Synthèse et étude de la réactivité de monomères méthacryliques comportant un hétéroatome : étude de leurs propriétés optiques

Abstract : Opticals (thio)methacrylic monomers cotaining heteroatom have been synthesized in this thesis. Various heterocycles and 1,3-dithioacetals derivatives have been introduced in the esterificant chain of the methacrylic system. Refractive index and Abbe number have been measured by using an Abbe refractometer for each compound in order to establish correlation between chemical structur and optical properties. In the third part of this thesis, the reactivity of methacrylic monomers containing sulfur have been studied. We have considered the dethioacetalization of 1,3-dithioacetal acrylic monomers as an entry to a new type of functionalized acrylic monomers. Pummerer reaction has also been studied
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Florence Caye. Synthèse et étude de la réactivité de monomères méthacryliques comportant un hétéroatome : étude de leurs propriétés optiques. Autre. Université Paul Verlaine - Metz, 1997. Français. ⟨NNT : 1997METZ060S⟩. ⟨tel-01777237⟩

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