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Self-assembly of a neutral platinum(II) complex into highly emitting microcrystalline fibers through metallophilic interactions

Abstract : The solvent-assisted self-assembly of a blue-emitting neutral platinum(II) complex into micrometer-long and highly crystalline fibers has been achieved. The aggregates show highly efficient (quantum yield up to 74%) polarized yellow-orange light emission, as a consequence of their high degree of supramolecular order imparted by weak non-covalent intermolecular (metal...metal and pi-pi) interactions.
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https://hal.univ-lorraine.fr/hal-01494557
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Submitted on : Thursday, March 23, 2017 - 4:19:49 PM
Last modification on : Tuesday, September 1, 2020 - 4:02:01 PM

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Matteo Mauro, Alessandro Aliprandi, Cristina Cebrian, Di Wang, Christian Kuebel, et al.. Self-assembly of a neutral platinum(II) complex into highly emitting microcrystalline fibers through metallophilic interactions. Chemical Communications, Royal Society of Chemistry, 2014, 50 (55), pp.7269-7272. ⟨10.1039/c4cc01045k⟩. ⟨hal-01494557⟩

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