Nitrosyl linkage photoisomerization in heteroleptic fluoride ruthenium complexes derived from labile nitrate precursors - Université de Lorraine Access content directly
Journal Articles New Journal of Chemistry Year : 2021

Nitrosyl linkage photoisomerization in heteroleptic fluoride ruthenium complexes derived from labile nitrate precursors

Abstract

Four complexes with trans -ON–Ru–F coordinate were synthesized from their nitrate precursors. Upon light irradiation, complexes I–III show reversible formation of highly stable linkage isomers MS2 which leads to a higher photogeneration temperature of MS1.
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Dates and versions

hal-03401192 , version 1 (25-10-2021)

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Artem A Mikhailov, Vladislav Yu. Komarov, Denis P Pishchur, Dominik Schaniel, Gennadiy A Kostin. Nitrosyl linkage photoisomerization in heteroleptic fluoride ruthenium complexes derived from labile nitrate precursors. New Journal of Chemistry, 2021, 45 (18), pp.8192-8202. ⟨10.1039/D1NJ01038G⟩. ⟨hal-03401192⟩
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