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Synthesis and physico-chemical studies of a novel layered structure with a heptanuclear Cd complex: (C9N4H28)Cd-7(H2O)(2)Cl-18 center dot nH(2)O(n=5.89)

Abstract : The inorganic-organic hybrid compound (C9N4H28)Cd-7(H2O)(2)Cl-18 center dot nH(2)O(n = 5.89) features an unusual cadmium chloride structure. The title complex adopts a layered structure consisting of double-chains and tetramers of [Cd phi(6)] (phi = Cl, O) octahedra. Crystallization water molecules and [C9H28N4](4+) tetracations are located in interstices of the successive corrugated layers. This compound has also been investigated by FT-IR and solid-state C-13, N-15 CP-MAS and 2D C-13-H NMR spectroscopies.
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https://hal.univ-lorraine.fr/hal-01521909
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Submitted on : Friday, May 12, 2017 - 2:44:10 PM
Last modification on : Friday, December 10, 2021 - 3:20:03 PM

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S. Soudani, J. -X. Mi, Frédéric Lefebvre, Christian Jelsch, C. Ben Nasr. Synthesis and physico-chemical studies of a novel layered structure with a heptanuclear Cd complex: (C9N4H28)Cd-7(H2O)(2)Cl-18 center dot nH(2)O(n=5.89). Journal of Molecular Structure, Elsevier, 2015, 1084, pp.46-54. ⟨10.1016/j.molstruc.2014.12.007⟩. ⟨hal-01521909⟩

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