Triesters non symétriques de l'acide tétrathiophosphorique : synthèse et réactivité

Abstract : Development of a general synthetic method for unsymmetrical triesters of the phosphorotetrathioic acid is described in this thesis. The method is based on the reaction of triethylammonium salts of phosphorotetrathioic diesters with electrophiles. Using the reactivity of the triethylammonium salts allows the synthesis of various functionnalized triesters as well as new polyheterocyclic (P, O, S, N) systems. Spectral data (1H, 13C and 31P NMR) for all the synthesized compounds have been determined and are discussed
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Alain Comel. Triesters non symétriques de l'acide tétrathiophosphorique : synthèse et réactivité. Autre. Université Paul Verlaine - Metz, 1992. Français. ⟨NNT : 1992METZ026S⟩. ⟨tel-01775987⟩

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