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Nouvelles réactions d'oxydoréduction polyphasiques en synthèse organique

Abstract : Supported reactifs present some advantages in organic synthesis : simplification of experimental procedures, use of common solvents, regeneration and reuse of support. The first goal of this work was the exploration of some new reactions using exchange resins. For classical functionel transformations or for sulfides and selenides preparations. Thus, we have realized : the hydrogenolysis of primary halides by a borohydrure resin. In the second part of this work, we extend the study of oxydatite properties of chlorite and hypochlorite salts. Thus we have found chemoselective conditions for the oxydation sulfide, sulfoxide using factorial design. We propose an previsionnal method for chemical shift determination in NMR 13C of sulfide, sulfone, sulfoxyde and selenide
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  • HAL Id : tel-01775564, version 1



Jean-Victor Weber. Nouvelles réactions d'oxydoréduction polyphasiques en synthèse organique. Chimie organique. Université Paul Verlaine - Metz, 1986. Français. ⟨NNT : 1986METZ026S⟩. ⟨tel-01775564⟩



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