Skip to Main content Skip to Navigation
Theses

Procédé multi-étagé de valorisation de déchets bois type panneaux de particules

Abstract : Within the environmental contexts of power generation and waste disposal, the present works deals with the validation and the optimisation of a multistage thermo chemical process of particleboard waste conversion (enhancement). These wastes are mostly associated with urea formaldehyde and melamine formaldehyde resins which contain a huge amount of nitrogen. Nitrogen causes the production of pollutants such as ammonia, isocyanic acid, cyanhydric acid and NOx... during classical thermo chemical process (combustion, pyrolysis and gasification). The process studied aims in a first time to remove nitrogen species from waste to produce a combustible solid and in a second time to convert this residual solid in a combustible gas. The first step consists in a low temperature pyrolysis (250°C to 400°C) during 3 to 15 minutes and assumes to eliminate 70 % of the initial nitrogen content for all studied conditions. The pyrolysis and/or the pyrolysis / gasification under water of the residue are then studied between 800°C and 1000°C. The higher temperature of reaction (1000°C) improves the production of gases and the energy efficiency of this second step and allow the production of hydrogen and carbon monoxide rich gases. The pyrolysis / gasification under water allows a total conversion of the solid which optimises the energy efficiency of the process. However, the pyrolysis under nitrogen produces a lower amount of gases but helps to catch a part of the nitrogen in the residual char. The char then produced is converted through an activation step, in an active char containing nitrogen functionalities with high adsorption capacities, especially for the trapping of phenol or other aromatic compounds in liquid phase. This multistage is thus a interesting way to enhance low cost raw matter like particleboard waste.
Document type :
Theses
Complete list of metadata

Cited literature [68 references]  Display  Hide  Download

https://hal.univ-lorraine.fr/tel-01748532
Contributor : Thèses Ul <>
Submitted on : Thursday, March 29, 2018 - 11:37:33 AM
Last modification on : Thursday, April 12, 2018 - 1:59:59 AM
Long-term archiving on: : Friday, September 14, 2018 - 3:15:58 AM

File

SCD_T_2008_0026_GIRODS.pdf
Files produced by the author(s)

Identifiers

  • HAL Id : tel-01748532, version 1

Citation

Pierre Girods. Procédé multi-étagé de valorisation de déchets bois type panneaux de particules. Autre. Université Henri Poincaré - Nancy 1, 2008. Français. ⟨NNT : 2008NAN10026⟩. ⟨tel-01748532⟩

Share

Metrics

Record views

403

Files downloads

1864