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Synthesis of bis-cellobiose and bis-glucose derivatives of azacrown macrocycles as hosts in complexes with acetylsalicylic acid and 4-acetamidophenol

Abstract : Two new C-2 symmetric bis-cellobiose and bis-glucose azacrown derivatives were prepared according to the one-step procedure using azacrown ethers and azidosaccharides. Their complexes with aspirin and paracetamol were studied with the use of proton NMR spectroscopy. It was found that these pseudo-cryptands bind aspirin and paracetamol but each one in a different manner.
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https://hal.univ-lorraine.fr/hal-01494553
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Submitted on : Thursday, March 23, 2017 - 4:19:41 PM
Last modification on : Tuesday, January 16, 2018 - 10:24:44 AM

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Michalina Pintal, Boguslaw Kryczka, Alain Marsura, Stanislaw Porwanski. Synthesis of bis-cellobiose and bis-glucose derivatives of azacrown macrocycles as hosts in complexes with acetylsalicylic acid and 4-acetamidophenol. Carbohydrate Research, Elsevier, 2014, 386, pp.18-22. ⟨10.1016/j.carres.2013.12.017⟩. ⟨hal-01494553⟩

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