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Nitrosyl linkage photoisomerization in heteroleptic fluoride ruthenium complexes derived from labile nitrate precursors

Abstract : Four complexes with trans -ON–Ru–F coordinate were synthesized from their nitrate precursors. Upon light irradiation, complexes I–III show reversible formation of highly stable linkage isomers MS2 which leads to a higher photogeneration temperature of MS1.
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https://hal.univ-lorraine.fr/hal-03401192
Contributor : Dominik Schaniel Connect in order to contact the contributor
Submitted on : Monday, October 25, 2021 - 12:03:45 PM
Last modification on : Wednesday, October 27, 2021 - 4:04:41 AM

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Artem Mikhailov, Vladislav Yu. Komarov, Denis Pishchur, Dominik Schaniel, Gennadiy Kostin. Nitrosyl linkage photoisomerization in heteroleptic fluoride ruthenium complexes derived from labile nitrate precursors. New Journal of Chemistry, Royal Society of Chemistry, 2021, 45 (18), pp.8192-8202. ⟨10.1039/D1NJ01038G⟩. ⟨hal-03401192⟩

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