Electronic properties of 1,3,5-tris[4-morpholinophenyl]benzene: a new molecular switch

Abstract : A new electron-donor, 1,3,5-tris[4-morpholinophenyl]benzene 1, was synthetised via nickel-catalysed arylamination reactions and characterised by cyclic voltammetry. It was found that electrochemical or chemical oxidation of 1 generates mono- or di(cation radical)s that are stable over 30 min at room temperature.
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https://hal.univ-lorraine.fr/hal-01942000
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Submitted on : Sunday, December 2, 2018 - 8:18:32 PM
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Christophe Desmarets, Raphaël Schneider, Yves Fort, Alain Walcarius. Electronic properties of 1,3,5-tris[4-morpholinophenyl]benzene: a new molecular switch. Inorganic Chemistry Communications, Elsevier, 2003, 6 (3), pp.278-280. ⟨10.1016/S1387-7003(02)00746-3⟩. ⟨hal-01942000⟩

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