Nitrosyl linkage photoisomerization in heteroleptic fluoride ruthenium complexes derived from labile nitrate precursors
Abstract
Four complexes with trans -ON–Ru–F coordinate were synthesized from their nitrate precursors. Upon light irradiation, complexes I–III show reversible formation of highly stable linkage isomers MS2 which leads to a higher photogeneration temperature of MS1.
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