

V. Zlatic, A. Hewson, and É. , New Materials for Thermoelectric Applications: Theory and Experiment, 2013.

T. C. Harman, P. J. Taylor, M. P. Walsh, and B. E. Laforge, Quantum Dot Superlattice Thermoelectric Materials and Devices, vol.297, pp.2229-2232, 2002.

J. P. Heremans, . Low-dimensional, and . Thermoelectricity, Acta Physica Polonica A, vol.108, p.609, 2006.

S. K. Bux, J. Fleurial, and R. B. Kaner, « Nanostructured materials for thermoelectric applications, Chem. Commun, vol.46, pp.8311-8324, 2010.

R. He, G. Schierning, and K. Nielsch, Thermoelectric Devices: A Review of Devices, Architectures, and Contact Optimization, vol.3, p.1700256, 2018.

K. Koumoto, T. Mori, and É. , Thermoelectric Nanomaterials: Materials Design and Applications, 2013.

S. B. Riffat, X. Ma, and . Thermoelectrics, Applied thermal engineering, vol.23, issue.8, pp.913-935, 2003.

Z. Ren, Y. Lan, and Q. Zhang, Advanced Thermoelectrics: Materials, Contacts, Devices, and Systems, 2017.

L. Onsager, Reciprocal relations in irreversible processes. II. », Physical review, vol.38, p.2265, 1931.

H. B. Casimir, « On Onsager's Principle of Microscopic Reversibility, Rev. Mod

, Chapitre I : Fondamentaux de la thermoélectricité 40

, Phys, vol.17, issue.2-3, pp.343-350

I. Prigogine, « Introduction to thermodynamics of irreversible processes, 1967.

H. B. Callen, On the theory of irreversible processes, 1947.

S. R. De-groot and P. Mazur, Non-equilibrium thermodynamics, 1984.

C. A. Domenicali, Irreversible thermodynamics of thermoelectricity, vol.26, p.237, 1954.

C. B. Vining, « An inconvenient truth about thermoelectrics », Nature Materials, vol.8, issue.2, pp.83-85, 2009.

G. J. Snyder and E. S. Toberer, Complex thermoelectric materials, vol.7, pp.105-114, 2008.

C. H. Goodman, « The prediction of semiconducting properties in inorganic compounds, Journal of Physics and Chemistry of Solids, vol.6, issue.4, pp.305-314, 1958.

J. Goldsmid, Bismuth Telluride and its Alloys as Materials for Thermoelectric Generation », Materials, vol.7, pp.2577-2592, 2014.

S. Scherrer, H. Scherrer, and . Bismuth-telluride, Antimony Telluride, and their Solid Solutions, pp.211-238, 1995.

G. D. Mahan and . Good-thermoelectrics, Ehrenreich et F. Spaepen, Éd, vol.51, pp.81-157, 1998.

K. V. Selvan, M. N. Hasan, and M. S. Ali, « State-of-the-Art Reviews and Analyses of Emerging Research Findings and Achievements of Thermoelectric Materials over the Past Years, Journal of Electronic Materials, déc, 2018.

D. M. Rowe and É. , CRC handbook of thermoelectrics, 1995.

C. Wood, « Materials for thermoelectric energy conversion, Rep. Prog. Phys, vol.51, issue.4, pp.459-539, 1988.

H. J. Goldsmid and G. S. Nolas, « A review of the new thermoelectric materials, Proceedings ICT2001. 20 International Conference on Thermoelectrics, pp.1-6, 2001.

T. M. Tritt, Thermoelectric Phenomena, Materials, and Applications, vol.41, pp.433-448, 2011.

S. Ballikaya, G. Wang, K. Sun, and C. Uher, Thermoelectric Properties of Triple-Filled BaxYbyInzCo4Sb12 Skutterudites », vol.40, pp.570-576, 2011.

X. Shi, « Multiple-Filled Skutterudites: High Thermoelectric Figure of Merit through Separately Optimizing Electrical and Thermal Transports, J. Am. Chem. Soc, vol.133, pp.7837-7846, 2011.

J. Martin, H. Wang, and G. S. Nolas, « Optimization of the thermoelectric properties of Ba8Ga16Ge30 », Appl. Phys. Lett, vol.92, p.222110, 2008.

G. J. Snyder, M. Christensen, E. Nishibori, T. Caillat, and B. B. Iversen, « Disordered zinc in Zn4Sb3 with phonon-glass and electron-crystal thermoelectric properties, Nat Mater, vol.3, issue.7, pp.458-463, 2004.

E. S. Toberer, « Traversing the Metal-Insulator Transition in a Zintl Phase: Rational Enhancement of Thermoelectric Efficiency in Yb14Mn1?xAlxSb11, Advanced Functional Materials, vol.18, pp.2795-2800, 2008.

X. Yan, « Stronger phonon scattering by larger differences in atomic mass and size in p-type half-Heuslers Hf1?xTixCoSb0.8Sn0.2 », Energy Environ. Sci, vol.5, issue.6, pp.7543-7548, 2012.

A. F. May, J. Fleurial, and G. J. Snyder,

, La3?xTe4 via Yb Substitution, vol.22, pp.2995-2999, 2010.

L. Zhao, BiCuSeO oxyselenides: new promising thermoelectric materials, vol.7, pp.2900-2924, 2014.

G. Kim, L. Shao, K. Zhang, and K. P. Pipe, « Engineered doping of organic semiconductors for enhanced thermoelectric efficiency, Nat Mater, vol.12, issue.8, pp.719-723, 2013.

K. Suekuni, « High-performance thermoelectric mineral Cu12?xNixSb4S13 tetrahedrite, Journal of Applied Physics, vol.113, p.43712, 2013.

C. Bourgès, « High-Performance Thermoelectric Bulk Colusite by Process Controlled Structural Disordering, J. Am. Chem. Soc, vol.140, pp.2186-2195, 2018.

C. Chen, H. Wang, Y. Chen, T. Day, and G. J. Snyder, « Thermoelectric properties of p-type polycrystalline SnSe doped with Ag, J. Mater. Chem. A, vol.2, pp.11171-11176, 2014.

D. Ibrahim, « Reinvestigation of the thermal properties of single-crystalline SnSe », Appl. Phys. Lett, vol.110, issue.3, p.32103, 2017.

T. Wei, « Distinct Impact of Alkali-Ion Doping on Electrical Transport Properties of Thermoelectric p-Type Polycrystalline SnSe, J. Am. Chem. Soc, vol.138, pp.8875-8882, 2016.

L. Zhao, C. Chang, G. Tan, M. G. Kanatzidis, and . Snse, Chapitre II : Modules thermoélectriques -Etat de l'art, vol.9, p.42, 2016.

I. I. Chapitre, Modules thermoélectriques -Etat de l'art, p.43

I. I. Chapitre, Modules thermoélectriques -Etat de l'art

, Chapitre II : Modules thermoélectriques -Etat de l'art

D. M. Rowe and É. , CRC handbook of thermoelectrics, 1995.

D. Champier, « Thermoelectric generators: A review of applications, Energy Convers. Manag, vol.140, pp.167-181, 2017.

D. B. Evans and L. Kobren, « An electron microprobe study of inclusions in lead telluride thermoelectric elements, p.15

D. Briand, E. Yeatman, and E. S. Roundy, Micro Energy Harvesting, 2015.

G. Nie, « Performance of Skutterudite-Based Modules, J. Electron. Mater, vol.46, issue.5, pp.2640-2644, 2017.

Q. H. Zhang, X. Y. Huang, S. Q. Bai, X. Shi, C. Uher et al., « Thermoelectric Devices for Power Generation: Recent Progress and Future Challenges », Adv. Eng. Mater, vol.18, issue.2, pp.194-213, 2016.

. «-advanced-thermoelectrics-|-materials, . Contacts, . Devices, ». Systems, &. Taylor et al.,

M. S. El-genk, H. H. Saber, T. Caillat, and J. Sakamoto, « Tests results and performance comparisons of coated and un-coated skutterudite based segmented unicouples, Energy Convers. Manag, vol.47, issue.2, pp.174-200, 2006.

G. J. Snyder, « Application of the compatibility factor to the design of segmented and cascaded thermoelectric generators, Appl. Phys. Lett, vol.84, pp.2436-2438, 2004.

K. W. Lindler, Use of multi-stage cascades to improve performance of thermoelectric heat pumps, Energy Convers. Manag, vol.39, issue.10, pp.1009-1014, 1998.

A. Schmitz, C. Stiewe, and E. E. Müller, « Preparation of Ring-Shaped Thermoelectric Legs from PbTe Powders for Tubular Thermoelectric Modules, J. Electron. Mater, vol.42, issue.7, pp.1702-1706, 2013.

D. T. Crane and L. E. Bell, « Progress Towards Maximizing the Performance of a Thermoelectric Power Generator, 2006 25th International Conference on Thermoelectrics, pp.11-16, 2006.

I. Stark, « Invited Talk: Thermal Energy Harvesting with Thermo Life, International Workshop on Wearable and Implantable Body Sensor Networks (BSN'06), pp.19-22, 2006.

M. Stordeur and I. Stark, « Low power thermoelectric generator-self-sufficient energy supply for micro systems, XVI ICT '97. Proceedings ICT'97. 16th International Conference on Thermoelectrics, pp.575-577, 1997.

Z. Wang, V. Leonov, and P. Fiorini, Van Hoof, « Realization of a wearable miniaturized thermoelectric generator for human body applications, Sens. Actuators Phys, vol.156, issue.1, pp.95-102, 2009.

K. Tappura, « A numerical study on the design trade-offs of a thin-film thermoelectric generator for large-area applications, Renew. Energy, vol.120, pp.78-87, 2018.

W. Glatz, S. Muntwyler, and C. Hierold, « Optimization and fabrication of thick flexible polymer based micro thermoelectric generator, Sens. Actuators Phys, vol.132, issue.1, pp.337-345, 2006.

Z. Wang, Y. Van-andel, M. Jambunathan, V. Leonov, R. Elfrink et al., Characterization of a Bulk-Micromachined Membraneless In-Plane Thermopile, vol.40, pp.499-503, 2011.

I. I. Chapitre, Modules thermoélectriques -Etat de l'art, p.75

J. Weber, K. Potje-kamloth, F. Haase, P. Detemple, F. Völklein et al., « Coin-size coiled-up polymer foil thermoelectric power generator for wearable electronics, Sens. Actuators Phys, vol.132, issue.1, pp.325-330, 2006.

D. E. Wesolowski, « Development of a Bi2Te3-based thermoelectric generator with highaspect ratio, free-standing legs, J. Mater. Res, vol.27, issue.8, pp.1149-1156, 2012.

D. M. Rowe and G. Min, « Design theory of thermoelectric modules for electrical power generation, IEE Proc. -Sci. Meas. Technol, vol.143, issue.6, pp.351-356, 1996.

J. Prado-gonjal, M. Phillips, P. Vaqueiro, G. Min, and A. V. Powell, Skutterudite Thermoelectric Modules with High Volume-Power-Density: Scalability and Reproducibility, vol.1, pp.6609-6618, 2018.

S. M. Jones, Space exploration applications, J. Sol-Gel Sci. Technol, vol.40, issue.2, pp.351-357, 2006.

Y. Zhang, « High-temperature and high-power-density nanostructured thermoelectric generator for automotive waste heat recovery, Energy Convers. Manag, vol.105, pp.946-950, 2015.

E. Brandon, Development of new high temperature power generating couples for the Advanced Thermoelectric Converter (ATEC), 2010.

J. Sakamoto, T. Caillat, J. Fleurial, S. Jones, J. Paik et al., « Improving Thermoelectric Device Performance and Durability through the Integration of Advanced, Aerogel-Based Ceramics, Electroceramic Materials and Applications, pp.275-290, 2011.

H. H. Saber, M. S. El-genk, and E. T. Caillat, « Tests results of skutterudite based thermoelectric unicouples, Energy Convers. Manag, vol.48, issue.2, pp.555-567, 2007.

Y. Gelbstein, G. Gotesman, Y. Lishzinker, Z. Dashevsky, and M. P. Dariel, « Mechanical properties of PbTe-based thermoelectric semiconductors, Scr. Mater, vol.58, issue.4, pp.251-254, 2008.

A. C. Kallel, G. Roux, and C. L. Martin, Thermoelectric and mechanical properties of a hot pressed nanostructured n-type Si80Ge20 alloy, Mater. Sci. Eng. A, vol.564, pp.65-70, 2013.
URL : https://hal.archives-ouvertes.fr/hal-00929759

L. Zhao, B. Zhang, J. Li, M. Zhou, W. Liu et al., « Thermoelectric and mechanical properties of nano-SiC-dispersed Bi2Te3 fabricated by mechanical alloying and spark plasma sintering, J. Alloys Compd, vol.455, issue.1, pp.259-264, 2008.

R. D. Schmidt, X. Fan, E. D. Case, and P. B. Sarac, « Mechanical properties of Mg2Si thermoelectric materials with the addition of 0-4 vol% silicon carbide nanoparticles (SiCNP), J. Mater. Sci, vol.50, issue.11, pp.4034-4046, 2015.

V. Ravi, Mechanical Properties of Thermoelectric Skutterudites », AIP Conf. Proc, vol.969, pp.656-662, 2008.

P. H. Le, C. Luo, S. Jian, T. Lin, and P. Yang, « Nanomechanical properties and fracture toughness of Bi3Se2Te thin films grown using pulsed laser deposition », Mater. Chem. Phys, vol.182, pp.72-76, 2016.

R. He, « Studies on mechanical properties of thermoelectric materials by nanoindentation, Phys. Status Solidi A, vol.212, issue.10, pp.2191-2195, 2015.

Y. Gelbstein, « Physical, Mechanical, and Structural Properties of Highly Efficient Nanostructured n-and p-Silicides for Practical Thermoelectric Applications, J. Electron. Mater, vol.43, issue.6, pp.1703-1711, 2014.

S. Leblanc, « Thermoelectric generators: Linking material properties and systems engineering for waste heat recovery applications, Sustain. Mater. Technol, vol.1, issue.2, pp.26-35, 2014.

I. I. Chapitre, Modules thermoélectriques -Etat de l'art, p.76

M. Rull-bravo, A. Moure, J. F. Fernández, and M. Martín-gonzález, Skutterudites as thermoelectric materials: revisited », vol.5, pp.41653-41667, 2015.

C. Yu, « Titanium-based thin film metallic glass as diffusion barrier layer for PbTebased thermoelectric modules, APL Mater, vol.7, issue.1, p.13001, 2019.

V. Ravi, « Thermal Expansion Studies of Selected High-Temperature Thermoelectric Materials, J. Electron. Mater, vol.38, issue.7, pp.1433-1442, 2009.

R. He, G. Schierning, and K. Nielsch, Thermoelectric Devices: A Review of Devices, Architectures, and Contact Optimization, vol.3, p.1700256, 2018.

A. Nour-eddine, D. Chalet, X. Faure, L. Aixala, and P. Chessé, « Optimization and characterization of a thermoelectric generator prototype for marine engine application, vol.143, pp.682-695, 2018.

A. Elghool, F. Basrawi, T. K. Ibrahim, K. Habib, H. Ibrahim et al., Idris, « A review on heat sink for thermo-electric power generation: Classifications and parameters affecting performance, Energy Convers. Manag, vol.134, pp.260-277, 2017.

A. Paraskevas and E. Koutroulis, « A simple maximum power point tracker for thermoelectric generators, Energy Convers. Manag, vol.108, pp.355-365, 2016.

A. Montecucco, J. Siviter, A. R. Knox, and . Simple, fast and accurate maximum power point tracking converter for thermoelectric generators, 2012 IEEE Energy Conversion Congress and Exposition (ECCE), pp.2777-2783, 2012.

I. Laird and D. D. Lu, « Steady state reliability of maximum power point tracking algorithms used with a thermoelectric generator, 2013 IEEE International Symposium on Circuits and Systems (ISCAS2013), pp.1316-1319, 2013.

J. Yan, X. Liao, D. Yan, and Y. Chen, « Review of Micro Thermoelectric Generator, J. Microelectromechanical Syst, vol.27, issue.1, pp.1-18, 2018.

Q. H. Zhang, X. Y. Huang, S. Q. Bai, X. Shi, C. Uher et al., « Thermoelectric Devices for Power Generation: Recent Progress and Future Challenges », Adv. Eng. Mater, vol.18, issue.2, pp.194-213, 2016.

K. Itoigawa, H. Ueno, M. Shiozaki, T. Toriyama, and E. S. Sugiyama, « Fabrication of flexible thermopile generator, J. Micromechanics Microengineering, vol.15, issue.9, pp.233-238, 2005.

W. Glatz, E. Schwyter, L. Durrer, and C. Hierold, « $\hboxBi_2\hboxTe_3$-Based Flexible Micro Thermoelectric Generator With Optimized Design, J. Microelectromechanical Syst, vol.18, issue.3, pp.763-772, 2009.

Y. Sun, C. Di, W. Xu, and E. D. Zhu, Advances in n-Type Organic Thermoelectric Materials and Devices, vol.0, p.1800825

H. Jin, « Hybrid Organic-Inorganic Thermoelectric Materials and Devices », Angew. Chem. Int. Ed, vol.0

. Bulova-thermatron,

D. Sur,

M. Kishi, « Micro thermoelectric modules and their application to wristwatches as an energy source, Eighteenth International Conference on Thermoelectrics. Proceedings, ICT'99 (Cat. No.99TH8407), pp.301-307, 1999.

R. Venkatasubramanian, E. Siivola, T. Colpitts, and B. O'quinn, « Thin-film thermoelectric devices with high room-temperature figures of merit, Nature, vol.413, pp.597-602, 2001.

I. I. Chapitre, Modules thermoélectriques -Etat de l'art, p.77

, Thermoelectric Modules | Laird Thermal Systems

D. Sur,

G. J. Snyder, J. R. Lim, C. Huang, and J. Fleurial, Thermoelectric microdevice fabricated by a MEMS-like electrochemical process, Nat. Mater, vol.2, issue.8, pp.528-531, 2003.

J. R. Lin, G. J. Snyder, C. Huang, J. A. Herman, M. A. Ryan et al., « Thermoelectric microdevice fabrication process and evaluation at the Jet Propulsion Laboratory (JPL), Twenty-First International Conference on Thermoelectrics, pp.535-539, 2002.

H. Bottner, « New thermoelectric components using microsystem technologies, J. Microelectromechanical Syst, vol.13, issue.3, pp.414-420, 2004.

H. Bottner, J. Nurnus, A. Schubert, and F. Volkert, « New high density micro structured thermogenerators for stand alone sensor systems, 2007 26th International Conference on Thermoelectrics, pp.306-309, 2007.

W. Glatz, E. Schwyter, L. Durrer, and C. Hierold, « $\hbox{Bi}_{2}\hbox{Te}_{3}$-Based Flexible Micro Thermoelectric Generator With Optimized Design, J. Microelectromechanical Syst, vol.18, issue.3, pp.763-772, 2009.

D. M. Rowe, D. V. Morgan, and J. H. Kiely, « Miniature low-power/high-voltage thermoelectric generator, Electron. Lett, vol.25, issue.2, pp.166-168, 1989.

M. Stordeur and I. Stark, « Low power thermoelectric generator-self-sufficient energy supply for micro systems, XVI ICT '97. Proceedings ICT'97. 16th International Conference on Thermoelectrics (Cat. No.97TH8291), pp.575-577, 1997.

H. Glosch, M. Ashauer, U. Pfeiffer, and E. W. Lang, « A thermoelectric converter for energy supply, Sens. Actuators Phys, vol.74, issue.1, pp.246-250, 1999.

M. Strasser, R. Aigner, M. Franosch, and G. Wachutka, « Miniaturized thermoelectric generators based on poly-Si and poly-SiGe surface micromachining, Sens. Actuators Phys, pp.535-542, 2002.

J. Xie, C. Lee, and H. Feng, « Design, Fabrication, and Characterization of CMOS MEMS-Based Thermoelectric Power Generators, J. Microelectromechanical Syst, vol.19, issue.2, pp.317-324

X. Yu, « CMOS MEMS-based thermoelectric generator with an efficient heat dissipation path, J. Micromechanics Microengineering, vol.22, issue.10, p.105011, 2012.

S. M. Yang, M. Cong, and E. T. Lee, « Application of quantum well-like thermocouple to thermoelectric energy harvester by BiCMOS process, Sens. Actuators Phys, vol.166, issue.1, pp.117-124, 2011.

S. M. Yang, T. Lee, and C. A. Jeng, « Development of a thermoelectric energy harvester with thermal isolation cavity by standard CMOS process, Sens. Actuators Phys, vol.153, issue.2, pp.244-250, 2009.

P. Kao, P. Shih, C. Dai, and M. Liu, « Fabrication and characterization of CMOS-MEMS thermoelectric micro generators, Sensors, vol.10, issue.2, pp.1315-1325, 2010.

J. H. Kiely, D. V. Morgan, and D. M. Rowe, « The design and fabrication of a miniature thermoelectric generator using MOS processing techniques, Meas. Sci. Technol, vol.5, issue.2, pp.182-189, 1994.

M. Stordeur and I. Stark, « Low power thermoelectric generator-self-sufficient energy supply for micro systems, XVI ICT '97. Proceedings ICT'97. 16th International Conference on Thermoelectrics, pp.575-577, 1997.

I. I. Chapitre, Modules thermoélectriques -Etat de l'art, p.78

M. Strasser, R. Aigner, M. Franosch, and G. Wachutka, « Miniaturized thermoelectric generators based on poly-Si and poly-SiGe surface micromachining, Sens. Actuators Phys, pp.535-542, 2002.

V. Leonov, Y. Van-andel, Z. Wang, R. J. Vullers, and C. Van-hoof, Micromachined polycrystalline si thermopiles in a T-shirt, pp.1-2011

J. Su, « A batch process micromachined thermoelectric energy harvester: fabrication and characterization, J. Micromechanics Microengineering, vol.20, issue.10, p.104005, 2010.

S. M. Yang, T. Lee, and M. Cong, « Design and verification of a thermoelectric energy harvester with stacked polysilicon thermocouples by CMOS process, Sens. Actuators Phys, vol.157, issue.2, pp.258-266

Z. Wang, Y. Van-andel, M. Jambunathan, V. Leonov, R. Elfrink et al., Characterization of a Bulk-Micromachined Membraneless In-Plane Thermopile, vol.40, pp.499-503, 2011.

K. Ziouche, Z. Yuan, P. Lejeune, T. Lasri, D. Leclercq et al., Silicon-Based Monolithic Planar Micro Thermoelectric Generator Using Bonding Technology, J. Microelectromechanical Syst, vol.26, issue.1, pp.45-47, 2017.

D. Tainoff, « Network of thermoelectric nanogenerators for low power energy harvesting, Nano Energy, vol.57, pp.804-810, 2019.

A. Jacquot, G. Chen, H. Scherrer, A. Dauscher, and B. Lenoir, « Modeling of on-membrane thermoelectric power supplies, Sens. Actuators Phys, vol.116, issue.3, pp.501-508, 2004.

A. Jacquot, W. L. Liu, G. Chen, J. P. Fleurial, A. Dauscher et al., « Fabrication and modeling of an in-plane thermoelectric micro-generator, Twenty-First International Conference on Thermoelectrics, pp.561-564, 2002.

M. Strasser, R. Aigner, C. Lauterbach, T. F. Sturm, M. Franosch et al., « Micromachined CMOS thermoelectric generators as on-chip power supply, Sens. Actuators Phys, vol.114, issue.2, pp.362-370, 2004.

P. Kao, P. Shih, C. Dai, and M. Liu, « Fabrication and characterization of CMOS-MEMS thermoelectric micro generators, Sensors, vol.10, issue.2, pp.1315-1325, 2010.

J. R. Lim, G. J. Snyder, C. K. Huang, J. A. Herman, M. A. Ryan et al., « Thermoelectric microdevice fabrication process and evaluation at the Jet Propulsion Laboratory (JPL), Proceedings ICT 2002: 21st International Conference on Thermoelectrics, pp.535-539, 2002.

M. Takashiri, T. Shirakawa, K. Miyazaki, and H. Tsukamoto, « Fabrication and characterization of bismuth-telluride-based alloy thin film thermoelectric generators by flash evaporation method, Sens. Actuators Phys, vol.138, issue.2, pp.329-334, 2007.

W. Wang, Y. Ji, H. Xu, H. Li, T. Visan et al., « A high packing density microthermoelectric power generator based on film thermoelectric materials fabricated by electrodeposition technology, Surf. Coat. Technol, vol.231, pp.583-589, 2013.

M. Kim, M. Kim, S. Lee, C. Kim, and Y. Kim, « Wearable thermoelectric generator for harvesting human body heat energy, Smart Mater. Struct, vol.23, issue.10, p.105002, 2014.

D. M. Rowe, D. V. Morgan, and J. H. Kiely, « Miniature low-power/high-voltage thermoelectric generator, Electron. Lett, vol.25, issue.2, pp.166-168, 1989.

A. Chen, D. Madan, P. K. Wright, and J. W. Evans, « Dispenser-printed planar thick-film thermoelectric energy generators, J. Micromechanics Microengineering, vol.21, issue.10, p.104006, 2011.

L. Francioso, « Thin film technology flexible thermoelectric generator and dedicated ASIC for energy harvesting applications, 5th IEEE International Workshop on Advances in Sensors and Interfaces IWASI, pp.104-107, 2013.

I. I. Chapitre, Modules thermoélectriques -Etat de l'art, p.79

M. Kishi, « Fabrication of a miniature thermoelectric module with elements composed of sintered Bi-Te compounds, XVI ICT '97. Proceedings ICT'97. 16th International Conference on Thermoelectrics (Cat. No.97TH8291), pp.653-656, 1997.

R. Roth, R. Rostek, K. Cobry, C. Köhler, M. Groh et al., « Design and Characterization of Micro Thermoelectric Cross-Plane Generators With Electroplated$\rm Bi_2\rm Te_3$,$\rm Sb_x\rm Te_y$, and Reflow Soldering, J. Microelectromechanical Syst, vol.23, issue.4, pp.961-971, 2014.

W. Zhang, J. Yang, and D. Xu, « A High Power Density Micro-Thermoelectric Generator Fabricated by an Integrated Bottom-Up Approach, J. Microelectromechanical Syst, vol.25, issue.4, pp.744-749, 2016.

W. Qu, M. Plötner, and W. Fischer, « Microfabrication of thermoelectric generators on flexible foil substrates as a power source for autonomous microsystems, J. Micromechanics Microengineering, vol.11, issue.2, pp.146-152, 2001.

Z. Lu, « Fabrication of flexible thermoelectric thin film devices by inkjet printing, Small Weinh. Bergstr. Ger, vol.10, pp.3551-3554, 2014.

A. Thorbeck, ». Start, and T. ,

«. Admin and . Generator,

D. Sur,

|. «-thermoelectric-power-generators and . Marlow,

D. Sur,

S. R. Brown, S. M. Kauzlarich, F. Gascoin, and G. J. Snyder, « Yb 14 MnSb 11 : New High Efficiency Thermoelectric Material for Power Generation, Chem. Mater, vol.18, issue.7, pp.1873-1877, 2006.

C. Stiewe, R. Sottong, J. De-boor, and E. E. Müller, Upscaled Synthesis of n-and p-Type Thermoelectric Skutterudite Single Legs by Gas Atomization and Current-Assisted Sintering, Phys. Status Solidi A, vol.215, p.1700995, 2018.

E. S. Toberer, « Traversing the Metal-Insulator Transition in a Zintl Phase: Rational Enhancement of Thermoelectric Efficiency in Yb14Mn1?xAlxSb11, Adv. Funct. Mater, vol.18, pp.2795-2800, 2008.

S. Ballikaya, G. Wang, K. Sun, and C. Uher, Thermoelectric Properties of Triple-Filled BaxYbyInzCo4Sb12 Skutterudites, vol.40, pp.570-576, 2011.

X. Yan, « Stronger phonon scattering by larger differences in atomic mass and size in ptype half-Heuslers Hf1?xTixCoSb0.8Sn0.2 », Energy Environ. Sci, vol.5, issue.6, pp.7543-7548, 2012.

K. V. Selvan, M. N. Hasan, and M. S. Ali, « State-of-the-Art Reviews and Analyses of Emerging Research Findings and Achievements of Thermoelectric Materials over the Past Years, J. Electron. Mater., déc, 2018.

A. F. May, J. Fleurial, and G. J. Snyder, « Optimizing Thermoelectric Efficiency in La3?xTe4 via Yb Substitution, vol.22, pp.2995-2999, 2010.

. Iu and . Kogut, « Nanostructure Features, Phase Relationships and Thermoelectric Properties of Melt-Spun and Spark-Plasma-Sintered Skutterudites », Acta Phys. Pol. A, vol.133, issue.4, pp.879-883, 2018.

X. Shi, « Multiple-Filled Skutterudites: High Thermoelectric Figure of Merit through Separately Optimizing Electrical and Thermal Transports, J. Am. Chem. Soc, vol.133, pp.7837-7846, 2011.

T. Caillat, J. Fleurial, G. N. Snyder, A. Zoltan, D. Zoltan et al., Eighteenth Chapitre II : Modules thermoélectriques -Etat de l'art, p.80

, International Conference on Thermoelectrics. Proceedings, ICT'99 (Cat. No.99TH8407), pp.473-476, 1999.

D. Zhao, C. Tian, S. Tang, Y. Liu, L. Jiang et al., « Fabrication of a CoSb3-based thermoelectric module, Mater. Sci. Semicond. Process, vol.13, issue.3, pp.221-224, 2010.

J. Q. Guo, « Development of Skutterudite Thermoelectric Materials and Modules, J. Electron. Mater, vol.41, issue.6, pp.1036-1042

S. Choi, « A Resistance Ratio Analysis for CoSb3-Based Thermoelectric Unicouples, J. Electron. Mater, vol.41, pp.1004-1010

J. García-cañadas, A. V. Powell, A. Kaltzoglou, P. Vaqueiro, and G. Min, « Fabrication and Evaluation of a Skutterudite-Based Thermoelectric Module for High-Temperature Applications, J. Electron. Mater, vol.42, issue.7, pp.1369-1374, 2013.

J. R. Salvador, « Conversion efficiency of skutterudite-based thermoelectric modules, Phys. Chem. Chem. Phys, vol.16, pp.12510-12520, 2014.

E. Alleno, « A thermoelectric generator based on an n-type clathrate and a p-type skutterudite unicouple, Phys. Status Solidi A, vol.211, issue.6, pp.1293-1300, 2014.

Q. Zhang, « Realizing high-performance thermoelectric power generation through grain boundary engineering of skutterudite-based nanocomposites, Nano Energy, vol.41, pp.501-510, 2017.

S. H. Park, « High-Power-Density Skutterudite-Based Thermoelectric Modules with Ultralow Contact Resistivity Using Fe-Ni Metallization Layers, ACS Appl. Energy Mater, vol.1, issue.4, pp.1603-1611, 2018.

D. Zhao, H. Geng, and X. Teng, « Fabrication and reliability evaluation of CoSb3/W-Cu thermoelectric element, J. Alloys Compd, vol.517, pp.198-203, 2012.

A. Muto, J. Yang, B. Poudel, Z. Ren, and G. Chen, Skutterudite Unicouple Characterization for Energy Harvesting Applications, vol.3, pp.245-251, 2013.

J. Fan, L. Chen, S. Bai, and X. Shi, Joining of Mo to CoSb3 by spark plasma sintering by inserting a Ti interlayer, Mater. Lett, vol.58, pp.3876-3878, 2004.

X. Y. Li, L. D. Chen, J. F. Fan, W. B. Zhang, T. Kawahara et al., Thermoelectric properties of Te-doped CoSb3 by spark plasma sintering, J. Appl. Phys, vol.98, issue.8, p.83702, 2005.

J. Prado-gonjal, M. Phillips, P. Vaqueiro, G. Min, and A. V. Powell, Skutterudite Thermoelectric Modules with High Volume-Power-Density: Scalability and Reproducibility, 2018.

L. Shi, X. Huang, M. Gu, and E. L. Chen, Interfacial structure and stability in Ni/SKD/Ti/Ni skutterudite thermoelements, vol.285, pp.312-317, 2016.

K. T. Wojciechowski, R. Zybala, and E. R. Mania, High temperature CoSb3-Cu junctions, vol.51, pp.1198-1202, 2011.

X. Li, L. Chen, J. Fan, S. Et, «. Bai et al., Ti/CoSb/sub 3/ joining technology for CoSb/sub 3/ based materials, ICT 2005. 24th International Conference on Thermoelectrics, pp.540-542, 2005.

P. Wei, W. Zhao, C. Dong, X. Yang, J. Yu et al., « Excellent performance stability of Ba and In double-filled skutterudite thermoelectric materials, Acta Mater, vol.59, issue.8, pp.3244-3254, 2011.

X. Xia, P. Qiu, X. Shi, X. Li, X. Huang et al., « High-Temperature Oxidation Behavior of Filled Skutterudites YbyCo4Sb12, J. Electron. Mater, vol.41, issue.8, pp.2225-2231

J. Leszczynski, K. T. Wojciechowski, and A. L. Malecki, Studies on thermal decomposition and oxidation of CoSb3, vol.105, p.211, 2011.

I. I. Chapitre, Modules thermoélectriques -Etat de l'art, p.81

E. Godlewska, K. Zawadzka, A. Adamczyk, M. Mitoraj, and K. Mars, Degradation of CoSb3 in Air at Elevated Temperatures, vol.74, pp.113-124, 2010.

D. Zhao, C. Tian, S. Tang, Y. Liu, and E. L. Chen, High temperature oxidation behavior of cobalt triantimonide thermoelectric material, J. Alloys Compd, vol.504, issue.2, pp.552-558, 2010.

H. Dong, X. Li, X. Huang, Y. Zhou, W. Jiang et al., « Improved oxidation resistance of thermoelectric skutterudites coated with composite glass, Ceram. Int, vol.39, issue.4, pp.4551-4557, 2013.

R. Hara, S. Inoue, H. T. Kaibe, and E. S. Sano, « Aging effects of large-size n-type CoSb3 prepared by spark plasma sintering, J. Alloys Compd, vol.349, issue.1, pp.297-301, 2003.

P. Qiu, X. Xia, X. Huang, M. Gu, Y. Qiu et al., Pesting"-like oxidation phenomenon of p-type filled skutterudite Ce0.9Fe3CoSb12 », J. Alloys Compd, vol.612, pp.365-371, 2014.

J. S. Sakamoto, T. Caillat, J. Fleurial, and G. J. Snyder, « Method of suppressing sublimation in advanced thermoelectric devices, vol.7480984, pp.27-2009

E. Godlewska, K. Zawadzka, K. Mars, R. Mania, K. Wojciechowski et al., Protective Properties of Magnetron-Sputtered Cr-Si Layers on CoSb3, vol.74, pp.205-213, 2010.

H. H. Saber and M. S. El-genk, « Effects of metallic coatings on the performance of skutteruditebased segmented unicouples, Energy Convers. Manag, vol.48, issue.4, pp.1383-1400, 2007.

D. Zhao, S. Bai, Q. Ma, M. Zuo, and X. Teng, Protective properties of YSZ/Ti film deposited on CoSb3 thermoelectric material, vol.98, pp.163-169, 2015.

H. Dong, X. Li, X. Huang, Y. Zhou, W. Jiang et al., « Improved oxidation resistance of thermoelectric skutterudites coated with composite glass, Ceram. Int, vol.39, issue.4, pp.4551-4557, 2013.

H. Dong, « Fabrication and thermal aging behavior of skutterudites with silica-based composite protective coatings, J. Alloys Compd, vol.527, pp.247-251

K. Zawadzka, E. Godlewska, K. Mars, M. Nocun, A. Kryshtal et al., Enhancement of oxidation resistance of CoSb3 thermoelectric material by glass coating, vol.119, pp.65-75, 2017.

D. Zhao, D. Wu, J. Ning, and M. Zuo, Protective Properties of Various Coatings on CoSb3 Thermoelectric Material, vol.46, pp.3036-3042, 2017.

I. Chapitre, Modélisation et calculs numériques des µ générateurs thermoélectriques, p.82

I. Chapitre, Modélisation et calculs numériques des µ générateurs thermoélectriques 83

I. Chapitre, Modélisation et calculs numériques des µ-générateurs thermoélectriques

I. Chapitre, Modélisation et calculs numériques des µ générateurs thermoélectriques

P. M. Mayer and R. J. Ram, « Optimization of Heat Sink-Limited Thermoelectric Generators, Nanoscale Microscale Thermophys. Eng, vol.10, issue.2, pp.143-155, 2006.

G. Min and D. M. Rowe, « Optimisation of thermoelectric module geometry for 'waste heat' electric power generation, J. Power Sources, vol.38, issue.3, pp.253-259, 1992.

M. Freunek, M. Müller, T. Ungan, W. Walker, and L. M. , New Physical Model for Thermoelectric Generators, J. Electron. Mater, vol.38, issue.7, pp.1214-1220, 2009.

L. L. Baranowski, G. J. Snyder, and E. S. Toberer, « Effective thermal conductivity in thermoelectric materials, J. Appl. Phys, vol.113, p.204904, 2013.

C. «-logiciel-de-modélisation and . Multiphysics®,

, « Méthode des éléments finis

D. Sur,

A. Ern and J. Guermond, Éléments finis: théorie, applications, mise en oeuvre, 2002.

«. Cobyla--, Constrained Optimization BY Linear Approximation -pyOpt »

D. Sur,

«. Cobyla,

D. Sur,

, « US Patent for Thermoelectric element Patent (Patent # 9, Justia Patents Search, vol.899, 2018.

D. Sur,

K. D. Hagen, « Heat transfer with applications, 1999.

G. J. Snyder, J. R. Lim, C. Huang, and J. Fleurial, Thermoelectric microdevice fabricated by a MEMS-like electrochemical process, Nat. Mater, vol.2, issue.8, pp.528-531, 2003.

H. Bottner, J. Nurnus, A. Schubert, and F. Volkert, « New high density micro structured thermogenerators for stand alone sensor systems, 2007 26th International Conference on Thermoelectrics, pp.306-309, 2007.

I. V. Chapitre, Fabrication et performances des générateurs à base des skutterudites, p.131

, Chapitre IV : Fabrication et performances des générateurs à base des skutterudites

E. Geczi, A. Jacquot, D. Kenfaui, I. Kogut, B. Lenoir et al., « Improved thermoelectric element and thermoelectric converter including at least one such element, pp.2-2017

D. M. Rowe, D. V. Morgan, and J. H. Kiely, « Miniature low-power/high-voltage thermoelectric generator, Electron. Lett, vol.25, issue.2, pp.166-168, 1989.

V. Ravi, « Thermal Expansion Studies of Selected High-Temperature Thermoelectric Materials, J. Electron. Mater, vol.38, issue.7, pp.1433-1442, 2009.

K. Placha, R. S. Tuley, M. Salvo, V. Casalegno, and K. Simpson, Solid-Liquid Interdiffusion (SLID) Bonding of p-Type Skutterudite Thermoelectric Material Using Al-Ni Interlayers », Materials, vol.11, p.2483, 2018.

M. Gu, X. Xia, X. Li, X. Huang, and E. L. Chen, « Microstructural evolution of the interfacial layer in the Ti-Al/Yb0.6Co4Sb12 thermoelectric joints at high temperature, J. Alloys Compd, vol.610, pp.665-670, 2014.

J. Fan, L. Chen, S. Bai, and X. Shi, Joining of Mo to CoSb3 by spark plasma sintering by inserting a Ti interlayer, Mater. Lett, vol.58, pp.3876-3878, 2004.

L. Shi, X. Huang, M. Gu, and E. L. Chen, Interfacial structure and stability in Ni/SKD/Ti/Ni skutterudite thermoelements, vol.285, pp.312-317, 2016.

A. Reuss, Berechnung der Fließgrenze von Mischkristallen auf Grund der Plastizitätsbedingung für Einkristalle, vol.9, pp.49-58, 1929.

S. L. Shinde, J. Goela, and É. , High Thermal Conductivity Materials, 2006.

P. Kolodner, High-precision thermal and electrical characterization of thermoelectric modules, Rev. Sci. Instrum, vol.85, issue.5, p.54901, 2014.

L. Rauscher, S. Fujimoto, H. T. Kaibe, and E. S. Sano, « Efficiency determination and general characterization of thermoelectric generators using an absolute measurement of the heat flow, Meas. Sci. Technol, vol.16, issue.5, pp.1054-1060, 2005.

J. R. Salvador, « Conversion efficiency of skutterudite-based thermoelectric modules, Phys. Chem. Chem. Phys, vol.16, pp.12510-12520, 2014.

Y. Zhang, « High-temperature and high-power-density nanostructured thermoelectric generator for automotive waste heat recovery, Energy Convers. Manag, vol.105, pp.946-950, 2015.

P. Canale and C. Servant, Thermodynamic Assessment of the Cu-Ti System Taking into Account the New Stable Phase CuTi3 », vol.93, pp.273-276, 2002.

D. Zhao, X. Li, L. He, W. Jiang, and E. L. Chen, High temperature reliability evaluation of CoSb3/electrode thermoelectric joints, vol.17, pp.136-141, 2009.

S. Choi, « A Resistance Ratio Analysis for CoSb3-Based Thermoelectric Unicouples, J. Electron. Mater, vol.41, pp.1004-1010

S. H. Park, « High-Power-Density Skutterudite-Based Thermoelectric Modules with Ultralow Contact Resistivity Using Fe-Ni Metallization Layers, ACS Appl. Energy Mater, vol.1, issue.4, pp.1603-1611, 2018.

J. García-cañadas, A. V. Powell, A. Kaltzoglou, P. Vaqueiro, and G. Min, « Fabrication and Evaluation of a Skutterudite-Based Thermoelectric Module for High-Temperature Applications, J. Electron. Mater, vol.42, issue.7, pp.1369-1374, 2013.

, Chapitre IV : Fabrication et performances des générateurs à base des skutterudites 194

J. Prado-gonjal, M. Phillips, P. Vaqueiro, G. Min, and A. V. Powell, Skutterudite Thermoelectric Modules with High Volume-Power-Density: Scalability and Reproducibility, vol.1, pp.6609-6618, 2018.

J. L. Murray and A. J. Mcalister, The Al-Si (Aluminum-Silicon) system », Bull. Alloy Phase Diagr, vol.5, p.74, 1984.

. Bibliographie,

M. Tokita, Materials Science Forum, vol.83, pp.308-311, 1999.

W. Chen, U. Anselmi-tamburini, J. E. Garay, J. R. Groza, and . Munir, Z. A. Materials Science and Engineering A, p.132, 2005.

J. R. Groza and . Zavaliangos, A. Reviews on Advanced Materials Science, vol.5, p.24, 2003.

O. Maldonado, Pulse method for simultaneous measurement of electric thermopower and heat conductivity at low temperatures, Cryogenics, vol.31, pp.908-912, 1992.

W. J. Parker, R. J. Jenkins, C. P. Butler, and G. L. Abbott, Flash Method of Determining Thermal Diffusivity, Heat Capacity, and Thermal Conductivity, J. Appl. Phys, vol.32, issue.9, pp.1679-1684, 1961.

B. Hay, J. Filtz, and J. Batsale, Mesure de la diffusivité thermique par la méthode flash, Méthodes surfaciques, p.42, 2004.

R. D. Cowan, Proposed Method of Measuring Thermal Diffusivity at High Temperatures, J. Appl. Phys, vol.32, issue.7, pp.1363-1370, 1961.

J. A. Cape and G. W. Lehman, Temperature and Finite Pulse-Time Effects in the Flash Method for Measuring Thermal Diffusivity, J. Appl. Phys, vol.34, issue.7, pp.1909-1913, 1963.

D. Josell, J. Warren, and A. Cezairliyan, Analysis for determining thermal diffusivity from thermal pulse experiments, J. Appl. Phys, vol.78, issue.11, pp.6867-6869, 1995.

J. Faure, Determination de la diffusivite thermique des isolants par la methode du signal tres bref, 1964.

J. Jamet and R. Jalin, Etude expérimentale de la dégradation thermique d'un matériau ablatif. Recherche aérospatiale, Recherche aérospatiale, vol.4, pp.233-244, 1974.

L. Clark and R. Taylor, Radiation loss in the flash method for thermal diffusivity, Journal of Applied Physics, pp.714-719, 1975.

J. Blumm and J. Opfermann, Improvement of the mathematical modeling of flash measurements, High Temperatures. High Pressures, vol.34, pp.515-521, 2002.

H. J. Hertz and . Reine, Angew. Math, vol.92, pp.156-171, 1882.

I. Sneddon, The relation between load and penetration in the axisymmetric boussinesq problem for a punch of arbitrary profile, International Journal of Engineering Science, vol.3, pp.47-57, 1965.

W. C. Oliver and G. M. Pharr, Measurement of hardness and elastic modulus by instrumented indentation: advances in understanding and refinements to methodology, J. Mater. Res, vol.19, issue.1, pp.3-20, 2004.

R. King, Elastic analysis of some punch problems for a layered medium, International Journal of Solids and Structures, vol.23, pp.1657-1664, 1987.