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Synthesis of new saccharide azacrown cryptands

Abstract : New cryptands including bis-azacrown and saccharidic moieties in their structure were prepared in several steps by applying Staudinger-aza-Wittig reaction (SAW). Syntheses have been started from cheap, easily available commercial compounds such as D-glucose, D-cellobiose and D-lactose subsequently transformed into their derivatives in fairly good yields (60-65%) and suitable to give desired final cryptands by direct SAW coupling reactions.
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Michalina Pintal, Florence Charbonniere-Dumarcay, Alain Marsura, Stanislaw Porwanski. Synthesis of new saccharide azacrown cryptands. Carbohydrate Research, 2015, 414, pp.51-59. ⟨10.1016/j.carres.2015.07.007⟩. ⟨hal-01495972⟩



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