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Theses

Synthèse d'aryl et de polyarylamines par catalyse au nickel pour le développement de nouveaux matériaux conducteurs

Abstract : This work describes the preparation of new nickel catalysts for C-N cross coupling reactions and the physicochemical caracterisation of new polyarylamines synthetised. In a first part, the Ni(0)/bpy catalyst was used for the synthesis of di- and triaminobenzenes from aryl chlorides. Among products prepared, 1,3,5-tris[4-aminophenyl]benzenes showed a original electrochemical behaviour and the formation by oxidation of charge transfert complexes was demonstrated. In the second part, the development of a new nickel catalyst, noted Ni(0)/SIPr in which nickel is coordinated by a N-heterocyclic carbene is described. Contrary to the Ni(0)/bpy catalyst, the Ni(0)/SIPr reagent is efficient for the arylation of all classes of amines. The synthesis of new naphthidines using the Ni(0)/SIPr catalyst, and their oxidation into stable di(radical cation) is finally reported.
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http://docnum.univ-lorraine.fr/prive/SCD_T_2003_0111_DESMARETS.pdf
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https://hal.univ-lorraine.fr/tel-01746536
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Submitted on : Thursday, March 29, 2018 - 10:39:53 AM
Last modification on : Tuesday, September 29, 2020 - 11:23:10 AM

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  • HAL Id : tel-01746536, version 1

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Christophe Desmarets. Synthèse d'aryl et de polyarylamines par catalyse au nickel pour le développement de nouveaux matériaux conducteurs. Autre. Université Henri Poincaré - Nancy 1, 2003. Français. ⟨NNT : 2003NAN10111⟩. ⟨tel-01746536⟩

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