Synthesis lead of two-dimensional sheets by spark discharge in liquid nitrogen - Université de Lorraine Accéder directement au contenu
Article Dans Une Revue Particuology Année : 2018

Synthesis lead of two-dimensional sheets by spark discharge in liquid nitrogen

Ahmad Hamdan
Cédric Noel
Jaafar Ghanbaja
Abdelkrim Redjaïmia
Thierry Belmonte

Résumé

A simple method to synthesise hexagonal lead sheets, which belong to the class of two-dimensional materials, is proposed. These objects are collected on a substrate located under two lead electrodes, between which nanosecond-pulsed spark discharges are ignited in liquid nitrogen. The hexagonal sheets are single crystals produced by gas phase condensation. Once nitrogen completely evaporates, the sheets change to PbO 2 by oxidation in air. The oxidation process induces stress that pleats the uppermost sheets or open cracks at the centre. The thickness of the individual objects typically varies from 4 to 20 nm. When the number of discharges is more than about 2000, in addition to sheets, two types of PbO 2 sticks start to form: bundles composed of nanosticks (length 5 m and diameter 50 nm) and isolated sticks (length 20 m and diameter 500 nm). These new nanostructures mainly form because of the way the discharge erodes the lead electrodes. Initially, anisotropic erosion driven by the orientation of the crystallographic planes of the lead crystals produces octahedra and nanosticks, and the nanosticks grow on the electrode surfaces as discharge proceeds. After about 2000 discharges, the nanosticks are sufficiently long that they can be easily broken, probably by mechanical stress, and they fall onto the underlying substrate.

Domaines

Plasmas Matériaux
Fichier principal
Vignette du fichier
Text Belmonte Particuology final.pdf (6.93 Mo) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)

Dates et versions

hal-02105351 , version 1 (09-05-2019)

Identifiants

Citer

Ahmad Hamdan, Hiba Kabbara, Cédric Noel, Jaafar Ghanbaja, Abdelkrim Redjaïmia, et al.. Synthesis lead of two-dimensional sheets by spark discharge in liquid nitrogen. Particuology , 2018, 40, pp.152-159. ⟨10.1016/j.partic.2017.10.012⟩. ⟨hal-02105351⟩
138 Consultations
148 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More