A bifunctional calixarene designed for immobilisation on a natural polymer and for metal complexation

Abstract : The present work describes the multi-step synthesis of a new bifunctional calix[4]arene designed for grafting on natural polymeric materials, such as water-soluble dextrans, and for metal complexation. The podand was then anchored to the polymer by means of a cyanuric linker. The resulting material showed an interesting ability to complex copper(I), giving stable yellowish light orange solids and aqueous solutions.
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https://hal.univ-lorraine.fr/hal-02086679
Contributor : Jean-Bernard Regnouf de Vains <>
Submitted on : Monday, April 1, 2019 - 3:04:59 PM
Last modification on : Tuesday, April 2, 2019 - 2:28:39 AM

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Philippe Engrand, Jean-Bernard Regnouf-De-Vains. A bifunctional calixarene designed for immobilisation on a natural polymer and for metal complexation. Tetrahedron Letters, Elsevier, 2002, 43 (49), pp.8863-8866. ⟨10.1016/S0040-4039(02)02203-7⟩. ⟨hal-02086679⟩

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