Kelvin’s Dissymmetric Models and Consistency Conditions of Multicomponent Gas-Liquid Equilibrium and Capillary Condensation

Abstract : To describe phase equilibrium of mixtures, we develop a nonclassical approach based on using different equations of state for gas and liquid. We show that not all the types of EOS are admissible but only those which verify some specific conditions of consistency. We developed the mathematical theory of this new approach for pure cores and for mixtures, in presence and absence of capillary forces, which leads to explicit analytical relationships for phase concentrations of chemical components. Several examples of comparison with experimental data for binary and ternary mixtures illustrate the feasibility of the suggested approach.
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International Journal of Thermodynamics, Hindawi Publishing Corporation, 2016, 2016, pp.3806364. 〈10.1155/2016/3806364〉
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https://hal.univ-lorraine.fr/hal-01409082
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Soumis le : lundi 5 décembre 2016 - 16:24:38
Dernière modification le : jeudi 11 janvier 2018 - 06:27:33

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Mikhail Panfilov, Alexandre Koldoba. Kelvin’s Dissymmetric Models and Consistency Conditions of Multicomponent Gas-Liquid Equilibrium and Capillary Condensation. International Journal of Thermodynamics, Hindawi Publishing Corporation, 2016, 2016, pp.3806364. 〈10.1155/2016/3806364〉. 〈hal-01409082〉

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