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Synthèse de monomères (méth)acryliques soufrés et/ou phosphorés comportant des fonctions pouvant générer des sels

Abstract : Watersoluble acrylic monomers containing sulfur and/or phosphorus have been synthesized in this thesis. Various salts-geneating functions have been introduced in the esterificant chain or in alpha position of the acrylic system. For this, simple methods have been investigated : condensation on acrylic system or transformation of groups already located in an acrylic monomer. Thus, (meth)acrylic sulphonates and sulphates have been obtained. New sulphured compounds containing acid function have been prepared and patented by Elf-Atochem. The reactivity of the acid function have also been studied. Phosphonic acid groups have been introduced in sulphurated (meth)acrylic monomers. Thio(meth)acrylic containing acid or phosphonic function have also been synthesized. Finally, the synthesis of (meth)acrylic xanthates and dithiocarbonates have been approached
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https://hal.univ-lorraine.fr/tel-01776007
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Michèle Curci. Synthèse de monomères (méth)acryliques soufrés et/ou phosphorés comportant des fonctions pouvant générer des sels. Autre. Université Paul Verlaine - Metz, 1992. Français. ⟨NNT : 1992METZ041S⟩. ⟨tel-01776007⟩

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