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Nitrosyl linkage photoisomerization in heteroleptic fluoride ruthenium complexes derived from labile nitrate precursors

Abstract : Four complexes with trans -ON–Ru–F coordinate were synthesized from their nitrate precursors. Upon light irradiation, complexes I–III show reversible formation of highly stable linkage isomers MS2 which leads to a higher photogeneration temperature of MS1.
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https://hal.univ-lorraine.fr/hal-03401192
Contributor : Dominik Schaniel Connect in order to contact the contributor
Submitted on : Monday, October 25, 2021 - 12:03:45 PM
Last modification on : Friday, April 1, 2022 - 3:56:23 AM
Long-term archiving on: : Wednesday, January 26, 2022 - 7:36:25 PM

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Artem A Mikhailov, Vladislav Yu. Komarov, Denis P Pishchur, Dominik Schaniel, Gennadiy A Kostin. Nitrosyl linkage photoisomerization in heteroleptic fluoride ruthenium complexes derived from labile nitrate precursors. New Journal of Chemistry, 2021, 45 (18), pp.8192-8202. ⟨10.1039/D1NJ01038G⟩. ⟨hal-03401192⟩

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