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I. Chapitre, Comportement en oxydation des alliages Ni-25Cr-xMn

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I. V. Chapitre, Comportement en oxydation à 1050 °C des alliages modèles Ni-25Cr-xMn-ySi (x variant de 0 à 1

I. ;. Chapitre, Comportement en oxydation à 1050°C des alliages modèles Ni-25Cr-xMn-ySi (x variant de 0 à 1,5% et y de 0 à 2% massique), p.131

. Iv, Influence du manganèse sur l'oxydation d'un alliage Ni-25Cr à 1050°C

, Caractérisations des oxydes après 100 h d'oxydation en thermobalance, p.131

. .. Observations-en-coupe,

.. .. Microstructure-de-la-couche-d'oxydes,

. .. Sous-air-sec,

, 3% de vapeur d'eau), Oxydation sous air humide

, Comportement en oxydation cyclique des alliages Ni-25Cr-xMn

, Détermination des constantes cinétiques sous air sec

, Traitement des données obtenues sous air humide

, Estimation des épaisseurs maximales des couches d'oxydes

, Discussion sur l'effet de la vapeur d'eau sur la volatilisation des oxydes formés sur les alliages Ni-25Cr-xMn (avec x compris entre 0 et 1,5% massique)

. Iv, Evolution du substrat métallique lors de l'oxydation des alliages Ni-25Cr-xMn, p.151

. Iv, Influence du silicium sur le comportement en oxydation d'un alliage Ni-25Cr-xSi (avec x compris entre 0,5 et 2% massique)

, Nature

. .. Observations-en-coupe,

, Comportement en oxydation cyclique des alliages Ni-25Cr-xSi

, Etude de l'évolution microstructurale et compositionnelle du substrat métallique lors de l'oxydation des alliages contenant du silicium

, Profil de concentration en silicium

, Détermination des coefficients d'interdiffusion dans l'alliage

, 5.1. Caractérisation des oxydes après 100 h d'oxydation, IV.5. Influence combinée du manganèse et du silicium sur la résistance à l'oxydation des alliages Ni-25Cr

, 6.1. Profils de concentration à travers la section des échantillons, Evolution des substrats métalliques des alliages contenant à la fois du manganèse et du silicium, p.178

, Détermination des coefficients de diffusion dans l'alliage

, 7.1. Effet des éléments mineurs sur les cinétiques d'oxydation

. .. Effet-du-manganèse,

. .. Effet-du-silicium,

, La diffusion des éléments dans les alliages modèles étudiés

, Comparaison de la résistance à l'oxydation

I. V. Chapitre, Comportement en oxydation à 1050 °C des alliages modèles Ni-25Cr-xMn-ySi (x variant de 0 à 1,5% et y de 0 à 2% massique) Références

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, Ces résultats paraissent en contradiction avec la position des marqueurs d'or observée après 10 h d'oxydation. En effet, sur toutes les nuances étudiées les marqueurs d'or sont observés à l'interface oxyde/gaz après 10 h d'oxydation à 1050 °C

, Des observations similaires ont déjà été faites sur des alliages Ni-30Cr, vol.9, p.1100

. °c.-en-effet and . Schmucker,

, Enfin la température de fusion de l'or (1064 °C) est relativement proche de celle employée dans la présente étude (1050 °C) et inférieure à celle employée par Schmucker (1150 °C)

, Dans ces conditions, il a déjà été observé lors d'essais d'oxydation en MEB environnemental que les marqueurs peuvent être

V. Chapitre, Etude des mécanismes de croissance des couches protectrices en présence de manganèse et de silicium

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