Addition of selenium(II) bromide to arylalkynylamides-a route to hypervalent T-shaped 10-Se-3 systems

Abstract : A route for the generation of hypervalent T-shaped 10-Se-3 systems is described involving an interaction between in situ prepared selenium(II) bromide and an aryl alkynyl amide derivative. The existence of hypervalent selenium in both the solid and solution states has been supported by X-ray analysis and Se-77 NMR data. (C) 2015 Elsevier Ltd. All rights reserved.
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Tetrahedron Letters, Elsevier, 2015, 56 (30), pp.4554-4557
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https://hal.univ-lorraine.fr/hal-01495209
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Soumis le : vendredi 24 mars 2017 - 16:22:58
Dernière modification le : mardi 16 janvier 2018 - 10:24:44

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Edgars Paegle, Sergey Belyakov, Gilbert Kirsch, Pavel Arsenyan. Addition of selenium(II) bromide to arylalkynylamides-a route to hypervalent T-shaped 10-Se-3 systems. Tetrahedron Letters, Elsevier, 2015, 56 (30), pp.4554-4557. 〈hal-01495209〉

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