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, O3-Sm1-O1, vol.83

, ) O1-Sm1-O2 ii, vol.87

, O3-Sm1-O7 i, vol.88

, O7w-Sm1-O8 i, vol.74

, ) O1-Sm1-O7 i, vol.137

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, Co1-O3w, vol.2, p.148

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, avec une dispersion étroite par rapport à la structure du composé (If)

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V. Tableau, Angles de liaison sélectionnés (º) autour du Sm avec leur déviation standard pour le composé (If) O3-Sm1-O9 i, vol.137

, O3-Sm1-O1 86,05 (5) O7w-Sm1-O10 i, vol.124, p.97

, O3-Sm1-O10 i, vol.86

, ) O7w-Sm1-O2 ii, vol.141, p.33

, O3-Sm1-O10w, vol.73, p.26

, ) O10w-Sm1-O10 i, vol.134

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, O2 ii -Sm1-O10 i 97, vol.70

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, O1-Sm1-O9 i, vol.132, p.31

. O1-sm1-o10-i, ) O9w-Sm1-O2 ii, vol.145, p.92

, O1-Sm1-O7w, vol.77, p.35

, O8w-Sm1-O9 i 96, O1-Sm1-O10w, vol.71

, ) O8w-Sm1-O10 i, vol.65, p.89

, O1-Sm1-O9w, vol.139, p.71

, O1-Sm1-O8w, vol.78, p.68

, Codes de symétrie: (i) x+1, y+1, z; (ii) ?x+1, ?y+2, ?z+1

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, Codes de symétrie: (i) ?x, ?y, ?z+2; (ii) ?x+1, ?y, ?z+2; (iii) ?x, ?y, ?z+1

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, Ni1-O3w, vol.1, issue.7, p.973

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, O4 i -Dy1-O2, vol.86

, ) O3-Dy1-O4 i, O6 ii -Dy1-O1, vol.112, p.2

, ) O3-Dy1-O6 ii, vol.135

, O7-Dy1-O6 ii, vol.139, pp.3-4

, O7-Dy1-O8 iii, vol.67

, O7-Dy1-O1, vol.68

, ) O2-Dy1-O1, O8 iii -Dy1-O4 i, vol.130, p.41

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, O8 iii -Dy1-O1, vol.121

, O8 iii -Dy1-O2, vol.140

, O5-Dy1-O4 i, vol.76, p.91

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, ) O1w-Dy1-O3, vol.49

, O2-Dy1-O6 ii, vol.74, p.9

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, O3w, O3w i , O4w, O4w i ) provenant des molécules d'eau et un atome d'azote (N1) du ligand 3,5-pdc 2-. Les quatre atomes d'oxygène (O3w, O3w i , O4w, O4w i ) des molécules d'eau et les deux atomes (O2w, N1) en position spéciale (plan miroir) sont respectivement à des distances de, L'ion Ni 2+ est quant à lui situé sur un plan miroir et il est hexacoordiné par cinq atomes d'oxygène (O2w, vol.1, p.81

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, Représentation Mercury de l'unité asymétrique du composé (II), les ellipsoïdes thermiques sont représentés à 50% de probabilité

A. Tableau, Distances interatomiques (Å) et angles (º) avec leur déviation standard Co1-O1 i, vol.2, p.44

, Co1-N1 ii, vol.2, p.203

, Co1-O1W, vol.2, p.44

, ) O1W-Co1-O1 i 96, O1 i -Co1-O1, vol.84

, ) O1W i -Co1-O1 i, O1-Co1-N1 ii, vol.137, p.41

, ) O1W-Co1-O1W i, O1 i -Co1-N1 ii, vol.137

, O1W i -Co1-O1 96, vol.23

, ) O1W i -Co1-N1 ii, O1W-Co1-O1, vol.89

V. Tableau, Distances interatomiques (Å) autour du Pr 3+ dans le composé (Ia) Pr1-O1, vol.2, p.4869

-. Pr1 and . Ii, , vol.2, p.5337

, Codes de symétrie: (i) x+1, y+1, z; (ii) ?x+1, ?y+2, ?z+1

V. Tableau, Distances interatomiques (Å) autour du Cu 2+ dans le composé (Ia) Cu1-O5w 1,9754 (5) Cu1-O3w, vol.2, p.4910

, Cu1-O6w, vol.1, issue.5, p.228

, Cu1-O4w, vol.2, p.226

, ) O8 i -Pr1-O7 i, Angles de liaison sélectionnés (º) avec leur déviation standard du composé (Ia) O1-Pr1-O8 i, vol.132

, ) O2 ii -Pr1-O8 i, O1-Pr1-O8w, vol.76

, ) O2 ii -Pr1-O10w, O1-Pr1-O2 ii, vol.65

, ) O2 ii -Pr1-O7 i, O1-Pr1-O7w, vol.77

, O1-Pr1-O9w, vol.140

, O1-Pr1-O10w, vol.71

, O1-Pr1-O7 i, vol.144

, O3-Pr1-O1, vol.83, p.661

, O3-Pr1-O8 i, vol.139, p.911

, ) O9W-Pr1-O8 i, O3-Pr1-O8w, vol.69

, O3-Pr1-O2 ii, vol.133

, ) O9W-Pr1-O2 ii, vol.139

, O3-Pr1-O9w, vol.89

, O3-Pr1-O10w, vol.71

, O3-Pr1-O7 i, vol.90

, Codes de symétrie: (i) x+1, y+1, z; (ii) ?x+1, ?y+2, ?z+1

V. Tableau, Angles de liaison sélectionnés (º) avec leur déviation standard du composé (Ia) O3w-Cu1-O4w, vol.176

, O3w-Cu1-N2, vol.86

. O5w-cu1, O6w, vol.176, issue.2

. O5w-cu1, O4w, vol.87, issue.2, pp.1-1

, ) O3w-Cu1-O5w, O5w-Cu1-N2, vol.89

, O5w-Cu1-N1 91, vol.97, p.6

. O6w-cu1, O4w, vol.89, issue.2

V. Tableau, Distances et angles caractérisant les liaisons hydrogène au sein du composé

D. ,

, O2w iv -H2wB···O7 0, vol.903, p.1

V. Tableau, Distances interatomiques (Å) autour du Nd 3+ dans le composé (Ib) Nd1-O3 2,3825 (5) Nd1-O9 i, vol.2, p.5941

, Nd1-O5w, vol.2, p.5392

, Nd1-O1, vol.2, p.4621

, Nd1-O6w, vol.2, p.4865

, Nd1-O2, vol.2, issue.5, p.4231

, Code de symétrie: (i) x?1, y?1, z

V. Tableau, Distances interatomiques (Å) autour du Cu 2+ dans le composé (Ib) Cu1-O4w, vol.1, p.261

, Cu1-N1, vol.2, p.2719

, Cu1-O3w, vol.1, issue.5, p.4921

V. Tableau, Angles de liaison sélectionnés (º) avec leur déviation standard du composé (Ib) O3-Nd1-O5w, vol.139

, O3-Nd1-O1, vol.133, pp.2-3

, ) O2-Nd1-O6w, O3-Nd1-O6w, vol.72

, ) O2-Nd1-O9 i, O3-Nd1-O2, vol.83

, O3-Nd1-O9 i, vol.89

, ) O2-Nd1-O7w, O3-Nd1-O10, vol.139

, ) O2-Nd1-O8w, vol.88, p.9

, ) O10-Nd1-O9 i, vol.69

, ) O7w-Nd1-O5w, O5w-Nd1-O1, vol.67

, ) O7w-Nd1-O1, O5w-Nd1-O6w, vol.68, p.5

, ) O7w-Nd1-O6w, O5w-Nd1-O9 i, vol.125

, ) O7w-Nd1-O9 i, vol.161

, O5w-Nd1-O8w, vol.137

, ) O7w-Nd1-O8w, O1-Nd1-O6w, vol.123

, O1-Nd1-O9 i 95, vol.847, p.41

, ) O8w-Nd1-O6w, O1-Nd1-O10, vol.68

, ) O8w-Nd1-O9 i, O6w-Nd1-O9 i, vol.138

, O6W-Nd1-O10, vol.129

, Code de symétrie: (i) x?1, y?1, z

V. Tableau, Angles de liaison sélectionnés (º) avec leur déviation standard du composé (Ib) O1w-Cu1-O2w, vol.176

. O1w-cu1, O3w, vol.92, issue.2, p.99

, ) O3w-Cu1-N2, O1w-Cu1-O4w, vol.91, p.0

, ) O3w-Cu1-O2w, O4w-Cu1-N1, vol.88, p.91

. O4w-cu1, ) O1w-Cu1-N1, O2w, vol.89, issue.3

, N1-Cu1-N2, vol.177

, N1-Cu1-O2w, vol.92

, Représentation Mercury de l'unité asymétrique du Composé (Ib), les ellipsoïdes thermiques sont représentés à 50% de probabilité

V. Tableau, Distances interatomiques (Å) autour du Nd 3+ dans le composé (Id) Eu1-O3, vol.2, p.544

, Eu1-O1, vol.2, p.545

, Eu1-O9w, vol.2, issue.6, p.493

, Code de symétrie: (i) ?x+2, ?y+1, ?z+2

V. Tableau, Distances interatomiques (Å) autour du Cu 2+ dans le composé (Id) Cu1-O3w, vol.1, p.30

, Cu1-O4w, vol.1, issue.5, p.265

, Cu1-N2, vol.2, p.475

V. Tableau, ) O9w-Eu1-O2 i, Angles de liaison sélectionnés (º) avec leur déviation standard du composé (Id) O3-Eu1-O1, vol.83

, O3-Eu1-O2 i, vol.133, pp.9-10

, O3-Eu1-O9, vol.89

. O3-eu1, O9w, vol.139, issue.1, p.6

, O3-Eu1-O7w, vol.72, p.39

, O3-Eu1-O8w, vol.89

, O3-Eu1-O10w, vol.69

, ) O8w-Eu1-O2 i, O1-Eu1-O2 i, vol.65

, O1-Eu1-O9w, vol.76

, O1-Eu1-O7w, vol.71

, O1-Eu1-O8w, vol.140

, ) O10w-Eu1-O2 i, O1-Eu1-O10w, vol.77

, O2 i -Eu1-O9, vol.95

, O2 i -Eu1-O10, vol.68

, O2 i -Eu1-O7w, vol.123

, Code de symétrie: (i) ?x+2, ?y+1, ?z+2

V. Tableau, Angles de liaison sélectionnés (º) avec leur déviation standard du composé (Id) O3w-Cu1-N2, vol.90

, ) O4w-Cu1-O5w, O3w-Cu1-N1, vol.88

. O3w-cu1, O5w, vol.88, issue.2, p.24

. O4w-cu1, O3w, vol.176, issue.8

, O4w-Cu1-N2, vol.89

, ) O3w-Cu1-O6w, O6w-Cu1-N2, vol.86, p.9

, ) O4w-Cu1-O6w, vol.58

. O6w-cu1, O5w, vol.176, issue.2, p.9

V. Tableau, Distances interatomiques (Å) autour du Gd 3+ dans le composé (Ie) Gd1-O1, vol.2, p.4226

-. Gd1 and . Ii, , vol.2, p.4336

, Gd1-O3, vol.2, p.4075

-. Gd1 and . Ii, , vol.2, p.4889

, Code de symétrie: (i) ?x+1, ?y, ?z+1

V. Tableau, Distances interatomiques (Å) autour du Cu 2+ dans le composé (Ie) Cu1-O4w, vol.1, p.243

, Cu1-O3w, vol.1, issue.2, p.218

V. Tableau, Angles de liaison sélectionnés (º) avec leur déviation standard du composé (Ie) O1-Gd1-O2 i 67,05 (5) O8 ii -Gd1-O7w, vol.129, p.7

. O1-gd1-o7 and . Ii, ) O8w-Gd1-O2 i, vol.145, p.1

. O1-gd1-o8 and . Ii, ) O8w-Gd1-O7 ii, vol.133, p.53

. O1-gd1, O8w, vol.78, issue.6, p.96

. O1-gd1, O7w, vol.71, issue.6, p.53

, O1-Gd1-O10w, vol.77, p.25

. O1-gd1, ) O7w-Gd1-O7 ii, vol.139, p.33

, O2 i -Gd1-O7 ii, vol.96, p.10

, O2 i -Gd1-O8 ii, vol.67, p.29

, ) O10w-Gd1-O7 ii, vol.124, p.96

, O3-Gd1-O1, vol.83, p.79

. O3-gd1-o2-i, ) O9w-Gd1-O2 i, vol.134, p.32

. O3-gd1-o7 and . Ii, , vol.88

. O3-gd1-o8 and . Ii, , vol.138, p.14

, O3-Gd1-O8w, vol.140, p.23

. O3-gd1, O7w, vol.72, issue.6, p.20

. O3-gd1, O10w, vol.70, issue.7, p.10

. O3-gd1, O9w, vol.86, issue.7, p.94

, Code de symétrie: (i) ?x+1, ?y, ?z+1

V. Tableau, Angles de liaison sélectionnés (º) avec leur déviation standard du composé (Ie) O4w-Cu1-O3w, vol.175, p.89

. O4w-cu1, O5w, vol.86, issue.8, p.41

, O4w-Cu1-N1 91,96 (7) N1-Cu1-O5w, vol.92, p.39

. O3w-cu1, O5w, vol.89, issue.8, p.50

, O6w-Cu1-N2, vol.87, p.42

, ) O4w-Cu1-O6w, vol.54, p.25

, Représentation Mercury de l'unité asymétrique du Composé (Ie), les ellipsoïdes thermiques sont représentés à 50% de probabilité

V. Tableau, Distances interatomiques (Å) autour du Eu 3+ dans le composé (Ig) Eu1-O3, vol.2, p.497

, Eu1-O2 ii, vol.2, p.507

, Eu1-O8w, vol.2, p.509

, Eu1-O10 i, vol.2, p.565

V. Tableau, Distances interatomiques (Å) autour du Co 2+ dans le composé (Ig) Co1-O5w, vol.2, p.134

, Co1-O4w, vol.2, p.139

, Co1-O6w, vol.2, p.145

V. Tableau, Angles de liaison sélectionnés (º) avec leur déviation standard du composé (Ig) O3-Eu1-O1, O7w-Eu1-O2 ii, vol.85

, O3-Eu1-O8w, vol.86, p.5

, O9 i -Eu1-O2 ii, vol.138, p.74

, O3-Eu1-O7w, vol.141, p.92

, O1-Eu1-O7w, vol.77

, O8W-Eu1-O7w, vol.83

, O3-Eu1-O10w, vol.70, p.91

, O1-Eu1-O10w, vol.78, p.2

. O8w-eu1, O10w, vol.135, issue.9, p.48

. O7w-eu1, O2 ii -Eu1-O9w, vol.137, p.41

, ) O3-Eu1-O10 i, vol.137, p.50

, ) O1-Eu1-O10 i, O1-Eu1-O9 i, vol.132, p.7

. O8w-eu1-o9-i, , vol.75

. O7w-eu1-o9-i, ) O7w-Eu1-O10 i, vol.74

, ) O10w-Eu1-O10 i, O10w-Eu1-O9 i 96, vol.50

. O3-eu1-o2 and . Ii, O9 i -Eu1-O10 i, vol.135, p.52

. O1-eu1-o2 and . Ii, ) O2 ii -Eu1-O10 i 97, vol.66, p.22

O. Ii, O9w-Eu1-O10 i, vol.138, p.45

, Code de symétrie: (i) x?1, y?1, z; (ii) ?x+1, ?y, ?z+1

V. Tableau, Angles de liaison sélectionnés (º) avec leur déviation standard du composé (Ig) O5w-Co1-O4w, vol.86, pp.6-7

, ) O3w-Co1-N2, O5w-Co1-O6w, vol.173

. O4w-co1, O6w, vol.87, issue.1

, O5w-Co1-O3w, vol.94, p.8

, ) O6w-Co1-N1, O4w-Co1-O3w, vol.178

, O6w-Co1-O3w, vol.91

, O5w-Co1-N2, vol.88, p.7

. O4w-co1, N2, vol.89, issue.1

, Représentation Mercury de l'unité asymétrique du Composé (Ig), les ellipsoïdes thermiques sont représentés à 50% de probabilité

V. Tableau, Distances interatomiques (Å) autour du Gd 3+ dans le composé (Ih) Gd1-O10 i, vol.2, p.3963

, Gd1-O2 ii, vol.2, p.4935

, Gd1-O7w, vol.2, p.429

, Gd1-O1, vol.2, p.3791

, Code de symétrie: (i) x?1, y?1, z; (ii) ?x+1, ?y, ?z+1

V. Tableau, Distances interatomiques (Å) autour du Co 2+ dans le composé (Ih) Co1-O5w, vol.2, p.845

, Co1-O4w, vol.2, p.144

, Co1-O3w, vol.2, p.141

V. Tableau, Angles de liaison sélectionnés (º) avec leur déviation standard du composé (Ih) O9 i -Gd1-O10 i, vol.51, p.12

, ) O8w-Gd1-O9 i, O9 i -Gd1-O2 ii, vol.67

O. Ii, , vol.69, p.9

. O9w-gd1-o10-i, , vol.137

. O9w-gd1-o9-i, ) O8w-Gd1-O2 ii, vol.129, p.35

O. Ii, , vol.123, p.71

. O1-gd1, ) O3-Gd1-O10 i, vol.78, p.26

. O7w-gd1-o10-i, ) O3-Gd1-O9 i, vol.125, p.4

. O7w-gd1-o9-i, , vol.74, p.98

. O7w-gd1, O9w, vol.68, issue.6, p.83

O. Ii, , vol.68, p.90

. O7w-gd1, O10w, vol.137, issue.7, p.77

, O1-Gd1-O10 i, vol.145, p.91

, O1-Gd1-O9 i, vol.132, p.27

, ) O2 ii -Gd1-O10 i 97, vol.71, p.22

. O1-gd1, ) O10w-Gd1-O10 i, vol.78

. O1-gd1, ) O10w-Gd1-O9 i 96, O8w, vol.139, issue.7, p.54

. O1-gd1-o2 and . Ii, , vol.66, p.9

, Code de symétrie: (i) x?1, y?1, z; (ii) ?x+1, ?y, ?z+1

V. Tableau, Angles de liaison sélectionnés (º) avec leur déviation standard du composé (Ih) O5w-Co1-N1, vol.90, p.33

, O5w-Co1-N2, vol.89, p.50

, O4w-Co1-O5w, vol.91, p.73

, O4w-Co1-N1, vol.88, p.67

, O3w-Co1-O5w, vol.94, p.60

, O3w-Co1-O4w, vol.173, p.15

. O3w-co1, O6w, vol.86, issue.8, p.30

. Tableau-a-54, Coordonnées atomiques et paramètres d'agitation thermique isotropiques équivalents (Å 2 ) du Composé

, O4w, vol.0, issue.9

, Au cours de cette thèse doctorale en cotutelle entre l'Université Assane Seck de Ziguinchor (Sénégal) et l'Université de Lorraine (France), il a été possible de mettre en évidence plusieurs nouvelles phases cristallines inédites de matériaux moléculaires, Résumé Il est désormais possible, en utilisant la méthode de synthèse par diffusion lente en milieu gel, d'élaborer de nouveaux matériaux moléculaires mixtes 4f-3d tridimensionnels présentant des propriétés physiques et chimiques très intéressantes

. Ln-=-pr, . Nd, . Sm, G. Eu, and M. Cu, A simple, economic, ecologic and environmentally friendly synthesis method that has been used until recently for the growth of mononuclear crystalline molecular materials. During this international joint PhD between Assane Seck Ziguinchor University (Senegal) and Lorraine University (France), it was possible to synthesize several novel crystalline phases of molecular materials. Ten new 4f-3d heteronuclear molecular materials was obtained by slow diffusion in gel medium and structurally characterized by single crystal X-ray diffraction. Eight of them belong to the same family of isostructural compounds, Mots clés : Milieu gel, Matériaux moléculaires, Systèmes mixtes 4f-3d, Lanthanides, Diffraction des rayons-X Abstract New tridimensional 4f-3d molecular materials can be obtained through crystal growth in gel medium

, Key words: Gel medium, Molecular materials, Mixed systems 4f-3d

M. Diallo, M. Camara, N. Claiser, I. Badiane, C. Lecomte et al., Journal de la Société Ouest-Africaine de Chimie J. Soc. Ouest-Afr. Chim, vol.046, pp.59-67, 2018.

, ème Année, Décembre, 2018.

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B. Xing, H. Li, Y. Zhu, Z. Zhao, Z. Sun et al., Two fluorescent lead phosphonates for highly selective sensing of nitroaromatics (NACs), Fe 3+ and MnO4 ? ions, RSC Adv, vol.6, issue.111, p.65, 2016.

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M. Diallo, M. Camara, N. Claiser, A. M. Badiane, and M. Souhassou, Claude Lecomte Journal de la Société Ouest-Africaine de Chimie J. Soc. Ouest-Afr. Chim, vol.048, pp.26-33, 2019.

A. Ème, Décembre, 2019.

, Code Chemical Abstracts, p.2

I. Cote and . France, <27680> Site Web

M. Diallo, , p.26

, Synthèse et caractérisation structurale d'un nouveau polymère de coordination à base du Dy(III) avec les ligands 2,5-pyridinedicarboxylate et oxalate

M. Diallo, ?. , M. Camara, ?. , N. Claiser et al.,

?. Lcpm-groupe, Matériaux Inorganiques : Chimie Douce et Cristallographie

C. ?-laboratoire, Résonance Magnétique et Modélisations, CRM2, UMR 7036

, 5-Pdc)(Oxa)0.5(H2O)2]n (avec 2,5-Pdc = 2,5-pyridinedicarboxylate et Oxa = oxalate) a été obtenu par voie hydrothermale et structuralement caractérisé par la diffraction des rayons-X sur monocristal à une température de 100K. Le composé présente une structure bidimensionnelle formé de chaînes en forme de zig-zag par les ligands 2,5-pyridinedicarboxylates, Ces chaînes sont ensuite reliées entre elles par les ligands oxalates pour donner les couches bidimensionnelles stabilisées par les interactions supramoléculaires

, Mots clés: Diffraction des rayons-X, Lanthanides, Polymères de coordination, Synthèse hydrothermale, vol.2, p.5

, Synthesis and structural characterization of a novel coordination polymer base on Dy(III) with pyridine-2,5-dicarboxylate and oxalate ligands

, 5-Pdc) and oxalic acid (H2Oxa) with DyCl3.6H2O under hydrothermal conditions gave a novel 2D coordination polymer, [Dy(2,5-Pdc) (single crystal X-ray diffraction. In this compound, pyridine-2,5-dicarboxylate ligands link Dy 3+ ions to give infinite zig-zag chains which are further bridged by bis-bidentate oxalate ligands to form 2D layers, Abstract : Direct reaction of pyridine-2,5-dicarboxylic acid, vol.22

, Keywords: X-ray diffraction, Lanthanides, Coordination polymers, Hydrothermal synthesis, 2,5 pyridinedicarboxylate

. *-auteur-de-correspondance,

M. Diallo, , p.29

. De-dy, L'ion Dy 3+ est hexacoordiné par un atome d'azote (N1 ii ) provenant du ligand pyridinedicarboxylate, trois atomes d'oxygène (O1, O2 iii , O3 ii ) provenant du même ligand, deux atomes d'oxygène (O5, O6 i ) provenant de l'oxalate et enfin deux atomes d'oxygène (O1w, O2w) provenant des molécules d'eau de coordination. Le polyèdre de coordination peut être décrit comme un antiprisme carré distordu (Figure 2) à cause de la coordinance élevée et constituée par des oxygènes de ligands différents présentant plusieurs modes de coordination, ) Å alors que les contacts Dy-O sont compris entre 2.279 (7) et 2.406 (8) Å (Tableau II) et sont comparables à celles observées dans les structures des composés analogues rapportées dans la littérature. Les angles O-Dy-O, vol.2

, Figure 1: Représentation de l'unité asymétrique, les ellipsoïdes thermiques sont représentés à 50% de probabilité

I. I. Tableau, Distances interatomiques (Å) autour du Dy 3+ Dy1-O5, vol.2, p.512

, Codes de symétrie: (i) -x, ?y+1, ?z+2; (ii) x?1, y+1, z; (iii) ?x+1, ?y+1, vol.2

I. Tableau, Angles de liaison sélectionnés (º) avec leur déviation standard O5-Dy1-O6 i, ) O3 ii -Dy1-O1w, vol.67, p.43

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, Codes de symétrie: (i) ?x, ?y+1, ) O3 i -Dy1-N1 i, vol.71

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M. Camara, I. Badiane, M. Diallo, C. Daiguebonne, and O. Guillou, Computing details Data collection: COLLECT (Bruker, 2004); cell refinement: SCALEPACK (Otwinowski & Minor, 1997); data reduction: DENZO and SCALEPACK (Otwinowski & Minor, 1997); program(s) used to solve structure: SHELXT (Sheldrick, 2015a); program(s) used to refine structure: SHELXL (Sheldrick, 2015b); molecular graphics: DIAMOND

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