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, Hz, 1H), 8.15 (d, J = 2.2 Hz, 1H), 8.11?8.08 (m, 1H), 8.06 (d, J = 2.3 Hz, 1H), 7.98 (d, J = 8.3 Hz, 1H) 7.87?7.80 (m, 3H), vol.7
, , p.100
,
, Hz, 1H), 8.11?8.06 (m,1H), 7.91 (d, J = 8.3 Hz, 1H), 7.24? 7.21 (m, 1H), vol.7
97 (s, 3H) ppm. 13 C NMR (100 MHz, vol.2 ,
Tris(2-chloroethyl)amine (100 mg, 0.41 mmol) and 2-pyridylimidawas filtered, washed twice with Et 2 O, and dried under vacuum to give L2 (98% yield), -imidazoliumpyridineethyl)amine (L2) ,
,
,
Using Schlenk techniques, ligand L2 (400 mg, 0.42 mmol) and FeCl 2 , (4 mg, 0.38 was filtered, washed twice with Et 2 O, and dried under vacuum to give C2 as an orange solid (15% yield). 1 H NMR (400 MHz ,
, Hz, 6H), 7.90 (d, J = 8.6 Hz, 3H), 7.21?7.18 (m, 6H), vol.7
, HR-MS calcd for C 30 H 30 FeN 10 P 2 F 12 m, Hz, 3H), 2.84 (t, J = 14.6 Hz, 3H), 1.95 (t, 3H) ppm. 13 C NMR (100 MHz
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