Driving Forces Controlling Host-Guest Recognition in Supercritical Carbon Dioxide Solvent. - Université de Lorraine Accéder directement au contenu
Article Dans Une Revue Chemistry - A European Journal Année : 2016

Driving Forces Controlling Host-Guest Recognition in Supercritical Carbon Dioxide Solvent.

Résumé

The formation of supramolecular host-guest complexes is a very useful and widely employed tool in chemistry. However, supramolecular chemistry in non-conventional solvents such as supercritical carbon dioxide (scCO2 ), one of the most promising sustainable solvents, is still in its infancy. In this work, we explored a successful route to the development of green processes in supercritical CO2 by combining a theoretical approach with experiments. We were able to synthesize and characterize an inclusion complex between a polar aromatic molecule (benzoic acid) and peracetylated-β-cyclodextrin, which is soluble in the supercritical medium. This finding opens the way to wide, environmental friendly, applications of scCO2 in many areas of chemistry, including supramolecular synthesis, reactivity and catalysis, micro and nano-particle formation, molecular recognition, as well as enhanced extraction processes with increased selectivity.

Domaines

Chimie

Dates et versions

hal-01496660 , version 1 (27-03-2017)

Identifiants

Citer

Francesca Ingrosso, Muhannad Altarsha, Florence Dumarçay, Gwendal Kevern, Danielle Barth, et al.. Driving Forces Controlling Host-Guest Recognition in Supercritical Carbon Dioxide Solvent.. Chemistry - A European Journal, 2016, 22 (9), pp.2972-2979. ⟨10.1002/chem.201503780⟩. ⟨hal-01496660⟩
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