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Cesium cation templated selective synthesis of a “cone-shaped” sugar macrotricyclic cryptand: A dual anion-cation molecular recognition of potassium tartrate

Abstract : Cesium templated Staudinger-aza-Wittig tandem reaction (S.A.W.) has been used in the synthesis of a bis-diazacrown-bis-cellobiosyl-tetra-ureido cryptand. A novel macrotricyclic compound having a “cone-shaped” configuration was selectively obtained. Additionally, first results on potential recognition properties of the cryptand are also given.
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https://hal.univ-lorraine.fr/hal-01496001
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Submitted on : Monday, March 27, 2017 - 10:38:39 AM
Last modification on : Monday, December 13, 2021 - 1:14:06 PM

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Stanislaw Porwanski, F. Moretti, Florence Dumarcay-Charbonnier, Alain Marsura. Cesium cation templated selective synthesis of a “cone-shaped” sugar macrotricyclic cryptand: A dual anion-cation molecular recognition of potassium tartrate. Annales Pharmaceutiques Françaises, Elsevier Masson, 2015, 74 (3), pp.198 - 204. ⟨10.1016/j.pharma.2015.11.003⟩. ⟨hal-01496001⟩

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