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Antimony-based intermetallic compounds for lithium-ion and sodium-ion batteries: synthesis, construction and application

Abstract : The development of alternative electrode materials with high energy densities and power densities for batteries has been actively pursued to satisfy the power demands for electronic devices and hybrid electric vehicles. Recently, antimony (Sb)-based intermetallic compounds have attracted considerable research interests as new candidate anode materials for high-performance lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs) due to their high theoretical capacity and suitable operating voltage. However, these intermetallic systems undergo large volume change during charge and discharge processes, which prohibits them from practical application. The rational construction of advanced anode with unique structures has been proved to be an effective approach to enhance its electrochemical performance. This review highlights the recent progress in improving and understanding the electrochemical performances of various Sb-based intermetallic compound anodes. The developments of synthesis and construction of Sb-based intermetallic compounds are systematically summarized. The electrochemical performances of various Sb-based intermetallic compound anodes are compared in its typical applications (LIBs or SIBs).
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https://hal.univ-lorraine.fr/hal-02896387
Contributor : JEAN JACQUES GAUMET Connect in order to contact the contributor
Submitted on : Friday, July 10, 2020 - 2:51:36 PM
Last modification on : Tuesday, November 29, 2022 - 12:12:15 PM

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Wen Luo, Jean-Jacques Gaumet, Li-Qiang Mai. Antimony-based intermetallic compounds for lithium-ion and sodium-ion batteries: synthesis, construction and application. Rare Metals, 2017, 36 (5), pp.321-338. ⟨10.1007/s12598-017-0899-4⟩. ⟨hal-02896387⟩

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