A self-assembled M2L4 cage incorporating electron-rich 9-(1,3-dithiol-2-ylidene)fluorene units - Université de Lorraine
Article Dans Une Revue New Journal of Chemistry Année : 2017

A self-assembled M2L4 cage incorporating electron-rich 9-(1,3-dithiol-2-ylidene)fluorene units

Vincent Croué
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Magali Allain
Yohann Morille
Sébastien Goeb
Marc Sallé

Résumé

An electron-rich redox-active M2L4 cage is depicted. The cage is constructed through coordination driven self-assembly of a 9-(1,3-dithiol-2-ylidene)fluorene bis-pyridyl ligand in the presence of the Pd(BF4)2(CH3CN)4 complex. The corresponding discrete structure has been fully characterized in the solution as well in the solid state (crystal structure), showing notably that each of the four ligands surrounding the cavity can be reversibly oxidized upon a one electron process.

Domaines

Chimie
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Dates et versions

hal-02564444 , version 1 (05-05-2020)

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Citer

Vincent Croué, Serhii Krykun, Magali Allain, Yohann Morille, Frédéric Aubriet, et al.. A self-assembled M2L4 cage incorporating electron-rich 9-(1,3-dithiol-2-ylidene)fluorene units. New Journal of Chemistry, 2017, 41 (9), pp.3238-3241. ⟨10.1039/C7NJ00062F⟩. ⟨hal-02564444⟩
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