Behaviour of tetramine inhibitors during pickling of hot rolled steels

Abstract : To avoid the dissolution of steel in industrial pickling process, tetramine inhibitors are added to the pickling bath. This study is devoted to the understanding of the action mechanism of these inhibitors in hydrochloric and sulphuric baths on non-alloyed and alloyed steels. Pickling experiments and characterization with XPS, Raman and infrared spectroscopies have shown that inhibitors work only in acid media and leached out from the steel surfaces during the rinsing operation just after pickling. The effectiveness of inhibitors depends on the acid media and the temperature. Experimental data are consistent with a surface mechanism, i.e., the so-called "outer-sphere" adsorption.
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https://hal.univ-lorraine.fr/hal-01497761
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Soumis le : mercredi 29 mars 2017 - 11:17:53
Dernière modification le : jeudi 24 mai 2018 - 10:32:01

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Marie-Jose Cornu, Alexey Koltsov, Sabrina Nicolas, Lydia Colom, Manuel Dossot. Behaviour of tetramine inhibitors during pickling of hot rolled steels. Applied Surface Science, Elsevier, 2014, 293, pp.24-36. 〈http://www.sciencedirect.com/science/article/pii/S0169433213022940〉. 〈10.1016/j.apsusc.2013.12.024 〉. 〈hal-01497761〉

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