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Capped guanidino-α-cyclodextrin first synthesis based on intramolecular Staudinger-Aza-Wittig (SAW) reaction

Abstract : An intramolecularly promoted SAW reaction between a phosphinimide and an isocyanate intermediate led to an original bridged trisubstituted ((A,C),E)-α-cyclodextrin. The latter was in a second step converted into a new capped (ACE)-(guanidino)-α-cyclodextrin.
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https://hal.univ-lorraine.fr/hal-01494586
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Submitted on : Thursday, March 23, 2017 - 4:32:36 PM
Last modification on : Monday, March 29, 2021 - 4:06:44 PM

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Cédric Couturier, Florence Dumarcay-Charbonnier, Alexandrine Lambert, Danielle Barth, Alain Marsura. Capped guanidino-α-cyclodextrin first synthesis based on intramolecular Staudinger-Aza-Wittig (SAW) reaction. Annales Pharmaceutiques Françaises, Elsevier Masson, 2014, 72 (6), pp.422 - 428. ⟨10.1016/j.pharma.2014.06.004⟩. ⟨hal-01494586⟩

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